US2804651A - Methods of providing reclaimed rubber - Google Patents

Methods of providing reclaimed rubber Download PDF

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US2804651A
US2804651A US39090753A US2804651A US 2804651 A US2804651 A US 2804651A US 39090753 A US39090753 A US 39090753A US 2804651 A US2804651 A US 2804651A
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rubber
methods
reclaimed rubber
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providing
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Chester H Peterson
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U S Rubber Reclaiming Co Inc
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U S Rubber Reclaiming Co Inc
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B17/00Recovery of plastics or other constituents of waste material containing plastics
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2021/00Use of unspecified rubbers as moulding material
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/62Plastics recycling; Rubber recycling

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  • This invention relates to methods for providing reclaimed rubber. In particular, it is directed to economical and effective methods adapted for the production of an improved reclaimed rubber product. To this end, the invention contemplates the provision of a method wherein the reclaim is extruded at a relatively low temperature and under relatively low pressure after the completion of the reclaiming operation. This is both more effective and more economical than a refining operation (e. g., by forming into a thin sheet between rolls) and sometimes than several sheeting operations; but it can be combined with a sheeting operation to provide an especially useful product.
  • a refining operation e. g., by forming into a thin sheet between rolls
  • the invention accordingly comprises the several steps and the relation and order of one or more of such steps with respect to each of the others, as exemplified in the following detailed disclosure, and the scope of the application of which will be indicated in the claims.
  • Figure 1 is a diagrammatic showing of one form of the invention
  • Fig. 2 is a vertical sectional view of the discharge end of the plasticator
  • Fig. 3 is a front view thereof.
  • Fig. 4 is a diagrammatic showing of a modification.
  • vulcanized rubber crumb is mixed with reclaiming agents at and passed into and subjected to a plasticizing reclaiming operation as by being passed thru a screw plasticator at 12 where it is reclaimed.
  • the plasticator may be one of the types exemplified in the Elgin et a1.
  • An outlet head portion as exemplified in Figs. 2 and 3 hereof, provides a clear, open 2 channel which is free of internal obstructions and whence the reclaim will issue in strip (s1ab or sheet) form.
  • the head comprises a half-inch plate 15 which is reduced to A" at aninner circular portion 18 which has a diameter of 2%" and the central portion of which is formedwith a tapering portion ending in an opening 19 which is 0.65" in height and 1.9" in horizontal extent.
  • a nose 20 which in the present instance is 4" in length and provides a channel 21 which conforms to the opening 19 and then tapers in the thickness dimension to 0.05" and expands in width to 2.5 to provide an opening 22.
  • the nose 20 is held in place by cooperating shoulders 23 and 24 on the nose and on a plate 25 which lies against and is secured to the plate 15. Pressures of over 800 p. s. i., and desirably 900 to 2500 p. s. i., are developed therein, and temperatures from 325 F. to 500 F.
  • the reclaimed material passes, as on a conveyor 27, thru a zone 28 wherein it is cooled, as by the surrounding atmosphere, and then is subjected to an extrusion step, as by being passed thru an extruder at 30, whence it issues in condition to be stored or to be shipped as indicated at 32.
  • the extruder in the present instance is a screw of the extruder type shown on page 261 of Extrusion of Plastics, Rubber, and Metals, by Simmons, Weith and Schack (Reinhold), but is watercooled rather than heated. Temperatures in the extruder run about 250 F. and may run from to 275 F.
  • the product has higher tensile strength and 300% modulus, and a higher Mooney than reclaims subjected to the usual refining operations, as well as improved working and handling properties.
  • a stock treated as above had a tensile of 1665 lbs. as compared with 1560 lbs. for a similar stock treated similarly except that, after reclaiming, it was sheeted instead of extruded; a 300% modulus of 755 as compared with 610, and a Mooney (ML/2l2/1-5) of thirty as compared with twenty-five.
  • An average of random runs of truck and bus tire reclaim showed a decrease of twelve Mooney units (ML/ 212/ 1-5 during extruding, whereas a greater average decrease-fifteen Mooney unitstook place during refining in random runs of truck and bus tire reclaim.
  • the average decrease during extruding in random runs of passenger tire reclaim was six Mooney units as against sixteen Mooney units during refining in random runs.
  • reclaim from the plasticating step 12 may be subjected to a sheeting step as by a sheeter at 40 prior to the extrusion step at 30 and the shipping step at 32.

