US2701783A - Process for the production of a high quality lube oil - Google Patents

Process for the production of a high quality lube oil Download PDF

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US2701783A
US2701783A US273642A US27364252A US2701783A US 2701783 A US2701783 A US 2701783A US 273642 A US273642 A US 273642A US 27364252 A US27364252 A US 27364252A US 2701783 A US2701783 A US 2701783A
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zone
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phenol
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Robert B Long
Walter M Basch
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Standard Oil Development Co
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G21/00Refining of hydrocarbon oils, in the absence of hydrogen, by extraction with selective solvents
    • C10G21/06Refining of hydrocarbon oils, in the absence of hydrogen, by extraction with selective solvents characterised by the solvent used
    • C10G21/08Inorganic compounds only

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  • the present invention is concerned with an improved process for the production of high quality lubricating oils.
  • the invention is more particularly directed toward an improved liquid-liquid contacting process wherein solvents having a preferential selectivity for the more aromatic type constituents are utilized for the treatment of lubricating oil fractions.
  • solvents of this character as for example phenol, are utilized in conjunction with a relatively small amount of ammonia whereby lubricating oils having a very low acidic content are produced.
  • solvents having a preferential selectivity for the more aromatic type of hydrocarbon constituents as compared to the more paralfinic type hydrocarbon constituents are for example, phenols, furfural, sulfur dioxide, nitrobenzene, aniline, cresols, chlorex, dimethylformamide, dipropiomtriles, ammonia, amines, etc. It is also known in the art to use in conjunction with these aromatic type solvents, solvent-modifying agents as for example, water, alcohols, esters and the like. Temperatures usually employed in the treating operation are in the range from 40 F. to 250 F., while the solvent to oil ratios are in the range from about 0.4 to 10 volume of solvent per volume of oil. These operations have been carried out either in batch or in countercurrent treating zone processes.
  • the neutralization number is an indication of the quantity of acidic materials present, usuallynaphthemc acids and related compounds.
  • the naphthenic aclds are very undesirable in a lubricating oil since under operating conditions of high temperatures and pressures they tend to cause excessive corrosion and sludgmg 1n the engine. Manufacturing experience has shown that a satisfactory viscosity index is about 60. However, when extracting distillate fractions (secured from Coastal crudes) boiling in the lubricating oil boiling range with phenol to this viscosity index, the neutralization number is about .2. This is not a satisfactory lubricating oil product for the reasons given.
  • the lubricating feed oils from these sources have neutralization numbers of about .7 and above.
  • lubricating oil fractions having a neutralization number above about 0.5 particularly above about 0.7, are contacted HIGH l with an aromatic type solvent preferably phenol.
  • an aromatic type solvent preferably phenol.
  • an amount of ammonia below about 1%, preferably below about 0.5% based upon the oil.
  • concentration of ammonia is 0.1 to 0.4% by volume based upon the oil.
  • the ammonia and phenol are handled in a distinct way to secure an efficient operation producing a high quality product.
  • FIG. 1 illustrates a single tower operation
  • Figure 2 illustrates an embodiment of the invention wherein a pretreat of the oil is carried out using a small amount of an ammoniaphenol solvent.
  • a lubricating oil fraction having a neutralization number above about 0.5 is introduced into the bottom of countercurrent treating zone 1 by means of line 2.
  • An aromatic acid type solvent preferably a phenol
  • ammonia is introduced into treating zone 1 at a point below the point of introduction of phenol by means of line 3.
  • the quantity of phenol used for purposes of illustration is in the range from about 0.4 to 1 volume of phenol per volume of oil.
  • the amount of ammonia used is below about 1% by volume, preferably below about 0.5 based upon the volume of oil feed, and most preferably in the range of from 0.1% to 0.4% based upon the volume of oil feed.
  • the ammonia may be added as ammonium hydroxide.
  • Temperature conditions in the countercurrent treating tower are in the range from about F. to 250 F. It is preferred that the top temperature be m the range from about F. to 250 F., while the temperature at the bottom of the tower be in the range from about 110 F. to 210 F.
  • a raffinate phase comprising phenol and parafiinic type constituents is removed overhead from zone 1 by means of line 4 and passed to a distillation zone 5.
