US2755206A - Tobacco smoking article - Google Patents
Tobacco smoking article Download PDFInfo
- Publication number
- US2755206A US2755206A US374486A US37448653A US2755206A US 2755206 A US2755206 A US 2755206A US 374486 A US374486 A US 374486A US 37448653 A US37448653 A US 37448653A US 2755206 A US2755206 A US 2755206A
- Authority
- US
- United States
- Prior art keywords
- capsule
- tobacco
- neutralizing
- filter body
- smoking article
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 235000002637 Nicotiana tabacum Nutrition 0.000 title claims description 34
- 230000000391 smoking effect Effects 0.000 title claims description 18
- 244000061176 Nicotiana tabacum Species 0.000 title 1
- 239000002775 capsule Substances 0.000 claims description 43
- 241000208125 Nicotiana Species 0.000 claims description 33
- 230000003472 neutralizing effect Effects 0.000 claims description 33
- 239000000463 material Substances 0.000 claims description 28
- 239000000779 smoke Substances 0.000 claims description 16
- 239000004615 ingredient Substances 0.000 claims description 14
- 239000002250 absorbent Substances 0.000 claims description 11
- 230000002745 absorbent Effects 0.000 claims description 11
- 239000012530 fluid Substances 0.000 claims description 11
- 238000009792 diffusion process Methods 0.000 claims description 3
- 230000004044 response Effects 0.000 claims description 3
- 235000019504 cigarettes Nutrition 0.000 description 18
- 239000000126 substance Substances 0.000 description 18
- 238000001914 filtration Methods 0.000 description 16
- 235000019506 cigar Nutrition 0.000 description 13
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
- 239000007788 liquid Substances 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- 235000015110 jellies Nutrition 0.000 description 4
- 239000008274 jelly Substances 0.000 description 4
- 239000006072 paste Substances 0.000 description 4
- 229920000742 Cotton Polymers 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical group [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 3
- 230000009471 action Effects 0.000 description 3
- HOPRXXXSABQWAV-UHFFFAOYSA-N anhydrous collidine Natural products CC1=CC=NC(C)=C1C HOPRXXXSABQWAV-UHFFFAOYSA-N 0.000 description 3
- HPYNZHMRTTWQTB-UHFFFAOYSA-N dimethylpyridine Natural products CC1=CC=CN=C1C HPYNZHMRTTWQTB-UHFFFAOYSA-N 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- OISVCGZHLKNMSJ-UHFFFAOYSA-N 2,6-dimethylpyridine Chemical compound CC1=CC=CC(C)=N1 OISVCGZHLKNMSJ-UHFFFAOYSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 210000003811 finger Anatomy 0.000 description 2
- 210000005224 forefinger Anatomy 0.000 description 2
- 230000036541 health Effects 0.000 description 2
- LELOWRISYMNNSU-UHFFFAOYSA-N hydrogen cyanide Chemical compound N#C LELOWRISYMNNSU-UHFFFAOYSA-N 0.000 description 2
- 238000007373 indentation Methods 0.000 description 2
- 210000004072 lung Anatomy 0.000 description 2
- 150000007524 organic acids Chemical class 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- -1 polyethylene Polymers 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 235000002906 tartaric acid Nutrition 0.000 description 2
- 239000011975 tartaric acid Substances 0.000 description 2
- 210000003813 thumb Anatomy 0.000 description 2
- SNICXCGAKADSCV-JTQLQIEISA-N (-)-Nicotine Chemical compound CN1CCC[C@H]1C1=CC=CN=C1 SNICXCGAKADSCV-JTQLQIEISA-N 0.000 description 1
- OHZCFWMJMWFNFP-ZVGUSBNCSA-L (2r,3r)-2,3-dihydroxybutanedioate;iron(2+) Chemical compound [Fe+2].[O-]C(=O)[C@H](O)[C@@H](O)C([O-])=O OHZCFWMJMWFNFP-ZVGUSBNCSA-L 0.000 description 1
- TUSDEZXZIZRFGC-UHFFFAOYSA-N 1-O-galloyl-3,6-(R)-HHDP-beta-D-glucose Natural products OC1C(O2)COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC1C(O)C2OC(=O)C1=CC(O)=C(O)C(O)=C1 TUSDEZXZIZRFGC-UHFFFAOYSA-N 0.000 description 1
- BSKHPKMHTQYZBB-UHFFFAOYSA-N 2-methylpyridine Chemical compound CC1=CC=CC=N1 BSKHPKMHTQYZBB-UHFFFAOYSA-N 0.000 description 1
- 235000010585 Ammi visnaga Nutrition 0.000 description 1
- 244000153158 Ammi visnaga Species 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- 239000001263 FEMA 3042 Substances 0.000 description 1
- 239000001828 Gelatine Substances 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- 229910021578 Iron(III) chloride Inorganic materials 0.000 description 1
- LRBQNJMCXXYXIU-PPKXGCFTSA-N Penta-digallate-beta-D-glucose Natural products OC1=C(O)C(O)=CC(C(=O)OC=2C(=C(O)C=C(C=2)C(=O)OC[C@@H]2[C@H]([C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)O2)OC(=O)C=2C=C(OC(=O)C=3C=C(O)C(O)=C(O)C=3)C(O)=C(O)C=2)O)=C1 LRBQNJMCXXYXIU-PPKXGCFTSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 235000015165 citric acid Nutrition 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- UTBIMNXEDGNJFE-UHFFFAOYSA-N collidine Natural products CC1=CC=C(C)C(C)=N1 UTBIMNXEDGNJFE-UHFFFAOYSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000011790 ferrous sulphate Substances 0.000 description 1
- 235000003891 ferrous sulphate Nutrition 0.000 description 1
- 229940057006 ferrous tartrate Drugs 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000003780 insertion Methods 0.000 description 1
- 230000037431 insertion Effects 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 1
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 1
