US2741912A

US2741912A - Apparatus for detecting gases or vapors

Info

Publication number: US2741912A
Application number: US325177A
Authority: US
Inventors: Schultze Karl
Original assignee: HERMANN SEWERIN VORM VULKAN WE
Current assignee: HERMANN SEWERIN VORM VULKAN WE; Hermann Sewerin Vorm Vulkan-Werk Firma GmbH
Priority date: 1951-12-19
Filing date: 1952-12-10
Publication date: 1956-04-17
Anticipated expiration: 1973-04-17

Description

April 17, 1956 SCHULTZE APPARATUS FOR DETECTING GASES OR VAPORS Filed Dec. 10, 1952 IHVEHTOR:

KARL Sc HULTZE 2,741,912 Patented Apr. 17, 1956..

APPARATUSYFOR DETECTING GASES R VAPORS Karl Schultze, Hamburg-Blankenese G,ermany,; assignor toEirmaI-IermannSewerin vorm. VulkanqWerk G. m. b. Hi, Gutersloh, Germany Application-December-lllg 1952; SrialNo. 325,177

(Elaimspriority, application Germany December19, 19,511.

21" Claims; (C11 73-23) The present-"invention relates to an apparatus for def tectingrgases or vapors in the air.

Mbre'particularly, thepresent invention: relates to.an

apparatus for detectingin the air gaseswhich are harmful to human beings or which are explosive in too great concentrations and for warning of an increase'ofsuch gases in the air.

Certain deviceshas already been provided for detecting vapors of gases such as gasoline or benzene-gases orvapors; carbonttetrachloride; ether,- carbon bisulfi'de, etc.

Theseknown devicesare either too insensitive or they'are only sensitiveto a particular gas. Usually these known detecting devices are of 'such-small sensitivity that the gas to be detected must be. enriched in.some'way which requires additional structures which cause the air to be moved through a reaction device-s0 that the indication can be obtained only through manual or mechanical methods of enriching the gas. Also,- thereaction means of these known structures must b'erenewed fromtime to time so that an automaticregistration" or indicationof the presence of certain' gases -.is not possible.-

However; it is quite important to solve this problemof providing such automatic detecting devices because the dangerto human beings and equipment resulting from-possible toxic effects, ignition, or explosion: of certain; gases is great; In mostcases the time when thedanger increases is unknown. The'above-mentioned type of gases are likelyto cause explosions when they are" present in the air in a concentration of between approximately 2 and" 6%- byvolume; and their capability" of har-mfully ailectinghuman beings is present at considerably lowerconcentrations;

0ne=of the objectsof the-present inventionis tosolvethe" above discussed problem by providing a very simple vide an: apparatus capable ofdetecting the presence of many'diflerent types of harmful gasesinthe air;

"Yet another object of the present invention is to pro vide an electrically operable detecting apparatus.

Still another object of thepresent invention is to provide an exceedingly simple detecting apparatus which is small in size and' capable of beingihconspicuously hungupat a predetermined part of a roomor the like to detect th'epresence of harmful gases or vapors in the air of the room.

With the above objects in view, the present invention mainly consists of an apparatus for detecting gases or .tsl

vapors in the air, this apparatus including a quantity-of granulated carbonsupported-in contactwith the surrounding atmosphere, and an electrical cireuit formedjin part by the carbon and includinganindicator for indicating variations: in the current passing through-ythe carbon.

