US2640000A - Flameproofing method and product - Google Patents

Flameproofing method and product Download PDF

Info

Publication number
US2640000A
US2640000A US75335847A US2640000A US 2640000 A US2640000 A US 2640000A US 75335847 A US75335847 A US 75335847A US 2640000 A US2640000 A US 2640000A
Authority
US
United States
Prior art keywords
flame
chlorinated
substance
film
inorganic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
Inventor
Leslie P Seyb
Clifford A Neros
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Diamond Shamrock Corp
Original Assignee
Diamond Alkali Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Diamond Alkali Co filed Critical Diamond Alkali Co
Priority to US75335847 priority Critical patent/US2640000A/en
Application granted granted Critical
Publication of US2640000A publication Critical patent/US2640000A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/0036—Dyeing and sizing in one process
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/47—Oxides or hydroxides of elements of Groups 5 or 15 of the Periodic Table; Vanadates; Niobates; Tantalates; Arsenates; Antimonates; Bismuthates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/08—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with halogenated hydrocarbons
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/03—Polysaccharides or derivatives thereof
    • D06M15/05—Cellulose or derivatives thereof
    • D06M15/07—Cellulose esters
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/03—Polysaccharides or derivatives thereof
    • D06M15/05—Cellulose or derivatives thereof
    • D06M15/09—Cellulose ethers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/227—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/227—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated
    • D06M15/233—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated aromatic, e.g. styrene
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
    • D06M15/267—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof of unsaturated carboxylic esters having amino or quaternary ammonium groups
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/327—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof
    • D06M15/333—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof of vinyl acetate; Polyvinylalcohol
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S428/00—Stock material or miscellaneous articles
    • Y10S428/92—Fire or heat protection feature
    • Y10S428/921—Fire or flameproofing
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31844—Of natural gum, rosin, natural oil or lac
    • Y10T428/31848—Next to cellulosic
    • Y10T428/31851—Natural oil
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/2041—Two or more non-extruded coatings or impregnations
    • Y10T442/2098—At least two coatings or impregnations of different chemical composition
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/2164—Coating or impregnation specified as water repellent
    • Y10T442/2205—Natural oil or wax containing
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/2631—Coating or impregnation provides heat or fire protection
    • Y10T442/2656—Antimony containing