- 229910000359 iron(II) sulfate Inorganic materials 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical class [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 229920003052 natural elastomer Polymers 0.000 description 1
- 229920001194 natural rubber Polymers 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229960002715 nicotine Drugs 0.000 description 1
- SNICXCGAKADSCV-UHFFFAOYSA-N nicotine Natural products CN1CCCC1C1=CC=CN=C1 SNICXCGAKADSCV-UHFFFAOYSA-N 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 239000000123 paper Substances 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid group Chemical class S(O)(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- GFYHSKONPJXCDE-UHFFFAOYSA-N sym-collidine Natural products CC1=CN=C(C)C(C)=C1 GFYHSKONPJXCDE-UHFFFAOYSA-N 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 239000005061 synthetic rubber Substances 0.000 description 1
- 235000015523 tannic acid Nutrition 0.000 description 1
- 229920002258 tannic acid Polymers 0.000 description 1
- LRBQNJMCXXYXIU-NRMVVENXSA-N tannic acid Chemical compound OC1=C(O)C(O)=CC(C(=O)OC=2C(=C(O)C=C(C=2)C(=O)OC[C@@H]2[C@H]([C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)O2)OC(=O)C=2C=C(OC(=O)C=3C=C(O)C(O)=C(O)C=3)C(O)=C(O)C=2)O)=C1 LRBQNJMCXXYXIU-NRMVVENXSA-N 0.000 description 1
- 229940033123 tannic acid Drugs 0.000 description 1
- 230000003313 weakening effect Effects 0.000 description 1
Images
Classifications
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/06—Use of materials for tobacco smoke filters
- A24D3/061—Use of materials for tobacco smoke filters containing additives entrapped within capsules, sponge-like material or the like, for further release upon smoking
Definitions
- This invention relates to tobacco smoking articles and, in particular, to means for neutralizing or absorbing the harmful ingredients in tobacco smoke.
- One object of this invention is to provide a tobacco smoking article, such as a cigar or cigarette, equipped with a rupturable capsule containing a neutralizing sub stance for the harmful ingredients in tobacco smoke.
- Another object is to provide a tobacco smoking article, such as a cigar or cigarette, of the foregoing character, wherein the capsule of neutralizing substance is ruptured by the user merely squeezing the butt of the article in which the capsule is embedded, thereby rupturing the capsule and releasing the substance, which in turn moistens the tobacco or absorbent filtering material adjacent the mouth with the neutralizing substance.
- Another object is to provide a tobacco smoking article of the foregoing character wherein the capsule has weakened portions in its wall thereof for facilitating the rupturing thereof.
- Another object is to provide a tobacco smoking article of the foregoing character wherein the capsule is mounted in a portion of filtering material, such as a cartridge or plug of cotton or the like mounted rearwardly of the tobacco, so that the neutralizing substance moistens the filtering material interposed between the smokers mouth and the tobacco.
- filtering material such as a cartridge or plug of cotton or the like mounted rearwardly of the tobacco
- Another object is to provide a cigar or cigarette holder having a portion of filtering material, such as a cartridge or plug of cotton, in which is mounted a rupturable capsule containing the foregoing neutralizing substance so that the protection can be obtained even though using conventional cigars or cigarettes lacking the built-in capsules.
- FIG. 1 is a central longitudinal section, partly in side elevation, of a tobacco-smoking article, particularly a cigarette, equipped with a rupturable capsule containing a neutralizing substance, according to one form of the invention;
- Figure 2 is a cross-section taken along the line 2-2 in Figure 1, with the capsule in elevation;
- Figure 3 is a longitudinal section through a modification of the invention consisting of a cigar or cigarette holder equipped with a neutralizing capsule and filter, for use with conventional cigars or cigarettes.
- tobacco smoke contains ingredients which are harmful to the health of the smoker, such as nicotine, pyridine, picoline, hydrogen sulfide, ammonia, methyl alcohol and hydrocyanic acid, lutidine, collidine, dimethylpyridine and trimethylpyridine.
- ingredients which are harmful to the health of the smoker such as nicotine, pyridine, picoline, hydrogen sulfide, ammonia, methyl alcohol and hydrocyanic acid, lutidine, collidine, dimethylpyridine and trimethylpyridine.
- the present invention provides means for making the neutralizing substance constantly available in a fresh condition by encasing it in an easily rupturable capsule located in the butt of the tobacco smoking article. such as a cigar or cigarette, or in the base of a smoking tobacco holder such as a cigarette or cigar holder.
- the capsule maintains the neutralizing substance, such as a liquid, paste or jelly, in a fresh condition over an indefinite period of time, because it is thus kept sealed 011 from the atmosphere yet it is instantly and easily brought into action by squeezing the portion of the article or device containing the capsule in order to rupture the capsule and distribute the neutralizing material in the path through which the tobacco smoke must pass in order to reach the mouth of the smoker.