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  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Extrusion Moulding Of Plastics Or The Like (AREA)

Description

p 1957 c. H. PETERSON 2,304,651
METHODS OF PROVIDING RECLAIMED RUBBER Filed Nov. 9, 1953 2 Sheets-Sheet l M/mva .90 .32 12 I I IOLAST/C/Z/NG flTPUD/NG SHIPPING Thqll.
BY ATTOl I Filed Nov. 9, 1953 Sept. 3, 1957' c. H. PETERSON METHODS OF PROVIDING RECLAIMEID RUBBER INVENTORZ ATTORNE United States Patent O fiiice Patented Sept. 3, 1957 IVIETHODS OF PROVIDING RECLAIMED RUBBER Chester H. Peterson, Eggertsville, N. Y., assignor to U. S. Rubber Reclaiming Co. Inc., Bulfalo, N. Y.
Application November 9, 1953, Serial No. 390,907
Claims. (CI. 18-48) This invention relates to methods for providing reclaimed rubber. In particular, it is directed to economical and effective methods adapted for the production of an improved reclaimed rubber product. To this end, the invention contemplates the provision of a method wherein the reclaim is extruded at a relatively low temperature and under relatively low pressure after the completion of the reclaiming operation. This is both more effective and more economical than a refining operation (e. g., by forming into a thin sheet between rolls) and sometimes than several sheeting operations; but it can be combined with a sheeting operation to provide an especially useful product.
The invention accordingly comprises the several steps and the relation and order of one or more of such steps with respect to each of the others, as exemplified in the following detailed disclosure, and the scope of the application of which will be indicated in the claims.
For a fuller understanding of the nature and objects of the invention, reference should be had to the following detailed description taken in connection with the accompanying drawings, in which:
' Figure 1 is a diagrammatic showing of one form of the invention;
Fig. 2 is a vertical sectional view of the discharge end of the plasticator;
Fig. 3 is a front view thereof; and
Fig. 4 is a diagrammatic showing of a modification.
In the embodiment of the invention exemplified in Fig. l, vulcanized rubber crumb is mixed with reclaiming agents at and passed into and subjected to a plasticizing reclaiming operation as by being passed thru a screw plasticator at 12 where it is reclaimed. The plasticator may be one of the types exemplified in the Elgin et a1. Patent 2,653,348. An outlet head portion, as exemplified in Figs. 2 and 3 hereof, provides a clear, open 2 channel which is free of internal obstructions and whence the reclaim will issue in strip (s1ab or sheet) form.
As exemplified, the head comprises a half-inch plate 15 which is reduced to A" at aninner circular portion 18 which has a diameter of 2%" and the central portion of which is formedwith a tapering portion ending in an opening 19 which is 0.65" in height and 1.9" in horizontal extent. Beyond this opening is a nose 20 which in the present instance is 4" in length and provides a channel 21 which conforms to the opening 19 and then tapers in the thickness dimension to 0.05" and expands in width to 2.5 to provide an opening 22. The nose 20 is held in place by cooperating shoulders 23 and 24 on the nose and on a plate 25 which lies against and is secured to the plate 15. Pressures of over 800 p. s. i., and desirably 900 to 2500 p. s. i., are developed therein, and temperatures from 325 F. to 500 F.
From the opening 22, the reclaimed material passes, as on a conveyor 27, thru a zone 28 wherein it is cooled, as by the surrounding atmosphere, and then is subjected to an extrusion step, as by being passed thru an extruder at 30, whence it issues in condition to be stored or to be shipped as indicated at 32. The extruder in the present instance is a screw of the extruder type shown on page 261 of Extrusion of Plastics, Rubber, and Metals, by Simmons, Weith and Schack (Reinhold), but is watercooled rather than heated. Temperatures in the extruder run about 250 F. and may run from to 275 F.