Definitions

  • This invention relates to the impregnation of natural or synthetic cellulosic fibers and fabrics with flameproofing and water-repelling substances and to the flameproofed impregnated cellulosic materials obtained. More particularly, the invention relates to methods of applying impregnating substances to such fibers and fabrics, which methods result in treated materials of tensile strength and storage life comparable to untreated materials.
  • the invention in general, contemplates the provision in stable relation upon a fibrous or fabric flammable material of fiameproofing and water-repelling substances including both inorganic flame retardant substances, such as antimony oxide, and highly chlorinated organic substances, such as chlorinated paraffin, such substances being maintained in entirely stable relationship on the treated material at ordinary temperatures but being adapted to co-act in flame retarding relationship upon exposure of the treated materials to flame temperatures.
  • inorganic flame retardant substances such as antimony oxide
  • highly chlorinated organic substances such as chlorinated paraffin
  • inorganic materials such as antimony oxide
  • organic materials such as chlorinated paraffin
  • a liquid medium either alone or with various added materials, such as resinous substances, designed to improve adherence of the flameproofing mixture to the fabric, dyes, fillers or the like, and. such suspension is applied to the cloth.
  • various added materials such as resinous substances, designed to improve adherence of the flameproofing mixture to the fabric, dyes, fillers or the like, and. such suspension is applied to the cloth.
  • the mixture of inorganic materials, chlorinated material and solvent is in intimate contact with the interstices of the fibers and upon the solvent being removed, the two flame retardant materials remain in such relationship and in contact with each other on the finished fabric.
  • the method of the present invention includes the application of the inorganic flame retardant substance and the chlorinated organic material to fabric in such a manner as normally to main tain said substances out of contact with each other and normally to maintain the chlorinated material out of contact with the fabric, while still permitting intimate contact to be readily established to produce flame inhibiting relationship at flame temperatures.
  • the present invention which permits the maintenance of the fibers of the fabric out of com tact with the chlorinated material during storage or use may be achieved by separating the fibers of the fabric from the chlorinated material with 3 an auxiliary water-repellent, normally hydrogen chloride inert, film which, in addition to func tioning as a screen between the chlorinated me. terial and the fibers, binds the inorganic flame retardant substance within the interstices of t is fibers.
  • the auxiliary film which is preferably water-repellent, improves the moisture-proof character of the treated fabric.
  • auxiliary film material may application of the chlorinated organic material to the thus initially treated fabric, the chlorihated material being preferably applied in a sol* vent therefor which is a non-solvent for the film material, a system will be obtained wherein.
  • chlorinated material though closely associated with the fabric and adapted to co-act with the inorganic flame retardant substance at flame temperatures, is nevertheless normally maintamed out of actual contact with the fibers of the fabric and with the inorganic materials whereby decomposition of the chlorinated material and release of HCl at other than flame temperatures cannot deleteriously affect the fibers of the fabric.
  • suspended particles of inorganic flame retardant material may be coated with the film forming material, particles of chlorinated material may be similarly so coated and present in the same suspension, whereby a system is achieved wherein the inorganic and organic ma terials are maintained in separated relationship in suspension in the same solvent.
  • the fabric is then contacted with a film forming material whereby the fibers of the fabric are essentially completel coated, whereupon the prepared suspension of coated inorganic and organic flame retardant material is applied to the thus treated fabric, achieving a finished material wherein as before, the flame retardant agents are separated from each other and particularly the chlorinated organic material is separated from the fibers of the fabric.
  • the flame retardant materials co-act to inhibit flaming as described above.
  • Still another and the preferred method of achieving the desirable results of this invention contemplates the application to the fabric of the inorganic flame retardant material suspended in a volatile solvent, followed by application of a film forming material thereto, and finally applying a solution of chlorinated material in a nonsolvent for the film forming material. It will be seen that under the conditions of this aspect of the invention, the desired normal separation of the flame retardant materials and the separation of chlorinated material from the fibers is again achieved, while also providing an environment for the flame retardant to co-act at flame temperatures.
  • the inorganic flame retardant substance to be used in the practice of the present invention may comprise salts of antimony, arsenic, and bismuth, or salts of phosphoric, boric or stannic acids or mixtures thereof.
  • compounds of antimony, particularly antimony trioxide (SbzOa) are preferred.
  • the highly chlorinated organic flame retardant substance may be any one of several types of chlorinated or ganic compounds, such as chlorinated oils of vegetable or animal origin, chlorinated paraflin wax, or wax-like substances.
  • the chlorinated substance be nontoxic to warm-blooded animals, readily soluble in organic solvents, and that such substance possess a low vapor pressure, while releasing sub stantial amounts of hydrogen chloride at flame temperatures
  • the preferred highly chlorinated organic substance for the practice of the present invention is a chlorinated paraffin wax containing between 40% and 70% of chemically coil bined chlorine, it also having been found advantageous to use mixtures of highly chlorinated paraflins, one component of such mixture containing about 40% of chemically combined chlorine and another component containing above 65% of chemically combined chlorine.
  • the film forming substance to be used in the practice of the present invention as a screen or barrier between the somewhat unstable chlorinated organic material and the fibers of the fabric, as well as the inorganic fiameproofing material may be drawn from a wide variety of film forming resinous materials which are characterized by substantial insolubility in at least one solvent in which the chlorinated material has substantial solubility.
  • the film forming screen material is preferably itself water-repellent when deposited as a film.
  • the film forming material must be readily decomposable at flame temperatures in order that the inorganic and organic flame retardant materials may co-act at such temperatures to inhibit burning of the fabric. At ordinary service temperatures, however, it is preferred that the film forming material be inert to conditions to which fabric may be exposed as well as to both the inorganic and organic constituents of the flameproofing coni position.
  • Heptanes to light kerosene substantially no aromatics.