- the neutralizing substance by chemical action attacks the harmful ingredients of the tobacco smoke and converts them to harmless chemical compounds, thereby preventing them from reaching the smokers mouth and lungs.
- Figure 1 shows a tobacco smoking article, generally designated 10, shown for purposes of example as a cigarette equipped with a rupturable capsule, generally designated 12, containing a neutralizing fluid substance in the form of a liquid, paste or jelly 14.
- a neutralizing fluid substance in the form of a liquid, paste or jelly 14.
- This when released, passes into and moistens a charge, cartridge or plug 16 of filtering material, such as cotton batting inserted in the rearward portion or butt 18 of the article 10 and encased in a tubular liner 26 of thin cardboard or other suitable flexible stiffening material for the ordinary cigarette paper wrapper 22 in which the tobacco 24 is rolled.
- the capsule 12 is spaced from the sides and from the front and rear ends of the filter body 16.
- the capsule 12 may be of any suitable material, such as gelatine, or polyethylene plastic, natural or synthetic rubber or a material having similar flexible yet rupturable properties. In order to increase the ease of rupturing the capsule 12, it is optionally provided with weakened portions or indentations 26 by thinning the wall 28 of the capsule.
- the indentations 26 are shown as dimples but may be otherwise shaped, and may be directed toward the portion of the filtering material 16 which it is desired to moisten with the neutralizing substance 14.
- the neutralizing substance 14 within the capsule 12 may consist of an organic acid such as tannic acid, tartaric acid or citric acid, ferrous sulfate, ferric chloride, ferrous tartrate, or the double sulfate of ferrous oxide and ammonia, or similar salts of the iron group, namely salts of iron, manganese, nickel and cobalt with mineral acids Such as hydrochloride or sulfuric acids or with organic acids such as tartaric or citric acid.
- an organic acid such as tannic acid, tartaric acid or citric acid, ferrous sulfate, ferric chloride, ferrous tartrate, or the double sulfate of ferrous oxide and ammonia
- similar salts of the iron group namely salts of iron, manganese, nickel and cobalt with mineral acids
- mineral acids such as hydrochloride or sulfuric acids or with organic acids such as tartaric or citric acid.
- the tobacco smoking article 10 such as a cigar or cigarette
- the capsule 12 contained in the butt thereof in the filtering charge.
- the user Prior to lighting the cigarette, the user places the butt thereof between his thumb and forefinger and squeezes it so as to compress the wrapper and tube 20, squeezing the capsule 12 so that it ruptures or breaks.
- Such rupture or breakage permits the neutralizing substance 14 to spurt out into the ical action which converts their harmful ingredients to harmless materials which are either absorbed in the filtering charge 16 or passed harmlessly into the smokers mouth.
- the present invention protects the health of the smoker by shielding his mouth and lungs from the above-mentioned harmful ingredients.
- the modification of the invention shown in Figure 3 consists of a neutralizing holder, generally designated 30, adapted to receive a conventional tobacco-smoking article 32, such as a cigarette or cigar having the usual wrapper 34 containing tobacco 36.
- the holder 30 consists of a cylindrical or tubular portion 38 having a bore 40 into which the article 32 is inserted, and also having a charge 42 of filtering material similar to the filtering material 16 of Figure l and similarly containing a rupturable capsule 44 with weakening portions 46 in the side wall 48 thereof.
- the capsule 44 in turn contains neutralizing material 50 in the form of liquid, paste or jelly, the same as the neutralizing substance 14 described above.
- the holder 30 is preferably made of a flexible or squeezable material such as polyethylene plastic so as to permit the tubular portion or side wall 33 thereof to be collapsed by squeezing, in order to rupture the capsule 44.
- the holder 30 is provided with an end wall 52 from which a mouthpiece 54 containing a smoke passageway 56 projects rearwardly to the rearward end 58 thereof.
- the operation of the modification of Figure 3 is simi lar in principle to that of the form of the invention shown in Figure l.
- the holders 30 are preferably sold separately from the cigarettes or cigars 32, and the latter inserted in the bore 40 of the former when smoking is to commence.
- the user Before lighting the cigar or cigarette 32, the user holds the tubular portion 38 outwardly of the capsule 44 between his thumb and forefinger and squeezes upon it, rupturing the capsule 44 and causing the neutralizing liquid, paste or jelly 50 to permeate the filtering charge 42 as before and thereby neutralize the harmful ingredients in the tobacco smoke when the smoker draws the smoke through the filtering charge 42 during smoking.
- the holder 30 may consist of the stem of any type of smoking device, the stem being of flexible or collapsible material in order to enable rupturing the capsule 44 in the above-described manner.
- the cartridge generally designated 60, comprising the assembly consisting of the plug 42 of absorbent or filtering material containing the rupturable capsule 44 with its harmful ingredient neutralizing fluid 50, may be sold as a unit separate from the holder 30 and inserted by the smoker in his own cigarette or cigar holder.
- the smoker preferably squeezes the cartridge 60 to rupture the capsule 44 and then instantly pushes it into the holder before the cartridge can expand by its absorption of the neutralizing liquid 50.
- the cartridge for example, can be pushed into the holder by means of a pencil or by the cigarette itself, while it is being inserted after the insertion of the cartridge 60. After the cartridge has been used sufficiently to require renewal, it is easily removed from the holder by means of a penknife, hairpin, bobby pin, match, toothpick or any other similar implement.
