US2772136A - Dyeing of textile materials using - Google Patents
Dyeing of textile materials using Download PDFInfo
- Publication number
- US2772136A US2772136A US2772136DA US2772136A US 2772136 A US2772136 A US 2772136A US 2772136D A US2772136D A US 2772136DA US 2772136 A US2772136 A US 2772136A
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- Prior art keywords
- bath
- molten metal
- fabric
- dye
- metal
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- Expired - Lifetime
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- 239000000463 material Substances 0.000 title claims description 40
- 238000004043 dyeing Methods 0.000 title claims description 20
- 239000004753 textile Substances 0.000 title claims description 18
- 239000000975 dye Substances 0.000 claims description 70
- 239000007800 oxidant agent Substances 0.000 claims description 38
- YZHUMGUJCQRKBT-UHFFFAOYSA-M Sodium chlorate Chemical compound [Na+].[O-]Cl(=O)=O YZHUMGUJCQRKBT-UHFFFAOYSA-M 0.000 claims description 8
- 230000001264 neutralization Effects 0.000 claims description 8
- 239000003638 reducing agent Substances 0.000 claims description 8
- 229940080281 sodium chlorate Drugs 0.000 claims description 8
- 230000001590 oxidative Effects 0.000 claims description 6
- 230000002411 adverse Effects 0.000 claims description 4
- 229910052751 metal Inorganic materials 0.000 description 50
- 239000002184 metal Substances 0.000 description 50
- 239000004744 fabric Substances 0.000 description 40
- 238000000034 method Methods 0.000 description 32
- QTBSBXVTEAMEQO-UHFFFAOYSA-N acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 18
- 210000002268 Wool Anatomy 0.000 description 14
- LPXPTNMVRIOKMN-UHFFFAOYSA-M Sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 description 12
- 229920000297 Rayon Polymers 0.000 description 10
- 239000000980 acid dye Substances 0.000 description 8
- 229910045601 alloy Inorganic materials 0.000 description 8
- 239000000956 alloy Substances 0.000 description 8
- AQHHHDLHHXJYJD-UHFFFAOYSA-N Proprasylyt Chemical compound C1=CC=C2C(OCC(O)CNC(C)C)=CC=CC2=C1 AQHHHDLHHXJYJD-UHFFFAOYSA-N 0.000 description 6
- REDXJYDRNCIFBQ-UHFFFAOYSA-N aluminium(3+) Chemical class [Al+3] REDXJYDRNCIFBQ-UHFFFAOYSA-N 0.000 description 6
- BDAGIHXWWSANSR-UHFFFAOYSA-N formic acid Chemical compound OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 6
- 238000007654 immersion Methods 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- 230000001603 reducing Effects 0.000 description 6
- 235000010288 sodium nitrite Nutrition 0.000 description 6
- VOBHRQFELWTZFS-AWLRYRRCSA-K trisodium;(4Z)-3-oxo-4-[(4-sulfonatonaphthalen-1-yl)hydrazinylidene]naphthalene-2,7-disulfonate Chemical compound [Na+].[Na+].[Na+].C1=CC=C2C(N/N=C3/C4=CC=C(C=C4C=C(C3=O)S(=O)(=O)[O-])S([O-])(=O)=O)=CC=C(S([O-])(=O)=O)C2=C1 VOBHRQFELWTZFS-AWLRYRRCSA-K 0.000 description 6
- AQXYVFBSOOBBQV-UHFFFAOYSA-N 1-amino-4-hydroxyanthracene-9,10-dione Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C(O)=CC=C2N AQXYVFBSOOBBQV-UHFFFAOYSA-N 0.000 description 4
- LZCLXQDLBQLTDK-UHFFFAOYSA-N Ethyl lactate Chemical compound CCOC(=O)C(C)O LZCLXQDLBQLTDK-UHFFFAOYSA-N 0.000 description 4
- 239000004677 Nylon Substances 0.000 description 4
- IHIXIJGXTJIKRB-UHFFFAOYSA-N Sodium orthovanadate Chemical compound [Na+].[Na+].[Na+].[O-][V]([O-])([O-])=O IHIXIJGXTJIKRB-UHFFFAOYSA-N 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-M acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 4