The novel features which are considered as characteristic for the invention are. set forth inparticular-in ,the appended claims. as to its constructionand-its method ofyoperation, to'-,

gether with additional objects; and advantages thereof, will be best understood from the following description. of. specific embodiments" when read 'in connection ,with,

the accompanying drawings, inwhich:

Fig. 1 is a side, elevationalview of one possiblestrue.

ture for carrying out the present invention; Fig. 2 is a top planview of the structure of Fig.1; Fig. 3 is a sectional view taken along. line A A of I Fig. l in the direction of the, arrows;,

Fig; 4 is a sectional view taken along line B-B of Fig, 1 in the direction, of'the arrows;

Fig. 5 is a sectional view taken alongline C C of Fig. 1 in the direction of the arrows;

Fig. 6 is a partly diagrammatic; elevational vieyv. of an. entire apparatus with which, the structure of Figs. 1-5 .is associated;

Fig, 7 is a perspective view of adifierent embodiment. of the invention;

Fig. 8'is a'transverse, sectional view in a horizontal. plane ofthe structure of Fig. 7; and

Fig. 9 is a transverse, sectional view in a vertical plane. of the structure of Fig. 7. i

The present invention takes advanta e of the fact that,

the electrical conductivity ofactivated carbon increases. when air mixed with the harmful gasor vapor to be detected comes intocontact with such. activated carbom.

It appears that such contact causes a swelling of the tween the plates 1 and: 3 by six Screw members 4. Each;

of

theplates

1, 2, and 3. is formed with a pair. of sharp. cornered triangular openings. 5-, and these pairsofopen ings fi h -plat 2 de e t alaw t g ashrq her: and-a i n h' a ho r. when the. nlatesa ea sembled.

The plate 2 is formed with two bores extending in wardly from an outer side edge thereof and respectively communicating with-the pair of openings 5 of the plate 2, these bores being closed by the removable-plug mem-. bets 6. As is apparent from Fig, 1, thesehores which: are closedby therplugsfi extendto the center of, thebase of the triangular openings 5.

Adjacent to the lower apexes of the, triangular open,- ingsS of the-center plate 2, as viewed inFig. 1, there are located apairof elongated; electrical contact members; 7 which extend into suitable openings formed in the plate, 2, these; contact members 7 extending from thesideedge ofi plate 2 which is opposite to the'plugs 6. A. Pair of electrically conductive set screws. 8' and; 9are respectively in contact with'the membe1=s7, the set screws 8, extending The invention itself; however, both;

10 of copper or brass sheet, for example, and one of these plates 10 is electrically connected to one of the members 7 through the set screw 8 while the other of the plates 10 is electrically connected to the other of the members 7 through the set screw 9, these plates 10 respectively contacting the

set screws

8 and 9. Those parts of the plates 10 which cover the openings of the plate 2 are formed with a plurality of small openings which are located very close to each other.

Thus, the central plate 2, together with the electrically conductive plates located against the opposite sides thereof, forms a pair of containers, at the openings 5 of the plate 2, each of which has opposite, electrically conductive, apertured side wall portions formed by the plates 10 which are insulated from each other. These openings 5 of the plate 2 are filled with granulated activated carbon through the bores closed by the plugs 6, or the openings 5 of the plate 2 may be filled with granulated carbon after one of the plates 1 and 3 and the plate 19 associated therewith is removed.

The above described structure thus forms a pair of electrically conductive cells .of activated carbon, and these cells are located in an electrical circuit which includes an ammeter-and/or an optical or aural electrical indicator. With such an arrangement the concentration of harmful gases or vapors in the air may be detected and indicated.

In Fig. 6 there is shown a frame 11 located about and spaced from a structure identical with that of Figs. 1-5 except that the top portions of the plates 10 are covered with an electrically non-conductive lacquer which extends slightly below the topmost parts of the openings 5 so that the top layer of activated carbon located in the openings 5 of: plate 2 does not contact any electrical conductors. It should be noted, h0wever, that the structure of Figs. 1-5, without any changes, could also be located in the frame 11. As is apparent from Fig. 6 the assembly is held within the frame 11 through the medium of eight coil springs 12 which respectively extend from the eight corners of the assembly of plates 13 to the inner eight corners of the frame 11, which is in the form of top and bottom horizontal plate portions interconnected by four vertical members extending between the corners of these plate portions, as shown in Fig. 6.