The product has higher tensile strength and 300% modulus, and a higher Mooney than reclaims subjected to the usual refining operations, as well as improved working and handling properties. A stock treated as above had a tensile of 1665 lbs. as compared with 1560 lbs. for a similar stock treated similarly except that, after reclaiming, it was sheeted instead of extruded; a 300% modulus of 755 as compared with 610, and a Mooney (ML/2l2/1-5) of thirty as compared with twenty-five.
An average of random runs of truck and bus tire reclaim showed a decrease of twelve Mooney units (ML/ 212/ 1-5 during extruding, whereas a greater average decrease-fifteen Mooney unitstook place during refining in random runs of truck and bus tire reclaim. The average decrease during extruding in random runs of passenger tire reclaim was six Mooney units as against sixteen Mooney units during refining in random runs.
It is possible, moreover, in accordance with the present invention, to obtain the advantages of the extrusion operation by subjecting thereto sheeted stock. As shown in Fig. 4, reclaim from the plasticating step 12 may be subjected to a sheeting step as by a sheeter at 40 prior to the extrusion step at 30 and the shipping step at 32.
While there are given above certain specific examples of this invention and its application in practical use and also certain modifications and alternatives, it should be understood that these are not intended to be exhaustive or to be limiting of the invention. On the contrary, these illustrations and the explanations herein are given in order to acquaint others skilled in the art with this invention and the principles thereof and a suitable manner of its application in practical use, so that others skilled in the art may be enabled to modify the invention and to adapt it and apply it in numerous forms, each as may be bested suited to the requirement of a particular use.
I claim:
1. The process of providing reclaimed rubber of improved tensile strength, viscosity, and modulus, which comprises working comminuted vulcanized rubber while progressively forcing it forward thru an elongated chamber and out of a restricted orifice in a hot plastic condition and in a continuous mass, conducting the mass thru the atmosphere to cool the mass and delivering it to a second elongated chamber, forcing it thru the second chamber while working it, and extruding it from the second chamber thru a restricted orifice.
2. A process as in claim 1 wherein the rubber is extruded from both chambers in continuous strip form.
3. A process as in claim 1 wherein the rubber is conducted upwardly from the first-mentioned chamber to said second chamber on a conveyor.
4. A process as in claim 1 wherein the rubber is con ducted over and between rolls from the first-mentioned chamber to said second chamber.
5. A process as in claim 1 wherein the rubber is forced thru said chambers by screws and wherein the pressure generated in the first-mentioned chamber is over 800 pounds per square inch.
References Cited in the file of this patent UNITED STATES PATENTS 1,680,171 Hollenbeck Aug. 7, 1928 (Other references on following page) 3 4 UNITED STATES PATENTS 2,595,210 Clinefelter Apr. 29, 1952 1,908,564 Slusser May 9, 1933 25151205 Gray 1952 2,286,966 Johnson June 16, 1942 OTHER REFERENCES 2,471,392' Campbell May 24, 1944 5 How to Slash Devulcamzatlon Tlme, Chem1ca1 En- 2371722 Wanderer 1945 gineering, pp. 192 and 194, July 1951.
2,499,913 Gordon Mar. 7, 1950 4 vii
US39090753 1953-11-09 1953-11-09 Methods of providing reclaimed rubber Expired - Lifetime US2804651A (en)

