US2628716A - Flotation process - Google Patents
Flotation process Download PDFInfo
- Publication number
- US2628716A US2628716A US654817A US65481746A US2628716A US 2628716 A US2628716 A US 2628716A US 654817 A US654817 A US 654817A US 65481746 A US65481746 A US 65481746A US 2628716 A US2628716 A US 2628716A
- Authority
- US
- United States
- Prior art keywords
- zinc
- sulphide
- ore
- flotation
- iron
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/001—Flotation agents
- B03D1/004—Organic compounds
- B03D1/012—Organic compounds containing sulfur
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D2201/00—Specified effects produced by the flotation agents
- B03D2201/02—Collectors
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D2203/00—Specified materials treated by the flotation agents; specified applications
- B03D2203/02—Ores
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S209/00—Classifying, separating, and assorting solids
- Y10S209/901—Froth flotation; copper
Definitions
- collectors capable of selectivelyfloating sulphide mmemls Such as copper and mm sulpm-de from which accounts for the various names which have pyrite or pyrrhotite; to effect economies through" higher recoveries, higher strength concentrates, simplified operation and/or reduced operating time; to obtain advantages as will be pointed out; and to avoid the disadvantages of theprior art. Further objects will appear as the description proceeds. These objects are accomplished in the present invention by carrying out froth flotation in the presence of a suitable thiopyrimidine.
- thiopyrimidines are effective collecting agents in the froth flotation of minerals, particularly sulphide minerals, and, because of their relative inability to float iron sulphides are particularly valuable inselectiveflotation of sulphide minerals containing pyrite or pyrrhotite.
- collectors of the invention I am able to float a wide variety of minerals and in many instances, as, for example, with sulphite copper-iron ores and sulphide leadzinc-iron ores to obtain improved concentrates and improved recovery along with greater flexibility of operation and shorter flotation periods.
- Thiopyrimidines which are eflective according to this invention, are compounds characterized by a 2-mercapto-1,3-diazine structure as represented by the following formula:
- R's are the same radical selected from the class consisting of methyl and ethyl radicals, such as may be obtained among other ways, by the condensation of ammonium thiocyanate with acetone or methyl ethyl ketone, or the corresponding alpha, beta unsaturated ketones resulting from the aldol condensation of acetone or methyl ethyl ketone.
- the products are well' deflned'compounds being crystal I have Claims. (Cl. 209-166) line solids of low water solubility even in the form of their alkali metal salts.
- this compound is represented when R is the ethyl radical. If the ring is numbered counterclockwise, the name is 2-mercapto'-4,6-diethyl-S-methyl dihydropyrimidine as disclosed in U. S. Patent 2,356,710.
- the thiopyrimidines as described above are utilized to condition the mineral in essentially the same manner as standard collecting agents such as xanthates, dithiophosphates and substituted thioureas. They may be incorporated in the mineral pulp in any suitable manner as, for example, in the liberation, classiflcation or conditioning operations along with such other reagents as frothers, depressants, con-' ditioners, other collectors, etc., as are commonly used or as may be desired, and the treated pulp subjected to froth flotation according to any suitable procedure.
- the effectiveness of the compounds of the invention depends upon the nature of the ore, the amount used, the pH, the time and like factors. In short their efficiency depends upon the usual variables which affect the efliciency of .collectors in froth flotation. In general, however, they are less susceptible to variation in pH and more efiective in depressing pyrite and pyrrhotite and, in particular cases, float less insolubles and give lower tailings, higher concentrates and better over-all yields than collectors commonly used.
- Another advantage of the compounds of this invention is the fact that lime can be used to give the desired pH even in cases where other flota tion agents now employed require the more costly soda ash as an alkalizing agent.
