US2653883A - Combination steel and die casting cleaning process - Google Patents

Combination steel and die casting cleaning process Download PDF

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US2653883A
US2653883A US259651A US25965151A US2653883A US 2653883 A US2653883 A US 2653883A US 259651 A US259651 A US 259651A US 25965151 A US25965151 A US 25965151A US 2653883 A US2653883 A US 2653883A
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steel
container
area
die cast
articles
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US259651A
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Julius A Thomas
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Ford Motor Co
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Ford Motor Co
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Priority to US259651A priority Critical patent/US2653883A/en
Priority to DEF10229A priority patent/DE918306C/en
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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23GCLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G1/00Cleaning or pickling metallic material with solutions or molten salts

Definitions

  • This invention is concerned with the electroplating industry and more particularly with that segment of the metal finishing industry in which large numbers of similar pieces are automatically electroplated.
  • chromium plating In the automotive industry it has been found commercially desirable to protect and decorate both fabricated steel parts and zinc base die cast parts by chromium plating.
  • Conventional chromium plating involves first a flash or strike of copper followed by a heavier copper plate upon which is superimposed a nickel plate. Finally a thin flash of chromium is added to the nickelplated surface. In this plating procedure, as in all plating procedures, it is necessary that surface to be covered be meticulously cleaned before plating.
  • the ordinary zinc base die castings are usually subjected to a dip in a tank containing water or other aqueous base cleaning solution, heated to about 150 F.
  • the instant invention has been developed to enable steel and zinc die castings to be cleaned in the sam apparatus. This invention is probably best understood from a study of the attached drawing which is a vertical section taken through the length of a cooling tank.
  • a steel tank is indicated at It) and is filled to a depth of about six feet with a layer of water H.
  • a layer of kerosene [2 about one inch in thickness is floated upon the top of layer of water H.
  • Adjacent one end of this tank are located air nozzles I3. These nozzles are positioned about twelve inches beneath the level of th kerosene-water interface and are pointed upwards.
  • the water is heated to about F. and a vigorous stream of air is forced through nozzles l3. This vigorous stream of air violently agitates the end of the tank in which the nozzles I3 are located and eifectively prevents the layer of kerosene l2 from extending over that portion of the tank.
  • the kerosene in this section of the tank occurs as an emulsion scattered throughout that portion of the tank.
  • the path of the die cast parts is indicated by the lower lines and the path of the steel parts by the upper lines.
  • th path of the die cast articles may be varied if convenient, so that they leave the tank through the kerosene layer or the emulsified area.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)

Description

Se t. 29, 1953 J. A. THOMAS 2,653,883
COMBINATION STEEL AND DIE CASTING CLEANING PROCESS I Filed Dec. 3, 1951 DIE. CA5T|-6 J UL /U-S A THOMAS INVENTOR.
'fm w A TTORNEYS VBY Patented Sept. 29, 1953 COIHBINATION STEEL AN DDIE CASTING swar s R E Julius A. Thomas, Monroe, Mich., assignor to- Ford Motor Company, Deal-born, Mich., a corporation of Delaware Application December 3, 1951, Serial N 0. 259,651
3 Claims.
This invention is concerned with the electroplating industry and more particularly with that segment of the metal finishing industry in which large numbers of similar pieces are automatically electroplated.
In the automotive industry it has been found commercially desirable to protect and decorate both fabricated steel parts and zinc base die cast parts by chromium plating. Conventional chromium plating involves first a flash or strike of copper followed by a heavier copper plate upon which is superimposed a nickel plate. Finally a thin flash of chromium is added to the nickelplated surface. In this plating procedure, as in all plating procedures, it is necessary that surface to be covered be meticulously cleaned before plating. The ordinary zinc base die castings are usually subjected to a dip in a tank containing water or other aqueous base cleaning solution, heated to about 150 F. upon which is floated a layer approximately 1 inch thick, of a Water insoluble hydrocarbon or other grease solvent having a boiling point range corresponding to ordinary kerosene. This is the first step in the cleaning process and is usually followed by a dip in a heated alkali phosphate bath.
This procedure is quite satisfactory for die castings but if it be used upon fabricated steel parts, unsatisfactory results are certain to ensue. Fabricated steel parts invariably contain crevices and seams produced in th manufacturing operations and particularly in spot-welding procedures. When such a part is passed through a layer of kerosene, this material fills such crevices and it is commercially impracticable to remove this kerosene with the thoroughness necessary to produce satisfactory plated articles. In the past this difficulty has required that separate cleaning lines be employed for steel parts and die cast parts despite the obvious economy which would be effected if both types of parts could be cleaned in the same apparatus.
The instant invention has been developed to enable steel and zinc die castings to be cleaned in the sam apparatus. This invention is probably best understood from a study of the attached drawing which is a vertical section taken through the length of a cooling tank.
In this drawing a steel tank is indicated at It) and is filled to a depth of about six feet with a layer of water H. A layer of kerosene [2 about one inch in thickness is floated upon the top of layer of water H. Adjacent one end of this tank are located air nozzles I3. These nozzles are positioned about twelve inches beneath the level of th kerosene-water interface and are pointed upwards. When the tank is in operation the water is heated to about F. and a vigorous stream of air is forced through nozzles l3. This vigorous stream of air violently agitates the end of the tank in which the nozzles I3 are located and eifectively prevents the layer of kerosene l2 from extending over that portion of the tank. Instead of occurring as a separate layer, the kerosene in this section of the tank occurs as an emulsion scattered throughout that portion of the tank.
In th operation of this tank, the operator permits the die cast parts to descend into the hot water through the unbroken kerosene layer occurring in all parts of the tank remote from nozzles l3. In this way advantage is taken of the very potent grease dissolving action of hot kerosene. When steel parts are to be cleaned, the operator causes these parts to enter and leave the cleaning tank only through that part of the tank in which the layer of kerosene has been dissipated by the action of the nozzles l3. In this Way the crevices of the steel parts will fill predominantly with water rather than kerosene and only sufficient kerosene in emulsion form contacts the steel part to perform the necessary cleaning operations. In the drawing the path of the die cast parts is indicated by the lower lines and the path of the steel parts by the upper lines. However, th path of the die cast articles may be varied if convenient, so that they leave the tank through the kerosene layer or the emulsified area.
By so operating this apparatus, it is possible to simultaneously employ the same cleaning and plating line to plate steel and die cast parts and avoid the expense of individual lines.
I claim as my invention:
1. The process of cleaning steel and die cast articles in a single container comprising filling said container with an aqueous base cleaning solution upon which is floated a layer of a water insoluble grease solvent, agitating one portion of the surface area of the container sufiiciently vigorously to substantially completely dissipate the grease solvent layer over the agitated area and emulsify the grease solvent, immersing the die cast articles into the container through an unagitated area, removing the die cast articles and immersing and removing the steel articles only through the agitated area.
2. The process of cleaning steel and die cast articles in a single container comprising filling said container with an aqueous base cleaning solution upon which is floated a layer of a water insoluble grease solvent, agitating one portion of the surface area by means of air Jets sufliciently vigorously to substantially completely dissipate the grease solvent layer over the agitated area immersing die cast articles into the container through the unagitated area, removing the die cast articles and immersing and removing the steel articles only through the agitated area.
3. The process of cleaning steel and die cast articles in a single container comprising filling said container with an aqueous base cleaning solution upon which is floated a layer of water insoluble grease solvent, agitating one portion of the surface area by means of an air stream introduced about twelve inches below the surface and in a vertical direction, immersing die cast articles into the container through the unagitated area, removing the die cast articles and immersing and removing th steel articles through the agitated area.
JULIUS A. THOMAS.
References Cited in the file of this patent UNITED STATES PATENTS Number Name Date 2,389,488 Dailey Nov. 20, 1945 2,538,340 Tomek Jan. 16, 1951