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 4
- 229910052797 bismuth Inorganic materials 0.000 description 4
- 229940116333 ethyl lactate Drugs 0.000 description 4
- 229920001778 nylon Polymers 0.000 description 4
- 159000000000 sodium salts Chemical class 0.000 description 4
- LJRGBERXYNQPJI-UHFFFAOYSA-M sodium;3-nitrobenzenesulfonate Chemical compound [Na+].[O-][N+](=O)C1=CC=CC(S([O-])(=O)=O)=C1 LJRGBERXYNQPJI-UHFFFAOYSA-M 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 229910052718 tin Inorganic materials 0.000 description 4
- ATJFFYVFTNAWJD-UHFFFAOYSA-N tin hydride Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 4
- 239000000080 wetting agent Substances 0.000 description 4
- QOSTVEDABRQTSU-UHFFFAOYSA-N 1,4-bis(methylamino)anthracene-9,10-dione Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C(NC)=CC=C2NC QOSTVEDABRQTSU-UHFFFAOYSA-N 0.000 description 2
- WHPNHQRWWMLKPJ-UHFFFAOYSA-N 1,4-dihydroxy-5,8-bis(2-hydroxyethylamino)anthracene-9,10-dione Chemical compound O=C1C2=C(O)C=CC(O)=C2C(=O)C2=C1C(NCCO)=CC=C2NCCO WHPNHQRWWMLKPJ-UHFFFAOYSA-N 0.000 description 2
- HWTDMFJYBAURQR-UHFFFAOYSA-M 2-nitrobenzenesulfonate Chemical compound [O-][N+](=O)C1=CC=CC=C1S([O-])(=O)=O HWTDMFJYBAURQR-UHFFFAOYSA-M 0.000 description 2
- NZZZRQWFPSONCU-UHFFFAOYSA-N 4-(nitromethyl)benzenesulfonic acid Chemical compound OS(=O)(=O)C1=CC=C(C[N+]([O-])=O)C=C1 NZZZRQWFPSONCU-UHFFFAOYSA-N 0.000 description 2
- 229920002456 HOTAIR Polymers 0.000 description 2
- FDZZZRQASAIRJF-UHFFFAOYSA-M Malachite green Chemical compound [Cl-].C1=CC(N(C)C)=CC=C1C(C=1C=CC=CC=1)=C1C=CC(=[N+](C)C)C=C1 FDZZZRQASAIRJF-UHFFFAOYSA-M 0.000 description 2
- -1 Woods metal Chemical class 0.000 description 2
- AKEKMOCAZDVZMG-UHFFFAOYSA-M [N+](=O)([O-])CC1=CC=C(C=C1)S(=O)(=O)[O-].[Na+] Chemical group [N+](=O)([O-])CC1=CC=C(C=C1)S(=O)(=O)[O-].[Na+] AKEKMOCAZDVZMG-UHFFFAOYSA-M 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 238000004061 bleaching Methods 0.000 description 2
- 239000007844 bleaching agent Substances 0.000 description 2
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 2
- 229910052793 cadmium Inorganic materials 0.000 description 2
- BIXZHMJUSMUDOQ-UHFFFAOYSA-N dichloran Chemical compound NC1=C(Cl)C=C([N+]([O-])=O)C=C1Cl BIXZHMJUSMUDOQ-UHFFFAOYSA-N 0.000 description 2
- UHXQPQCJDDSMCB-UHFFFAOYSA-L disodium;3-[[9,10-dioxo-4-(2,4,6-trimethyl-3-sulfonatoanilino)anthracen-1-yl]amino]-2,4,6-trimethylbenzenesulfonate Chemical compound [Na+].[Na+].CC1=CC(C)=C(S([O-])(=O)=O)C(C)=C1NC(C=1C(=O)C2=CC=CC=C2C(=O)C=11)=CC=C1NC1=C(C)C=C(C)C(S([O-])(=O)=O)=C1C UHXQPQCJDDSMCB-UHFFFAOYSA-L 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 235000019253 formic acid Nutrition 0.000 description 2
- 238000005470 impregnation Methods 0.000 description 2
- 229910001092 metal group alloy Inorganic materials 0.000 description 2
- 239000000344 soap Substances 0.000 description 2
- KEAYESYHFKHZAL-UHFFFAOYSA-N sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- GTKIEPUIFBBXJQ-UHFFFAOYSA-M sodium;2-[(4-hydroxy-9,10-dioxoanthracen-1-yl)amino]-5-methylbenzenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C1=CC(C)=CC=C1NC1=CC=C(O)C2=C1C(=O)C1=CC=CC=C1C2=O GTKIEPUIFBBXJQ-UHFFFAOYSA-M 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 229910000634 wood's metal Inorganic materials 0.000 description 2