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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3030665A (en) * 1958-03-05 1962-04-24 Eagleton Sidney Douglas Refining thermoplastic resins
US3236928A (en) * 1961-07-10 1966-02-22 Leyman Corp Method of producing curved radially aligned matrix bonded fine particle permanent magnets
US3790326A (en) * 1971-11-26 1974-02-05 Conwed Corp Extrusion apparatus
US4146508A (en) * 1975-05-29 1979-03-27 U.S. Rubber Reclaiming Co., Inc. Process of reclaiming rubber and refining reclaimed rubber
US4161464A (en) * 1978-03-24 1979-07-17 The B. F. Goodrich Company Devulcanized rubber composition and process for preparing same
US4264481A (en) * 1978-07-03 1981-04-28 Trelleborg Ab Process of reclaiming rubber
US4469817A (en) * 1981-11-19 1984-09-04 Toyoda Gosei Co., Ltd. Method for reclamation of vulcanized rubber
US4577971A (en) * 1983-01-12 1986-03-25 Burcham George R Blending rubber for retreading
US5415823A (en) * 1993-03-24 1995-05-16 Julius Peter Method and apparatus for manufacturing rubber mixtures

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1680171A (en) * 1923-09-22 1928-08-07 Oscar D Hollenbeck Apparatus for use in rubber factories
US1908564A (en) * 1930-04-12 1933-05-09 Goodyear Tire & Rubber Apparatus for removing and conveying plastic material from mills
US2286966A (en) * 1939-06-03 1942-06-16 Farrel Birmingham Co Inc Method of refining rubber
US2371722A (en) * 1940-10-24 1945-03-20 Du Pont Process for washing and drying coagula of rubber and similar materials
US2471392A (en) * 1946-09-25 1949-05-24 Campbell Charles Herbert Refining reclaimed rubber with cooling of the rubber to facilitate separation of tailings
US2499913A (en) * 1945-11-09 1950-03-07 Farrel Birmingham Co Inc Machine for treating rubber
US2595210A (en) * 1949-06-11 1952-04-29 James C Clinefelter Machine for feeding, working, and mixing plastic material
US2615205A (en) * 1949-05-13 1952-10-28 Western Electric Co Method of processing vulcanizable elastomer compounds

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1680171A (en) * 1923-09-22 1928-08-07 Oscar D Hollenbeck Apparatus for use in rubber factories
US1908564A (en) * 1930-04-12 1933-05-09 Goodyear Tire & Rubber Apparatus for removing and conveying plastic material from mills
US2286966A (en) * 1939-06-03 1942-06-16 Farrel Birmingham Co Inc Method of refining rubber
US2371722A (en) * 1940-10-24 1945-03-20 Du Pont Process for washing and drying coagula of rubber and similar materials
US2499913A (en) * 1945-11-09 1950-03-07 Farrel Birmingham Co Inc Machine for treating rubber
US2471392A (en) * 1946-09-25 1949-05-24 Campbell Charles Herbert Refining reclaimed rubber with cooling of the rubber to facilitate separation of tailings
US2615205A (en) * 1949-05-13 1952-10-28 Western Electric Co Method of processing vulcanizable elastomer compounds
US2595210A (en) * 1949-06-11 1952-04-29 James C Clinefelter Machine for feeding, working, and mixing plastic material

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3030665A (en) * 1958-03-05 1962-04-24 Eagleton Sidney Douglas Refining thermoplastic resins
US3236928A (en) * 1961-07-10 1966-02-22 Leyman Corp Method of producing curved radially aligned matrix bonded fine particle permanent magnets
US3790326A (en) * 1971-11-26 1974-02-05 Conwed Corp Extrusion apparatus
US4146508A (en) * 1975-05-29 1979-03-27 U.S. Rubber Reclaiming Co., Inc. Process of reclaiming rubber and refining reclaimed rubber
US4161464A (en) * 1978-03-24 1979-07-17 The B. F. Goodrich Company Devulcanized rubber composition and process for preparing same
US4264481A (en) * 1978-07-03 1981-04-28 Trelleborg Ab Process of reclaiming rubber
US4469817A (en) * 1981-11-19 1984-09-04 Toyoda Gosei Co., Ltd. Method for reclamation of vulcanized rubber
US4577971A (en) * 1983-01-12 1986-03-25 Burcham George R Blending rubber for retreading
US5415823A (en) * 1993-03-24 1995-05-16 Julius Peter Method and apparatus for manufacturing rubber mixtures

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