  • Temperature and pressure conditions in distillation zone 5 are adapted to remove overhead by means of line 6 phenol which is preferably recycled to line 40.
  • a high quality lubricating oil product of a satisfactory neutralization number is removed from the bottom of distillation zone 5 by means of line 8.
  • a solvent extract phase is removed from the bottom of extraction zone 1 by means of line 9 and passed to an initial distillation zone 10. Temperature and pressure conditions in zone 10 are adapted to remove overhead by means of line 3 ammonia which is recycled to zone 1 as hereinbefore described. Fresh ammonia may be added to the system by means of line 11.
  • a solvent extract phase free of ammonia is removed from the bottom of distillation zone 10 by means of line 12 and introduced into a second distillation zone 13. Temperature and pressure'conditions in zone 13 are adapted to remove overhead by means of line 14 the phenol which is preferably recycled to the system by means of line 40. A solvent free extract oil is removed by means of line 15 and handled or further refined as desired. It is to be understood that zones 1, 5, 10 and 13 may comprise any suitable number and arrangement of stages.
  • a feed oil similar to that utilized with respect to the description of Figure 1 is introduced into solvent treating zone 20 by means of line 21.
  • the oil flowsupwardly in zone 20 and countercurrently contacts a downfiowing solvent mixture comprising ammonia and phenol which is introduced into the top of zone 20 by means of line 22.
  • the amount of solvent mixture utilized per volume of oil is in the range from about 0.2 to 1, preferably in the range from about 0.4 to 0.6.
  • the solvent mixture per se preferably comprises from 0.2 to 0.4% ammonia based upon the volume of oil.
  • Temperature conditions are preferably in the range from about 110 F. to F. at atmospheric pressure to 20 p. s. i. g.
  • the treated raflinate phase comprising phenol and oil, and free of naphthenic and related acidic materials is removed overhead from zone 20 by means of line 42.
  • This raifinate phase is introduced into the bottom of a second treating zone 23.
  • zone 23 the oil flows upwardly and countercurrently contacts additional downfiowing phenol which is introduced into the top of zone 23 by means of line 24.
  • Treating conditions in zone 23 are the same as in zone 1 of Figure 1 without further addition of ammonia.
  • the ratfinate phase is removed overhead from zone 23 by means of line 25 and passed to distillation zone 26. Temperature and pressure conditions in zone 26 are adapted to remove overhead by means of line 27 phenol which is preferably recycled to zone 23 by means of line 24. A high quality lubricating oil fraction of a satisfactory neutralization number is removed from the bottom of distillation zone 26 by means of line 28. A solvent extract phase is removed from the bottom of zone 23 by means of line 29 and passed to distillation zone 30. Temperature and pressure conditions in zone 30 are adapted to remove overhead by means of line 31 phenol which is preferably recycled to zone 23. An extract phase free of solvent is removed from the bottom of zone 30 by means of line 32 and may be further refined or handled as desired.
  • the solvent extract phase comprising naphthenic or equivalent salts, phenol and ammonia, is removed from the bottom of zone 20 by means of line 33 and passed to distillation zone 34. Temperature and pressure conditions in zone 34 are adapted to remove overhead by means of line 35 ammonia which is preferably recycled to zone 20 by means of line 22.
  • An extract phase comprising naphthenic acid salts is removed from the bottom of zone 34 by means of line 36 and passed to distillation zone 37 wherein temperature and pressure conditions are adapted to remove overhead by means of line 38 phenol which is preferably recycled to zone 20 by means of line 22.
  • An oil phase comprising a high concentration of naphthenic acids and their salts is removed from the bottom of zone 37 by means of line 39. This stream is rich in naphthenic and equivalent acids and may be processed and handled as desired to segregate the same.
  • the present invention is broadly concerned with the treatment of lubricating oil feed fractions, particularly those lubricating oil feed fractions having a high acidic content with an aromatic type solvent and using in conjunction therewith a relatively low concentration of ammonia.
  • the invention is particularly applicable to the treatment of feed oils (Coastal and Colombian type distillates) having a neutralization number in excess of 0.5, preferably above about .7 in the range of 1.0 to 3.0 to make high yields of treated oil, e. g., greater than 70% of feed.