From one of the contact members 7 there extends an electrical lead 13 which passes through a bored cap member 14 to one of the contacts of the ammeter 15, and a similar lead extends from the other of the contacts of the ammeter through a battery, or a diiferent source of current, to the other of the members 7. The ammeter 15 is provided in the usual way with a switch for cutting it into and out of the circuit. As is shown in Fig. 6, the ammeter in the particular example is provided with a face 16 having thereon a dial extending from 0 to 2.0 milliamperes.

In Figs. 7-9 there is shown a different embodiment of the structure of Figs. 1-5. In the embodiment of Figs. 7-9, there are provided a pair of electrically conductive,

apertured tubes

17 and 18 which are coaxially arranged with the outer tube 17 located about the inner tube 18 to form an annular cylindrical space therewith. This annular cylindrical space is divided up by a plurality of electrically non-conductive partitions 19 which extend radially from the axis of

tubes

17 and 18 and which extend along the entire length of these tubes. In the particular example illustrated, the partitions 19 divide the space between the

tubes

17 and 18 into five cells each of which is filled with granulated activated carbon 23.

The bottom end of the annular space between the

tubes

17 and 18 is closed by an annular ring 20 of electrically non-conductive material which is joined to the

tubes

17 and 18, and the top end of this annular space is closed by a removable cover 21, as illustrated, this cover 21 also being made of an electrically non-conductive material and being formed with a pair of openings through which the leads 22 extend, these leads being respectively connected to the tubes17 and 18 and being adapted to be located in a circuit such as that shown in Fig. 6. It will be noted that cover member 21 is annular so that the space in the interior of tube 18 is open at the top and bottom, and therefore the air may contact the activated carbon through the tube 18 as well as through the tube 17.

With the apparatus of the invention it is sufficient to obtain the current from a battery which need only have a potential of three volts. Although the grains of activated carbon may have any shape, the best results are obtained when the granulated carbon is in the form of spherical pellets having a diameter of approximately 2 mm. It has been found that when both of the cells of the structure of Figs. 1-5 are each filled with 14 to 16 pellets of this size, the ammeter may be controlled through a shunt in such a way that the full 2 milliampere stroke of the pointer is used, such an indication of 2 milliamperes corresponding to a concentration in the air of approximately 0.5% by volume of light gasoline. Through further suitable shunt arrangements, for example, according to multiples of 5, it is possible to use the apparatus with higher concentrations which correspond to the concentration values where explosions are likely to occur and which begin at a concentration approximately 1% by volume.

Through electrical connections of this type the apparatus may be used with devices for sounding alarms or giving other warnings, and the value of the voltage and milliamperes of the apparatus is kept low enough so that the device itself is protected against explosions. To further increase the safety of the device, fuses of 20 milliamperes, for example, may be connected in the circuit.

When there are no harmful gases or vapors in the air, there is, in the apparatus of Fig. 6, a continuous residual current in the carbon of approximately 0.5 milliampere. Concentrations of O0.5% by volume of light gasoline in the air give readings of 0.5-2.0 milliamperes, and it is therefore possible to have the scale of the ammeter read directly in concentration by volume, if desired.

At higher voltages the sensitivity of the apparatus is increased, but the movement of the ammeter needle is much more vigorous and any curves inscribed by such a moving needle or a suitable device connected thereto are extremely jagged.

The actual dimensions of the apparatus are quite small. Thus, the structure of Figs. 1-5 need be only as large as a match box, and, if desired, the structure of Figs. 7-9 may be made as small as a thimble. Instead of apertured walls to provide access of the outer air to the activated carbon, porous walls may be used. The apertures of the plates 10 are preferably of less than 1 mm. in diameter and are located so close to each other that apertures, for example, are located in a square cm. Also, it is possible to provide a corresponding number of small slits instead. It is necessary that the plates 10 be quite rigid or strongly reinforced so that they are capable of withstanding the pressure of the expanding grains of carbon. Instead of a plastic material, the plate 2 may be made of a porous ceramic material or of sintered glass or the like. Also, an entire cell may be made out of a porous electrically non-conductive material and opposite inner surfaces thereof may be provided with an electrically conductive coating to contact the carbon. In such an arrangement the non-conductive Walls are porous so that the conductive parts need not be porous.

