US2770650A - Process fortheeproduction of - Google Patents
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- US2770650A US2770650A US2770650DA US2770650A US 2770650 A US2770650 A US 2770650A US 2770650D A US2770650D A US 2770650DA US 2770650 A US2770650 A US 2770650A
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- 238000000034 method Methods 0.000 title claims description 48
- 239000007789 gas Substances 0.000 claims description 60
- 238000004519 manufacturing process Methods 0.000 claims description 38
- 229920001567 Vinyl ester Polymers 0.000 claims description 26
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 22
- 238000007906 compression Methods 0.000 claims description 16
- -1 VINYL ESTERS Chemical class 0.000 claims description 12
- 230000003197 catalytic Effects 0.000 claims description 12
- 238000005201 scrubbing Methods 0.000 claims description 10
- HSFWRNGVRCDJHI-UHFFFAOYSA-N acetylene Chemical compound C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 claims description 8
- 239000003795 chemical substances by application Substances 0.000 claims description 8
- 238000004821 distillation Methods 0.000 claims description 8
- 238000004064 recycling Methods 0.000 claims description 4
- VRDIULHPQTYCLN-UHFFFAOYSA-N Prothionamide Chemical compound CCCC1=CC(C(N)=S)=CC=N1 VRDIULHPQTYCLN-UHFFFAOYSA-N 0.000 claims 2
- 150000002762 monocarboxylic acid derivatives Chemical class 0.000 claims 2
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 description 90
- QTBSBXVTEAMEQO-UHFFFAOYSA-N acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 54
- 238000006243 chemical reaction Methods 0.000 description 22
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 20
- 239000003054 catalyst Substances 0.000 description 18
- XTXRWKRVRITETP-UHFFFAOYSA-N vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 18
- 229940117958 vinyl acetate Drugs 0.000 description 18
- 239000002253 acid Substances 0.000 description 12
- 239000000376 reactant Substances 0.000 description 8
- 150000001735 carboxylic acids Chemical class 0.000 description 6
- 238000001816 cooling Methods 0.000 description 6
- HCHKCACWOHOZIP-UHFFFAOYSA-N zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 6
- 229910052725 zinc Inorganic materials 0.000 description 6
- 239000011701 zinc Substances 0.000 description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- 238000006555 catalytic reaction Methods 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000002360 explosive Substances 0.000 description 4
- 239000012535 impurity Substances 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N AI2O3 Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 229940022663 Acetate Drugs 0.000 description 2
- LWJROJCJINYWOX-UHFFFAOYSA-L Mercury(II) chloride Chemical compound Cl[Hg]Cl LWJROJCJINYWOX-UHFFFAOYSA-L 0.000 description 2
- DJWUNCQRNNEAKC-UHFFFAOYSA-L Zinc acetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O DJWUNCQRNNEAKC-UHFFFAOYSA-L 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 2
- WRYNUJYAXVDTCB-UHFFFAOYSA-M acetyloxymercury Chemical compound CC(=O)O[Hg] WRYNUJYAXVDTCB-UHFFFAOYSA-M 0.000 description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 2
- 150000001558 benzoic acid derivatives Chemical class 0.000 description 2
- 150000004648 butanoic acid derivatives Chemical class 0.000 description 2
- 150000001661 cadmium Chemical class 0.000 description 2
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 2
- 229910052793 cadmium Inorganic materials 0.000 description 2
- GLPMHULIKFGNIJ-UHFFFAOYSA-N cadmium(2+);dioxido(dioxo)chromium Chemical class [Cd+2].[O-][Cr]([O-])(=O)=O GLPMHULIKFGNIJ-UHFFFAOYSA-N 0.000 description 2
- 125000004432 carbon atoms Chemical group C* 0.000 description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 2
- 229910002091 carbon monoxide Inorganic materials 0.000 description 2
- 239000000969 carrier Substances 0.000 description 2
- 239000003610 charcoal Substances 0.000 description 2
- 239000000571 coke Substances 0.000 description 2
- 238000009833 condensation Methods 0.000 description 2
- 230000005494 condensation Effects 0.000 description 2
- 230000003247 decreasing Effects 0.000 description 2
- 230000001419 dependent Effects 0.000 description 2
- 238000006073 displacement reaction Methods 0.000 description 2
- GFJVXXWOPWLRNU-UHFFFAOYSA-N ethenyl formate Chemical class C=COC=O GFJVXXWOPWLRNU-UHFFFAOYSA-N 0.000 description 2
- 125000000219 ethylidene group Chemical group [H]C(=[*])C([H])([H])[H] 0.000 description 2
- 238000004880 explosion Methods 0.000 description 2
- 239000011261 inert gas Substances 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229960002523 mercuric chloride Drugs 0.000 description 2
- 150000002730 mercury Chemical class 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-M propionate Chemical class CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- 230000001105 regulatory Effects 0.000 description 2
- 229910002027 silica gel Inorganic materials 0.000 description 2
- 239000000741 silica gel Substances 0.000 description 2