Claims (1)

1. THE PROCESS OF CLEANING STEEL AND DIE CAST ARTICLES IN A SINGLE CONTAINER COMPRISING FILLING SAID CONTAINER WITH AN AQUEOUS BASE CLEANING SOLUTION UPON WHICH IS FLOATED A LAYER OF A WATER INSOLUBLE GREASE SOLVENT, AGITATING ONE PORTION OF THE SURFACE AREA OF THE CONTAINER SUFFICIENTLY VIGOROUSLY TO SUBSTANTIALLY COMPLETELY DISSIPATE THE GREASE SOLVENT LAYER OVER THE AGITATED AREA AND EMULSIFY THE GREASE SOLVENT, IMMERSING THE DIE CAST ARTICLES INTO THE CONTAINER THROUGH AN UNAGICATED AREA, REMOVING THE CAST ARTICLES AND IMMERSING AND REMOVING THE STEEL ARTICLES ONLY THROUGH THE AGITATED AREA.
US259651A 1951-12-03 1951-12-03 Combination steel and die casting cleaning process Expired - Lifetime US2653883A (en)

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US259651A US2653883A (en) 1951-12-03 1951-12-03 Combination steel and die casting cleaning process
DEF10229A DE918306C (en) 1951-12-03 1952-10-25 Process and device for joint cleaning of steel and injection molding

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US259651A US2653883A (en) 1951-12-03 1951-12-03 Combination steel and die casting cleaning process

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3000766A (en) * 1958-04-28 1961-09-19 Horizons Inc Metal cleaning process
US3094469A (en) * 1958-07-12 1963-06-18 Dehydag Gmbh Process for cleaning metal objects
US3888693A (en) * 1972-03-20 1975-06-10 Allied Chem Multi-phase rinse and recovery method
US4619706A (en) * 1985-02-28 1986-10-28 Texo Corporation Method for stripping organic coatings from substrates
US5573598A (en) * 1995-03-06 1996-11-12 Masonite Corporation Method of cleaning pressing and/or curing apparatus
US5603881A (en) * 1993-06-25 1997-02-18 Masonite Corporation Alkali metal salts as surface treatments for fiberboard

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL204775A (en) * 1955-02-24

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2389488A (en) * 1942-11-24 1945-11-20 Jr William H Dailey Method of agitation of pickling baths
US2538340A (en) * 1945-11-14 1951-01-16 Arthur O Tomek Sand scrubbing device and method

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2389488A (en) * 1942-11-24 1945-11-20 Jr William H Dailey Method of agitation of pickling baths
US2538340A (en) * 1945-11-14 1951-01-16 Arthur O Tomek Sand scrubbing device and method

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3000766A (en) * 1958-04-28 1961-09-19 Horizons Inc Metal cleaning process
US3094469A (en) * 1958-07-12 1963-06-18 Dehydag Gmbh Process for cleaning metal objects
US3888693A (en) * 1972-03-20 1975-06-10 Allied Chem Multi-phase rinse and recovery method
US4619706A (en) * 1985-02-28 1986-10-28 Texo Corporation Method for stripping organic coatings from substrates
US5603881A (en) * 1993-06-25 1997-02-18 Masonite Corporation Alkali metal salts as surface treatments for fiberboard
US5573598A (en) * 1995-03-06 1996-11-12 Masonite Corporation Method of cleaning pressing and/or curing apparatus

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Publication number Publication date
DE918306C (en) 1954-09-23

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