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
- D06B1/00—Applying liquids, gases or vapours onto textile materials to effect treatment, e.g. washing, dyeing, bleaching, sizing or impregnating
- D06B1/04—Applying liquids, gases or vapours onto textile materials to effect treatment, e.g. washing, dyeing, bleaching, sizing or impregnating by pouring or allowing to flow on to the surface of the textile material
- D06B1/06—Applying liquids, gases or vapours onto textile materials to effect treatment, e.g. washing, dyeing, bleaching, sizing or impregnating by pouring or allowing to flow on to the surface of the textile material flowing along an inclined surface
Definitions
- This invention relates to a process of dyeing textile materials in which the material after application of the dye thereto is passed through a bath of molten metal.
- British patent specification No. 620,584 describes such a process which may use an alloy such as Woods metal, and in which the dye liquor may fioat on the surface of the molten metal; alternatively the dye liquor may be padded on to the material before entering the molten metal.
- a process of dyeing textile materials with dyestuffs as aforesaid, in which the material after application of an aqueous dye liquor thereto is passed through a bath of molten metal, characterised by the fact that the material prior to entering the molten metal is treated with a mild oxidising agent which tends to counteract the reducing action of the molten metal.
- oxidising agent is added to the aqueous dye liquor, but it may be applied in any convenient manner to the material, e. g., by padding or spraying.
- the oxidising agent may be, for example, the sodium salt of rn-nitrobenzene sulphonic acid and the sodium salt of nitro-toluene-p-sulphonic acid.
- the mildness of the oxidising agent is limited on the one hand by the desirability that it should not be strong enough to destroy the dyestufi (by bleaching) or to oxidizev rapidly the molten metal or its alloy components.
- Cadmium 10 and has temperature 100 C. Dry scoured woolen fabric is preheated by passing over steam heated cylinders so that it enters the dye with a temperature of 90 C. The fabric speed is 20 yards per minute giving immersion times of 0.67 second for the dye liquor and 10 seconds for the molten metal. The fabric leaves the metal through a wash liquor floating on the exit surface and this aqueous bath (temperature 90 C.) contains 1% of commercial acetic acid. The fabric is finally rinsed and dried and is coloured purple.
- the dye liquor described is made up, stored and pumped to the surface of the molten metal at 80 C. the metal temperature being 95 C. Dry scoured acetate rayon fabric and nylon fabric is preheated by passing through a hot air chamber so that it enters the dye with a temperature of 80 C. The fabric speed is 30 yards per minute giving immersion times of 0.44 second for the dye and 6.7 seconds for the metal. The fabric leaves the metal through hot water (temperature C.) floating on the exit surface of the metal and is finally rinsed and dried. It is coloured red.
- Example 3 Dyeing of wool fabric with acid dyes 5 grms./litre Lissamine Fast Violet 2B8 (imperial Chemical Industries) 10 grms. per litre Teepol X (wetting agent) 10 grms. per litre ethyl lactate 5 grms. per litre sodium nitrite.