- 150000004760 silicates Chemical class 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 229960001866 silicon dioxide Drugs 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000002023 wood Substances 0.000 description 2
- 239000004246 zinc acetate Substances 0.000 description 2
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/02—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen
- C07C69/12—Acetic acid esters
- C07C69/14—Acetic acid esters of monohydroxylic compounds
- C07C69/145—Acetic acid esters of monohydroxylic compounds of unsaturated alcohols
- C07C69/15—Vinyl acetate
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/04—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/04—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
- C07C67/05—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation
- C07C67/055—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation in the presence of platinum group metals or their compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/48—Separation; Purification; Stabilisation; Use of additives
- C07C67/52—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation
- C07C67/54—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation by distillation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/007—Esters of unsaturated alcohols having the esterified hydroxy group bound to an acyclic carbon atom
- C07C69/01—Vinyl esters
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/02—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen
- C07C69/12—Acetic acid esters
- C07C69/14—Acetic acid esters of monohydroxylic compounds
Definitions
- the vapor-phase catalytic reaction between acetylene and a carboxylic acid to produce a vinyl ester is a well known reaction.
- the acetylene and carboxylic acid vapors can be conducted through the reaction zone in stoichiometric proportions.
- advantages are obtained if the rate of supply of the acetylene is greatly in excess of the rate of fixation.
- optimum results are achieved when the feed to the reactors consists, for example, of approximately four moles of acetylene per mole of carboxylic acid with the level of con version maintained at about. 30-35% per pass.
- the heat of compression is transferred to a small gas stream which becomes hotter and hotter until heat losses to the atmosphere balance the heat of compression.
- These temperatures in the case of compression of acetylene could readily range between ZOO-300 F. and cause a real hazard or threat of explosion.
- Another object is to provide a process for the production of vinyl esters, such as vinyl acetate from acetylene and a carboxylic acid, whereby hazards attendant upon acetylene handling are materially reduced.
- a still further object is to provide a process of optimum efliciency for the production of vinyl esters by the vapor-phase catalytic reaction of acetylene and a carboxylic acid whereby both capital and operating costs are minimized.
- an acetylene-containing gas stream made up of recycled gas and fresh feed acetylene is passed through a constantspeed compressor.
- the output from the compressor is controlled so that a predetermined proportion of the flow is admixed with the vaporized'carboxylic acid and directed into a catalytic reactor while the remainder of the stream by-passes the reactor and is cooled by introducing it into the product gas stream emerging from the reactor and then passing the mixed stream into a condenser where the vinyl acetate present is condensed.
- Acetylene and any other non-condensable gases from the condenser are recycled to the compressor and again processed in the same manner.
- the condensate is then purified by conventional distillation techniques to recover the pure vinyl ester.
- Dry, pure acetylene gas is fed via line 1 into the pipe 2 where it is admixed with an acetylene-rich recycle stream.
- the combined streams contain 95 volume percent acetylene.
- the recycle stream is about 10 times as large as the fresh feed acetylene stream.
- the combined stream is passed into the compressor 3 and as it comes from the compressor through line 4 it is regulated by means of a flow recording controller 5 so that the flow is divided and a stream of acetylene-containing gas containing approximately 93% C2H2 is admixed with vaporized acetic acid entering at point 6 and fed to the reactor 7.
- the reactor is packed with a catalyst of zinc acetate impregnated on coke and maintained at a temperature from 200220 C.
- the remainder of the flow in line 4 is diverted via line 8 to by-pass the reactor and is cooled by introducing it into line 9 where it blends with the product gases from the reactor.
- the relative flow in streams 4 and Sis controlled by process demand.
- the product demand is high, the flow via line 8 is small; on the other hand, when the flow of reactants to the process is low, the flow through line 8 is high.
- the temperature is thus controlled so that the maximum tempera ture rise is about 50 P. which for 90-95% acetylene in the pressure range of 0-8 p. s. i. g. employed falls within the non-explosive range.
