US2630406A - Method of separating hydrocarbons - Google Patents
Method of separating hydrocarbons Download PDFInfo
- Publication number
- US2630406A US2630406A US188060A US18806050A US2630406A US 2630406 A US2630406 A US 2630406A US 188060 A US188060 A US 188060A US 18806050 A US18806050 A US 18806050A US 2630406 A US2630406 A US 2630406A
- Authority
- US
- United States
- Prior art keywords
- ethylbenzene
- fraction
- boron trichloride
- fractions
- mixture
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title claims description 19
- 150000002430 hydrocarbons Chemical class 0.000 title description 16
- 229930195733 hydrocarbon Natural products 0.000 title description 15
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 claims description 50
- FAQYAMRNWDIXMY-UHFFFAOYSA-N trichloroborane Chemical compound ClB(Cl)Cl FAQYAMRNWDIXMY-UHFFFAOYSA-N 0.000 claims description 19
- 239000008096 xylene Substances 0.000 claims description 14
- 150000003738 xylenes Chemical class 0.000 claims description 12
- 239000007788 liquid Substances 0.000 claims description 7
- 239000011369 resultant mixture Substances 0.000 claims description 7
- 239000000203 mixture Substances 0.000 description 15
- URLKBWYHVLBVBO-UHFFFAOYSA-N Para-Xylene Chemical group CC1=CC=C(C)C=C1 URLKBWYHVLBVBO-UHFFFAOYSA-N 0.000 description 14
- 238000009835 boiling Methods 0.000 description 14
- IVSZLXZYQVIEFR-UHFFFAOYSA-N m-xylene Chemical group CC1=CC=CC(C)=C1 IVSZLXZYQVIEFR-UHFFFAOYSA-N 0.000 description 10
- 238000004821 distillation Methods 0.000 description 9
- 239000004215 Carbon black (E152) Substances 0.000 description 8
- 238000004508 fractional distillation Methods 0.000 description 8
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 7
- 238000000926 separation method Methods 0.000 description 6
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 5
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- -1 alkyl aromatic hydrocarbons Chemical class 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000006356 dehydrogenation reaction Methods 0.000 description 1
- 238000000895 extractive distillation Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- SYSQUGFVNFXIIT-UHFFFAOYSA-N n-[4-(1,3-benzoxazol-2-yl)phenyl]-4-nitrobenzenesulfonamide Chemical class C1=CC([N+](=O)[O-])=CC=C1S(=O)(=O)NC1=CC=C(C=2OC3=CC=CC=C3N=2)C=C1 SYSQUGFVNFXIIT-UHFFFAOYSA-N 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical class OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 230000008707 rearrangement Effects 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 229930195734 saturated hydrocarbon Natural products 0.000 description 1
- 238000001577 simple distillation Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 229930195735 unsaturated hydrocarbon Natural products 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C7/00—Purification; Separation; Use of additives
- C07C7/04—Purification; Separation; Use of additives by distillation
- C07C7/05—Purification; Separation; Use of additives by distillation with the aid of auxiliary compounds
- C07C7/08—Purification; Separation; Use of additives by distillation with the aid of auxiliary compounds by extractive distillation
Definitions
- This invention relates to a method for separating hydrocarbons and particularly to a process for separating aromatic hydrocarbons containing eight carbon atoms per molecule.
- An object of this invention is to separate hydrocarbons having closely related boiling points.
- Another object of this invention is to separate hydrocarbons present in fractions of aromatic hydrocarbons containing eight carbon atoms per molecule.
- Another object of this invention is to separate ethylbenzene from a mixture also containing xylenes, particularly metaand para-xylenes.
- One embodiment of this invention relates to a process for separating hydrocarbons present in a narrow boiling hydrocarbon fraction which comprises commingling said fraction with boron trichloride, fractionally distilling the resultant mixture and separately collecting the different fractions.
- Another embodiment of this invention relates to a method of separating ethylbenzene from a fraction comprising essentially ethylbenzene and the xylenes which consists in mixing said fraction with boron trichloride, fractionally distilling the resultant mixture, and separately collecting the different fractions.
- a further embodiment of this invention relates to a process for separating ethylbenzene from a fraction comprising essentially ethylbenzene and the xylenes which consists in mixing with said fraction from about 0.2 to about 2 liquid volumes or boron trichloride to form a mixture, fractionally distilling said mixture, and separately collecting the different fractions.
- the procedure consists in mixing one volume of the aromatic hydrocarbon fraction with from about 0.2 to about 2 liquid volumes of boron trichloride and then subjecting the resultant mixture to a fractional distillation.