- wrapper 22 and liner 20 are preferably extended rearwardly of the filtering charge, cartridge or plug 16 a suflicient distance to prevent the tongue from contacting the filtering material. 111 this manner, the smoker avoids any unpleasant or unfamiliar taste which might otherwise be associated with or arise from the neutralizing substance which moistens the filtering material 16.
- a tobacco smoking article having means therein for neutralizing the harmful ingredients of tobacco smoke, said article comprising a wrapper, an elongated mass of tobacco arranged in closely packed form in said wrapper and having a forward end adapted to be ignited and a rearward end, a filter body of absorbent material disposed adjacent said rearward end, a flexible tubular tember enclosing said filter body, a collapsible hollow capsule disposed within said filter body at a location spaced from the sides and from the front and rear ends of the filter body, said capsule having a wall sufliciently weak to be rupturable in response to the application of finger pressure thereto, and a neutralizing fluid for harmful tobacco smoke ingredients disposed within said capsule whereby the user by squeezing the tubular member and the portion of said filter body containing said collapsible capsule causes breakage thereof and ejection of said neutralizing fluid into the absorbent material with consequent diffusion of said fluid through said absorbent material.
- a tobacco smoking holder having means therein for neutralizing the harmful ingredients of tobacco smoke, said holder comprising a flexible tubular member having a socket therein configured to receive the rearward end of an elongated roll of tobacco, a mouthpiece extending rearwardly from said tubular member and hav' ing a smoke passageway therethrough, a filter body of absorbent material disposed in said tubular member at the rear end of said socket, a collapsible hollow capsule disposed within said filter body at a location spaced from the sides and from the front and rear ends of the filter body, said capsule having a wall sufficiently weak to be rupturable in response to the application of finger pressure thereto, and a neutralizing fluid for harmful tobacco smoke ingredients disposed within said capsule, whereby the user by squeezing the tubular member and the portion of said filter body contairning said collapsible capsule causes breakage thereof and ejection of said neutralizing fluid into the absorbent material with consequent diffusion of said fluid through said absorbent material.
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Cigarettes, Filters, And Manufacturing Of Filters (AREA)
Description
July 7, 1956 E. v. STATIA, sR
TOBACCO SMOKING ARTICLE Filed Aug. 17, 1953 INVENTOR. Z c/zM/P 745% 77a 57:
flag/5 United States Patent TOBACCO SMOKING ARTICLE Edwin V. Statia, Sr., Detroit, Mich., assignor of one-half to Edward L. Chapman, Detroit, Mich.
Application August 17, 1953, Serial No. 374,486
2 Claims. (Cl. 131-10) This invention relates to tobacco smoking articles and, in particular, to means for neutralizing or absorbing the harmful ingredients in tobacco smoke.
One object of this invention is to provide a tobacco smoking article, such as a cigar or cigarette, equipped with a rupturable capsule containing a neutralizing sub stance for the harmful ingredients in tobacco smoke.
Another object is to provide a tobacco smoking article, such as a cigar or cigarette, of the foregoing character, wherein the capsule of neutralizing substance is ruptured by the user merely squeezing the butt of the article in which the capsule is embedded, thereby rupturing the capsule and releasing the substance, which in turn moistens the tobacco or absorbent filtering material adjacent the mouth with the neutralizing substance.
Another object is to provide a tobacco smoking article of the foregoing character wherein the capsule has weakened portions in its wall thereof for facilitating the rupturing thereof.
Another object is to provide a tobacco smoking article of the foregoing character wherein the capsule is mounted in a portion of filtering material, such as a cartridge or plug of cotton or the like mounted rearwardly of the tobacco, so that the neutralizing substance moistens the filtering material interposed between the smokers mouth and the tobacco.
Another object is to provide a cigar or cigarette holder having a portion of filtering material, such as a cartridge or plug of cotton, in which is mounted a rupturable capsule containing the foregoing neutralizing substance so that the protection can be obtained even though using conventional cigars or cigarettes lacking the built-in capsules.
Other objects and advantages will become apparent during the course of the following description of the accompanying drawings, wherein:
- Figure 1 is a central longitudinal section, partly in side elevation, of a tobacco-smoking article, particularly a cigarette, equipped with a rupturable capsule containing a neutralizing substance, according to one form of the invention;
Figure 2 is a cross-section taken along the line 2-2 in Figure 1, with the capsule in elevation; and
Figure 3 is a longitudinal section through a modification of the invention consisting of a cigar or cigarette holder equipped with a neutralizing capsule and filter, for use with conventional cigars or cigarettes.
It has long been known that tobacco smoke contains ingredients which are harmful to the health of the smoker, such as nicotine, pyridine, picoline, hydrogen sulfide, ammonia, methyl alcohol and hydrocyanic acid, lutidine, collidine, dimethylpyridine and trimethylpyridine. Attempts to filter out these harmful components of tobacco smoke have hitherto been unsatisfactory other than on a laboratory scale, because of the dilficulty of devising an adequate filter and also of making a suitable Patented July 17, 1956 neutralizing substance always available and in a fresh condition.
The present invention provides means for making the neutralizing substance constantly available in a fresh condition by encasing it in an easily rupturable capsule located in the butt of the tobacco smoking article. such as a cigar or cigarette, or in the base of a smoking tobacco holder such as a cigarette or cigar holder. The capsule maintains the neutralizing substance, such as a liquid, paste or jelly, in a fresh condition over an indefinite period of time, because it is thus kept sealed 011 from the atmosphere yet it is instantly and easily brought into action by squeezing the portion of the article or device containing the capsule in order to rupture the capsule and distribute the neutralizing material in the path through which the tobacco smoke must pass in order to reach the mouth of the smoker. The neutralizing substance by chemical action attacks the harmful ingredients of the tobacco smoke and converts them to harmless chemical compounds, thereby preventing them from reaching the smokers mouth and lungs.