  • the amount of ammonia utilized should be below about 1% by volume, preferably below about 0.5% by volume in the range of about .l% to .4% based upon the oil.
  • Example 1 A lubricating oil fraction of the following specifications:
  • Phenol Phenol Solvent (1.0% gig 3? water) Ammonia) Temperature, F 130 130 Solvent Treat, Vol. Percent on Oil 100 100 Ratfinatc Yield, Vol. Percent by R. I .r 77 77 Solubility of oil in Extract Phase, Vol. Percent. 21 21 Solubility of Solvent in Rafi. Phase, Vol. Percent 13 13 Raflinate Quality:
  • Example 2 A feed oil having the following inspections:
  • Example 3 A feed oil having the following inspections:
  • Process for the production of a high quality lubricating oil product having a low neutralization number from a feed oil having a relatively high neutralization number which comprises contacting said feed oil with a solvent having a preferential selectivity for the more aromatic type 85 constituents as compared to the more parafiinic type constituents and using in conjunction with said solvent from about 0.2 to 0.4 volume of ammonia based upon the amount of feed oil, separating a raflinate phase and re covering said high quality lubricating oil product therefrom.
  • Process for the production of a high quality lubricating oil product having a low neutralization number from a feed oil having a relatively high neutralization number which comprises introducing said feed oil into the bottom of a countercurrent treating zone.
  • a solvent having a preferential selectivity for the more aromatic type constituents as compared to the more parafiinic typc constituents into the top of said countercurrent treating zone, introducing into said zone at a point intermediate the point of introduction of said oil and said solvent-from about 0.2 to 0.4 volume of ammonia based upon the amount of feed oil, removing from the top of said zone a rafiinate phase comprising oil and solvent, separating from said rafimate phase the solvent to secure a high quality lubricating oil having a relatively low neutralization number.
  • Process for the production of a high quality lubricating oil of a low neutralization number which comprises contacting a feed oil having a relatively high neutralization number in an initial solvent treating zone with a relatively small quantity of a solvent mixture comprising a solvent having a preferential selectivity for the more aromatic type constituents as compared to the more parafiinic type constituents and from about 0.2 to 0.4 volume of ammonia based upon the amount of feed oil, separating a rafiinate phase free of ammonia from said initial zone and contacting the same in a secondary treating zone with additional quantities of a solvent having a preferential selectivity for the more aromatic type constituents as compared to the more paraffinic type constituents, separating a rafiinate phase from said secondary treating zone and removing the solvent therefrom to produce a lubricating oil fraction of a low neutralization number.

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Description

' Feb.'8, 19.55 I R. 5. LONG El AL 2,701,783 1 PROCESS FOR THE PRODUCTION oF' A HIGHQUALITY LUBE OIL Filed Fb. .27; 1952.
PHeNoL PHENQL mam-1 NHEJDHEINQL .4'2. 5i
. I PHEJJQL Y 7 "2i v S55 NH? 8 5 5 W v o H 6H I'L Aims mlteum Emach.
United States Patent PROCESS FOR THE PRODUCTION OF A QUALITY LUBE OIL Robert B. Long, Wanamassa, and Walter M. Busch, Rumson, N. 1., assignors to Standard Oil Development Company, a corporation of Delaware Application February 27, 1952, Serial No. 273,642
8 Claims. (Cl. 19614.12)
The present invention is concerned with an improved process for the production of high quality lubricating oils. The invention is more particularly directed toward an improved liquid-liquid contacting process wherein solvents having a preferential selectivity for the more aromatic type constituents are utilized for the treatment of lubricating oil fractions. In accordance with the present invention, solvents of this character, as for example phenol, are utilized in conjunction with a relatively small amount of ammonia whereby lubricating oils having a very low acidic content are produced.
