US2645568A - Jet fuel containing tau-butyl thiophene - Google Patents

Description

Patented July 14, 1953 NT OFFICE JET FUEL CONTAINING t-BUTYL THIOPHENE Jack M. Godsey, Wenonah, N. J assignor to S- cony-Vacuum Oil Company, Incorporated, a corporation of New York No Drawing. Application April 21, 1949, Serial No. 88,897

2 Claims. 44-453) This invention is directed to improved fuels utilizable in jet combustion devices. It is particularly directed to jet combustion fuels havingimproved jet combustion properties through the addition thereto of small amounts of an additive material. f

The simplest form of jet combustion mechanism is a tube with one end closed, in which a combustible is burned. The expanding gases of combustion issuing from the open end, of the tube give rise to a reaction effect which drives the tube in a direction opposite to that of the emission of the gases. The most complicated forms presently proposed consist of the same propulsion or jet tube, plus a compressor to supply air for combustion, plus a gas turbine which extracts enough energy from the departing gases to drive the compressor. In present commercial forms, the com pressor and turbine are assembled axially upon a common shaft, spaced far enough apart to permit a number of combustion chambers to be arranged about the shaft beween the compressor and turbine with an exhaust tube extending rearwardly from the turbine. In essence, the term jet combustion, as now commonly applied, and as used in this specification, refers to a method of combustion wherein fuel is continuously introduced into and continuously burned in a confined space for the purpose of deriving power directly from the hot products of combustion.

In practice, the range of conditions over which a jet combustion. device mayoperate may become quite limited for ill-chosen or ill-adapted fuels. Even though a combustible mixture be present, the flame will be blown out if the rate of fuel feed. is too far increased. Yet, high rates of fuel feed ar necessary to obtain high heat release,

which is high power delivery. Fuels with low blow-out levels can furnish only limited power and limited flexibility under conditions of operation; Consequently the flame stability of a fuel is ofmajor importance.

It has been found that flame stability of a fuel is correlated with a property of the fuel which is readily reproducible on a laboratory basis, using apparatus which is simple when compared to a commercial combustion tube, and with consideraably less procedural difliculty. This correlated property is the rate of flame propagation as measured in a Bunsen-type burner, using the method of Smith and Pickering (J. Res. Natl. Bur. Stds. 17, '7 (1936)). In this procedure, the rate of flame propagation is measured at a number of fuel-air ratios by photographing the flame and measuring the slope of the flame cone.

Desirable levels of commercial operability may be found in fuels having rates of flame propagation of the order of 1.4 feet per second and higher. Ben zol, an'excellent fuel, has a rate of flame propagation of about 1.6 feet per second, at a fuel mixture temperature of 230 F., a pressure of 1 atmosphere, and an air flow rate of 3.15 pounds/ hour.

The present invention is predicated upon the discovery that small amounts of a-t-butyI thiophene or of B-t-butyl thiophene or of mixtures of aand B-t-butyl thiophenes, when added to a fuel, will materially improve the combustion stability thereof. These butyl thiophenes have the following structural formulae:

a-t-butyl thiophene B-t-butyl thiophene These compounds are readily produced in accordance with known methods of the prior art. In general, in accordance with prior art processes, thiophene is alkylated with suitable alkylating agents, such as olefin and alcohols, in the presence of alkylating agents, such as sulfuric acid, dihydroxyfluoboric acid, aluminum chloride, boron trifluoride, phosphoric acid, and aluminasilica-type catalysts (Kutz et al., Journal of the American Chemical Society, 68, 1477; and Caesar, Journal of the American Chemical Society, '70, 3623 (1948) In accordance with these processes of the prior art, when thiophene is alkylated with t-butyl alcohol, in the presence of an aluminasilica-type catalyst, the reaction product is a mixture of about a-t-butyl thiophene and about 30% 'B-t-butyl thiophene.

In the practic of the present invention, the amount of additive (t-butyl thiophenes) used falls within the range varying between about 0.1% and about 2.0% by weight. Greater amounts, up to 10%, may be used if desired, although, in general, no outstanding results seem to occur. Conceivably and within the scope of the present invention, the jet fuel additives con-.

templated herein may be marketed or procured as concentrates, viz., jet combustion fuels containing upwards of 10% and up to 49% by weight of the additives. These concentrates are subsequently added to a jet combustion fuel in such proportions as to produce the effective concentration of additive in the fuel desired. 1. e., a

sufiicient amount to improve the jet combustion properties of the jet combustion fuel.

