US2631979A - Rust inhibiting composition - Google Patents

Rust inhibiting composition Download PDF

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US2631979A
US2631979A US182420A US18242050A US2631979A US 2631979 A US2631979 A US 2631979A US 182420 A US182420 A US 182420A US 18242050 A US18242050 A US 18242050A US 2631979 A US2631979 A US 2631979A
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oil
inhibiting composition
rust inhibiting
rusting
rust
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US182420A
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John P Mcdermott
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Standard Oil Development Co
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Standard Oil Development Co
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Priority to US182420A priority Critical patent/US2631979A/en
Priority to GB29234/50A priority patent/GB689267A/en
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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/188—Carboxylic acids; metal salts thereof
    • C10L1/1881—Carboxylic acids; metal salts thereof carboxylic group attached to an aliphatic carbon atom
    • C10L1/1883—Carboxylic acids; metal salts thereof carboxylic group attached to an aliphatic carbon atom polycarboxylic acid
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M1/00—Liquid compositions essentially based on mineral lubricating oils or fatty oils; Their use as lubricants
    • C10M1/08—Liquid compositions essentially based on mineral lubricating oils or fatty oils; Their use as lubricants with additives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/14—Synthetic waxes, e.g. polythene waxes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/16—Paraffin waxes; Petrolatum, e.g. slack wax
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/17—Fisher Tropsch reaction products
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/121—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms
    • C10M2207/123—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms polycarboxylic
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/129—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of thirty or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/22—Acids obtained from polymerised unsaturated acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/287—Partial esters
    • C10M2207/289—Partial esters containing free hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/08—Thiols; Sulfides; Polysulfides; Mercaptals
    • C10M2219/082—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms
    • C10M2219/085—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms containing carboxyl groups; Derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/135—Steam engines or turbines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2050/00—Form in which the lubricant is applied to the material being lubricated
    • C10N2050/10—Semi-solids; greasy

Definitions

  • This invention relates to rust preventing 'oil compositions and more particularly to mineral lubricating oil compositions which tend to inhibit rusting and corrosion of metal parts which are exposed to moisture.
  • a primary object of the present invention is the preparation of compositions which may be employed as internal combustion engine lubricants and which will also serve for protection of exposed surfaces of such engines when the same are not in use.
  • rusting begins within a very short period of time after the engine is shut down.
  • the compositions of the present invention are particularly valuable in preventing such rusting and they are useful not only in the lubrication of internal combustion engines, but with oil bases of suitable viscosity they may be employed as turbine oils or as lubricants for fire arms, ordnance equipment, industrial machinery, etc., and for any lubricating purposes where metal surfaces are exposed to humid air.
  • the compounds may also be added to other mineral oil bases and employed in motor fuels, emulsions, hydrocarbon polymers, polishes, paints, sprays, and the like.
  • compositions of the present invention consist essentially of a hydrocarbon oil solvent containing dissolved therein polymerized linoleic acid.
  • Linoleic acid may be polymerized by heating at a temperature of 330-360 C. in the presence of a small amount of water or in an atmosphere of steam for a period of 3 to 8 hours at pressures varying between 85 and 400 lbs. per sq. in.
  • the resulting product consists essentially of the dimer, but minor proportions of the trimer are also formed. Methods for carrying out this procedure in detail may be found in the article by Charles G. Goebel, Journal of the American Oil Chemists Society, vol. 24, pp. 65-8 (1947). The dimer is of particular interest in connection with the present invention.
  • the linoleic acid polymer may be advantageously employed as the active rust preventing ingredient in any hydrocarbon solvent, especially of the petroleum hydrocarbon type, and such solvent oils may, for example, be naphthas, spindle oils, light and heavy lubricating oil fractions, etc., and may be used when other ingredients are present such as in greases, sprays, paints,
  • compositions were prepared by dissolving 1% and 2% by weight, respectively, of polymerized linoleic acid (consisting of dimer, 12% trimer, and 3% monomer) in a lubricating oil base stock consisting of a conventionally refined Coastal naphthenic oil of 40 seconds viscosity (Saybolt) at 210 F. These blends and a sample of the unblerfded base stock were submitted to a humidity cabinet test to determine the degree to which the oils prevent the rusting of a steel surface in a warm humid atmosphere.
  • a turbine oil composition was prepared by discontaining other ad- 3 solving 0.1% by weight of polymerized linoleic acid (composition as in Example 1) in a solvent extracted Mid-continent lubricating oil fraction of 150 seconds (Saybolt) viscosity at 100 F. Samples of this composition and of the unblended base oil were submitted to the standard ASTM turbine oiltrusttest,gdesignation -D6651 47T; using the procedure prescribed'for distilled water. The-- procedure, in brief, is carried out as follows: 350
  • the beaker is placed in an oil bathmaintained. at 140 F.
  • a cold rolled steel specimen of cylindrical shape, one-ha1f inchringdiamfiter andi53/z l inches long is suspended in-the oil; Then-50ml; of the oil is removed and 30 m1. of distilled water added. The oil and Water are stirred together-for, 24 hours, after which the condition of the; st,.ee.l; specimen was observed.