It will be seen from the arrangement of Figs. 15 that a single plate 10 may form the electrode for a plurality of cells, and the triangular shapeof the openings 5 of the plate 2 assures filling of these openings from the bottom up. The grains are preferably located in these openings of the plate 2 in such a way that they may move located. thereover. structure. takes place, it is possible for'the topmost layer of the grainstomove considerably anditherefore to dis: turb. the. setting, of the apparatus.- made upon installation thereofl" Toavoid this, the apparatus is yieldably sup: ported'onthe springs 12 as shown in Fig. 6. Also, it is possible. tolocate. against the top layer of. carbon. grains a layer of cotton wadding or the like so. as. to prevent such movement of'the grains while not pressing. apprea ciably against the latter. Another. way of greatly reducingthe. effect. oflmovement the top. layer of carbon grains. is. to. providethe metal plates with an insulating. coating',.aswas described. above in connection. with Fig. 6.. Withthis arrangement the topmost layer of. the carbon. is. located. between. the. non-conductive parts of the plates 10,. so. that the. current in following; the line. of least resistance does not. pass. through. the topmost layer of the carbon. and insteadpasses only through the lower. part of. the granulated carbon.

Structures of thetype:describedabovemay be mounted in.rooms. in the same-way as thermometers or thermostats,. and. itis unnecessary to: provide any means for forcing the: air through the apparatus. The. electrical leads extending from the cells may be of any desired length.

v If. apotentialofi 5. volts is setup across the electrodes formed. by the plates 10, then there will be a residual current of 5-10 milliamperes-passing:throughthe carbon, andanrammeter different from thatzof Fig; 6-would have to be usedi with. the apparatus. In an arrangement. of thistlatter type, if. the air has a. concentration of: 0.1% by volume. of gasoline, the arnmeter will. immediately begin. to indicate a. rise in. current, andwhen the concentrationreaches 0.3%. the ammeter'willread between 50 and. 60' milliamperes. These values are obtained when the cells-are-filled with'about 60 pellets of carbon having a diameter'of from 2. to 3 mm; and where the. plates 10 or. thetubes=1-7- and 18 are located at a: distance of. 5' mm.. from each other. i

When; the: concentration of harmful gases on vapors decreases; the: current flowing through the carbon. also decreases. and: the reading on the ammeter goes down;. Without any; further preparation or handling of any type;, the readings of; the ammeter will automatically go up.- when. the: concentration. of harmful gases or vapors in. the air increases. It is: possible to provide electrical alarms; which operate to provide continuous sounds as soon: as the concentration of harmful gases or vapors exceeds a predetermined value andiwhich ends when this concentratiom goes. below such. a value.

It. has been' shown: that; the sensitivity of the: cells. is increasedl when they are higher. than they are: wide, and Figs. 5: and* 9?- clearly show that the height of the cellsis several: times as: great as the space: between the. walls E0.- otr the tubes 17: and; 181 As was mentioned above, pellets ofi carbon having a diameter of 1-2 mm. are preferred; and: ther reason-1 for this is. that the residual: electtsicalI current can be very accurately determined and maintain! constant with: grains of this type.

Instead of providing a plate 2 of non-conductive material it is possible to. make this plate of conductive material and insulate' e same from the plates 10; Also, the sensitivity of the apparatus may be increased by the use of amplifiers or the like such as are used in communication circuits.