The jet combustion fuels of the present invention may contain other materials or additives for improving other characteristics thereof. Carbon deposition-reducing additives, gum inhibitors, and starting aids are mentioned by way of non-limiting examples of other additives which may be present in the jet combustion fuels of the present invention.

The addition of ocor of B-t-butyl thiophene or of mixtures thereof may be made to fuels of a fairly wide variety of boiling ranges, specific gravity, etc. Suitable base fuels for .use .in .accordance with this invention include those having the character of light gasolines up to those having the character of gas oils; synthetic fuels, such as those manufactured by the Fischer- Tropsch process, can be used, as can be fuels derived from coal or wood distillation. It is also contemplated to add these combustion improving additives to liquid alcohols .or combinations ofalcohols and other base fuels. The preferred fuel is, however, a hydrocarbon distillate fuel boiling within the range of about 100 F. toabout 600 F.

The physical characteristics of a few examples of suitable base fuels are given hereinafter for illustrative purposes:

1. Hydrocarbon distillate fuel Boiling range 105535 F. Gravity 53 A. P. I.

' Vapor pressure 5.4 Reid, pounds.

Freezing point Below -76 F. Sulfur 0.03%, by weight. Bromine No 15 Aromatics 15% by volume. Viscosity .773 centistokes,

at 100 F. 2. Reference fuel- Boiling range 205 225 F. Gravity 716' A. P. I. Vapor pressure 1.7 Reid, pounds. Freezing point Below -76 'F. Sulfur Bromine No 0 Aromatics 0 Viscosity .623 centistokes,

at 100 F. 3. Hydrocarbon distillate fuel Boiling range 320-470" F.

Gravity 36.5 A. P. .I. Freezing point Below -76 F. Sulfur 0.035%by weight. Bromine No 1 Aromatics 12.1% by volume. Viscosity 1.48 centistokes,

at 100 F.

The following examples are given for the purpose of illustrating the present invention and for indicating the advantages thereof. It must be clearly understood, however, that these examples are non-limiting. It will be appreciated by those skilled in the art that numerous types of jet combustion fuels, other than the standard reference fuel described hereinafter, may be used for the purpose contemplated herein.

In these tests areference fuel was used which was substantially 2,2,4-trimethylpentane, commonly known as S-reference fuel. The rate of flame propagation using the standard reference fuel was compared with that of a blend of the S- reference fuel with a mixture of 0.5% of at-butyl thiophene plus B-t-butyl thiophene, in accordance with the procedure of Smith and Pickering referred to vhereinbefore. In these tests, the additive was .a mixture of a-t-butyl thiophene with 40% B-t-butyl thiophene. The fuel mixture was maintained ata temperature of about 230 F.; under a pressure of 1 atmosphere, and the air flow rate was controlled It will be seen that by adding as little as 05% of the additive material to the fuel, an increase of over 5% in rate of flame propagation can be obtained, which, as indicated hereinbefore, means a substantial improvement in combustion stability.

This application is a continuation-in-part of the .copending application, Serial No. 746,325, filed on may 6, 1947, now abandoned.

Iclaim:

1. A liquid capable of being utilized as a fuel in jet combustion mechanisms, which consists essentiallyof ahydrocarbon distillate having an initial boiling point of about F. and a final boiling point of about 600 F. and boiling substantially continuously between said points, and between abouto-l and about 10.0% by weight of a t-butyl thiophene.

2. A liquid capable of being utilized as a fuel in jet combustion mechanisms, which consists essentially of 'a hydrocarbon distillate having an initial boiling point of aboutlOO F. and a final boiling pointof about 600 F. and boiling substantially continuously between said points, and between about '0.1,% and about 100 by weight of a mixture of wt-buty-l thiophene with S-t-butyl thiophene.

JACK M. GODSEY.

References Cited in the file of this patent UNITED STATES PATENTS Number Name Date 2,429,575 App'leby et al Oct. 21, 1947 2,501,124 Heath Mar. 21, 1950 2,557,019 Morris et al June 12, 1951.

Claims (1)

1. A LIQUID CAPABLE OF BEING UTILIZED AS A FUEL IN JET COMBUSTION MECHANISMS, WHICH CONSISTS ESSENTIALLY OF A HYDROCARBON DISTILLATE HAVING AN INITIAL BOILING POINT OF ABOUT 100* F. AND FINAL BOILING POINT OF ABOUT 600* F. AND BOILING SUBSTANTIALLY CONTINUOUSLY BETWEEN SAID POINTS, AND BETWEEN ABOUT 0.1% AND ABOUT 10.0% BY WEIGHT OF A T-BUTYL THIOPHENE.