US290655A - Chaeles l - Google Patents
Chaeles l Download PDFInfo
- Publication number
- US290655A US290655A US290655DA US290655A US 290655 A US290655 A US 290655A US 290655D A US290655D A US 290655DA US 290655 A US290655 A US 290655A
- Authority
- US
- United States
- Prior art keywords
- water
- paper
- ammonia
- albumen
- cubic centimeters
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- YGSDEFSMJLZEOE-UHFFFAOYSA-N Salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 20
- 239000000203 mixture Substances 0.000 description 12
- 229960004889 salicylic acid Drugs 0.000 description 12
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 10
- PEDCQBHIVMGVHV-UHFFFAOYSA-N glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 10
- 235000011187 glycerol Nutrition 0.000 description 10
- 238000000034 method Methods 0.000 description 10
- 229910052788 barium Inorganic materials 0.000 description 8
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium(0) Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 8
- VEXZGXHMUGYJMC-UHFFFAOYSA-M chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 8
- 239000003086 colorant Substances 0.000 description 8
- QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 6
- VHUUQVKOLVNVRT-UHFFFAOYSA-N ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 6
- 235000011114 ammonium hydroxide Nutrition 0.000 description 6
- 238000004040 coloring Methods 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- 230000001264 neutralization Effects 0.000 description 6
- GRYLNZFGIOXLOG-UHFFFAOYSA-N nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 6
- QAOWNCQODCNURD-UHFFFAOYSA-L sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 6
- SQGYOTSLMSWVJD-UHFFFAOYSA-N Silver nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 239000004615 ingredient Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 229910052709 silver Inorganic materials 0.000 description 4
- 239000004332 silver Substances 0.000 description 4
- KEAYESYHFKHZAL-UHFFFAOYSA-N sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 4
- 229910052708 sodium Inorganic materials 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- 230000002745 absorbent Effects 0.000 description 2
- 239000002250 absorbent Substances 0.000 description 2
- 230000015271 coagulation Effects 0.000 description 2
- 238000005345 coagulation Methods 0.000 description 2
- GRWZHXKQBITJKP-UHFFFAOYSA-L dithionite(2-) Chemical compound [O-]S(=O)S([O-])=O GRWZHXKQBITJKP-UHFFFAOYSA-L 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- -1 glyccrine Chemical compound 0.000 description 2
- 101700052348 neg-1 Proteins 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 230000001235 sensitizing Effects 0.000 description 2
- 231100000202 sensitizing Toxicity 0.000 description 2
- 238000006467 substitution reaction Methods 0.000 description 2
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C7/00—Multicolour photographic processes or agents therefor; Regeneration of such processing agents; Photosensitive materials for multicolour processes
- G03C7/26—Silver halide emulsions for subtractive colour processes
Definitions
- the object of this invention is to produce colored photographic pictures in which the natural colors of the objects from which the negatives are taken will be rendered in conjunction with the impression taken from the negative, and in which the delicate gradations of light and shade in the photograph will not be obscured.
- the invention consists in applying to photographic paper in a raw state an even coating of a mixture of egg-albumen, neutral sulphate of barium, chloride of ammonia, salicylic acid, and glycerine; then floating the coated paper, when dry, on a bath of nitrate of silver and water; then exposing the paper under a negative; then fixing the impression in a bath of water, hyposulphite of sodium, and concentrated ammonia; then applying the colors in a mixture of albumen, salicylic acid, glycerine, aqua'ammonia, and water, and then passing the colored print through a bath of alcohol, water, and nitric acid, as will be here inafter fully described.
- ingrein a bath prepared of the following ingredients: To one hundred and sixty cubic centimeters of water are added fifteen cubic centimeters of concentrated ammonia, for the purpose of again softening and making absorbent the albumen used in the preparation of the paper, and which was coagulated by the action of the silver in sensitizing the said paper; or the print may be fixed in a fixing-bath to which the ammonia has been added, prepared as follows: To one hundred and sixty cubic centimeters of water are added thirty grams of hydrosulphite of sodium and fifteen cubic centimeters of concentrated aqua-ammonia.
- the barium is used for the purpose of keeping, by its opacity, the print on the surface of the paper, and also for holding thefree nitrate of silver, or that remaining in excess of the quantity used to convert the chloride of ammonium into chloride and subohloride of silver until the impression by light is formed,
- the vehicle used to distribute the color is composed of the following ingredients, viz: Thirty cubic centimeters of albumen, ten decigrams of salicylic acid, ten cubic centimeters of glycerine, one cubic centimeter of aqua-ammonia, and a sufficient quantity of water to cause the mixture to work well.
- the colors are applied with a brush, and when the coloring is finished the prints are passed through a bath formed of four cubic centimeters of alcohol, from ten to twelve cubic centimeters of water, and one cubic centimeter of nitric acid, to set the color by the coagulation of the albumen in the vehicle.
- the pictures are now ready to mount, but to further proteet them they may be varnished, glazed, or burnished by the ordinary methods.