- the combined gases are passed to the condenser 10 where they are cooled to 0 F.
- the condensate is withdrawn via line 11 and sent to a conventional distillation train for recovery of the pure vinyl acetate.
- Gases from thecondenser are recycled via line 12 to the compressor.
- a portion of the recycle gas stream is vented to prevent the build-up of inert material in the system by passing the gas through line 13 into a vent scrubber 14 Where the vented gases are scrubbed with acetic acid which enters through line 15 to remove acetylene.
- Inert gases after scrubbing are discharged to the atmosphere or to a flare through line 16.
- the acetylene may be recovered readily from its acetic acid solution by stripping in one of the columns of the purification system and returned to the system for re-use.
- the acetylene and carboxylic acid vapor mixture can be passed through the reactor in equimolecular proportions or with either reactant in excess. It is preferred to operate at an acetylene to acid molecular ratio of 4 to 1. At this ratio,- about 30-40% of the acid is reacted per pass. These dilute conditions and partial reaction promote increased catalyst life.
- catalysts commonly employed for the vapor-phase reaction of acetylene and carboxylic acids may be employed in the process of the invention.
- Suitable catalysts include zinc or cadmium salts of the carboxylic acids of which it is desired to prepare the vinyl esters, mercury salts such as mercury acetate, mercuric chloride, etc., free phosphoric acid, zinc and cadmium chromates, and silicates and polysilicates of zinc and cadmium.
- These compounds may be supported on carriers such as activated carbon, wood charcoal, silicagel, activated alumina, etc. i
- the process of the invention is operated at temperatures in the range of ISO-300 C.
- the upper temperature limit at which the process is operable de pends upon the thermal stability of the compounds involved.
- the use of temperatures within the range of 180-300 C. is preferred.
- the actual values selected within the preferred range are dependent upon the prop- Optimum temperature is one which is high enough to maintain the acid in a vaporous condition during contact with the catalyst and one at which catalyst efliciency approaches a maximum as indicated by an exothermic effect within the catalyst bed.
- a process for the production of vinyl esters which comprises the following steps: compressing an acetylenecontaining gas stream by means of a constant-output com- .pressor; combining a predetermined portion thereof as it comes from the compressor with a quantity of vaporized aliphatic monocarboxylic acid and passing said combined stream into a catalytic reactor; injecting the remainder of said acetylene-containing stream into the compressor; combining a predetermined portion thereof as it comes from the compressor with a quantity of vaporized acetic acid and passing said combined stream into a catalytic reactor; injecting the remainder of said acetylone-containing stream into the product gas stream emerging from the reactor and passing said mixed gas stream into a condenser where the vinyl acetate is condensed; recycling the acetylene and other non-condensable gases to the compression step; venting a portion of said recycled gases through a scrubber where the acetic acid is employed as the scrubbing agent to remove acetylene; and purifying the
Description
v H, 1956 W. H. STANTON PROCESS FOR THE PRODUCTION OF VINYL ESTERS Filed Jan. 26, 1953 acted, twelve moles of acetylene are fed. content of the recycle stream is limited to about 10%.
United States Patent PROCESS FOR THE PRODUCTION OF VINYL ESTERS Walter H. Stanton, Texas City, Tex., assignor to Monsanto Chemical Company, St. Louis, Mo., a corporation of Delaware This invention relates to the production of vinyl esters generally and more particularly to an improved process for the production of vinyl acetate.
The vapor-phase catalytic reaction between acetylene and a carboxylic acid to produce a vinyl ester is a well known reaction. The acetylene and carboxylic acid vapors can be conducted through the reaction zone in stoichiometric proportions. However, advantages are obtained if the rate of supply of the acetylene is greatly in excess of the rate of fixation. Hence, optimum results are achieved when the feed to the reactors consists, for example, of approximately four moles of acetylene per mole of carboxylic acid with the level of con version maintained at about. 30-35% per pass.
Operation under the above conditions leads to a large recycle of acetylene gas: for every mole of acetylene re- The inert Higher percentages, while they serve to reduce the explosive hazards connected with the handling of acetylene, tend to repress the reaction of acetylene and the carboxylic acid. Recycle of the acetylene-rich stream necessitates the use of some form of compressor. The ideal type of compressor in this application from the standpoint of economy in both capital cost and operation is a positive displacement rotary-type compressor. At low production rates, however, a large recycle occurs, and, with the constant output required in the operation of such a rotary compressor, which is normally driven by a constant speed motor, a high temperature rise occurs. The heat of compression is transferred to a small gas stream which becomes hotter and hotter until heat losses to the atmosphere balance the heat of compression. These temperatures in the case of compression of acetylene could readily range between ZOO-300 F. and cause a real hazard or threat of explosion.