It will be understood that each. of the elements desCribedabove, or two or more together, may also find a useful. application inother types 015 apparatus for detecting. gases. or vapors-differing. from the types described above;

- While'the invention has been illustrated and described as: embodied in electrical apparatus for detecting gases onvapors, it is not: intended to be. limited to the details showmusince various modifications and structural changes.

When a. vigorous. movement. of; the

may be. made without departinginany way from the spiritof'the present invention;

Without further. analysis, the foregoing will'lso fully. reveal the. gist of the present invention that others can by applyingcurrent knowledge readily adapt it for various applications without. omitting features that f'rom the standpointof prior. art, fairly constituteessential characeristics.

of the generic or specific aspects of. this invention and, therefore, such adaptations shouldand are intended to.be comprehended;within the meaning and. range of equivalence of: the following claims.

What is claimed as new. and desired to be secured by Letters Patent is:.

1'. Apparatus for detectingga-ses or vapors in the air, comprising, in combination, a quantity of granulated activated" carbon; container means surrounding and' engaging said carbon along the depth thereof. and supportingat least apart of said quantity ofgranulatedcarbon.in.contact with the surroundingatmosphere said container, being. at least partially filled by. said carbon, said container means includingapair of electrically conductive walllportions spaced andiinsulated from each other andcontacting. said. carbon the latter substantially bridging said electrically conductive wall'portions in mass-like form, said pair of Wallportions being adapted to be connected to a source of potential". to form a circuit for establishing a currentflow through said carbon; and electrical indicator means connected electrically to one of'said wall portions and. adapted to be placedl'insaid circuit for indicating a variation in the current 'passingthrough said granulated carbon.

2. Apparatus for detecting gases or vapors in the air, comprising-in combinatioma quantity of granulated activated carbon; container means surrounding and engaging said'carbon along the depth thereof andsupporting at least apart of said quantity of; granulated carbon in contact. with the: surroundingatmosphere, said container being at least partially. fill'edlby said. carbon, said container means including a, pair of opposite, electrically conductive wall portions-spaced and insulated from each other and contacting, said carbon the latter substantially bridging said elect-rically conductive. wall? portion inmass-like form, said pain of. wall portions beingadapted to be connected to a source of-potential' to form a circuit for establishing a current, fi'ow through said carbon; and electrical indicator means. connected electrically to one of said wall portions and. adapted to be placed in said circuit for indicating a variation. in the current passing through said granulated: carbon.

3.. Apparatus for detecting. gases or vapors in the. air, comprising, in combination, a container having opposite,. electrically conductive, apertured side wall portions which are insulatedlfromeach other; a quantity of granulated activatedl'carbonlocatedin. and substantially fillingsaid container: and contacting said side wall. portions thereof, said" side wall". portions being adapted to be connected to a source ofpotential to form a circuit for establishing a current. fl'ow' through said carbon; and electrical indicating means connected electrically to one of said wall portions and. adapted to be placed in said circuit to indicate a varia: tion inthe, current. flowing throughv said carbon.

4. Apparatus for detecting gases or vapors in the air, comprising, in combination, a container having opposite,. electrically conductive, apertured side wall portions whichare insulatedfrom'each other and which have a height substantially greater than the space between said side wall portions; a quantity of granulated activated carbon located in and substantially filling said container and contacting. saidtside Wall portions thereof, said side wall portions being. adapted to be connected to a source of potential to formfa circuitfor establishing a current flow through. said. carbon", and electrical indicating means connected electrically to one ofsaid wallportions and adapted to be placed in said circuit to. indicate a. variation in the current flowingthroughsaid carbon.

5. Apparatus for detecting gases or vapors. in the air,v

comprising, in combination, a plate of electrically nonconductive material formed with an opening passing transversely therethrough; a pair of electrically conductive, apertured plates respectively located against opposite sides of said electrically non-conductive plate and covering said opening thereof; a quantity of granulated activated carbon located in said opening between and substantially bridging in mass-like form said pair of electrically conductive plates, said pair of plates being adapted to be connected to a source of potential to form a circuit for establishing a current flow through said carbon; and an electrical indicating means electrically connected to one of said apertured plates and adapted to be placed in said circuit to indicate a variation in the current flowing through said carbon.