- collectors of this invention are generally useiul in collecting awide variety of minerals, particu-' larly sulphide minerals, they are more particularly useful in effecting selective flotation of certain sulphide minerals such as copper and zinc ores containing relatively large quantities of 4 mesh, 46.2% minus 200 mesh with 6 lbs. of lime and 0.2 lb. of 2mercapto-4,4,6-trimethy1-3,4- dihydropyrimidine (obtained by the condensation of mesityl oxide with ammonium thiocyanate) per ton or ore.
- the ground ore was conditioned for 20 minutes and then subjected to a 10 minute flotation at 25% solids to which 0.1 lb. per ton pine oil was added one half at the start and the other half at five minutes. Two rougher concentrates were produced; the first taken for the first two minutes of the rougher float and the second for the last eight minutes. The results are tabulated below in Table I.
- Such terms as copper.-iron-ores and zinc-iron ores are intended to include virgin ores, concentrates, tailings and like products which contain the named metals with or without other values in admixture with aw "The amount required varies according to the particular ore and according to the effectiveness oi the particular compound used but is of the same'orde r' of magnitude as the required amounts of'likeagents of the prior art. Suitable results have been obtained within the limits of 0.0025 to 02025% by weight of the mineral (0.05 to 0.5 lb. perton) but greater or lesser quantities may be For any particular compound and any particular mineral those skilled in the art, hav-. ing inmind these principles will readily be able in view of the data given below to determine suitable amounts.
- EXAIVIPLE II A. Standard procedure-A sulphide lead-zinciron ore obtained from Park City, Utah area, was ground to 2.3% plus mesh screen and 77.9% minus 200 mesh screen along with 5 lbs. soda ash, 0.2 lb. sodium cyanide, 1.0 lb, zinc sulfate and 0.025 lb. Minerec B per ton, and subjected to a. three minute flotation at 25% solids with the addition at the start of 0.05 lb.
- B23 alcohols are a mixture of higher molecular weight alcohols, about C1, obtained by high pressure synthesis, which are commonly used in about equal admixture with pine, oil in order to obtain a more brittle froth
- pine oil and 0.01 lb. potassium ethyl xanthate per ton to give lead rougher once rate nd. trail T ead rou her. tails was conditioned for 10 minutes with the addition of 0.05 lb. B23 alcohols and pine oil, 0.05 lb. potassium ethyl xanthate, 2.0 lbs. of lime and 0.5 lb. of copper sulfate per ton and subjected to a 10 minute flotation to give zinc rougher concentrate and tails.
- Table II The results are given in Table II.
- the collectors of the invention have also been found unusually effective in the treatment of marmatite ores, natural zinc-sulfide ores containing large amounts of pyrite.
- the collectors of the invention are unusually effective in flotating the zinc sulphides in these ores from the pyrite gangue.
- marmatite zinciron ore assaying 0.04% lead and 5.42% zinc was subjected to froth flotation using Z-mercapto- 4,4,6-trimethyl-3,4-dihydropyrimidine in comparison with sodium isopropyl xanthate which is commonly used as a collector for this ore.
- R's are the same radical selected from the class consisting of methyl and ethyl radicals and subjecting the pulp to froth flotation.
- the Rs are the same radical selected from a class consisting of methyl and ethyl radicals and subjecting the pulp to froth flotation.
- means of froth flotation comprising, the steps of: selectively floating lead sulphide leaying; a lead, tails containing the bulk of the zinc. and iron.
Landscapes
- Manufacture And Refinement Of Metals (AREA)
Description
Patented Feb. 17, 1 953 UNITED STATES PATENT OFFICE FLOTATION rnoonss William H. Hill, Mount Lebanon, Pa., assignor to Koppel-s Company, Inc., Pittsburgh, Pa., a corporation of Delaware N Drawing.