Referring to the drawings in detail, Figure 1 shows a tobacco smoking article, generally designated 10, shown for purposes of example as a cigarette equipped with a rupturable capsule, generally designated 12, containing a neutralizing fluid substance in the form of a liquid, paste or jelly 14. This, when released, passes into and moistens a charge, cartridge or plug 16 of filtering material, such as cotton batting inserted in the rearward portion or butt 18 of the article 10 and encased in a tubular liner 26 of thin cardboard or other suitable flexible stiffening material for the ordinary cigarette paper wrapper 22 in which the tobacco 24 is rolled. The capsule 12 is spaced from the sides and from the front and rear ends of the filter body 16.
The capsule 12 may be of any suitable material, such as gelatine, or polyethylene plastic, natural or synthetic rubber or a material having similar flexible yet rupturable properties. In order to increase the ease of rupturing the capsule 12, it is optionally provided with weakened portions or indentations 26 by thinning the wall 28 of the capsule. The indentations 26 are shown as dimples but may be otherwise shaped, and may be directed toward the portion of the filtering material 16 which it is desired to moisten with the neutralizing substance 14.
The neutralizing substance 14 within the capsule 12 may consist of an organic acid such as tannic acid, tartaric acid or citric acid, ferrous sulfate, ferric chloride, ferrous tartrate, or the double sulfate of ferrous oxide and ammonia, or similar salts of the iron group, namely salts of iron, manganese, nickel and cobalt with mineral acids Such as hydrochloride or sulfuric acids or with organic acids such as tartaric or citric acid.
In the use of the invention, let it be assumed that the tobacco smoking article 10, such as a cigar or cigarette, is manufactured with the capsule 12 contained in the butt thereof in the filtering charge. Prior to lighting the cigarette, the user places the butt thereof between his thumb and forefinger and squeezes it so as to compress the wrapper and tube 20, squeezing the capsule 12 so that it ruptures or breaks. Such rupture or breakage permits the neutralizing substance 14 to spurt out into the ical action which converts their harmful ingredients to harmless materials which are either absorbed in the filtering charge 16 or passed harmlessly into the smokers mouth. Thus, the present invention protects the health of the smoker by shielding his mouth and lungs from the above-mentioned harmful ingredients.
The modification of the invention shown in Figure 3 consists of a neutralizing holder, generally designated 30, adapted to receive a conventional tobacco-smoking article 32, such as a cigarette or cigar having the usual wrapper 34 containing tobacco 36. The holder 30 consists of a cylindrical or tubular portion 38 having a bore 40 into which the article 32 is inserted, and also having a charge 42 of filtering material similar to the filtering material 16 of Figure l and similarly containing a rupturable capsule 44 with weakening portions 46 in the side wall 48 thereof. The capsule 44 in turn contains neutralizing material 50 in the form of liquid, paste or jelly, the same as the neutralizing substance 14 described above.
The holder 30 is preferably made of a flexible or squeezable material such as polyethylene plastic so as to permit the tubular portion or side wall 33 thereof to be collapsed by squeezing, in order to rupture the capsule 44. The holder 30 is provided with an end wall 52 from which a mouthpiece 54 containing a smoke passageway 56 projects rearwardly to the rearward end 58 thereof.
The operation of the modification of Figure 3 is simi lar in principle to that of the form of the invention shown in Figure l. The holders 30 are preferably sold separately from the cigarettes or cigars 32, and the latter inserted in the bore 40 of the former when smoking is to commence. Before lighting the cigar or cigarette 32, the user holds the tubular portion 38 outwardly of the capsule 44 between his thumb and forefinger and squeezes upon it, rupturing the capsule 44 and causing the neutralizing liquid, paste or jelly 50 to permeate the filtering charge 42 as before and thereby neutralize the harmful ingredients in the tobacco smoke when the smoker draws the smoke through the filtering charge 42 during smoking.
It will be evident from Figures 3 that the holder 30 may consist of the stem of any type of smoking device, the stem being of flexible or collapsible material in order to enable rupturing the capsule 44 in the above-described manner.
It will also be evident from Figure 3 that the cartridge, generally designated 60, comprising the assembly consisting of the plug 42 of absorbent or filtering material containing the rupturable capsule 44 with its harmful ingredient neutralizing fluid 50, may be sold as a unit separate from the holder 30 and inserted by the smoker in his own cigarette or cigar holder. In such instance, the smoker preferably squeezes the cartridge 60 to rupture the capsule 44 and then instantly pushes it into the holder before the cartridge can expand by its absorption of the neutralizing liquid 50. The cartridge, for example, can be pushed into the holder by means of a pencil or by the cigarette itself, while it is being inserted after the insertion of the cartridge 60. After the cartridge has been used sufficiently to require renewal, it is easily removed from the holder by means of a penknife, hairpin, bobby pin, match, toothpick or any other similar implement.
From Figure 1 it will be seen that the wrapper 22 and liner 20 are preferably extended rearwardly of the filtering charge, cartridge or plug 16 a suflicient distance to prevent the tongue from contacting the filtering material. 111 this manner, the smoker avoids any unpleasant or unfamiliar taste which might otherwise be associated with or arise from the neutralizing substance which moistens the filtering material 16.