6. Apparatus for detecting gases or vapors in the air, comprising, in combination, a plate of electrically nonc'onductive material formed with an opening passing transversely therethrough; a pair of electrically conductive apertured plates respectively located against opposite sides of said electrically non-conductive plate and covering said opening thereof; a quantity of granulated activated carbon located in said opening between and contacting said pair of electrically conductive plates and substantially filling said opening, said pair of electrically conductive, apertured plates being adapted to be connected to a source of potential to form a circuit for establishing a current flow through said carbon; and an electrical indicating means electrically connected to one of said apertured plates and adapted to be placed in said circuit to indicate a variation in the current flowing through said carbon.

7. Apparatus for detecting gases or vapors in the air, comprising, in combination, a plate of electrically nonconductive material formed with an opening passing transversely therethrough and being formed with a bore extending from an edge of said plate to said opening; a pair of electrically conductive, apertured plates respectively located against opposite sides of said electrically non-conductive plate and covering said opening thereof; a quantity of granulated activated carbon located in said opening between and substantially bridging in mass-like form said pair of electrically conductive plates, said pair of electrically conductive, apertured plates being adapted to be connected to a source of potential to form a circuit for establishing a current flow through said carbon; a cover located over said bore so that said opening may be supplied with said carbon through said bore when said cover is removed; and an electrical indicating means electrically connected to one of said apertured plates and adapted to be placed in said circuit to indicate a variation in the current flowing through said carbon.

8. Apparatu for detecting gases or vapors in the air, comprising, in combination, a plate of electrically nonconductive material formed with a triangular opening passing transversely therethrough; a pair of electrically conductive, apertured plates respectively located against opposite sides of said electrically non-conductive plate and covering said opening thereof; a quantity of granulated activated carbon located in said opening between and substantially bridging in mass-like form said pair of electrically conductive plates, said pair of electrically conductive, apertured plates being adapted to be connected to a source of potential to form a circuit for establishing a current flow through said carbon; and an electrical indicating means electrically connected to one of said apertured plates and adapted to be placed in said circuit to indicate a variation in the current flowing through said carbon.

9. Apparatus for detecting gases or vapors in the air, comprising, in combination, a plate of electrically nonconductive material formed with a triangular opening passing transversely therethrough; a pair of electrically conductive, apertured plates respectively located against opposite sides of said electrically non-conductive plate and covering said opening thereof; a quantity of granulated activated carbon located in said opening between and substantially bridging in mass-like form said pair of electrically conductive plates, said pair of electrically conductive, apertured plates being adapted to be connected to a source of potential to form a circuit for establishing a current flow through said carbon; an electrical indicating means electrically connected to one of said apertured plates and adapted to be placed in said circuit to indicate a variation in the current flowing through said carbon; and support means supporting said plates in a substantially vertical position.

10. Apparatus for detecting gases or vapors in the air, comprising, in combination, a plate of electrically nonconductive material formed with a triangular opening passing transversely therethrough; a pair of electrically conductive, apertured plates respectively located against opposite sides of said electrically non-conductive plate and covering said opening thereof; a quantity of granulated activated carbon located in said opening between and substantially bridging in mass-like form said pair of electrically conductive plates, said pair of electrically conductive, apertured plates being adapted to be connected to a source of potential to form a circuit for establishing a current flow through said carbon; an electrical indicating means electrically connected to one of said apertured plates and adapted to be placed in said circuit to indicate a variation in the current flowing through said carbon;

and support means supporting said plates in a substantially vertical position with the base of said triangular opening located at the topmost part thereof.