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Lubricants (AREA)
  • Preventing Corrosion Or Incrustation Of Metals (AREA)

Description

Patented Mar. 17, 1953 iii-- v 2,631,979 RUST INHIBI'ITING COMPOSITION John P. McDermott, Roselle, N. J., assignor to Standard Oil Development Company, a corporation of Delaware No Drawing. Application August 30, 1950, Serial No. 182,420
, g This invention relates to rust preventing 'oil compositions and more particularly to mineral lubricating oil compositions which tend to inhibit rusting and corrosion of metal parts which are exposed to moisture.
A primary object of the present invention is the preparation of compositions which may be employed as internal combustion engine lubricants and which will also serve for protection of exposed surfaces of such engines when the same are not in use. When operating engines in climates having a high humidity, rusting begins within a very short period of time after the engine is shut down. The compositions of the present invention are particularly valuable in preventing such rusting and they are useful not only in the lubrication of internal combustion engines, but with oil bases of suitable viscosity they may be employed as turbine oils or as lubricants for fire arms, ordnance equipment, industrial machinery, etc., and for any lubricating purposes where metal surfaces are exposed to humid air. The compounds may also be added to other mineral oil bases and employed in motor fuels, emulsions, hydrocarbon polymers, polishes, paints, sprays, and the like.
The compositions of the present invention consist essentially of a hydrocarbon oil solvent containing dissolved therein polymerized linoleic acid. Linoleic acid may be polymerized by heating at a temperature of 330-360 C. in the presence of a small amount of water or in an atmosphere of steam for a period of 3 to 8 hours at pressures varying between 85 and 400 lbs. per sq. in. The resulting product consists essentially of the dimer, but minor proportions of the trimer are also formed. Methods for carrying out this procedure in detail may be found in the article by Charles G. Goebel, Journal of the American Oil Chemists Society, vol. 24, pp. 65-8 (1947). The dimer is of particular interest in connection with the present invention. This is believed to have the formula- The linoleic acid polymer may be advantageously employed as the active rust preventing ingredient in any hydrocarbon solvent, especially of the petroleum hydrocarbon type, and such solvent oils may, for example, be naphthas, spindle oils, light and heavy lubricating oil fractions, etc., and may be used when other ingredients are present such as in greases, sprays, paints,
1 Claim. (Cl. 252-57) 2 etc., and in lubricating oils ditives such as detergents, pour depressants, thickeners, extreme pressure agents, other rust inhibitors such as degras, petroleum sulfonates, pentaerythritol monooleate, lauryl mercapto acetic acid, sorbitan oleate, and the like. In the preparation of plastic type products, cut-back asphalts, microcrystalline waxes, synthetic waxes, and the like are included in the formulation. Concentrations of the polymer in hydrocarbon solvents may vary from 0.025 to 5%, although concentrations of 1 to 2% are more generally preferred, especially when the composition is a mineral lubricating oil.
In the examples below are given detailed descriptions of laboratory tests which were applied to determine the effectiveness of compositions of the present invention, but it is to be understood that these examples are given for illustrative purposes and are not to be construed as limiting the scope of the invention in any way.
Erample 1 Compositions were prepared by dissolving 1% and 2% by weight, respectively, of polymerized linoleic acid (consisting of dimer, 12% trimer, and 3% monomer) in a lubricating oil base stock consisting of a conventionally refined Coastal naphthenic oil of 40 seconds viscosity (Saybolt) at 210 F. These blends and a sample of the unblerfded base stock were submitted to a humidity cabinet test to determine the degree to which the oils prevent the rusting of a steel surface in a warm humid atmosphere. This test was conducted by dipping panels of 1020 cold rolled steel, 2" x 4" in size, in the oil samples and hanging them in an AN-H-31 humidity cabinet maintained at a temperature of 120 1: 2 F., the panels being surrounded by air of humidity. Failure under this test is considered to take place when rusting occurs to an extent greater than three rust spots, no one of which is greater than 1 mm. in diameter. Results are shown in the following table:
A turbine oil composition was prepared by discontaining other ad- 3 solving 0.1% by weight of polymerized linoleic acid (composition as in Example 1) in a solvent extracted Mid-continent lubricating oil fraction of 150 seconds (Saybolt) viscosity at 100 F. Samples of this composition and of the unblended base oil were submitted to the standard ASTM turbine oiltrusttest,gdesignation -D6651 47T; using the procedure prescribed'for distilled water. The-- procedure, in brief, is carried out as follows: 350
ml. of the oil sample is placed in a beaker and;
the beaker is placed in an oil bathmaintained. at 140 F. A cold rolled steel specimen of cylindrical shape, one-ha1f inchringdiamfiter andi53/z l inches long is suspended in-the oil; Then-50ml; of the oil is removed and 30 m1. of distilled water added. The oil and Water are stirred together-for, 24 hours, after which the condition of the; st,.ee.l; specimen was observed.
The results of the testscarried out as described above were as follows:
- Amount'of Oil Composit on Busting Baseoll Heavy rusting; Base oilj-D. 1% polymerized linolcic acid N o rusting.
What is claimed is:
A mineral lubricating 011 containing dissolved therein 0.1% to 2% of a polymerized linoleic acid which consists essentially of the dimer.
JOHN P. MCDERMOTT.
REFERENCES CITED The following references are of record in the file. of this patent:
UNITED. STATES PATENTS Number Name Date 2,124,628 Moser July 26, 1938 2,3,34,15,82v Fuchs Nov. 9, 194
OTHER REFERENCES Polar Type Rust Inhibitors-Baker et al.- Industrial. 8: Engineering;- Chemrvol. 40,-.-p s. 23.38120. 2347, pg.1.23,43;per.-.tinent.;..
US182420A 1950-08-30 1950-08-30 Rust inhibiting composition Expired - Lifetime US2631979A (en)