What I claim is:
l. A tobacco smoking article having means therein for neutralizing the harmful ingredients of tobacco smoke, said article comprising a wrapper, an elongated mass of tobacco arranged in closely packed form in said wrapper and having a forward end adapted to be ignited and a rearward end, a filter body of absorbent material disposed adjacent said rearward end, a flexible tubular tember enclosing said filter body, a collapsible hollow capsule disposed within said filter body at a location spaced from the sides and from the front and rear ends of the filter body, said capsule having a wall sufliciently weak to be rupturable in response to the application of finger pressure thereto, and a neutralizing fluid for harmful tobacco smoke ingredients disposed within said capsule whereby the user by squeezing the tubular member and the portion of said filter body containing said collapsible capsule causes breakage thereof and ejection of said neutralizing fluid into the absorbent material with consequent diffusion of said fluid through said absorbent material.
2. A tobacco smoking holder having means therein for neutralizing the harmful ingredients of tobacco smoke, said holder comprising a flexible tubular member having a socket therein configured to receive the rearward end of an elongated roll of tobacco, a mouthpiece extending rearwardly from said tubular member and hav' ing a smoke passageway therethrough, a filter body of absorbent material disposed in said tubular member at the rear end of said socket, a collapsible hollow capsule disposed within said filter body at a location spaced from the sides and from the front and rear ends of the filter body, said capsule having a wall sufficiently weak to be rupturable in response to the application of finger pressure thereto, and a neutralizing fluid for harmful tobacco smoke ingredients disposed within said capsule, whereby the user by squeezing the tubular member and the portion of said filter body contairning said collapsible capsule causes breakage thereof and ejection of said neutralizing fluid into the absorbent material with consequent diffusion of said fluid through said absorbent material.
References Cited in the file of this patent UNITED STATES PATENTS 253,296 Kinney Feb. 7, 1882 1,952,352 Banks Mar. 27, 1934 2,401,617 Cochran June 4, 1946 2,489,675 Roberts Nov. 29, 1949 2,543,190 Musekamp Feb. 27, 1951 2,579,403 Slomowitz Dec. 18, 1951 2,595,606 Pohjola May 6, 1952 FOREIGN PATENTS 243,199 Great Britain Nov. 26, 1925 348,974 Great Britain May 21, 1931
Claims (1)
1. A TOBACCO SMOKING ARTICLE HAVING MEANS THEREIN FOR NEUTRALIZING THE HARMFUL INGREDIENTS OF TOBACCO SMOKE, SAID ARTICLE COMPRISING A WRAPPER, AN ELONGATED MASS OF TOBACCO ARRANGED IN CLOSELY PACKED FORM IN SAID WRAPPER AND HAVING A FORWARD END ADAPTED TO BE IGNITED AND A REARWARD END, A FILTER BODY OF ABSORBENT MATERIAL DISPOSED ADJACENT SAID REARWARD END, A FLEXIBLE TUBULAR MEMBER ENCLOSING SAID FILTER BODY, A COLLAPSIBLE HOLLOW CAPSULE DISPOSED WITHIN SAID FILTER BODY AT A LOCATION SPACED FROM THE SIDES AND FROM THE FRONT AND REAR ENDS OF THE FILTER BODY, SAID CAPSULE HAVING A WALL SUFFICIENTLY WEAK TO BE RUPTURABLE IN RESPONSE TO THE APPLICATION OF FINGER PRESSURE THERETO, AND A NEUTRALIZING FLUID FOR HARMFUL TOBACCO SMOKE INGREDIENTS DISPOSED WITHIN SAID CAPSULE WHEREBY THE USER BY SQUEEZING THE TUBULAR MEMBER AND THE PORTION OF SAID FILTER BODY CONTAINING SAID COLLAPSIBLE CAPSULE CAUSES BREAKAGE THEREOF AND EJECTION OF SAID NEUTRALIZING FLUID INTO THE ABSORBENT MATERIAL WITH CONSEQUENT DIFFUSION OF SAID FLUID THROUGH SAID ABSORBENT MATERIAL.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US374486A US2755206A (en) | 1953-08-17 | 1953-08-17 | Tobacco smoking article |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US374486A US2755206A (en) | 1953-08-17 | 1953-08-17 | Tobacco smoking article |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US2755206A true US2755206A (en) | 1956-07-17 |
Family
ID=23477044
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US374486A Expired - Lifetime US2755206A (en) | 1953-08-17 | 1953-08-17 | Tobacco smoking article |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US2755206A (en) |
Cited By (46)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2796869A (en) * | 1954-02-12 | 1957-06-25 | Aquafilter Corp | Tobacco filter |
| US2808057A (en) * | 1955-03-11 | 1957-10-01 | Matthias F Jaksch | Cigarette and filter therefor |
| US2863461A (en) * | 1955-12-05 | 1958-12-09 | Jr Harry W Frost | Cigarette filter construction |