  • the film forming substance may be applied to the cloth in any of the previously described sequences of steps by any suitable means, such as hot rolling, calendering, flame spraying, solution spraying, brushing, doctoring, or-the like.
  • any film forming resin especially the water insoluble members of such class of resins which is insoluble in a solvent in which the chlorinated material is soluble, may be employed herein.
  • urea-formaldehyde condensation product (50% solution) '72 parts, xylol 350 parts.
  • Bath 111' A hotxylol solution of polyethylene having an average molecular weight of about 15,000.
  • Bath III Chlorinated parafiln 'wax containing 40% of chemically combined chlorine 120 parts, comminuted calcium carbonate 200 parts, ureaformaldehyde condensation product (50% solution') 26 parts, cold xylol 633 parts.
  • a heavy canvas material (14 ounce duck) is dipped in bath I and removed, dried at 190 F. for 30 minutes, and then dipped in bath II and dried at 190 F; for 30 minutes, and then dipped in bath III and dried at 190 F. for 30 minutes.
  • E-ll of the J efiersonville Quartermaster Depot, Specification N0. 242, Section F-3 the follow-- ing' results are obtained as an average from several specimens tested: Duration of the flaming (seconds)-0; Length of char (inches)-2%..
  • Example II (O1ivedrab colored coating) Bath I: Antimony minuted calcium carbon-ate parts, xylol 375 parts. Bath II: A 10% solution of polyethylene in hot xylol similar to that used in Example I. Bath III: Chromium oxide (CrzO3) 46 parts, yellow iron oxide 34 parts, red iron oxide 24 parts.
  • a heavy canvas material (14 ounce duck) is dipped in bath I and dried at F. for 30 minutes and is found to have increased in weight by 25.6% based on the original weight of the cloth. This is followed by dipping in bath II and drying at 190 F. for 30 minutes; after this drying, the weight of the deposited film is 4.6% of the original weight of the untreated cloth. This is followed by dipping in bath III, drying at 190 F. for 30 minutes, following which the material has increased by 35.6% of the original weight of the untreated cloth, giving a total pickup from all three baths of 65.8% based on the weight of the untreated cloth.
  • a fire test made by the same specification as that used in Example I gives the following results: Duration of flaming (seconds) 1; length of char (inches) 3. An examination of the cross-section of this material shows that none of the materials contained in bath III penetrate the material which was applied in bath II and further that no pigmented portion is in contact with the fibers of the canvas duck.
  • Example III Using the same parts and proportions as in Example I for bath I, a 10% solution of methyl methacrylate-in acetone for bath II, and the same proportions described in Example I for bath III, all dissolved (or in the case of calcium carbonate suspended) in cyclohexane, the procedure of Example I results in a water-repellent material having flame retardant properties similar to that of the product of Example I and having shelf and normal use life equal to untreated cloth.
  • a fibrous cellulosic material of substantial flame-retardant properties comprising, in com-- bination, a fibrous cellulosic base, a non-halogenated inorganic, flame-retardant substance deposited thereon, a resinous, organic, non-halogenated, heat-decomposable, film-forming substance overlaying said inorganic flame-retardant substance deposited upon said cellulosic base, and a highly chlorinated organic flame-retardant substance having a low vapor pressure, capable of releasing substantial amounts of hydrogen chloride at flame temperatures, deposited upon said film-forming substance so as to be maintained out of contact with said cellulosic base and said inorganic flame-retardant substance by means of said filmforming substance.
  • a fibrous cellulosic material having deposited thereon, a non-halogenated inorganic, flameproofing agent comprising antimony oxide ($102.03), a heat-decomposable, non-halogenated, film-forming, resinous substance overlaying said inorganic flameproofing composition on said cellulosic material, and a highly chlorinated organic flame-retardant substance having a low vapor pressure, capable of releasing substantial amounts of hydrogen chloride at flame temperatures, deposited upon said film-forming substance, said chlorinated organic flame-retardant substance consisting essentially of chlorinated paraffin wax containing more than 40% of chemically combined chlorine.
  • a fibrous cellulosic material of substantial flame-retardant properties comprising, in combination, a fibrous cellulosic base, a non-halogenated inorganic, flame-retardant substance se-' lected from the group consisting of antimony oxide, salts of antimony, arsenic, and bismuth, salts of phosphoric, boric, and stannic acids, and mixtures of said salts, deposited thereon, a film of a heat-decomposable, non-halogenated, filmforming, resinous solid selected from the group consisting of cellulose ethers, cellulose esters, polyethylene, polystyrene, polyvinyl butyral, and polyacrylic acid esters, overlaying said inorganic flame-retardant substance deposited upon said film, said highly chlorinated organic flame-retardant substance being selected from the group consisting of chlorinated vegetable oils, chlorinated animal oils, and chlorinated paraffin wax.
  • the method of fiameproofing a fibrous cellulosic material which includes the steps of (1) impregnating said material with a non-halogenated inorganic, flame-retardant substance, (2) depositing upon the thus-impregnated cellulosic material a film of a heat-decomposable, organic, non-halogenated, polymeric, film-forming, resinous substance inert to said inorganic flameretardant substance and to highly chlorinated organic substances, thereby to form a screen between said inorganic flame-retardant substance and highly chlorinated organic substances subsequently applied thereto, and (3) applying to the composite thus formed, a highly chlorinated organic flame-retardant substance having low vapor pressure, and capable of releasing substantial amounts of hydrogen chloride at flame temperatures.
  • the method of impregnating a fibrous cellulosic material with a fiameproofing, water-repellent coating which includes the steps of (1) impregnating said material with a substance selected from the group consisting of antimony trioxide, salts of antimony, arsenic, and bismuth, salts of phosphoric, boric, and stannic acids, and mixtures of said salts, (2) app ying to the thusimpregnated material a solution of a heat-decomposable, organic, non-halogenated, filmforming, resinous solid selected from the group consisting of cellulose ethers, cellulose esters,
  • the method of impregnating a fibrous cellulosic material with a flame-retardant, waterrepellent coating which includes the steps of (1) impregnating said material with antimony trioxide, (2) applying to the thus-impregnated cellulosic material, a solution of a heat-decomposable, organic, non-halogenated, film-forming, resinous substance selected from the group consisting of cellulose ethers, cellulose esters, polyethylene, polystyrene, polyvinyl butyral, and polyacrylic acid esters, (3) evaporating the solvent from the solution applied to said impregnated material to deposit a film of said resinous substance upon said impregnated cellulose material, (4) applying to said film a solution of chlorinated parafiln wax in a solvent which is substantially a non-solvent for said resinous, film-forming substance, said chlorinated paraffin wax containing from 40%-70% of chemically combined chlorine, and (5) evaporating the solvent from said solution of said chlorin