It is well known in the art to contact hydrocarbon fractions with solvents having a preferential selectivity for the more aromatic type of hydrocarbon constituents as compared to the more paralfinic type hydrocarbon constituents. Solvents of this character are for example, phenols, furfural, sulfur dioxide, nitrobenzene, aniline, cresols, chlorex, dimethylformamide, dipropiomtriles, ammonia, amines, etc. It is also known in the art to use in conjunction with these aromatic type solvents, solvent-modifying agents as for example, water, alcohols, esters and the like. Temperatures usually employed in the treating operation are in the range from 40 F. to 250 F., while the solvent to oil ratios are in the range from about 0.4 to 10 volume of solvent per volume of oil. These operations have been carried out either in batch or in countercurrent treating zone processes.
While the solvent treating operations, as described and known in the art, have been entirely satisfactory for improving the viscosity index and other critical factors of most lubricating oil fractions by the removal of aromatic type constituents, certain difiiculties have been encountered when the feed oil has a relatively high neutralization number. Phenol, for example, will not produce a satisfactory treated oil with a satisfactory neutralization number unless an excessive amount of the solvent be employed. This results in lower yields of treated oil having excessively good quality in all properties other than neutralization number. Normally, it is considered that a satisfactory lubricating oil should have a neutralization number not in excess of about 0.1 (acidity as measured in mg. KOH per gr. oil).
The neutralization number is an indication of the quantity of acidic materials present, usuallynaphthemc acids and related compounds. The naphthenic aclds are very undesirable in a lubricating oil since under operating conditions of high temperatures and pressures they tend to cause excessive corrosion and sludgmg 1n the engine. Manufacturing experience has shown that a satisfactory viscosity index is about 60. However, when extracting distillate fractions (secured from Coastal crudes) boiling in the lubricating oil boiling range with phenol to this viscosity index, the neutralization number is about .2. This is not a satisfactory lubricating oil product for the reasons given. The lubricating feed oils from these sources have neutralization numbers of about .7 and above.
In accordance with the present invention, lubricating oil fractions, having a neutralization number above about 0.5 particularly above about 0.7, are contacted HIGH l with an aromatic type solvent preferably phenol. In accordance with the present invention there is used in conjunction with the phenol or equivalent solvent, an amount of ammonia below about 1%, preferably below about 0.5% based upon the oil. The preferred range of concentration of ammonia is 0.1 to 0.4% by volume based upon the oil. In accordance with the present invention, the ammonia and phenol are handled in a distinct way to secure an efficient operation producing a high quality product.
The process of the present invention may be readily 2,701,783 Patented Feb. 8, 1955 understood by reference to the attached drawing illustrating embodiments of the same. Figure 1 illustrates a single tower operation, while. Figure 2 illustrates an embodiment of the invention wherein a pretreat of the oil is carried out using a small amount of an ammoniaphenol solvent.
Referring specifically to Figure l, a lubricating oil fraction having a neutralization number above about 0.5 is introduced into the bottom of countercurrent treating zone 1 by means of line 2. An aromatic acid type solvent, preferably a phenol, is introduced into the top of countercurrent treating zone 1 by means of line 40, In accordance with a preferred adaptation of the invention, ammonia is introduced into treating zone 1 at a point below the point of introduction of phenol by means of line 3. The quantity of phenol used for purposes of illustration is in the range from about 0.4 to 1 volume of phenol per volume of oil. The amount of ammonia used is below about 1% by volume, preferably below about 0.5 based upon the volume of oil feed, and most preferably in the range of from 0.1% to 0.4% based upon the volume of oil feed. It is to be understood that the ammonia may be added as ammonium hydroxide. Temperature conditions in the countercurrent treating tower are in the range from about F. to 250 F. It is preferredthat the top temperature be m the range from about F. to 250 F., while the temperature at the bottom of the tower be in the range from about 110 F. to 210 F. A raffinate phase comprising phenol and parafiinic type constituents is removed overhead from zone 1 by means of line 4 and passed to a distillation zone 5. Temperature and pressure conditions in distillation zone 5 are adapted to remove overhead by means of line 6 phenol which is preferably recycled to line 40. A high quality lubricating oil product of a satisfactory neutralization number is removed from the bottom of distillation zone 5 by means of line 8.