11. Apparatus for detecting gases or vapors in the air, comprising, in combination, a plate of electrically nonconductive material formed with a triangular opening passing transversely therethrough; a pair of electrically conductive, apertured plates respectively located against opposite sides of said electrically non-conductive plate and covering said opening thereof; a quantity of granulated activated carbon located in said opening between and substantially bridging in mass-like form said pair of electrically conductive plates, said pair of electrically conductive, apertured plates being adapted to be connected to a source of potential to form a circuit for establishing a current flow through said carbon; an electrical indicating means electrically connected to one of said apertured plates and adapted to be placed in said circuit to indicate a variation in the current flowing through said carbon; and resilient support means resiliently supporting said plates in a substantially vertical position.

12. Apparatus for detecting gases or vapors in the air, comprising, in combination, a plate of electrically nonconductive material formed with a triangular opening passing transversely therethrough; a pair of electrically conductive, apertured plates respectively located against opposite sides of said electrically non-conductive plate and covering said opening thereof; a quantity of granulated activated carbon located in said opening between and substantially bridging in mass-like form said pair of electrically conductive plates, said pair of electrically conductive, apertured plates being adapted to be connected to a source of potential to form a circuit for establishing a current flow through said carbon; an electrical indicating means electrically connected to one of said apertured plates and adapted to be placed in said circuit to indicate a variation in the current flowing through said carbon; a frame located about and being spaced from said plates; and a plurality of springs carried by said frame, being connected to said plates, and yieldably supporting the latter in a substantially vertical position.

13. Apparatus for detecting gases or vapors in the air, comprising, in combination, a first plate of electrically nonconductive material formed with an opening passing transversely therethrough; a pair of second, apertured plates respectively located against opposite sides of said first plate and covering said opening thereof, said second plates having opposite electrical conductive portions located over only a part of said opening; a quantity of granulated activated carbon located in said opening between said pair of second plates substantially bridging in electrically conductive outer tube coaxial with said inner tube, located about the latter, and being spaced therefrom to define an annular cylindrical space therewith; an annular ring member of electrically non-conductive material located in said annular space between said tubes at one end of the latter to form a bottom wall for said annular space; an electrically non-conductive cover located on said tubes over said annularspace at the end of said tubes distant from said bottom wall; granulated activated carbon located in and substantially filling said annular space; and a pair of electrical leads extending respectively from said inner and outer tubular members so that an electrical circuit may be completed through said carbon to determine variations in current flowing through said carbon.

15. Apparatus for detecting gases or vapors in the air, comprising, in combination, an elongated, apertured, electrically conductive inner tube; an elongated apertured, electrically conductive outer tube coaxial with said inner tube, located about the latter, andbeing spaced therefrom to define an annular cylindrical space therewith; an annular ring member of electrically non-conductive material located in said annular space between said tubes at one end of the latter to form a bottom wall for said annular space; an electrically non-conductive cover located on said tubes over said annular space at the end of said tubes distant from said bottom wall; granulated activated carbon located in and substantially filling said annular space; a pair of electrical leads extending respectively from said inner and outer tubular members so that an electrical circuit may be completed through said carbon to determine variations in current flowing through said carbon; and a plurality of electrically non-conductive plates extending substantially radially from the axis of said tubes and being located in said annular space and extending along the length thereof in a direction substantially parallel to said axis to divide said annular space a plurality of cells insulated from each other by said plates.

16. Apparatus for detecting gases or vapors in the air, comprising, in combination, a porous container; electrically conductive coating portions insulated from each other and located at spaced parts of said'container on the interior thereof; a quantity of granulated activated carbon located in said container substantially bridging in masslike form said coating portions, said coating portions being adapted to be connected to a source of potential to form a circuit for establishing a current flow through said carbon; and electrical indicating means connected electrically to one of said portions and adapted to be placed in saidcircuit to indicate a variation in the current flowing through said carbon.