- a boron trichloride is a liquid which boils at a temperature of about 13 C. and melts near 107 C.
- the mixing with the aromatic hydrocarbon fraction is preferably carried out in a closed reactor which may be operated under pressure and may also be cooled by suitable means. From the reactor-mixer, the resultant mixture is then conducted to suitable fractional distillation equipment using either batch-type or continuous-type of fractional distillation.
- the mixture of aromatic hydrocarbon and boron trichloride is distilled through a suitable fractional distillation column and the distillate is collected in several fractions of gradual increasing boiling point. Each of these separate fractions may then be subjected in turn to another fractional distillation to effect further concentration or enrichment of ethylbenzene and the xylenes in different portions of the distillate.
- the distillation treatment may also be carried out in a continuous manner by continuously charging portion of the boron trichloride.- aromatic hydrocarbon fraction to a fractional distilling column which is operated so as to take overhead a relatively lower boiling fraction which is thus separated from higher boiling materials which are withdrawn from the bottom of the fractionator and if desired are conducted to another similar fractional distillation column. Also the overhead distillate from this column in which the ethylbenzene content has been increased relatively to the xylene content may be conducted to another similar fractional distillation column in order to effect further ethylbenzene enrichment of the low boiling fraction thereof.
- boron trichloride as an additive to hydrocarbon fractions to achieve isomer separation by extractive distillation may also be extended to other hydrocarbon systems. Thus, for example, it may be employed to effect separation of benzene and cyclohexane which can not be separated by simple distillation methods.
- Other hydrocarbon fractions containing saturated hydrocarbons and aromatic hydrocarbons or containing unsaturated hydrocarbons such as oleflnic hydrocarbons may also be subjected to this separation treatment by utilizing boron trichloride as an additive and then fractionally distilling the resultant mixture.
- a mixture of xylenes and ethylbenzene of known composition was distilled in the presence of boron trichloride.
- the several fractions taken overhead were freed of boron trichloride by water-washing and analyzed by the ultraviolet method.
- Most of the added boron trichloride distilled before the hydrocarbon part, but small amounts of boron trichloride continued to come overhead with the hydrocarbon fractions. This could possibly indicate a constant boiling mixture of boron trichloride and hydrocarbon.
- a run was carried out using as charging stock a mixture of isomers analyzing para-xylene 35%, meta-xylene 34%, ortho-xylene and ethylbenzene 31%.
- the ethylbenzene which is separated from xylenes in this process may be dehydrogenated to styrene in the presence of a dehydrogenation catalyst or it may be used as an intermediate for organic synthesis.
- the xylenes which are also obtained from this separation treatment may be used as solvents or they may be oxidized to produce benzene dicarboxylic acids, some of which have utility in the manufacture of resins and plastics.
- a method of separating ethylbenzene from a fraction comprising essentially ethylbenzene and xylenes which comprises mixing said fraction with liquid boron trichloride, fractionally distilling the resultant mixture, and separately collecting the different fractions.
- a process for separating ethylbenzene from a fraction comprising essentially ethylbenzene and xylenes which comprises mixing with said fraction from about 0.2 to about 2 liquid volumes of boron trichloride to form a mixture, fractionally distilling said mixture, and separately collecting the different fractions of distillation prodnot.
- a process for separating ethylbenzene from a fraction comprising essentially ethylbenzene, meta-xylene and para-xylene which comprises mixing with said fraction from about 0.2 to about 2 liquid volumes of boron trichloride to form a mixture, fractionally distilling said mixture, separately collecting the different fractions of distillation product, recovering ethylbenzene from the lower boiling fractions of said distillation product, and. recovering xylenes from the higher boiling fractions of said distillation product.
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Analytical Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Water Supply & Treatment (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Description
Patented Mar. 3, 1953 2,630,406 METHOD OF SEPARATING HYDROCARBONS Carl B. Linn, Riverside, Ill., assignor to Universal Oil Products Company, Chicago, 111., a corporation of Delaware No Drawing. Application October 2, 1950,
Serial N0. 188,060 7 3 Claims.
This invention relates to a method for separating hydrocarbons and particularly to a process for separating aromatic hydrocarbons containing eight carbon atoms per molecule.
An object of this invention is to separate hydrocarbons having closely related boiling points.
Another object of this invention is to separate hydrocarbons present in fractions of aromatic hydrocarbons containing eight carbon atoms per molecule.
Another object of this invention is to separate ethylbenzene from a mixture also containing xylenes, particularly metaand para-xylenes.