- This dye liquor is pumped to the surface of the molten metal bath at 98 C.
- the metal alloy has the composition:
- Dry, scoured woolen fabric is preheated by passing over steam-heated cylinders so that it enters the dye with a temperature of 98 C.
- the time of immersion in the molten metal is 15 seconds and the fabric leaves the metal by way of an exit floating liquor containing 1% of 80% acetic acid and at a temperature of 98 C.
- the fabric is further treated in continuous manner in 5 grms. per litre acetic acid (80%) for two minutes, then rinsed and dried to give a bright violet coloured fabric.
- Example 4 Dyeing of wool fabric with acid dyes Scoured wool serge fabric is impregnated in a twobowl padding mangle with a liquor containing 10 grms. per litre sodium meta nitro-benzene sulphonate and I grams. per litre ethyl lactate. This fabric either in the wet condition or alternatively dried, is dyed by the method described in Example 1 but using the following dye liquor:
- Teepol X wetting agent
- Shell chemicals 5 grins. per litre of the acid dye Lissamine Fast Violet 2BS (I. C. I. Ltd.) (no colour index No.)
- the fabric leaving the molten metal bath is rinsed and dried giving a coloured fabric which is brighter and bluer than a dyeing carried out in the absence of the pretreatment with oxidising agent.
- Dye liquor used in a padder would have the same compositions as in the foregoing examples.
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Coloring (AREA)
Description
United States Patent DYEING 0F TEXTILE MATERIALS USING MOLTEN METAL Robert S. E. Hannay, Edinburgh, Scotland, and William Kilby, Lancaster, England, assignors to Standfast Dyers and Printers Limited No Drawing. Application May 19, 1952, Serial No. 288,761
Claims priority, application Great Britain May 26, 1951 12 Claims. (Cl. 81)
The present application is a continuation-in-part of application Serial No. 722,042, filed January 14, 1947, and now forfeited in favor of application Serial No. 407,- 962, filed February 3, 1954, which has issued as Patent No. 2,693,995.
This invention relates to a process of dyeing textile materials in which the material after application of the dye thereto is passed through a bath of molten metal. British patent specification No. 620,584 describes such a process which may use an alloy such as Woods metal, and in which the dye liquor may fioat on the surface of the molten metal; alternatively the dye liquor may be padded on to the material before entering the molten metal.
It has been observed that contact of molten alloys such as Woods alloy with wet textile materials produces a slight reducing action which has an adverse effect on the colour of some dyestufis which have been used in aqueous solution for impregnation of the textile. Such dyestuffs are known to be affected by reducing agents and may even be completely destroyed by strong reducing agents. They are to be found principally amongst the classes known as wool dyes and acetate rayon dyes. Examples of such dyestuffs are:
Wool dyes:
Alizan'n Fast Green GGW Carbolan Brilliant Green SGS Lissamine Fast Violet 2138 Polar Brilliant Blue RAW Solway Blue 3GA Carbolan Blue BS Solway Purple (C. l. 1073) Acetate rayon dyes:
Duranol Scarlet B Duranol Scarlet 2G Duranol Red 2B Duranol Blue Green B Duranol Brilliant Blue G Duranol Blue 26 Such dyestuifs are referred to hereinafter as dyestuffs as aforesaid. It is the purpose of this invention to make possible the use of such dyestuffs by countering the reducing action of the metal.
In accordance with the present invention, we provide a process of dyeing textile materials with dyestuffs as aforesaid, in which the material after application of an aqueous dye liquor thereto is passed through a bath of molten metal, characterised by the fact that the material prior to entering the molten metal is treated with a mild oxidising agent which tends to counteract the reducing action of the molten metal. Preferably such oxidising agent is added to the aqueous dye liquor, but it may be applied in any convenient manner to the material, e. g., by padding or spraying.
