US2668109A - Machinable titanium base tellurium alloy - Google Patents

Machinable titanium base tellurium alloy Download PDF

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Publication number
US2668109A
US2668109A US289005A US28900552A US2668109A US 2668109 A US2668109 A US 2668109A US 289005 A US289005 A US 289005A US 28900552 A US28900552 A US 28900552A US 2668109 A US2668109 A US 2668109A
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United States
Prior art keywords
titanium
alloys
machinable
machinability
titanium base
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Expired - Lifetime
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US289005A
Inventor
Harry P Croft
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Kennecott Corp
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Kennecott Copper Corp
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Publication date
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Priority to US289005A priority Critical patent/US2668109A/en
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C14/00Alloys based on titanium

Definitions

  • This invention relates to titani m-base alloys and, more particularly, to titanium-base alloys characterized by good machining properties.
  • Yet another object of this invention is to provide free-machining alloys comprising titanium and tellurium.
  • this invention relates to free-machining titanium-base alloys comprising titanium, and from about 0.02% to about 0.45% tellurium, particularly alloys containing from 0.05% to0.40% tellurium.
  • tellurium as an alloying element in titanium presents substantial difiiculty because of the low boiling point and high vapor pressure of tellurium. For this reason, it is desirable to form a master alloy of titanium and tellurium to provide a relatively high-boiling point compound for subsequent addition to perature range of from 950 1 to 1000 F., the tellurium reacts exothermally with the tirms, Conn.,-assignorto Copper Corporation,
  • taniumproducing compounds having a metallic appearance. These compounds, or master alloys, may then be used in preparing titanium-lick luriumalloys of any desired composition.
  • titanium used in preparing the alloys of the present invention may be produced by either the magnesium-reduction method or by the iodide process, or in any other way, and may contain small amounts of impurities, such as carbon, iron, and nitrogen.
  • a titanium-base alloy consisting essentially of from .02% to .45% tellurium, balance titanium, characterized by an improved machinability of at least 104 as determined by a lathe test as compared with for an unalloyed titanium specimen.
  • a titanium-base alloy consisting essentially of from .05% to .40% tellurium, balance titanium, characterized by an improved machinability of at least 104 as determined by a lathe test as compared with 100 for an unalloyed titanium specimen.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Powder Metallurgy (AREA)