One embodiment of this invention relates to a process for separating hydrocarbons present in a narrow boiling hydrocarbon fraction which comprises commingling said fraction with boron trichloride, fractionally distilling the resultant mixture and separately collecting the different fractions.
Another embodiment of this invention relates to a method of separating ethylbenzene from a fraction comprising essentially ethylbenzene and the xylenes which consists in mixing said fraction with boron trichloride, fractionally distilling the resultant mixture, and separately collecting the different fractions.
A further embodiment of this invention relates to a process for separating ethylbenzene from a fraction comprising essentially ethylbenzene and the xylenes which consists in mixing with said fraction from about 0.2 to about 2 liquid volumes or boron trichloride to form a mixture, fractionally distilling said mixture, and separately collecting the different fractions.
I have found that boron trichloride in admixture with a hydrocarbon fraction boiling near 135 C. and containing principally meta-xylene, para-xylene and ethylbenzene becomes enriched in ethylbenzene in the lower boiling fractions but that the ethylbenzene concentration fall off in the higher boiling fractions and conversely the para-xylene content is relatively lower in the lowboiling fractions and higher in the high-boiling fractions. This observation is employed advantageously in the present process as a method of separating these isomeric alkyl aromatic hydrocarbons which boil too near the same boiling point temperature to permit a separation to be made by a simple fractional distillation; paraxylene, however, can be separated by a distillation procedure.
In applying my separation method to a mixture of Ca aromatic hydrocarbons comprising ethylbenzene and the xylenes, particularly metaxylene and para-xylene, the procedure consists in mixing one volume of the aromatic hydrocarbon fraction with from about 0.2 to about 2 liquid volumes of boron trichloride and then subjecting the resultant mixture to a fractional distillation. A boron trichloride is a liquid which boils at a temperature of about 13 C. and melts near 107 C., the mixing with the aromatic hydrocarbon fraction is preferably carried out in a closed reactor which may be operated under pressure and may also be cooled by suitable means. From the reactor-mixer, the resultant mixture is then conducted to suitable fractional distillation equipment using either batch-type or continuous-type of fractional distillation.
In a typical batch-type operation, the mixture of aromatic hydrocarbon and boron trichloride is distilled through a suitable fractional distillation column and the distillate is collected in several fractions of gradual increasing boiling point. Each of these separate fractions may then be subjected in turn to another fractional distillation to effect further concentration or enrichment of ethylbenzene and the xylenes in different portions of the distillate.
The distillation treatment may also be carried out in a continuous manner by continuously charging portion of the boron trichloride.- aromatic hydrocarbon fraction to a fractional distilling column which is operated so as to take overhead a relatively lower boiling fraction which is thus separated from higher boiling materials which are withdrawn from the bottom of the fractionator and if desired are conducted to another similar fractional distillation column. Also the overhead distillate from this column in which the ethylbenzene content has been increased relatively to the xylene content may be conducted to another similar fractional distillation column in order to effect further ethylbenzene enrichment of the low boiling fraction thereof.
The use of boron trichloride as an additive to hydrocarbon fractions to achieve isomer separation by extractive distillation may also be extended to other hydrocarbon systems. Thus, for example, it may be employed to effect separation of benzene and cyclohexane which can not be separated by simple distillation methods. Other hydrocarbon fractions containing saturated hydrocarbons and aromatic hydrocarbons or containing unsaturated hydrocarbons such as oleflnic hydrocarbons may also be subjected to this separation treatment by utilizing boron trichloride as an additive and then fractionally distilling the resultant mixture.
The nature of this invention is illustrated further by the following example which should not be construed to limit unduly the generally broad scope of the invention.
A mixture of xylenes and ethylbenzene of known composition was distilled in the presence of boron trichloride. The several fractions taken overhead were freed of boron trichloride by water-washing and analyzed by the ultraviolet method. Most of the added boron trichloride distilled before the hydrocarbon part, but small amounts of boron trichloride continued to come overhead with the hydrocarbon fractions. This could possibly indicate a constant boiling mixture of boron trichloride and hydrocarbon.
A run was carried out using as charging stock a mixture of isomers analyzing para-xylene 35%, meta-xylene 34%, ortho-xylene and ethylbenzene 31%.
50 ml. of isomer mixture was mixed with 46 ml. of BCl: and distilled to give the following data:
b Most of B01; added distilled here.
From the above table, it is noted that ethylbenzene was concentrated in fraction 1 while fraction 3 and the distillation bottoms became more enriched in the mixture of para-xylene and meta-xylene. The indicated presence of 2% of ortho-xylene in distillation bottoms may be within the limits of error of the methods employed in analyzing the diiferent fractions obtained in this distillation; the possibility of its arising from a re-arrangement reaction, however, is not ruled out. These hydrocarbon determinations were 4 carried out by means of ultraviolet analysis supplemented by infrared.