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)

Description

Patented May 26, l953 FLAMEPROOFING METHOD AND PRODUCT Leslie P. Seyb, Painesville, and Clifford A. Neros, Willoughby, Ohio, assignors to Diamond Alkali Company, Cleveland, Ohio, a corporation of Delaware No Drawing. Application June 7, 1947, Serial No. 753,358
8 Claims.
This invention relates to the impregnation of natural or synthetic cellulosic fibers and fabrics with flameproofing and water-repelling substances and to the flameproofed impregnated cellulosic materials obtained. More particularly, the invention relates to methods of applying impregnating substances to such fibers and fabrics, which methods result in treated materials of tensile strength and storage life comparable to untreated materials.
The invention, in general, contemplates the provision in stable relation upon a fibrous or fabric flammable material of fiameproofing and water-repelling substances including both inorganic flame retardant substances, such as antimony oxide, and highly chlorinated organic substances, such as chlorinated paraffin, such substances being maintained in entirely stable relationship on the treated material at ordinary temperatures but being adapted to co-act in flame retarding relationship upon exposure of the treated materials to flame temperatures. In the following specification, the invention is described with relation to its application to woven fabric, such as cotton duck, it being understood, however, that any fibrous or woven material of cellulosic origin may be similarly treated and the advantages of the invention thus obtained.
The flameproofing of fabrics has heretofore been proposed; furthermore, the provision of fabric impregnated with an inorganic flame retardant substance, such as antimony oxide, combined with an organic flame retardant substance, such as highly chlorinated paraffin, is also known. These prior proposals have envisioned the inhibition of flaming at flame temperature both by the individual action of the flame retardant materials and by the combined chemical action of the two substances.
The prior art, however, has not provided an entirely satisfactory solution to the flameproofing of fabrics in that while the action of the materials applied to the fabrics has been satisfactory at flame temperatures, the flameproofing materials on the fabric have resulted in a tendering or weakening of treated fabrics at normal temperatures, especially after relatively extended periodsof storage or use and particularly at mildly elevated temperatures or under conditions of exposure to sunlight, such as can be expected to be encountered in ordinary storage and use.
According to prior practice, inorganic materials, such as antimony oxide, and organic materials, such as chlorinated paraffin, are suspended or dispersed in a liquid medium either alone or with various added materials, such as resinous substances, designed to improve adherence of the flameproofing mixture to the fabric, dyes, fillers or the like, and. such suspension is applied to the cloth. Thus, the mixture of inorganic materials, chlorinated material and solvent is in intimate contact with the interstices of the fibers and upon the solvent being removed, the two flame retardant materials remain in such relationship and in contact with each other on the finished fabric.
It is known that highly chlorinated organic materials, such as chlorinated paraffins, are some what unstable and tend, especially when heated, to dehydrochlorinate releasing hydrogen chloride; in fact, it is generally believed that at least part of the flameproofing character of the abovementioned mixture lies in this property and in the subsequent reaction of antimony oxide with hydrogen chloride to form antimony oxychloride, which is characterized by notable inhibition of combustion. Accordingly, at flame temperatures the ready release of hydrogen chloride is desired, for Whatever the theory of its action, it is known that flameprooflng compositions which do not release hydrogen chloride at such temperatures are relatively inefficient. Y
The spontaneous release of hydrogen chloride from the chlorinated material on the fabric, which release takes place at an appreciable rate at ordinary temperatures of storage or use, is, however, quite another matter and results in a relatively substantial loss of tensile strength of prior art treated fabrics and in relatively short times. Various neutralizing substances, such as calcium carbonate, have been included in flameproofing materials for the purpose of nullifying the harmful effect of released hydrogen chloride but such modifications have also failed to produce a flameproofed fabric having satisfactory storage life.
As a result of the present invention, however, it is now appreciated that the intimate contact of the highly chlorinated organic substances with the fibers of the fabric is detrimental thereto; the hydrogen chloride released acting to tender or lessen the tensile strength of the cellulosic materials. Decomposition of chlorinated materials results presumably in part from spontaneous action and in part from contact with the normal environment of such materials in storage or use, such as light, air and moisture. In addition, the inorganic flame retardant materials or impurities normally present therein, which heretofore have been in intimate contact with the highly chlorinated material, play a substantial role in this undesired production of hydrogen chloride.
The method of the present invention includes the application of the inorganic flame retardant substance and the chlorinated organic material to fabric in such a manner as normally to main tain said substances out of contact with each other and normally to maintain the chlorinated material out of contact with the fabric, while still permitting intimate contact to be readily established to produce flame inhibiting relationship at flame temperatures.
The present invention, which permits the maintenance of the fibers of the fabric out of com tact with the chlorinated material during storage or use may be achieved by separating the fibers of the fabric from the chlorinated material with 3 an auxiliary water-repellent, normally hydrogen chloride inert, film which, in addition to func tioning as a screen between the chlorinated me. terial and the fibers, binds the inorganic flame retardant substance within the interstices of t is fibers. In addition to enhancing the storage life of the fabric, the auxiliary film, which is preferably water-repellent, improves the moisture-proof character of the treated fabric.
Application of the auxiliary film material may application of the chlorinated organic material to the thus initially treated fabric, the chlorihated material being preferably applied in a sol* vent therefor which is a non-solvent for the film material, a system will be obtained wherein. the
chlorinated material, though closely associated with the fabric and adapted to co-act with the inorganic flame retardant substance at flame temperatures, is nevertheless normally maintamed out of actual contact with the fibers of the fabric and with the inorganic materials whereby decomposition of the chlorinated material and release of HCl at other than flame temperatures cannot deleteriously affect the fibers of the fabric.
It is also within the contemplation of the in vention that suspended particles of inorganic flame retardant material may be coated with the film forming material, particles of chlorinated material may be similarly so coated and present in the same suspension, whereby a system is achieved wherein the inorganic and organic ma terials are maintained in separated relationship in suspension in the same solvent. The fabric is then contacted with a film forming material whereby the fibers of the fabric are essentially completel coated, whereupon the prepared suspension of coated inorganic and organic flame retardant material is applied to the thus treated fabric, achieving a finished material wherein as before, the flame retardant agents are separated from each other and particularly the chlorinated organic material is separated from the fibers of the fabric. Upon reaching flame temperatures however, the flame retardant materials co-act to inhibit flaming as described above.