Application March 15, 1946,
Serial No. 654,817
collectors capable of selectivelyfloating sulphide mmemls Such as copper and mm sulpm-de from which accounts for the various names which have pyrite or pyrrhotite; to effect economies through" higher recoveries, higher strength concentrates, simplified operation and/or reduced operating time; to obtain advantages as will be pointed out; and to avoid the disadvantages of theprior art. Further objects will appear as the description proceeds. These objects are accomplished in the present invention by carrying out froth flotation in the presence of a suitable thiopyrimidine. found that certain thiopyrimidines are effective collecting agents in the froth flotation of minerals, particularly sulphide minerals, and, because of their relative inability to float iron sulphides are particularly valuable inselectiveflotation of sulphide minerals containing pyrite or pyrrhotite. By means of the collectors of the invention, I am able to float a wide variety of minerals and in many instances, as, for example, with sulphite copper-iron ores and sulphide leadzinc-iron ores to obtain improved concentrates and improved recovery along with greater flexibility of operation and shorter flotation periods.
Thiopyrimidines which are eflective according to this invention, are compounds characterized by a 2-mercapto-1,3-diazine structure as represented by the following formula:
Est
in which the R's are the same radical selected from the class consisting of methyl and ethyl radicals, such as may be obtained among other ways, by the condensation of ammonium thiocyanate with acetone or methyl ethyl ketone, or the corresponding alpha, beta unsaturated ketones resulting from the aldol condensation of acetone or methyl ethyl ketone. The products are well' deflned'compounds being crystal I have Claims. (Cl. 209-166) line solids of low water solubility even in the form of their alkali metal salts.
These compounds may exist in one or more of the following tautometric forms:
been applied to these in the prior art. The product obtained from mesityl oxide and ammonium thiocyanate, for example, is variously shown or designated as 2-mercapto-4,4,6-trimethyl-3,4-dihydropyrimidine or 2-mercapto-4,6,6-trimethyl- .1,6 -dihydropyrimidine (structure I);
fmethylor 2-mercapto-4,6,6-trimethyl dihydropyrimidine or Z-mercapto 4,4,6 trimethyl A metadiazin (structureIIIi depending on the bered clockwise or counterclockwise. In the enol form the mercapto hydrogenmay be replaced by inorganic radicals forming salts. Suitable methods for their preparation are disclosed in U. S. Patents 2,131,790; 2,181,217; 2,234,848; and 2,244,547. p
The compound 2-mercapto-4,4,6-trimethyl-3,4 dihydropyrimidine results also when acetone or diacetone is used instead of mesityl oxide. "Thus the same type of compound is obtained from ketones which by self condensation aldol con densation) or by dehydration are capable of forming alpha, beta, unsaturated ketones.
Methyl ethyl ketone or-its self condensation product, 5-methyl-4-penten-3-one, similarly condenses with ammonium thiocyanate to give 2- mercapto-4,6-diethyl-4-methyl dihydropyrimidine. In the above formula this compound is represented when R is the ethyl radical. If the ring is numbered counterclockwise, the name is 2-mercapto'-4,6-diethyl-S-methyl dihydropyrimidine as disclosed in U. S. Patent 2,356,710.
In carrying out flotation processes in accordance with the invention the thiopyrimidines as described above are utilized to condition the mineral in essentially the same manner as standard collecting agents such as xanthates, dithiophosphates and substituted thioureas. They may be incorporated in the mineral pulp in any suitable manner as, for example, in the liberation, classiflcation or conditioning operations along with such other reagents as frothers, depressants, con-' ditioners, other collectors, etc., as are commonly used or as may be desired, and the treated pulp subjected to froth flotation according to any suitable procedure.