Description

Patented Feb. 2, 1954 Harry P. Croiit, Greens Fa Kennecott N. Y., a corporationof No Drawing, Application May 20', 1952," Serial No. 289.005
2 Claims.
This invention relates to titani m-base alloys and, more particularly, to titanium-base alloys characterized by good machining properties.
In the past, little has been known concerning the machinability of titanium metal and, consequently, there is practically no information relative to machinable alloys of titanium. Separate publications have compared the machinability of titanium to that of stainless steel, in one instance, and to that of free-machining stainless steel in another instance. since the machinability of stainless steel and free-machining stainless steel difier by a factor of about two, it will be apparent that the actual machinability of titanium metal is a somewhat controversial subject. In view of recent interest in titanium alloys and their applications, it has become increasingly desirable that information relative to the machinability of titanium alloys be obtained and that titanium alloys having good machining properties be developed.
It is, therefore, an object of this invention to provide alloys of titanium which are readily machinable.
It is a further object of this invention to provide free-machining alloys of titanium comprising titanium and an element having low solubility in titanium.
Yet another object of this invention is to provide free-machining alloys comprising titanium and tellurium.
Other objects and advantages of this invention will be apparent, in view of the following detailed description thereof:
In general, this invention relates to free-machining titanium-base alloys comprising titanium, and from about 0.02% to about 0.45% tellurium, particularly alloys containing from 0.05% to0.40% tellurium.
The introduction of tellurium as an alloying element in titanium presents substantial difiiculty because of the low boiling point and high vapor pressure of tellurium. For this reason, it is desirable to form a master alloy of titanium and tellurium to provide a relatively high-boiling point compound for subsequent addition to perature range of from 950 1 to 1000 F., the tellurium reacts exothermally with the tirms, Conn.,-assignorto Copper Corporation,
New York New York,
taniumproducing compounds having a metallic appearance. These compounds, or master alloys, may then be used in preparing titanium-lick luriumalloys of any desired composition.
'Ii-Te alloys of the present invention have been prepared and evaluated for machinability with results as tabulated in Table I below. Two common types of machining operations have been used in evaluating the machining properties of the present alloys. These two operations,
turning on a lathe and cutting with a saw, arebelieved to be representative machining operations and to afford a reasonable evaluation of relative machinability. Data I are reported on the basis of the machinability of unalloyed titanium as a reference. A value Avg. feed on alloy Index- 100X Av feed on standard Table I Oompositiom Percent Te i gg fi gg 1 Balance titanium.
Lathe tests reported above were made on a glnalloyed attendant loss of mechanical properties. Table II below shows that mechanical properditions of this invention:
Table II Ultimate 0.2Percent Elonge- Reduc- Vickers gggfi s'laensigiJ StYieldth tion, Pcralign of Hardreng reng cent in tea ness Percent Te p. s. i. p. s. i. l-inch Percent Number Unalloyed- 75, 400 54, 300 29 51 183 0.07 so, 600 66, 000 30 55 201 83, 200 64, 000 29 45 204 79, 200 60, 000 27 45 190 78, 600 54, 500 28 44 203 1 Balance essentially all titanium.
From Table II it is clear that the alloys of this invention possess increased tensile strength and yield strength, as compared with unalloyed titanium, and. retain excellent ductility properties without sacrifice of hardness.
It will be clear that useful alloys with increased properties of machinability and good machinability and good mechanical properties have been disclosed herein. It will be understood that the particular properties and descriptions are not intended to limit the scope of the invention but are presented for illustrative purposes only. The
titanium used in preparing the alloys of the present invention may be produced by either the magnesium-reduction method or by the iodide process, or in any other way, and may contain small amounts of impurities, such as carbon, iron, and nitrogen.
What is claimed is:
l. A titanium-base alloy consisting essentially of from .02% to .45% tellurium, balance titanium, characterized by an improved machinability of at least 104 as determined by a lathe test as compared with for an unalloyed titanium specimen.
2. A titanium-base alloy consisting essentially of from .05% to .40% tellurium, balance titanium, characterized by an improved machinability of at least 104 as determined by a lathe test as compared with 100 for an unalloyed titanium specimen. HARRY P. CROFT.
References Cited in the file of this patent Goldhofi, R. M., et a1.: TheInfluence of Insoluble Phases on Machinability of Titanium, published as ASM Preprint #30, 1952.

Claims (1)

1. A TITANIUM-BASE ALLOY CONSISTING ESSENTIALLY OF FROM .02% TO .45% TELLURIUM, BALANCE TITANIUM, CHARACTERIZED BY AN IMPROVED MACHINABILITY OF AT LEAST 104 AS DETERMINED BY A LATHE TEST AS COMPARED WITH 100 FOR AN UNALLOYED TITANIUM SPECIMEN.
US289005A 1952-05-20 1952-05-20 Machinable titanium base tellurium alloy Expired - Lifetime US2668109A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2771359A (en) * 1955-03-24 1956-11-20 Beryllium Corp Rare earth master alloys
US2797996A (en) * 1953-12-07 1957-07-02 Rem Cru Titanium Inc Titanium base alloys
US2902529A (en) * 1956-09-11 1959-09-01 Rca Corp Thermoelectric materials and elements utilizing them
EP0199198A1 (en) * 1985-04-12 1986-10-29 Daido Tokushuko Kabushiki Kaisha Free-cutting ti alloy

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
None *

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2797996A (en) * 1953-12-07 1957-07-02 Rem Cru Titanium Inc Titanium base alloys
US2771359A (en) * 1955-03-24 1956-11-20 Beryllium Corp Rare earth master alloys
US2902529A (en) * 1956-09-11 1959-09-01 Rca Corp Thermoelectric materials and elements utilizing them
EP0199198A1 (en) * 1985-04-12 1986-10-29 Daido Tokushuko Kabushiki Kaisha Free-cutting ti alloy

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