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Application Number Priority Date Filing Date Title
US182420A US2631979A (en) 1950-08-30 1950-08-30 Rust inhibiting composition
GB29234/50A GB689267A (en) 1950-08-30 1950-11-29 Improvements in or relating to rust inhibiting compositions

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Cited By (33)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2673184A (en) * 1953-02-27 1954-03-23 Standard Oil Dev Co Lubricating grease prepared from the esters of the dimer of linoleic acid
US2718503A (en) * 1953-02-20 1955-09-20 Gulf Research Development Co Anticorrosion agents consisting of the monamides of dimerized fatty acids
US2767144A (en) * 1953-12-28 1956-10-16 Gulf Oil Corp Partial fatty acid esters of alkitol anhydrides and a dimeric acid, as corrosion inhibitors
US2773032A (en) * 1954-05-13 1956-12-04 Gulf Oil Corp Rust inhibiting lubricating oil compositions
US2786028A (en) * 1955-05-04 1957-03-19 Gulf Oil Corp Anti-corrosive lubricating oil
US2789951A (en) * 1954-08-19 1957-04-23 Gulf Oil Corp Compunded turbine oils
US2794782A (en) * 1954-08-02 1957-06-04 Monsanto Chemicals Anti-rust emulsion resistant mineral oil composition
US2830021A (en) * 1953-12-28 1958-04-08 Gulf Oil Corp Lubricant containing an aliphatic amine salt of monoalkyl ester of a dimeric acid
US2833713A (en) * 1955-04-18 1958-05-06 Standard Oil Co Corrosion inhibited motor oils
US2833714A (en) * 1955-09-28 1958-05-06 Standard Oil Co Lubricant compositions
US2849399A (en) * 1956-04-09 1958-08-26 Exxon Research Engineering Co Improved lubricating composition
US2880095A (en) * 1955-08-23 1959-03-31 Standard Oil Co Aqueous antirust compositions
US2882229A (en) * 1955-08-31 1959-04-14 Standard Oil Co Lubricant compositions
US2883339A (en) * 1955-10-18 1959-04-21 Standard Oil Co Lubricant compositions
US2888401A (en) * 1957-02-06 1959-05-26 Petrolite Corp Prevention of rust and corrosion
US2908649A (en) * 1956-10-01 1959-10-13 Monsanto Chemicals Anti-rust emulsion resistant mineral oil composition
US2914479A (en) * 1955-04-26 1959-11-24 Standard Oil Co Upper cylinder lubricant and tune-up solvent composition
US2944920A (en) * 1955-11-07 1960-07-12 Emery Industries Inc Process for lubricating and promoting the cohesion of textile fibers
US3048542A (en) * 1959-01-30 1962-08-07 Texaco Inc Lubricating compositions
US3071549A (en) * 1959-12-17 1963-01-01 Monsanto Chemicals Preservative-type functional fluids
US3074886A (en) * 1958-12-05 1963-01-22 Texaco Inc Lubricating composition
US3208945A (en) * 1963-05-31 1965-09-28 California Research Corp Rust resistant lubricant composition
US3287267A (en) * 1966-11-22 Antirust oil
US3450627A (en) * 1967-08-10 1969-06-17 Nalco Chemical Co Purifying used metalworking lubricating oils
US3476533A (en) * 1965-07-15 1969-11-04 Texaco Inc Jet fuel composition
US3857789A (en) * 1970-10-27 1974-12-31 Gaf Corp Slushing oil or rust inhibiting compositions
US4028117A (en) * 1974-05-30 1977-06-07 Edwin Cooper & Company Limited Corrosion inhibitors
US4177768A (en) * 1979-01-19 1979-12-11 Ethyl Corporation Fuel compositions
US4185594A (en) * 1978-12-18 1980-01-29 Ethyl Corporation Diesel fuel compositions having anti-wear properties
US4227889A (en) * 1978-12-26 1980-10-14 Ethyl Corporation Compression ignition fuels for use in diesel engine having anti-wear properties
EP0597803A1 (en) * 1992-11-10 1994-05-18 Alusuisse-Lonza Services Ag Method for cleaning rolling oils
US6699822B2 (en) 2002-06-07 2004-03-02 Georgia-Pacific Resin, Inc. Sulfated dicarboxylic acids for lubrication, emulsification, and corrosion inhibition
WO2011033526A2 (en) 2009-09-17 2011-03-24 Bharat Petroleum Corporation Limited Gasohol fuel composition for internal combustion engines