| US2869558A (en) * | 1957-05-06 | 1959-01-20 | Edward L Redford | Cigar having a tip or mouthpiece |
| US2893399A (en) * | 1957-07-25 | 1959-07-07 | Hans G Jacoby | Smoking article with filtering means |
| US2968305A (en) * | 1957-08-12 | 1961-01-17 | Filtox S A | Filter cigarette |
| US2979058A (en) * | 1957-01-15 | 1961-04-11 | Olin Mathieson | Manufacture of laminated filter tip |
| US3010458A (en) * | 1958-04-22 | 1961-11-28 | Mac Farland Aveyard & Company | Device for removal of tar and other deleterious substances from tobacco smoke |
| US3091243A (en) * | 1961-01-11 | 1963-05-28 | Frank C Guida | Self-extinguishing cigarette |
| US3163168A (en) * | 1962-12-17 | 1964-12-29 | Herbert C Lytton | Smoke purifying devices |
| US3204643A (en) * | 1962-04-03 | 1965-09-07 | Belgo Internat | Cigar tip |
| US3297038A (en) * | 1964-04-20 | 1967-01-10 | Homburger Freddy | Filter cigarette |
| US3334636A (en) * | 1964-06-23 | 1967-08-08 | Alexander A Zuber | Filter for smokers' article |
| US3339558A (en) * | 1966-10-28 | 1967-09-05 | Haskett Barry F | Smoking article and filter therefor containing vitamin a |
| US3339557A (en) * | 1965-03-12 | 1967-09-05 | Lew W Karalus | Cigarette and smoke filter and flavor means |
| US3347231A (en) * | 1963-04-17 | 1967-10-17 | Chang Chien-Hshuing | Imitation cigarette |
| US3366121A (en) * | 1964-12-15 | 1968-01-30 | H 2 O Filter Corp | Filter cigarettes |
| US3390686A (en) * | 1965-12-21 | 1968-07-02 | American Tobacco Co | Tobacco smoke filter element |
| US3428049A (en) * | 1965-12-21 | 1969-02-18 | American Tobacco Co | Tobacco smoke filter element |
| US3513859A (en) * | 1967-11-06 | 1970-05-26 | H2O Filter Corp The | Filter for smoking devices |
| US3515146A (en) * | 1967-06-27 | 1970-06-02 | Raymond N Nealis | Aromatic filter |
| US3863647A (en) * | 1972-12-22 | 1975-02-04 | Richard A Unger | Pipe smoking |
| US4452259A (en) * | 1981-07-10 | 1984-06-05 | Loews Theatres, Inc. | Smoking articles having a reduced free burn time |
| US4865056A (en) * | 1987-01-23 | 1989-09-12 | Japan Tobacco Inc. | Easily breakable plastic capsule and a water filter for a cigarette using the same |
| US6631722B2 (en) * | 1993-09-30 | 2003-10-14 | British-American Tobacco Company Limited | Tobacco smoke filter elements |
| US20060174901A1 (en) * | 2005-02-04 | 2006-08-10 | Philip Morris Usa Inc. | Flavor capsule for enhanced flavor delivery in cigarettes |
| US20070012327A1 (en) * | 2005-05-03 | 2007-01-18 | Philip Morris Usa Inc. | Cigarettes and filter subassemblies with squeezable flavor capsule and methods of manufacture |
| US20110023896A1 (en) * | 2003-06-23 | 2011-02-03 | R. J. Reynolds Tobacco Company | Filtered cigarette incorporating a breakable capsule |
| US20110232659A1 (en) * | 2010-03-26 | 2011-09-29 | Philip Morris Usa Inc. | Methods of manufacturing cigarettes and filter subassemblies with squeezable flavor capsule |
| WO2013020280A1 (en) * | 2011-08-10 | 2013-02-14 | 深圳梵活生物科技有限公司 | Cigarette filter and manufacturing method thereof, cigarette and method of use thereof |
| WO2012156702A3 (en) * | 2011-05-13 | 2013-04-25 | British American Tobacco (Investments) Limited | Additive-containing member |
| US20130140030A1 (en) * | 2011-12-01 | 2013-06-06 | E. Edward Rankin | Apparatus and method for dispensing chemicals into a well |
| WO2014040111A1 (en) | 2012-09-17 | 2014-03-20 | Tannpapier Gmbh | Mouthpiece lining paper |
| WO2014040109A1 (en) | 2012-09-17 | 2014-03-20 | Tannpapier Gmbh | Layer composite for a filter of an article to smoke |
| US20140182607A1 (en) * | 2011-05-13 | 2014-07-03 | British American Tobacco (Investments) Limited | Additive release component |
| US20140182614A1 (en) * | 2011-05-13 | 2014-07-03 | British American Tobacco (Investments) Limited | Additive release component |
| CN104705791A (en) * | 2015-01-30 | 2015-06-17 | 航翊科技股份有限公司 | cigarette filter unit |
| US9089163B2 (en) | 2010-12-01 | 2015-07-28 | Tobacco Research And Development Institute (Proprietary) Limited | Feed mechanism |
| US9307789B2 (en) | 2011-12-01 | 2016-04-12 | Tannpapier Gmbh | Mouthpiece lining paper for a smoking article |
| CN105495692A (en) * | 2016-01-19 | 2016-04-20 | 华健 | Filter tip with replaceable breakable bead core rod |
| US9339059B2 (en) | 2011-12-23 | 2016-05-17 | Tannpapier Gmbh | Mouthpiece lining paper, formed as a film/foil, of a filter cigarette |
| JP2016105718A (en) * | 2010-03-24 | 2016-06-16 | エッセントラ フィルター プロダクツ ディベロップメント カンパニー プライベート リミティド | Tobacco smoke filter |