The oxidising agent may be, for example, the sodium salt of rn-nitrobenzene sulphonic acid and the sodium salt of nitro-toluene-p-sulphonic acid.
ice
The mildness of the oxidising agent is limited on the one hand by the desirability that it should not be strong enough to destroy the dyestufi (by bleaching) or to oxidizev rapidly the molten metal or its alloy components. Ex-
amples of suitable stronger oxidising agents are:
Sodium ortho-vanadate Sodium chlorate (neutral dye bath) Sodium nitrite (neutral dye bath) At the other end of the scale any oxidising agent however mild would have some beneficial effect with some dyes.
The following examples show the composition of some dye liquors made up according to the improved process:
Example 1.Dyeing of wool fabricwith acid dyes Percent Bismuth 50 Lead 26.7
Tin 13.3
Cadmium 10 and has temperature 100 C. Dry scoured woolen fabric is preheated by passing over steam heated cylinders so that it enters the dye with a temperature of 90 C. The fabric speed is 20 yards per minute giving immersion times of 0.67 second for the dye liquor and 10 seconds for the molten metal. The fabric leaves the metal through a wash liquor floating on the exit surface and this aqueous bath (temperature 90 C.) contains 1% of commercial acetic acid. The fabric is finally rinsed and dried and is coloured purple.
Example 2.Dyein'g acetate rayon fabric or nylon fabric with dispersed acetate dyes 1O grms./litre of Duranol Red 2B 300 Pdr. a dispersed acetate dye supplied by I. C. I. Ltd.
5 grms./litre soap.
l0 grms./litre sodium-m-nitrobenzene-sulphonate.
The dye liquor described is made up, stored and pumped to the surface of the molten metal at 80 C. the metal temperature being 95 C. Dry scoured acetate rayon fabric and nylon fabric is preheated by passing through a hot air chamber so that it enters the dye with a temperature of 80 C. The fabric speed is 30 yards per minute giving immersion times of 0.44 second for the dye and 6.7 seconds for the metal. The fabric leaves the metal through hot water (temperature C.) floating on the exit surface of the metal and is finally rinsed and dried. It is coloured red.
Example 3.-Dyeing of wool fabric with acid dyes 5 grms./litre Lissamine Fast Violet 2B8 (imperial Chemical Industries) 10 grms. per litre Teepol X (wetting agent) 10 grms. per litre ethyl lactate 5 grms. per litre sodium nitrite.
This dye liquor is pumped to the surface of the molten metal bath at 98 C.
The metal alloy has the composition:
52.5% Bismuth 15.5% tin 32.0% lead and is maintained at 98 C.
Dry, scoured woolen fabric is preheated by passing over steam-heated cylinders so that it enters the dye with a temperature of 98 C. The time of immersion in the molten metal is 15 seconds and the fabric leaves the metal by way of an exit floating liquor containing 1% of 80% acetic acid and at a temperature of 98 C. The fabric is further treated in continuous manner in 5 grms. per litre acetic acid (80%) for two minutes, then rinsed and dried to give a bright violet coloured fabric.
The following is an example showing the application of the oxidising agent to the material otherwise than by addition to the dye liquor:
Example 4.-Dyeing of wool fabric with acid dyes Scoured wool serge fabric is impregnated in a twobowl padding mangle with a liquor containing 10 grms. per litre sodium meta nitro-benzene sulphonate and I grams. per litre ethyl lactate. This fabric either in the wet condition or alternatively dried, is dyed by the method described in Example 1 but using the following dye liquor:
l0 grms. per litre Teepol X (wetting agent) (Shell chemicals) 5 grins. per litre of the acid dye Lissamine Fast Violet 2BS (I. C. I. Ltd.) (no colour index No.)
grins. per litre formic acid.
The fabric leaving the molten metal bath is rinsed and dried giving a coloured fabric which is brighter and bluer than a dyeing carried out in the absence of the pretreatment with oxidising agent.
Dye liquor used in a padder would have the same compositions as in the foregoing examples.
The invention is also applicable in conjunction with the inventions set forth in applicants copending applications, Serial Nos. 46,804; 90,995; 90,996 and 90,998, the first three applications being now abandoned and the last having issued as Patent No. 2,693,689.