A solvent extract phase is removed from the bottom of extraction zone 1 by means of line 9 and passed to an initial distillation zone 10. Temperature and pressure conditions in zone 10 are adapted to remove overhead by means of line 3 ammonia which is recycled to zone 1 as hereinbefore described. Fresh ammonia may be added to the system by means of line 11.
A solvent extract phase free of ammonia is removed from the bottom of distillation zone 10 by means of line 12 and introduced into a second distillation zone 13. Temperature and pressure'conditions in zone 13 are adapted to remove overhead by means of line 14 the phenol which is preferably recycled to the system by means of line 40. A solvent free extract oil is removed by means of line 15 and handled or further refined as desired. It is to be understood that zones 1, 5, 10 and 13 may comprise any suitable number and arrangement of stages.
Referring specifically to Figure 2, a feed oil similar to that utilized with respect to the description of Figure 1 is introduced into solvent treating zone 20 by means of line 21. The oil flowsupwardly in zone 20 and countercurrently contacts a downfiowing solvent mixture comprising ammonia and phenol which is introduced into the top of zone 20 by means of line 22. When utilizing this pretreatment, the amount of solvent mixture utilized per volume of oil is in the range from about 0.2 to 1, preferably in the range from about 0.4 to 0.6. The solvent mixture per se preferably comprises from 0.2 to 0.4% ammonia based upon the volume of oil. Temperature conditions are preferably in the range from about 110 F. to F. at atmospheric pressure to 20 p. s. i. g.
The treated raflinate phase comprising phenol and oil, and free of naphthenic and related acidic materials is removed overhead from zone 20 by means of line 42. This raifinate phase is introduced into the bottom of a second treating zone 23. In zone 23 the oil flows upwardly and countercurrently contacts additional downfiowing phenol which is introduced into the top of zone 23 by means of line 24. Treating conditions in zone 23 are the same as in zone 1 of Figure 1 without further addition of ammonia.
The ratfinate phase is removed overhead from zone 23 by means of line 25 and passed to distillation zone 26. Temperature and pressure conditions in zone 26 are adapted to remove overhead by means of line 27 phenol which is preferably recycled to zone 23 by means of line 24. A high quality lubricating oil fraction of a satisfactory neutralization number is removed from the bottom of distillation zone 26 by means of line 28. A solvent extract phase is removed from the bottom of zone 23 by means of line 29 and passed to distillation zone 30. Temperature and pressure conditions in zone 30 are adapted to remove overhead by means of line 31 phenol which is preferably recycled to zone 23. An extract phase free of solvent is removed from the bottom of zone 30 by means of line 32 and may be further refined or handled as desired.
The solvent extract phase comprising naphthenic or equivalent salts, phenol and ammonia, is removed from the bottom of zone 20 by means of line 33 and passed to distillation zone 34. Temperature and pressure conditions in zone 34 are adapted to remove overhead by means of line 35 ammonia which is preferably recycled to zone 20 by means of line 22. An extract phase comprising naphthenic acid salts is removed from the bottom of zone 34 by means of line 36 and passed to distillation zone 37 wherein temperature and pressure conditions are adapted to remove overhead by means of line 38 phenol which is preferably recycled to zone 20 by means of line 22. An oil phase comprising a high concentration of naphthenic acids and their salts is removed from the bottom of zone 37 by means of line 39. This stream is rich in naphthenic and equivalent acids and may be processed and handled as desired to segregate the same.
The present invention is broadly concerned with the treatment of lubricating oil feed fractions, particularly those lubricating oil feed fractions having a high acidic content with an aromatic type solvent and using in conjunction therewith a relatively low concentration of ammonia. The invention is particularly applicable to the treatment of feed oils (Coastal and Colombian type distillates) having a neutralization number in excess of 0.5, preferably above about .7 in the range of 1.0 to 3.0 to make high yields of treated oil, e. g., greater than 70% of feed. As pointed out heretofore, the amount of ammonia utilized should be below about 1% by volume, preferably below about 0.5% by volume in the range of about .l% to .4% based upon the oil.
The process of the present invention may be more flully understood by the following examples illustrating t e same.