Still another and the preferred method of achieving the desirable results of this invention contemplates the application to the fabric of the inorganic flame retardant material suspended in a volatile solvent, followed by application of a film forming material thereto, and finally applying a solution of chlorinated material in a nonsolvent for the film forming material. It will be seen that under the conditions of this aspect of the invention, the desired normal separation of the flame retardant materials and the separation of chlorinated material from the fibers is again achieved, while also providing an environment for the flame retardant to co-act at flame temperatures.
The inorganic flame retardant substance to be used in the practice of the present invention may comprise salts of antimony, arsenic, and bismuth, or salts of phosphoric, boric or stannic acids or mixtures thereof. In general, compounds of antimony, particularly antimony trioxide (SbzOa), are preferred. The highly chlorinated organic flame retardant substance may be any one of several types of chlorinated or ganic compounds, such as chlorinated oils of vegetable or animal origin, chlorinated paraflin wax, or wax-like substances. In general, it is preferred that the chlorinated substance be nontoxic to warm-blooded animals, readily soluble in organic solvents, and that such substance possess a low vapor pressure, while releasing sub stantial amounts of hydrogen chloride at flame temperatures, The preferred highly chlorinated organic substance for the practice of the present invention is a chlorinated paraffin wax containing between 40% and 70% of chemically coil bined chlorine, it also having been found advantageous to use mixtures of highly chlorinated paraflins, one component of such mixture containing about 40% of chemically combined chlorine and another component containing above 65% of chemically combined chlorine.
The film forming substance to be used in the practice of the present invention as a screen or barrier between the somewhat unstable chlorinated organic material and the fibers of the fabric, as well as the inorganic fiameproofing material, may be drawn from a wide variety of film forming resinous materials which are characterized by substantial insolubility in at least one solvent in which the chlorinated material has substantial solubility. In addition, of course, in order to enhance the ultimate water-repellency of the fabric treated, the film forming screen material is preferably itself water-repellent when deposited as a film. Also, the film forming material must be readily decomposable at flame temperatures in order that the inorganic and organic flame retardant materials may co-act at such temperatures to inhibit burning of the fabric. At ordinary service temperatures, however, it is preferred that the film forming material be inert to conditions to which fabric may be exposed as well as to both the inorganic and organic constituents of the flameproofing coni position.
In the following table are set forth various examples of resinous film forming substances which meet the above conditions; many other specific examples will occur to those skilled in the art without departing from the scope of the invention herein.
oxide '(SbaOs) 100 parts, urea-formaldehyde con-- densation product (50% solution) 72 parts, com- Table "A 1 Film Forming Material Solvent Chlorinated Material Solvent Ethyl Cellulose Acetone.-- Chlorinated Paraffin" Chain Hydrocarbons. Polyethylene Hot Xylol. Cold Xylol. Cellulose Acetate.. Acetone Chain Hydrocarbons. Styrene Resins Do. Polyvinyl Entry 1. Do. Methylmethacrylat Cyclohexane. Ethylmethacrylate--. Do. Iso-Propylmethac late Hexane. n-Butylmethacrylate Do. n-lropylmethacrylate...- Do. Iso-Butylmethacrylate. Do.
Heptanes to light kerosene (duodecane) substantially no aromatics.
The film forming substance may be applied to the cloth in any of the previously described sequences of steps by any suitable means, such as hot rolling, calendering, flame spraying, solution spraying, brushing, doctoring, or-the like.
It will be appreciated that the adoption of different chlorinated materials from chlorinated paraflin in the practice of the present invention may introduce slight variations in the information, given in the table above. However, as stated hereinbefore, any film forming resin, especially the water insoluble members of such class of resins which is insoluble in a solvent in which the chlorinated material is soluble, may be employed herein. Also, it will be appreciated from the foregoing that, though there exist a number of variations which may be resorted to inthe practiceof the. present method, it is in general preferred, to obtain the desired protection of the fibers of the fabric, that the film forming material be applied to the fabric prior to application thereto of the chlorinated material.
For a more complete understanding of the present invention and in order to enable those skilled in the art to practice the same, the following specific examples are offered, it being understood that the same'are to be taken as illustrative only. 1 Y
Example I BathI: Antimony oxide (SbzOa) 200 parts,
urea-formaldehyde condensation product (50% solution) '72 parts, xylol 350 parts. Bath 111' A hotxylol solution of polyethylene having an average molecular weight of about 15,000. Bath III: Chlorinated parafiln 'wax containing 40% of chemically combined chlorine 120 parts, comminuted calcium carbonate 200 parts, ureaformaldehyde condensation product (50% solution') 26 parts, cold xylol 633 parts.
A heavy canvas material (14 ounce duck) is dipped in bath I and removed, dried at 190 F. for 30 minutes, and then dipped in bath II and dried at 190 F; for 30 minutes, and then dipped in bath III and dried at 190 F. for 30 minutes. The material is found to have increased in weight after the, third dip.=by .-about60=%- of the original weight of the untreated cloth. Usingthe standard fire test, E-ll of the J efiersonville Quartermaster Depot, Specification N0. 242, Section F-3, the follow-- ing' results are obtained as an average from several specimens tested: Duration of the flaming (seconds)-0; Length of char (inches)-2%..
Example II (O1ivedrab colored coating) Bath I: Antimony minuted calcium carbon-ate parts, xylol 375 parts. Bath II: A 10% solution of polyethylene in hot xylol similar to that used in Example I. Bath III: Chromium oxide (CrzO3) 46 parts, yellow iron oxide 34 parts, red iron oxide 24 parts.
Ramapo Blue (dye) 2 parts, comminuted calcium carbonate 50 parts, copper naphthenate (8% solution in xylol) 45 parts, chlorinated paraffin wax containing 40% of chemically combined chlorine 100 parts, chlorinated parafiin wax containing 70% of chemically combined chlorine (70% solution on xylol) 60 parts, cold xylol 255 parts. I
A heavy canvas material (14 ounce duck) is dipped in bath I and dried at F. for 30 minutes and is found to have increased in weight by 25.6% based on the original weight of the cloth. This is followed by dipping in bath II and drying at 190 F. for 30 minutes; after this drying, the weight of the deposited film is 4.6% of the original weight of the untreated cloth. This is followed by dipping in bath III, drying at 190 F. for 30 minutes, following which the material has increased by 35.6% of the original weight of the untreated cloth, giving a total pickup from all three baths of 65.8% based on the weight of the untreated cloth. A fire test made by the same specification as that used in Example I gives the following results: Duration of flaming (seconds) 1; length of char (inches) 3. An examination of the cross-section of this material shows that none of the materials contained in bath III penetrate the material which was applied in bath II and further that no pigmented portion is in contact with the fibers of the canvas duck.