We claim:
1. In a process of dyeing textile materials with dyestuifs which are adversely afiected by reducing agents in which the material after application of an aqueous 4 dye liquor thereto is passed through a bath of molten metal, the improvement which comprises incorporating into the impregnated material entering the molten metal a mild oxidizing agent incapable of exerting a rapid oxidizing influence upon the metal of the molten bath and also of insufficient strength to bleach the dyestufi said oxidizing agent having no greater oxidizing strength than sodium chlorate in a neutral bath.
2. A process according to claim 1, wherein the oxidising agent is added to the aqueous dye liquor.
3. A process according to claim 1, wherein the oxidising agent is contained in a liquor and the material is impregnated with the oxidising liquor prior to entering the dye liquor.
4. A process according to claim 3, wherein the material is impregnated with the oxidising liquor in a padding mangle.
5. A process according to claim 1 wherein the dyestutf V is an acid wool dye.
6. A process according to claim 1 wherein the dyestuff is an acetate rayon dye.
7. A process according to claim 1 wherein the aqueous dye liquor floats on the bath of molten metal and the textile material passes through said dye liquor and directly therefrom into and through said molten metal bath.
8. The process of claim 1, wherein the oxidizing agent is sodium-m-nitrobenzene-sulphonate.
9. The process of claim 1, wherein the oxidizing agent is sodium nitrotoluene-p-sulphonate.
10. The process of claim 1, wherein the oxidizing agent is sodium ortho vanadate.
11. The process of claim 1, wherein the oxidizing agent is sodium chlorate.
12. The process of claim 1, wherein the oxidizing agent is sodium nitrite.
Great Britain Jan. 23, 1952. France Oct. 10, 1944
Claims (1)
1. IN A PRCESS OF DYEING TEXTILE MATERIALS WITH DYESTUFFS WHICH ARE ADVERSELY AFFECTED BY REDUCING AGENTS IN WHICH THE MATERIAL AFTER APPLICATION OF AN AQUEOUS DYE LIQUOR THERETO IS PASSED THROUGH A BATH OF MOLTEN METAL, THE IMPROVEMENT WHICH COMPRISES INCORPORATING INTO THE IMPREGNATED MATERIAL ENTERING THE MOLTEN METAL A MILD OXIDIZING AGENT INCAPABLE OF EXERTING A RAPID OZIDIZING INFLUENCE UPON THE METAL OF THE MOLTEN BATH AND ALSO OF INSUFFICIENT STRENGTH TO BLEACH THE DYESTUFF SAID OXIDIZING AGENT HAVING NO GREATER OXIDIZING STRENGTH THAN SODIUM CHLORATE IN A NEUTRAL BATH.
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US2772136A true US2772136A (en) | 1956-11-27 |
Family
ID=3446213
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US2772136D Expired - Lifetime US2772136A (en) | Dyeing of textile materials using |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US2772136A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3117957A (en) * | 1958-12-19 | 1964-01-14 | Du Pont | Reactive polymeric dyes containing triazine |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR900758A (en) * | 1941-08-30 | 1945-07-09 | Ig Farbenindustrie Ag | Process for heat treatment of textile materials and products thus obtained |
| GB665454A (en) * | 1948-05-04 | 1952-01-23 | Standfast Dyers & Printers Ltd | Improvements relating to the treatment of textile and like materials |
-
0
- US US2772136D patent/US2772136A/en not_active Expired - Lifetime
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR900758A (en) * | 1941-08-30 | 1945-07-09 | Ig Farbenindustrie Ag | Process for heat treatment of textile materials and products thus obtained |
| GB665454A (en) * | 1948-05-04 | 1952-01-23 | Standfast Dyers & Printers Ltd | Improvements relating to the treatment of textile and like materials |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3117957A (en) * | 1958-12-19 | 1964-01-14 | Du Pont | Reactive polymeric dyes containing triazine |
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