It is an object of this invention, therefore, to provide an improved process for the production of vinyl esters by the vapor-phase reaction of acetylene and a carboxylic acid in the presence of suitable catalysts.
Another object is to provide a process for the production of vinyl esters, such as vinyl acetate from acetylene and a carboxylic acid, whereby hazards attendant upon acetylene handling are materially reduced.
A still further object is to provide a process of optimum efliciency for the production of vinyl esters by the vapor-phase catalytic reaction of acetylene and a carboxylic acid whereby both capital and operating costs are minimized.
It has now been discovered that the recycle stream from such a compressor can be readily cooled by introducing it into the product gas stream downstream of the reactor and then passing this mixed stream into a condenser for cooling and partial condensation. This method of cooling is particularly advantageous since it provides for equally efiicient plant operation at various production levels and permits keying production to demand without the usual elaborate storage equipment and 'ice accessory plant equipment required for such changes. The economies thus made possible are obvious. The method is practicable because at times of large recycle, i. e., decreased production rates, the condensers in the system are operating well below rated capacity. Conversely, at high production rates, low recycle rates prevail and the cooling operation is equally feasible. In addition, the hazards inherent in the handling of acetylene are minimized since the acetylene stream is significantly diluted by its injection into the product stream. According to the invention, an acetylene-containing gas stream made up of recycled gas and fresh feed acetylene is passed through a constantspeed compressor. The output from the compressor is controlled so that a predetermined proportion of the flow is admixed with the vaporized'carboxylic acid and directed into a catalytic reactor while the remainder of the stream by-passes the reactor and is cooled by introducing it into the product gas stream emerging from the reactor and then passing the mixed stream into a condenser where the vinyl acetate present is condensed. Acetylene and any other non-condensable gases from the condenser are recycled to the compressor and again processed in the same manner. The condensate is then purified by conventional distillation techniques to recover the pure vinyl ester.
The process of the invention is illustrated in the following detailed description of a preferred embodiment of the invention for the production of vinyl acetate from acetylene and acetic acid. References are made to the attached drawing which represents a diagrammatic flowsheet.
Dry, pure acetylene gas is fed via line 1 into the pipe 2 where it is admixed with an acetylene-rich recycle stream. The combined streams contain 95 volume percent acetylene. The recycle stream is about 10 times as large as the fresh feed acetylene stream. The combined stream is passed into the compressor 3 and as it comes from the compressor through line 4 it is regulated by means of a flow recording controller 5 so that the flow is divided and a stream of acetylene-containing gas containing approximately 93% C2H2 is admixed with vaporized acetic acid entering at point 6 and fed to the reactor 7. The reactor is packed with a catalyst of zinc acetate impregnated on coke and maintained at a temperature from 200220 C. The remainder of the flow in line 4 is diverted via line 8 to by-pass the reactor and is cooled by introducing it into line 9 where it blends with the product gases from the reactor. The relative flow in streams 4 and Sis controlled by process demand. When the product demand is high, the flow via line 8 is small; on the other hand, when the flow of reactants to the process is low, the flow through line 8 is high. The temperature is thus controlled so that the maximum tempera ture rise is about 50 P. which for 90-95% acetylene in the pressure range of 0-8 p. s. i. g. employed falls within the non-explosive range.
The combined gases are passed to the condenser 10 where they are cooled to 0 F. The condensate is withdrawn via line 11 and sent to a conventional distillation train for recovery of the pure vinyl acetate. Gases from thecondenser are recycled via line 12 to the compressor. A portion of the recycle gas stream is vented to prevent the build-up of inert material in the system by passing the gas through line 13 into a vent scrubber 14 Where the vented gases are scrubbed with acetic acid which enters through line 15 to remove acetylene. Inert gases after scrubbing are discharged to the atmosphere or to a flare through line 16. The acetylene may be recovered readily from its acetic acid solution by stripping in one of the columns of the purification system and returned to the system for re-use.
'erties of the acid and the activity of the catalyst.