The ethylbenzene which is separated from xylenes in this process may be dehydrogenated to styrene in the presence of a dehydrogenation catalyst or it may be used as an intermediate for organic synthesis. The xylenes which are also obtained from this separation treatment may be used as solvents or they may be oxidized to produce benzene dicarboxylic acids, some of which have utility in the manufacture of resins and plastics.
I claim as my invention:
1. A method of separating ethylbenzene from a fraction comprising essentially ethylbenzene and xylenes which comprises mixing said fraction with liquid boron trichloride, fractionally distilling the resultant mixture, and separately collecting the different fractions.
2. A process for separating ethylbenzene from a fraction comprising essentially ethylbenzene and xylenes which comprises mixing with said fraction from about 0.2 to about 2 liquid volumes of boron trichloride to form a mixture, fractionally distilling said mixture, and separately collecting the different fractions of distillation prodnot.
3. A process for separating ethylbenzene from a fraction comprising essentially ethylbenzene, meta-xylene and para-xylene which comprises mixing with said fraction from about 0.2 to about 2 liquid volumes of boron trichloride to form a mixture, fractionally distilling said mixture, separately collecting the different fractions of distillation product, recovering ethylbenzene from the lower boiling fractions of said distillation product, and. recovering xylenes from the higher boiling fractions of said distillation product.
CARL B. LINN.
REFERENCES CITED The following references are of record in the file of this patent:
UNITED STATES PATENTS Number Name Date 2,521,444 Brooke et a1 Sept. 5, 1950 2,528,892 Lien et a1. Nov. 7, 1950
Claims (1)
1. A METHOD OF SEPARATING ETHYLBENZENE FROM A FRACTION COMPRISING ESSENTIALLY ETHYLBENZENE AND XYLENES WHICH COMPRISES MIXING SAID FRACTION WITH LIQUID BORON TRICHLORIDE, FRACTIONALLY DISTILLING THE RESULTANT MIXTURE, AND SEPARATELY COLLECTING THE DIFFERENT FRACTIONS.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US188060A US2630406A (en) | 1950-10-02 | 1950-10-02 | Method of separating hydrocarbons |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US188060A US2630406A (en) | 1950-10-02 | 1950-10-02 | Method of separating hydrocarbons |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US2630406A true US2630406A (en) | 1953-03-03 |
Family
ID=22691636
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US188060A Expired - Lifetime US2630406A (en) | 1950-10-02 | 1950-10-02 | Method of separating hydrocarbons |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US2630406A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2726275A (en) * | 1951-11-20 | 1955-12-06 | Standard Oil Co | Separation of ethylbenzene from mixed c8h10 aromatic hydrocarbons |
| US2736691A (en) * | 1954-10-25 | 1956-02-28 | Phillips Petroleum Co | Separation of aromatic hydrocarbons by extractive distillation with phosphorous tribromide |
| US2739992A (en) * | 1951-11-20 | 1956-03-27 | Standard Oil Co | Extraction of ethylbenzene from naphthas with hf-agf |
| US5445715A (en) * | 1995-03-27 | 1995-08-29 | Lloyd Berg | Separation of m-xylene from xylenes by azeotropic distillation |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2521444A (en) * | 1946-06-28 | 1950-09-05 | California Research Corp | Treatment of isomeric aromatic compounds |
| US2528892A (en) * | 1948-08-25 | 1950-11-07 | Standard Oil Co | Xylenes separation |
-
1950
- 1950-10-02 US US188060A patent/US2630406A/en not_active Expired - Lifetime
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2521444A (en) * | 1946-06-28 | 1950-09-05 | California Research Corp | Treatment of isomeric aromatic compounds |
| US2528892A (en) * | 1948-08-25 | 1950-11-07 | Standard Oil Co | Xylenes separation |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2726275A (en) * | 1951-11-20 | 1955-12-06 | Standard Oil Co | Separation of ethylbenzene from mixed c8h10 aromatic hydrocarbons |
| US2739992A (en) * | 1951-11-20 | 1956-03-27 | Standard Oil Co | Extraction of ethylbenzene from naphthas with hf-agf |
| US2736691A (en) * | 1954-10-25 | 1956-02-28 | Phillips Petroleum Co | Separation of aromatic hydrocarbons by extractive distillation with phosphorous tribromide |
| US5445715A (en) * | 1995-03-27 | 1995-08-29 | Lloyd Berg | Separation of m-xylene from xylenes by azeotropic distillation |
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