Example III Using the same parts and proportions as in Example I for bath I, a 10% solution of methyl methacrylate-in acetone for bath II, and the same proportions described in Example I for bath III, all dissolved (or in the case of calcium carbonate suspended) in cyclohexane, the procedure of Example I results in a water-repellent material having flame retardant properties similar to that of the product of Example I and having shelf and normal use life equal to untreated cloth.
While we have described in detail certain forms of our invention and certain specific examples of its practice, we do not wish to be understood as limiting ourselves to the use of such examples as we realize that changes within the scope of the invention are possible, and we further intend each step in the following claims to refer to all equivalentsteps for accomplishing the same result in substantially the same 'or equivalent manner, it being our purpose to cover our invention broadly in whatever form its principle may be utilized.
What is claimed is:
l. A fibrous cellulosic material of substantial flame-retardant properties comprising, in com-- bination, a fibrous cellulosic base, a non-halogenated inorganic, flame-retardant substance deposited thereon, a resinous, organic, non-halogenated, heat-decomposable, film-forming substance overlaying said inorganic flame-retardant substance deposited upon said cellulosic base, and a highly chlorinated organic flame-retardant substance having a low vapor pressure, capable of releasing substantial amounts of hydrogen chloride at flame temperatures, deposited upon said film-forming substance so as to be maintained out of contact with said cellulosic base and said inorganic flame-retardant substance by means of said filmforming substance.
2. A fibrous cellulosic material having deposited thereon, a non-halogenated inorganic, flameproofing agent comprising antimony oxide ($102.03), a heat-decomposable, non-halogenated, film-forming, resinous substance overlaying said inorganic flameproofing composition on said cellulosic material, and a highly chlorinated organic flame-retardant substance having a low vapor pressure, capable of releasing substantial amounts of hydrogen chloride at flame temperatures, deposited upon said film-forming substance, said chlorinated organic flame-retardant substance consisting essentially of chlorinated paraffin wax containing more than 40% of chemically combined chlorine.
3. A fibrous cellulosic material of substantial flame-retardant properties comprising, in combination, a fibrous cellulosic base, a non-halogenated inorganic, flame-retardant substance se-' lected from the group consisting of antimony oxide, salts of antimony, arsenic, and bismuth, salts of phosphoric, boric, and stannic acids, and mixtures of said salts, deposited thereon, a film of a heat-decomposable, non-halogenated, filmforming, resinous solid selected from the group consisting of cellulose ethers, cellulose esters, polyethylene, polystyrene, polyvinyl butyral, and polyacrylic acid esters, overlaying said inorganic flame-retardant substance deposited upon said film, said highly chlorinated organic flame-retardant substance being selected from the group consisting of chlorinated vegetable oils, chlorinated animal oils, and chlorinated paraffin wax.
4. The article of claim 3 in which the inorganic flame-retardant substance is antimony oxide (812203), the heat-decomposable, non-halogenated, film-forming, resinous solid is polyethylene, and the highly chlorinated organic flameretardant substance is chlorinated paraflln wax containing from 40%-70% of chemically combined chlorine.
5. The method of fiameproofing a fibrous cellulosic material, which includes the steps of (1) impregnating said material with a non-halogenated inorganic, flame-retardant substance, (2) depositing upon the thus-impregnated cellulosic material a film of a heat-decomposable, organic, non-halogenated, polymeric, film-forming, resinous substance inert to said inorganic flameretardant substance and to highly chlorinated organic substances, thereby to form a screen between said inorganic flame-retardant substance and highly chlorinated organic substances subsequently applied thereto, and (3) applying to the composite thus formed, a highly chlorinated organic flame-retardant substance having low vapor pressure, and capable of releasing substantial amounts of hydrogen chloride at flame temperatures.
6. The method of impregnating a fibrous cellulosic material with a fiameproofing, water-repellent coating, which includes the steps of (1) impregnating said material with a substance selected from the group consisting of antimony trioxide, salts of antimony, arsenic, and bismuth, salts of phosphoric, boric, and stannic acids, and mixtures of said salts, (2) app ying to the thusimpregnated material a solution of a heat-decomposable, organic, non-halogenated, filmforming, resinous solid selected from the group consisting of cellulose ethers, cellulose esters,
polyethylene, polystyrene, polyvinyl butyral, and polyacrylic acid esters, (3) evaporating the solvent from the solution deposited upon said impregnated material to leave a film of said resinous solid overlaying said impregnated material, (4) applying to said film upon said impregnated material, a solution of a highly chlorinated organic flame-retardant substance selected from the group consisting of chlorinated vegetable oils, chlorinated animal oils, and chlorinated paraifin wax containing from 40 of chemically combined chlorine, the solvent of said solution of said highly chlorinated organic substance being substantially a non-solvent for said film-forming, resinous solid, and (5) evaporating the solvent from said solution of said highly chlorinated organic substance applied to said film.
7. The method of impregnating a fibrous cellulosic material with a flame-retardant, waterrepellent coating, which includes the steps of (1) impregnating said material with antimony trioxide, (2) applying to the thus-impregnated cellulosic material, a solution of a heat-decomposable, organic, non-halogenated, film-forming, resinous substance selected from the group consisting of cellulose ethers, cellulose esters, polyethylene, polystyrene, polyvinyl butyral, and polyacrylic acid esters, (3) evaporating the solvent from the solution applied to said impregnated material to deposit a film of said resinous substance upon said impregnated cellulose material, (4) applying to said film a solution of chlorinated parafiln wax in a solvent which is substantially a non-solvent for said resinous, film-forming substance, said chlorinated paraffin wax containing from 40%-70% of chemically combined chlorine, and (5) evaporating the solvent from said solution of said chlorinated parafiin wax applied to said film.
8. The method of claim 7 in which said heatdecomposable, organic, non-halogenated, filmforming, resinous substance is polyethylene.
LESLIE P. SEYB, CLIFFORD A. NEROS.
References Cited in the file of this patent UNITED STATES PATENTS Number (Other references on following page) Number 9 UNITED STATES PATENTS Name Date Meyer July 31, 1945 Laughlin et a1 Feb. 25, 1947 Czeczowitzka July 22, 1947 White Sept. 23, 1947 McGill et a1 Oct. 7, 1947 Sullivan Nov. 18, 1947 Johnson et a1 Jan. 10, 1950 10 FOREIGN PATENTS Number Country Date 552,909 Great Britain Apr. 29, 1943 OTHER REFERENCES Little, Flameproofing Textile Fabrics, A. C. S., Monograph Series No. 104, published 1947, pages 240, 241, 249.