3 V In carrying out the novel improved process of this invention, the specific reactants, quantities of reactants, and reaction conditions set forth in the preferred embodiment are subject to substantial variation. Although the process is particularly advantageous when a constantspeed compressor is employed for compression of the feed and recycle gases, there are obvious advantages in its employment when the equipment includes a variablespeed compressor. Neither is the process limited to the production of vinyl acetate; it is equally applicable to the preparation of vinyl esters generally. Vinyl formates, propionates, butyrates, benzoates, etc., may be produced by the process of the invention by reacting the respective carboxylic acids with acetylene. Lower aliphatic monocarboxylic acids containing from one to seven carbon atoms are to be preferred.
As mentioned previously, the acetylene and carboxylic acid vapor mixture can be passed through the reactor in equimolecular proportions or with either reactant in excess. It is preferred to operate at an acetylene to acid molecular ratio of 4 to 1. At this ratio,- about 30-40% of the acid is reacted per pass. These dilute conditions and partial reaction promote increased catalyst life.
Any of the catalysts commonly employed for the vapor-phase reaction of acetylene and carboxylic acids may be employed in the process of the invention. Suitable catalysts include zinc or cadmium salts of the carboxylic acids of which it is desired to prepare the vinyl esters, mercury salts such as mercury acetate, mercuric chloride, etc., free phosphoric acid, zinc and cadmium chromates, and silicates and polysilicates of zinc and cadmium. These compounds may be supported on carriers such as activated carbon, wood charcoal, silicagel, activated alumina, etc. i
In general, the process of the invention is operated at temperatures in the range of ISO-300 C. The upper temperature limit at which the process is operable de pends upon the thermal stability of the compounds involved. The use of temperatures within the range of 180-300 C. is preferred. The actual values selected within the preferred range are dependent upon the prop- Optimum temperature is one which is high enough to maintain the acid in a vaporous condition during contact with the catalyst and one at which catalyst efliciency approaches a maximum as indicated by an exothermic effect within the catalyst bed.
Operation at atmospheric pressure is preferred but, if it is necessary in some instances to insure a practical rate of reaction, superatmospheric pressures may be employed.
While the process of the invention has been described with relation to the preparation of vinyl esters, it is equally applicable with the proper adjustment of temperatures, acetylene-to-acid molecular ratios, etc., known to those skilled in the art in the production of ethylidene diesters with all the attendant advantages.
What is claimed is:
1. A process for the production of vinyl esters which comprises the following steps: compressing an acetylenecontaining gas stream by means of a constant-output com- .pressor; combining a predetermined portion thereof as it comes from the compressor with a quantity of vaporized aliphatic monocarboxylic acid and passing said combined stream into a catalytic reactor; injecting the remainder of said acetylene-containing stream into the compressor; combining a predetermined portion thereof as it comes from the compressor with a quantity of vaporized acetic acid and passing said combined stream into a catalytic reactor; injecting the remainder of said acetylone-containing stream into the product gas stream emerging from the reactor and passing said mixed gas stream into a condenser where the vinyl acetate is condensed; recycling the acetylene and other non-condensable gases to the compression step; venting a portion of said recycled gases through a scrubber where the acetic acid is employed as the scrubbing agent to remove acetylene; and purifying the condensed vinyl acetate by conventional distillation techniques.
3. In a process for the production of vinyl esters by the catalytic vapor-phase reaction of acetylene and aliphatic monocarboxylic acids to produce a gaseous product containing the vinyl ester, unreacted acetylene and acid, and other impurities, wherein said product gas' is condensed and unreacted acetylene and other non-condensable gases are recycled to the reactor and combined with make-up acetylene, a portion of said recycled gases being vented through a scrubber where the carboxylic acid is employed as the scrubbing agent to remove acetylene, the improvement which comprises injecting anypredetermined portion of said combined gas stream after compression in a constant-output compressor into the product gas stream emerging from the reactor. h
4 In a process for the production of vinyl{ acetate by the catalytic vapor-phase reaction of acetylene and acetic acid to' produce a gaseous product containing vinyl ace tate, unreacted acetylene and acetic acid, and other impurities, wherein said product is condensed and unreacted acetylene and other non-condensable gases are recycled to the reactor and combined with make-up acetylene, a portion of said recycled gases being vented through a scrubber where acetic acid is employed as the scrubbing agent to remove acetylene, the improvement which comprises injecting any predetermined portion of said combined gas stream after compression in a constant-output compressor into the product gas stream emerging from the reactor. 7
References Cited in the file of this'patent UNITED STATES PATENTS 7 2,066,075 Reppe et al. Dec. 29, 1936 2,472,084 Beller et al. June 7, 1949 2,472,086 Beller et al June 7, 1949 2,547,916 Wenner Apr. 3, 1951 2,552,425 Halbig May 8,
OTHER REFERENCES Copenhave'r et al.: Acetylene & Carbon Monoxide Chemistry (1949 pps.'25-2 8.