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2124628A (en) * 1934-03-26 1938-07-26 Sheil Dev Company Process for manufacturing lubricants
US2334158A (en) * 1941-09-29 1943-11-09 Shell Dev Rust-preventive composition

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2124628A (en) * 1934-03-26 1938-07-26 Sheil Dev Company Process for manufacturing lubricants
US2334158A (en) * 1941-09-29 1943-11-09 Shell Dev Rust-preventive composition

Cited By (36)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3287267A (en) * 1966-11-22 Antirust oil
US2718503A (en) * 1953-02-20 1955-09-20 Gulf Research Development Co Anticorrosion agents consisting of the monamides of dimerized fatty acids
US2673184A (en) * 1953-02-27 1954-03-23 Standard Oil Dev Co Lubricating grease prepared from the esters of the dimer of linoleic acid
US2767144A (en) * 1953-12-28 1956-10-16 Gulf Oil Corp Partial fatty acid esters of alkitol anhydrides and a dimeric acid, as corrosion inhibitors
US2830021A (en) * 1953-12-28 1958-04-08 Gulf Oil Corp Lubricant containing an aliphatic amine salt of monoalkyl ester of a dimeric acid
US2773032A (en) * 1954-05-13 1956-12-04 Gulf Oil Corp Rust inhibiting lubricating oil compositions
US2794782A (en) * 1954-08-02 1957-06-04 Monsanto Chemicals Anti-rust emulsion resistant mineral oil composition
US2789951A (en) * 1954-08-19 1957-04-23 Gulf Oil Corp Compunded turbine oils
US2833713A (en) * 1955-04-18 1958-05-06 Standard Oil Co Corrosion inhibited motor oils
US2914479A (en) * 1955-04-26 1959-11-24 Standard Oil Co Upper cylinder lubricant and tune-up solvent composition
US2786028A (en) * 1955-05-04 1957-03-19 Gulf Oil Corp Anti-corrosive lubricating oil
US2880095A (en) * 1955-08-23 1959-03-31 Standard Oil Co Aqueous antirust compositions
US2882229A (en) * 1955-08-31 1959-04-14 Standard Oil Co Lubricant compositions
US2833714A (en) * 1955-09-28 1958-05-06 Standard Oil Co Lubricant compositions
US2883339A (en) * 1955-10-18 1959-04-21 Standard Oil Co Lubricant compositions
US2944920A (en) * 1955-11-07 1960-07-12 Emery Industries Inc Process for lubricating and promoting the cohesion of textile fibers
US2849399A (en) * 1956-04-09 1958-08-26 Exxon Research Engineering Co Improved lubricating composition
US2908649A (en) * 1956-10-01 1959-10-13 Monsanto Chemicals Anti-rust emulsion resistant mineral oil composition
US2888401A (en) * 1957-02-06 1959-05-26 Petrolite Corp Prevention of rust and corrosion
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