Claims (1)

1. A FIBROUS CELLULOSIC MATERIAL OF SUBSTANTIAL FLAME-RETARDANT PROPERTIES COMPRISING, IN COMBINATION, A FIBROUS CELLULOSIC BASE, A NON-HALOGENATED INORGANIC, FLAME-RETARDANT SUBSTANCE DEPOSITED THEREON, A RESINOUS, ORGANIC, NON-HALOGENATED HEAT-DECOMPOSABLE, FILM-FORMING SUBSTANCE OVERLAYING SAID INORGANIC FLAME-RETARDANT SUBSTANCE DEPOSITED UPON SAID CELLULOSIC BASE, AND A HIGHLY CHLORINATED ORGANIC FLAME-RETARDANT SUBSTANCE HAVING A LOW VAPOR PRESSURE, CAPABLE OF RELEASING SUBSTANTIAL AMOUNT OF HYDROGEN CHLORIDE AT FLAME TEMPERATURES, DEPOSITED UPON SAID FILM-FORMING SUBSTANCE SO AS TO BE MAINTAINED OUT OF CONTACT WITH SAID CELLULOSIC BASE AND SAID INORGANIC FLAME-RETARDANT SUBSTANCE BY MEANS OF SAID FILM-FORMING SUBSTANCE.
US75335847 1947-06-07 1947-06-07 Flameproofing method and product Expired - Lifetime US2640000A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US75335847 US2640000A (en) 1947-06-07 1947-06-07 Flameproofing method and product

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US75335847 US2640000A (en) 1947-06-07 1947-06-07 Flameproofing method and product

Publications (1)

Publication Number Publication Date
US2640000A true US2640000A (en) 1953-05-26

Family

ID=25030300

Family Applications (1)

Application Number Title Priority Date Filing Date
US75335847 Expired - Lifetime US2640000A (en) 1947-06-07 1947-06-07 Flameproofing method and product

Country Status (1)

Country Link
US (1) US2640000A (en)

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2720279A (en) * 1953-04-02 1955-10-11 Fram Corp Pleated paper carburetor air filter
US2733776A (en) * 1956-02-07 Filters for respirators
US2754217A (en) * 1953-06-26 1956-07-10 Vita Var Corp Fire retardant paint
US2867549A (en) * 1956-03-06 1959-01-06 Albemarle Paper Mfg Company Process for flameproofing paper
US2881097A (en) * 1956-02-02 1959-04-07 Harshaw Chem Corp Mildewcide and flameproofing composition and products produced therefrom
US2913428A (en) * 1957-10-04 1959-11-17 Hooker Chemical Corp Flame resistant unsaturated polyester composition containing an organic antimony compound
US2985540A (en) * 1958-05-19 1961-05-23 Kimberly Clark Co Manufacture of cellulosic product
US3031425A (en) * 1957-10-04 1962-04-24 Hooker Chemical Corp Flame resistant polyester compositions containing antimony
US3034939A (en) * 1960-01-07 1962-05-15 St Regis Paper Co Laminating method and composition
US3650819A (en) * 1968-10-08 1972-03-21 American Cyanamid Co Durable fire-retardant finish for cellulosic textile materials
US3655422A (en) * 1970-09-18 1972-04-11 Kimberly Clark Co Fire retarding treatment
US3941758A (en) * 1974-03-04 1976-03-02 Hooker Chemicals & Plastics Corporation Halogen containing fire retardant additive with improved heat stability

Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1860506A (en) * 1928-10-27 1932-05-31 Anaconda Wire & Cable Co Nonsticky flame-proofed electrical conduit, etc.
US2010015A (en) * 1933-10-10 1935-08-06 Plastergon Wall Board Company Fire resisting article and method of making same
US2178625A (en) * 1938-01-07 1939-11-07 Wm E Hooper & Sons Company Fireproofing treatment and composition
GB552909A (en) * 1941-10-27 1943-04-29 Louis Arnold Jordan Improvements in and relating to weather-resistant fire-proofing processes for fibres and fabrics
US2380775A (en) * 1942-04-09 1945-07-31 Meyer Hans Compound fabrics and process for producing the same
US2416447A (en) * 1943-07-27 1947-02-25 Du Pont Weather resistant flameproof paper
US2424386A (en) * 1942-06-19 1947-07-22 Texproof Ltd Method of coating textile fabric with polyvinyl resin
US2427997A (en) * 1944-01-07 1947-09-23 Clarence B White Flame resistant fabric material
US2428716A (en) * 1941-01-25 1947-10-07 Ici Ltd Method of coating fabric with polyvinyl chloride
US2431001A (en) * 1945-04-27 1947-11-18 Du Pont Coated fabric
US2494391A (en) * 1947-05-28 1950-01-10 Du Pont Fire-resistant opaque window shade material and process of making same

Patent Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1860506A (en) * 1928-10-27 1932-05-31 Anaconda Wire & Cable Co Nonsticky flame-proofed electrical conduit, etc.
US2010015A (en) * 1933-10-10 1935-08-06 Plastergon Wall Board Company Fire resisting article and method of making same
US2178625A (en) * 1938-01-07 1939-11-07 Wm E Hooper & Sons Company Fireproofing treatment and composition
US2428716A (en) * 1941-01-25 1947-10-07 Ici Ltd Method of coating fabric with polyvinyl chloride
GB552909A (en) * 1941-10-27 1943-04-29 Louis Arnold Jordan Improvements in and relating to weather-resistant fire-proofing processes for fibres and fabrics
US2380775A (en) * 1942-04-09 1945-07-31 Meyer Hans Compound fabrics and process for producing the same
US2424386A (en) * 1942-06-19 1947-07-22 Texproof Ltd Method of coating textile fabric with polyvinyl resin
US2416447A (en) * 1943-07-27 1947-02-25 Du Pont Weather resistant flameproof paper
US2427997A (en) * 1944-01-07 1947-09-23 Clarence B White Flame resistant fabric material
US2431001A (en) * 1945-04-27 1947-11-18 Du Pont Coated fabric
US2494391A (en) * 1947-05-28 1950-01-10 Du Pont Fire-resistant opaque window shade material and process of making same

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2733776A (en) * 1956-02-07 Filters for respirators
US2720279A (en) * 1953-04-02 1955-10-11 Fram Corp Pleated paper carburetor air filter
US2754217A (en) * 1953-06-26 1956-07-10 Vita Var Corp Fire retardant paint
US2881097A (en) * 1956-02-02 1959-04-07 Harshaw Chem Corp Mildewcide and flameproofing composition and products produced therefrom
US2867549A (en) * 1956-03-06 1959-01-06 Albemarle Paper Mfg Company Process for flameproofing paper
US2913428A (en) * 1957-10-04 1959-11-17 Hooker Chemical Corp Flame resistant unsaturated polyester composition containing an organic antimony compound
US3031425A (en) * 1957-10-04 1962-04-24 Hooker Chemical Corp Flame resistant polyester compositions containing antimony
US2985540A (en) * 1958-05-19 1961-05-23 Kimberly Clark Co Manufacture of cellulosic product
US3034939A (en) * 1960-01-07 1962-05-15 St Regis Paper Co Laminating method and composition
US3650819A (en) * 1968-10-08 1972-03-21 American Cyanamid Co Durable fire-retardant finish for cellulosic textile materials
US3655422A (en) * 1970-09-18 1972-04-11 Kimberly Clark Co Fire retarding treatment
US3941758A (en) * 1974-03-04 1976-03-02 Hooker Chemicals & Plastics Corporation Halogen containing fire retardant additive with improved heat stability

Similar Documents

Publication Publication Date Title
US2640000A (en) Flameproofing method and product
US2413163A (en) Flameproof organic fibrous material and composition therefor
US2326233A (en) Fireproofing composition
US2178625A (en) Fireproofing treatment and composition
US2427997A (en) Flame resistant fabric material
US5126387A (en) Flame retardant compositions and method of use
US2286744A (en) Process of fireproofing
US2407668A (en) Fire resistant coating compsition
US2462803A (en) Fireproofing compositions
US2378714A (en) Fireproofing compositions
US2594547A (en) Fabric material provided with paraffin coating
US2184600A (en) Method of producing waterproof air transmissive fabrics for garments
US2672427A (en) Process for rendering films and the like water-repellent, greaseproof, and moistureproof
US2463983A (en) Flameproofing composition
US2390780A (en) Process of making coated textile materials and the articles produced therefrom
US3475199A (en) Fire-retardant coating
US3694305A (en) Flame retardant fire barrier composition and laminant
US2167278A (en) Fireproofing composition
US2424831A (en) Composition for waterproofing and fireproofing textile material, and the treated material
US2536988A (en) Flame resistant and mildew resistant composition for cellulose fibers and fabrics
US2073004A (en) Fireproof material
US1852998A (en) Water and fire resistant coated material
US2755534A (en) Making a dyed flameproof fabric
US2913427A (en) Water repellent composition and article coated therewith
US2118787A (en) Painting and similar composition