Claims (1)
1. A PROCESS FOR THE PRODUCTION OF VINYL ESTERS WHICH COMPRISES THE FOLLOWING STEPS: COMPRESSING AN ACETYLENECONTAINING GAS STREAM BY MEANS OF A CONSTANT-OUTPUT COMPRESSOR; COMBINING A PREDETERMINED PORTION THEREOF AS IT COMES FROM THE COMPRESSOR WITH A QUANTITY OF VAPORIZED ALIPHATIC MONOCARBOXYLIC ACID AND PASSING SAID COMBINED STREAM INTO A CATALYTIC REACTOR; INJECTING THE REMAINDER OF SAID ACETYLENE-CONTAING STREAM INTO THE PRODUCT GAS STREAM EMERGING FROM THE REACTOR AND PASSING SAID MIXED GAS STREAM INTO A CONDENSER WHERE THE VINYL ESTER IS CONDENSED; RECYCLING THE ACETYLENE AND OTHER NONCOMDENSABLE GASES TO THE COMPRESSION STEP; VENTING A PROTION OF SAID RECYCLED GASES THROUGH A SCRUBBER WHERE THE CARBOXYLIC ACID IS EMPLOYED AS THE SCRUBBING AGENT TO REMOVE ACETYLENE; AND PURIFIYING THE CONDENSED ESTER BY CONVENTIONAL DISTILLATION TECHNIUES.
Publications (1)
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US2770650A true US2770650A (en) | 1956-11-13 |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3031496A (en) * | 1959-05-13 | 1962-04-24 | Chemical Construction Corp | Vinyl acetate process |
US3217032A (en) * | 1960-01-21 | 1965-11-09 | Kurashiki Rayon Co | Preparation of vinyl esters |
DE1233387B (en) * | 1964-04-18 | 1967-02-02 | Hoechst Ag | Process for the preparation of carboxylic acid vinyl esters |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2066075A (en) * | 1932-03-05 | 1936-12-29 | Ig Farbenindustrie Ag | Vinyl esters of carboxylic acids and their production |
US2472086A (en) * | 1945-10-10 | 1949-06-07 | Gen Aniline & Film Corp | Carburetor process for acetylene reactions |
US2472084A (en) * | 1945-10-10 | 1949-06-07 | Gen Aniline & Film Corp | Carburetor process for acetylene reactions |
US2547916A (en) * | 1946-10-16 | 1951-04-03 | Monsanto Chemicals | Multistage continuous reaction process for the production of vinyl acetate |
US2552425A (en) * | 1941-09-17 | 1951-05-08 | Halbig Paul | Method of producing vinyl chloride |
-
0
- US US2770650D patent/US2770650A/en not_active Expired - Lifetime
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2066075A (en) * | 1932-03-05 | 1936-12-29 | Ig Farbenindustrie Ag | Vinyl esters of carboxylic acids and their production |
US2552425A (en) * | 1941-09-17 | 1951-05-08 | Halbig Paul | Method of producing vinyl chloride |
US2472086A (en) * | 1945-10-10 | 1949-06-07 | Gen Aniline & Film Corp | Carburetor process for acetylene reactions |
US2472084A (en) * | 1945-10-10 | 1949-06-07 | Gen Aniline & Film Corp | Carburetor process for acetylene reactions |
US2547916A (en) * | 1946-10-16 | 1951-04-03 | Monsanto Chemicals | Multistage continuous reaction process for the production of vinyl acetate |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3031496A (en) * | 1959-05-13 | 1962-04-24 | Chemical Construction Corp | Vinyl acetate process |
US3217032A (en) * | 1960-01-21 | 1965-11-09 | Kurashiki Rayon Co | Preparation of vinyl esters |
DE1233387B (en) * | 1964-04-18 | 1967-02-02 | Hoechst Ag | Process for the preparation of carboxylic acid vinyl esters |
US3346627A (en) * | 1964-04-18 | 1967-10-10 | Hoechst Ag | Preparation of vinyl esters from acetylene in the presence of a mixed zinc salt catalyst |
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