17. Apparatus for detecting gases or vapors in the air,

comprising, in combination, a resilient support means; an electrically non-conductive plate formed with an opening extending transversely thcrethrough and being carried in a substantially vertical position by said resilient support means; a pair of cover members respectively located against opposite sides of said plates over said opening thereof and having aperturecl, electrically conductive portions extending almost up to the top of said opening; granulated activated carbon located in and substantially filling said opening, said electrically conductive portions being adapted to be connected to a source of potential to form a circuit for establishing a current flow through said carbon; and an electrical indicating means connected electrically to one of said portions and adapted to be placed in said circiut to indicate variations in the current flowing through said carbon. 4

.18. Apparatus for detecting gases or vapors in the air comprising, in combination, a quantity of granulated activated carbon; container and contact means surrounding and engaging said carbon along the depth thereof, supporting at least part of said quantity of granulated carbon in contact with the surrounding atmosphere, and electrically contacting said carbon at a pair of spaced portions thereof, said pair of spaced portions being adapted to be connected to a source of potential to form a circuit for establishing a current flow through said carbon; and electrical indicator means connected electrically to one of said portions through said contact means and adapted to be placed in said circuit for indicating a variation in the current passing through said granulated carbon.

19. Apparatus for detecting gases or vapors in the air comprising, in combination, a quantity of granulated activated carbon; means forming a pair of spaced electrically conductive portions engaging said carbon at spaced portions thereof, respectively, and forming a container surrounding and engaging said carbon along the depth thereof and supporting at least a part of said quantity of granulated carbon in contact with the surrounding atmosphere, said pair of electrically conductive portions being adapted to be connected to a source of potential to form a circuit for establishing a current flow through said carbon; and an electrical indicator means electrically connected to one of said portions and adapted to be placed in said circuit for indicating a variation in the current pasing through said granulated carbon.

20. Apparatus as defined in claim 19 and wherein said granulated carbon is in the form of spherical pellets.

21. Apparatus as defined in claim 19 and wherein said granulated carbon is in the form of spherical pellets having a diameter of approximately 1.5 mm.

References Cited in the file of this patent UNITED STATES PATENTS 2,047,638 Kott July 14, 1936 2,327,060 Pollak et al Aug. 17, 1943 2,589,983, Blodgett et al. Mar. 18, 1952 FOREIGN PATENTS 25,046 Great Britain 1913 134,243 Great Britain Nov. 6, 1919 963,759 France July 20, 1950

Claims

1. APPARATUS FOR DETECTING GASES OR VAPORS IN THE AIR, COMPRISING, IN COMBINATION, A QUANTITY OF GRANULATED ACTIVATED CARBON; CONTAINER MEANS SURROUNDING AND ENGAGING SAID CARBON ALONG THE DEPTH THEREOF AND SUPPORTING AT LEAST A PART OF SAID QUANTITY OF GRANULATED CARBON IN CONTACT WITH THE SURROUNDING ATMOSPHERE SAID CONTAINER BEING AT LEAST FILLED BY SAID CARBON, SAID CONTAINER MEANS INCLUDING A PAIR OF ELECTRICALLY CONDUCTIVE WALL PORTIONS SPACED AND INSULATED FROM EACH OTHER AND CONTACTING SAID CARBON THE LATTER SUBSTANTIALLY BRIDGING SAID ELECTRICALLY CONDUCTIVE WALL PORTIONS IN MASS-LIKE FORM, SAID PAIR OF WALL PORTIONS BEING ADAPTED TO BE CONNECTED TO A SOURCE OF POTENTIAL TO FORM A CIRCUIT FOR ESTABLISHING A CURRENT FLOW THROUGH SAID CARBON; AND ELECTRICAL INDICATOR MEANS CONNECTED ELECTRICALLY TO ONE OF SAID WALL PORTIONS AND ADAPTED TO BE PLACED IN SAID CIRCUIT FOR INDICATING A VARIATION IN THE CURRENT PASSING THROUGH SAID GRANULATED CARBON.