Example 1 A lubricating oil fraction of the following specifications:
Feed stock Refractive index (R. I.) at 20 C 1.5022
Aniline point, F 180 Spec. gravity at 60 F 0.9144
Vis. at 100 F. SUS 285 Vis. at 210 F. SUS 47.0
Pour, F -30 Neut. No., mgs. KOI-I/gtn. oil 1.44
was contacted with phenol containing 1% water and with phenol containing 0.9 weight per cent of ammonia in single stage batch treats.
The results of these operations are as follows:
Phenol Phenol Solvent (1.0% gig 3? water) Ammonia) Temperature, F 130 130 Solvent Treat, Vol. Percent on Oil 100 100 Ratfinatc Yield, Vol. Percent by R. I .r 77 77 Solubility of oil in Extract Phase, Vol. Percent. 21 21 Solubility of Solvent in Rafi. Phase, Vol. Percent 13 13 Raflinate Quality:
R. I. at 20 C 1. 4940 1.4942 Aniline Point, F 191 193 Spec Gravity at 60 F-.. 0. 9019 0. 9011 V15 at 100 F SUS Vis at 210 F SUS-... Pour, F Neut. No., mgs. KOH/gm Extract Quality:
R. I. at 20 1, 5292 1.5289 Spec. Gravity at 60 F 0. 9581 0. 9566 From the above it is apparent that in a single stage the ammonia produced 21 treated oil of appreciably lower neutralization number.
Example 2 A feed oil having the following inspections:
Feed inspections was contacted countercurrently with a phenol solvent with and without ammonia using the same number of stages in both cases. The results of these operations are as follows:
Stages 19 19 Treat, Vol. Percent on Oil 89 87 Water, Percent on Phenol 9. 8 9. 8+0. 2 Wt. Percent N Br. Water in]. Percent on Phenol--- 2. 1 1. 6 Yield, V0 Percent (Grav.) 82. 9 80.1 Raflinate Inspections:
Gravity at 60 F., API. 24.9 25. 0 R. I. at 20 C 1.4982 1.4979 Neut No., mgs. KOH/gm... .13 0.03 0010 T. R 1% 1% We at 100 F SSU 354 374 Via at 210 F SSU 51.6 52.2 Viscosity Index. 63 61 Extract Inspections:
Gravity at 60 F., APL 6. 4 8.4 R. I. at 20 C 1. 5754 1. 5681 From the above it is apparent that the 0.03 neutralization number represents an excellent quality oil and meets the requlrements of 0.1 maximum, whereas the run without ammonia does not meet the desired requirement.
Example 3 A feed oil having the following inspections:
was countercurrently phenol extracted with and without ammonia and then clay contacted. The results of these operations are as follows:
Phenol Extractton+ Clay Contacting Processing Method Without 0.1% NH; N H: in Solvent Extraction data:
Treat, Vol. Percent 81 91 Rafl. Yield, Vol. Pereen 88 86 Color, '1. R 2% 3% Neut. No. mgs. KGB/gm-.- 0.23 0.11 Super Filtrol used, gal o. 3 o. 3 Finished Oil Yield, 01. Percent" 83 Finished Oil Quality:
Neut. No., mgs. KOH/ 0.10 0.03 Bligh No., SD 37 40 In lane Lite, 1111.. 40 30 Color, T. R 10% 11% Color Hold (16 Hrs. at 210 F.) TR 10 9 10 From the above it is apparent that a feed oil having a neutralization number of 1.15 was satisfactorily solvent treated in accordance with the present invention to secure 3 satisfactory product having a neutralization number of What is claimed is:
1. Process for the production of a high quality lubricating oil product having a low neutralization number from a feed oil having a relatively high neutralization number which comprises contacting said feed oil with a solvent having a preferential selectivity for the more aromatic type 85 constituents as compared to the more parafiinic type constituents and using in conjunction with said solvent from about 0.2 to 0.4 volume of ammonia based upon the amount of feed oil, separating a raflinate phase and re covering said high quality lubricating oil product therefrom.