| US9462828B2 (en) | 2009-03-09 | 2016-10-11 | British American Tobacco (Investments) Limited | Apparatus for introducing objects into filter rod material |
| US9554594B2 (en) | 2003-09-30 | 2017-01-31 | R.J. Reynolds Tobacco Company | Filtered cigarette incorporating an adsorbent material |
| EP3311681A1 (en) | 2013-03-28 | 2018-04-25 | Philip Morris Products S.a.s. | Smoking article including a flavour delivery member |
| WO2022058396A1 (en) * | 2020-09-16 | 2022-03-24 | Jt International | Article with a refreshing liquid substance |
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Cited By (72)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2796869A (en) * | 1954-02-12 | 1957-06-25 | Aquafilter Corp | Tobacco filter |
| US2808057A (en) * | 1955-03-11 | 1957-10-01 | Matthias F Jaksch | Cigarette and filter therefor |
| US2863461A (en) * | 1955-12-05 | 1958-12-09 | Jr Harry W Frost | Cigarette filter construction |
| US2979058A (en) * | 1957-01-15 | 1961-04-11 | Olin Mathieson | Manufacture of laminated filter tip |
| US2869558A (en) * | 1957-05-06 | 1959-01-20 | Edward L Redford | Cigar having a tip or mouthpiece |
| US2893399A (en) * | 1957-07-25 | 1959-07-07 | Hans G Jacoby | Smoking article with filtering means |
| US2968305A (en) * | 1957-08-12 | 1961-01-17 | Filtox S A | Filter cigarette |
| US3010458A (en) * | 1958-04-22 | 1961-11-28 | Mac Farland Aveyard & Company | Device for removal of tar and other deleterious substances from tobacco smoke |
| US3091243A (en) * | 1961-01-11 | 1963-05-28 | Frank C Guida | Self-extinguishing cigarette |
| US3204643A (en) * | 1962-04-03 | 1965-09-07 | Belgo Internat | Cigar tip |
| US3163168A (en) * | 1962-12-17 | 1964-12-29 | Herbert C Lytton | Smoke purifying devices |
| US3347231A (en) * | 1963-04-17 | 1967-10-17 | Chang Chien-Hshuing | Imitation cigarette |
| US3297038A (en) * | 1964-04-20 | 1967-01-10 | Homburger Freddy | Filter cigarette |
| US3334636A (en) * | 1964-06-23 | 1967-08-08 | Alexander A Zuber | Filter for smokers' article |
| US3366121A (en) * | 1964-12-15 | 1968-01-30 | H 2 O Filter Corp | Filter cigarettes |
| DE1298032B (en) * | 1964-12-15 | 1969-06-19 | H 2 O Filter Corp | Cigarette filters |
| US3339557A (en) * | 1965-03-12 | 1967-09-05 | Lew W Karalus | Cigarette and smoke filter and flavor means |
| US3390686A (en) * | 1965-12-21 | 1968-07-02 | American Tobacco Co | Tobacco smoke filter element |
| US3428049A (en) * | 1965-12-21 | 1969-02-18 | American Tobacco Co | Tobacco smoke filter element |
| US3339558A (en) * | 1966-10-28 | 1967-09-05 | Haskett Barry F | Smoking article and filter therefor containing vitamin a |
| US3515146A (en) * | 1967-06-27 | 1970-06-02 | Raymond N Nealis | Aromatic filter |
| US3513859A (en) * | 1967-11-06 | 1970-05-26 | H2O Filter Corp The | Filter for smoking devices |
| US3863647A (en) * | 1972-12-22 | 1975-02-04 | Richard A Unger | Pipe smoking |
| US4452259A (en) * | 1981-07-10 | 1984-06-05 | Loews Theatres, Inc. | Smoking articles having a reduced free burn time |
| US4865056A (en) * | 1987-01-23 | 1989-09-12 | Japan Tobacco Inc. | Easily breakable plastic capsule and a water filter for a cigarette using the same |
| US7249605B2 (en) | 1993-09-30 | 2007-07-31 | British American Tobacco (Investments) Ltd. | Tobacco smoke filter elements |
| US6631722B2 (en) * | 1993-09-30 | 2003-10-14 | British-American Tobacco Company Limited | Tobacco smoke filter elements |
| US20040074507A1 (en) * | 1993-09-30 | 2004-04-22 | Macadam Kevin Gerard | Tobacco smoke filter elements |
| US20110232658A1 (en) * | 2003-06-23 | 2011-09-29 | R.J. Reynolds Tobacco Company | Filtered cigarette incorporating a breakable capsule |
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| US7984719B2 (en) | 2003-06-23 | 2011-07-26 | R. J. Reynolds Tobacco Company | Filtered cigarette incorporating a breakable capsule |
| US9554594B2 (en) | 2003-09-30 | 2017-01-31 | R.J. Reynolds Tobacco Company | Filtered cigarette incorporating an adsorbent material |
| US7578298B2 (en) | 2005-02-04 | 2009-08-25 | Philip Morris Usa Inc. | Flavor capsule for enhanced flavor delivery in cigarettes |
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| US9462828B2 (en) | 2009-03-09 | 2016-10-11 | British American Tobacco (Investments) Limited | Apparatus for introducing objects into filter rod material |
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| US20110232659A1 (en) * | 2010-03-26 | 2011-09-29 | Philip Morris Usa Inc. | Methods of manufacturing cigarettes and filter subassemblies with squeezable flavor capsule |
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