The effectiveness of the compounds of the invention depends upon the nature of the ore, the amount used, the pH, the time and like factors. In short their efficiency depends upon the usual variables which affect the efliciency of .collectors in froth flotation. In general, however, they are less susceptible to variation in pH and more efiective in depressing pyrite and pyrrhotite and, in particular cases, float less insolubles and give lower tailings, higher concentrates and better over-all yields than collectors commonly used. Another advantage of the compounds of this invention is the fact that lime can be used to give the desired pH even in cases where other flota tion agents now employed require the more costly soda ash as an alkalizing agent. Thus while the collectors of this invention are generally useiul in collecting awide variety of minerals, particu-' larly sulphide minerals, they are more particularly useful in effecting selective flotation of certain sulphide minerals such as copper and zinc ores containing relatively large quantities of 4 mesh, 46.2% minus 200 mesh with 6 lbs. of lime and 0.2 lb. of 2mercapto-4,4,6-trimethy1-3,4- dihydropyrimidine (obtained by the condensation of mesityl oxide with ammonium thiocyanate) per ton or ore. The ground ore was conditioned for 20 minutes and then subjected to a 10 minute flotation at 25% solids to which 0.1 lb. per ton pine oil was added one half at the start and the other half at five minutes. Two rougher concentrates were produced; the first taken for the first two minutes of the rougher float and the second for the last eight minutes. The results are tabulated below in Table I.
1 B. Procedure A was repeated except that 2- mercapto-4,4,6-trimethyl-3,4 dihydropyrimidine was increased to 0.3 pound per ton of ore.
C. The ore was ground as in procedure A with 12 lbs. of lime per ton, conditioned for twenty minutes with 2 lbs. of sodium sulphite per ton and subjected to a ten minute flotation period at 25% solids to which,0.025 lb. Minerec B (Minerec B is'a trade name for collectors obtained by dissolving a xanthate, probably potassium butyl xanthate, in ethyl chloro carbonate), 0.1 lb, of pine oil and 0.1 lb. potassium ethyl xanthate per ton were added. Two rougher concentrates were talren as in procedure A; the results are tabulated below in Table I.
Table I.-Fl otation of copper sulfide according to the invention (A and B) as compared with the prior art (C) R0. Conc.=Rougher Concentrate.
Ro. Tails=Rouglicr Tails.
pyrite. Thus through the col ectors of the inveii'tion it is possible to produce a high grade coponc ntr te essentially iree of p rit with r a tively low insoluhles from low grade sulphide cQ'pp'er-iron ores and to providejhi'gh grade'zinc concentrates from sulphide zinc-iron ores with unusually high recoveries of zinc. Such terms as copper.-iron-ores and zinc-iron ores are intended to include virgin ores, concentrates, tailings and like products which contain the named metals with or without other values in admixture with aw "The amount required varies according to the particular ore and according to the effectiveness oi the particular compound used but is of the same'orde r' of magnitude as the required amounts of'likeagents of the prior art. Suitable results have been obtained within the limits of 0.0025 to 02025% by weight of the mineral (0.05 to 0.5 lb. perton) but greater or lesser quantities may be For any particular compound and any particular mineral those skilled in the art, hav-. ing inmind these principles will readily be able in view of the data given below to determine suitable amounts.
The invention may be more fully understood by reierence to the following examples in which the are by weight unless otherwise specified.
EXAMPLE I A- ll 5. 51 91 fl fl P 'J I A e q ite m. ing about 6% copper'wa's ground to 4.0% 15111565 It is significant to note from the data given in the above table that better selective flotation of copper sulphide is obtained according to the procedures of the invention than are obtained with a standard treatment using ethyl xanthate. The 14.9% by weight of the secondary concentrate of the standard test C shows a large circulating load of iron, a factor undesirable in plant operation. It should be noted also that in the pro cedures according to the invention it is not necessary to use sodium sulphite as a depressant for iron; moreover that these advantageous results are obtained without sacrifice in the percent recovery of copper.