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Coloring Foods And Improving Nutritive Qualities (AREA)
Description
dients are beaten to a froth and allowed to Miran TATES PATENT- OFFICE.
CHARLES L. WRIGHT,
or NEW YORK, n. Y.
SPECIFICATION forming partof Letters Patent No. 290,655, dated December 18, 1883.
Application filed Apl'illB, 1883. (No specimens.)
To all, whom it may concern Be it known that I, CHARLES L. WRIGHT, of the city, county, and State of New York, have invented a new and useful Improvement in the Process of Coloring Photographs, of which the following is a full, clear, and exact description.
The object of this invention is to produce colored photographic pictures in which the natural colors of the objects from which the negatives are taken will be rendered in conjunction with the impression taken from the negative, and in which the delicate gradations of light and shade in the photograph will not be obscured.
The invention consists in applying to photographic paper in a raw state an even coating of a mixture of egg-albumen, neutral sulphate of barium, chloride of ammonia, salicylic acid, and glycerine; then floating the coated paper, when dry, on a bath of nitrate of silver and water; then exposing the paper under a negative; then fixing the impression in a bath of water, hyposulphite of sodium, and concentrated ammonia; then applying the colors in a mixture of albumen, salicylic acid, glycerine, aqua'ammonia, and water, and then passing the colored print through a bath of alcohol, water, and nitric acid, as will be here inafter fully described.
In carrying my improvement into practical effect, I take good photographic paper, in a raw or unprepared state, and with a soft flat brush apply an even coating of a mixture prepared as follows: To thirty grams of eggalbumen are added ten grams of neutral sulphate of barium, one gram ofchloride of ammonium, five decigrams of salicylic acid, and four grams of glycerine. These ingrein a bath prepared of the following ingredients: To one hundred and sixty cubic centimeters of water are added fifteen cubic centimeters of concentrated ammonia, for the purpose of again softening and making absorbent the albumen used in the preparation of the paper, and which was coagulated by the action of the silver in sensitizing the said paper; or the print may be fixed in a fixing-bath to which the ammonia has been added, prepared as follows: To one hundred and sixty cubic centimeters of water are added thirty grams of hydrosulphite of sodium and fifteen cubic centimeters of concentrated aqua-ammonia. The barium is used for the purpose of keeping, by its opacity, the print on the surface of the paper, and also for holding thefree nitrate of silver, or that remaining in excess of the quantity used to convert the chloride of ammonium into chloride and subohloride of silver until the impression by light is formed,
and also for so subdividing the film of albucausing the photograph and color to appear in conjunction. The vehicle used to distribute the color is composed of the following ingredients, viz: Thirty cubic centimeters of albumen, ten decigrams of salicylic acid, ten cubic centimeters of glycerine, one cubic centimeter of aqua-ammonia, and a sufficient quantity of water to cause the mixture to work well. The colors are applied with a brush, and when the coloring is finished the prints are passed through a bath formed of four cubic centimeters of alcohol, from ten to twelve cubic centimeters of water, and one cubic centimeter of nitric acid, to set the color by the coagulation of the albumen in the vehicle. The pictures are now ready to mount, but to further proteet them they may be varnished, glazed, or burnished by the ordinary methods.
I do not wish to limit myself to the details of the above-described process, as it is evident that substantially the same efi'ect might be produced by changing the proportions of the materials used, or by the substitution therefor of other equivalent materials, which need not be specifically mentioned.
Having thus fully described my invention, I claim as new and desire to secure by Letters Patent- 4 which consists in applying to photographic 1. The process of making colored photographs, substantially as herein described,
2. The process of preparing photographic paper to receive the impression from the neg- 1 ative, substantially as herein described,which consists in applying to'the paper an even coat- 2o ing of a mixture of egg-albumen, neutral sulphate of barium, chloride of ammonium, salicylic acid, and glycerine, in or about the proportions as set forth.
3. The process of coloring photographic 25 prints, which consists in applying the colors in a mixture of albumen, salicylic acid, glyccrine, aqua-ammonia, and Water, and then passing the colored prints through a setting bath of alcohol, Water, and nitric acid, in or 30 about the proportions as set forth. W
' CHARLES L. \VRIGHT.
lVitn esses:
J AMES T. GRAHAM, O. SEDGWICK.
Publications (1)
Publication Number | Publication Date |
---|---|
US290655A true US290655A (en) | 1883-12-18 |
Family
ID=2359843
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US290655D Expired - Lifetime US290655A (en) | Chaeles l |
Country Status (1)
Country | Link |
---|---|
US (1) | US290655A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2973262A (en) * | 1956-06-22 | 1961-02-28 | Gevaert Photo Prod Nv | Light-sensitive photographic paper |
-
0
- US US290655D patent/US290655A/en not_active Expired - Lifetime
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2973262A (en) * | 1956-06-22 | 1961-02-28 | Gevaert Photo Prod Nv | Light-sensitive photographic paper |
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