2. Process as defined by claim 1 wherein said solvent comprises a phenol.
3. Process as defined by claim 1 wherein said feed oil has a neutralization number above about .5.
4. Process as defined by claim 1 wherein said feed oil has sat neutralization number in the range from about lto 5. Process for the production of a high quality lubricating oil product having a low neutralization number from a feed oil having a relatively high neutralization number which comprises introducing said feed oil into the bottom of a countercurrent treating zone. introducing a solvent having a preferential selectivity for the more aromatic type constituents as compared to the more parafiinic typc constituents into the top of said countercurrent treating zone, introducing into said zone at a point intermediate the point of introduction of said oil and said solvent-from about 0.2 to 0.4 volume of ammonia based upon the amount of feed oil, removing from the top of said zone a rafiinate phase comprising oil and solvent, separating from said rafimate phase the solvent to secure a high quality lubricating oil having a relatively low neutralization number.
6. Process as defined by claim 5 wherein the feed oil is characterized by having a neutralization number in the range from about 1 to 3.
7. Process for the production of a high quality lubricating oil of a low neutralization number which comprises contacting a feed oil having a relatively high neutralization number in an initial solvent treating zone with a relatively small quantity of a solvent mixture comprising a solvent having a preferential selectivity for the more aromatic type constituents as compared to the more parafiinic type constituents and from about 0.2 to 0.4 volume of ammonia based upon the amount of feed oil, separating a rafiinate phase free of ammonia from said initial zone and contacting the same in a secondary treating zone with additional quantities of a solvent having a preferential selectivity for the more aromatic type constituents as compared to the more paraffinic type constituents, separating a rafiinate phase from said secondary treating zone and removing the solvent therefrom to produce a lubricating oil fraction of a low neutralization number.
8. Process as defined by claim 7 wherein the neutralization number of the feed oil to said initial stage is above about .5%.
References Cited in the file of this patent UNlTED STATES PATENTS 2.092,l99 Arveson Sept. 7, 1937 2,270,674 Pilat et a] Jan. 20, 1942 2,346,639 Andrews et al. Apr. 18, 1944 2,424,158 Fuqua et al. July 15, 1947 2,645,596 Axe July 14, 1953

Claims (1)

1. PROCESS FOR THE PRODUCTION OF A HIGH QUALITY LUBRICATING OIL PRODUCT HAVING A LOW NEUTRALIZATION NUMBER FROM A FEED OIL HAVING A RELATIVELY HIGH NEUTRALIZATION NUMBER WHICH COMPRISES CONTACTING SAID FEED OIL WITH A SOLVENT HAVING A PREFERENTIAL SELECTIVITY FOR THE MORE AROMATIC TYPE CONSTITUENTS AS COMPARED TO THE MORE PARAFFINIC TYPE CONSTITUENTS AND USING IN CONJUNCTION WITH SAID SOLVENT FROM ABOUT 0.2 TO 0.4 VOLUME % OF AMMONIA BASED UPON THE AMOUNT OF FEED OIL, SEPARATING A RAFFINATE PHASE AND RECOVERING SAID HIGH QUALITY LUBRICATING OIL PRODUCT THEREFROM.
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Cited By (9)

* Cited by examiner, † Cited by third party
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US2772218A (en) * 1953-12-08 1956-11-27 Exxon Research Engineering Co Process for the upgrading of hydrocarbons by hydrogen-donor diluent cracking
US2846354A (en) * 1955-09-07 1958-08-05 Pure Oil Co Method of reducing corrosion and plugging of solvent extraction process equipment
US2865839A (en) * 1956-06-19 1958-12-23 Exxon Research Engineering Co Process for improving the quality of lubricating oils
US2966456A (en) * 1957-01-02 1960-12-27 Sun Oil Co Removing acids from petroleum
US2976310A (en) * 1957-05-31 1961-03-21 Monsanto Chemicals Multiple step continuous contacting of immiscible substances
US4589979A (en) * 1985-08-22 1986-05-20 Nalco Chemical Company Upgrading heavy gas oils
US4752381A (en) * 1987-05-18 1988-06-21 Nalco Chemical Company Upgrading petroleum and petroleum fractions
US4758672A (en) * 1987-05-18 1988-07-19 Nalco Chemical Company Process for preparing naphthenic acid 1,2-imidazolines
US4827033A (en) * 1987-05-18 1989-05-02 Nalco Chemical Company naphthenic acid amides

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