EXAIVIPLE II A. Standard procedure-A sulphide lead-zinciron ore obtained from Park City, Utah area, was ground to 2.3% plus mesh screen and 77.9% minus 200 mesh screen along with 5 lbs. soda ash, 0.2 lb. sodium cyanide, 1.0 lb, zinc sulfate and 0.025 lb. Minerec B per ton, and subjected to a. three minute flotation at 25% solids with the addition at the start of 0.05 lb. B23 alcohols (B23 alcohols are a mixture of higher molecular weight alcohols, about C1, obtained by high pressure synthesis, which are commonly used in about equal admixture with pine, oil in order to obtain a more brittle froth) and pine oil and 0.01 lb. potassium ethyl xanthate per ton to give lead rougher once rate nd. trail T ead rou her. tails was conditioned for 10 minutes with the addition of 0.05 lb. B23 alcohols and pine oil, 0.05 lb. potassium ethyl xanthate, 2.0 lbs. of lime and 0.5 lb. of copper sulfate per ton and subjected to a 10 minute flotation to give zinc rougher concentrate and tails. The results are given in Table II.
proved effective whereas .3 lb. per ton of the xanthate was required. The same collector of the invention was also found effective in floating zinc sulphide in a marmatite zinc ore assaying 15.4% zinc, 0.4% lead and 30.4% iron. With the prior art collectors such as Aerofloat 25, soda Table II .-Flotation of zinc sulfide according to the prior art Percent Composition Percent Distribution Product agi Pb Zn Fe Pb Zn Fe Pb. R0. Conc 19.1 70.2 3. 42 2. 4 96.2 7.1 8. 7 Pb. R0. Tails- 80. 9 0. 65 10. 50 5. 94 3. 8 92. 9 91. 3 Heads 100 13. 93 9. 16 5. 27 100 100 100 Zn. R0. 00110. 18. 9 1.8 43. 48 2. 5 2. 4 89. 7 8.9 Zn. R0. Tails 62. 0 0.3 0. 47 7.0 1.4 3. 2 82. 4 Pb. R0. Tails 80.9 0.65 10.50 5. 94 3.8 92. 9 91. 3
B. The standard procedure was repeated substituting 0.2 lb./ton of 2-mercapto-4.4,6-trimethyl-Sjl-dihydropyrimidine for the 0.05 lb./ton of potassium ethyl xanthate in the zinc circuit. The results are given in Table III.
Table III.FZotation of the sulfide according to the invention From the data of Tables II and III it may be seen that process of the invention produced a zinc tail assaying less than half that obtained with xanthate and that the grade of concentrate was about better.
The above procedures were carried out with fine ore because coarse zinc is generally difficult to float selectively. When the procedures were repeated with coarse ore, about 62% minus 200 mesh, the zinc tails in the standard increased from 0.47%, Table II, to 0.98%; whereas with 2- meroapto 4,4,6-trimethyl-3,4-dihydropyrimidine the zinc tails increased only to 0.3%.
The collectors of the invention have also been found unusually effective in the treatment of marmatite ores, natural zinc-sulfide ores containing large amounts of pyrite. The collectors of the invention are unusually effective in flotating the zinc sulphides in these ores from the pyrite gangue. For example, marmatite zinciron ore assaying 0.04% lead and 5.42% zinc was subjected to froth flotation using Z-mercapto- 4,4,6-trimethyl-3,4-dihydropyrimidine in comparison with sodium isopropyl xanthate which is commonly used as a collector for this ore. In all tests a brittle froth was obtained with the xanthate making the froth removal from both rougher and cleaner cells diflicult, whereas with the collector of the invention satisfactory frothing conditions were obtained throughout. The collector of the invention proved more selective in that considerably less circulating load was involved than obtained with the xanthate. The process of the invention also produced a higher grade cleaner concentrate assaying 46% zinc as compared with 43% for the xanthate. .2 lb. per ton or less of the collector of the invention ash is required as the alkaline reagent. By using the collector of the invention it was found possible to obtain effective flotation with this ore using lime as the alkaline reagent, moreover the collector of the invention proved more potent and more selective in the lime circuit than the Aerofioat 25 in the soda ash.
The foregoing examples serve to illustrate typical embodiments of the invention and to point out some of the advantages of the invention with respect to the prior art practices. It is to be understood, however, that the invention is not limited to these particular embodiments or to any of the details thereof but that the invention may be variously embodied within the scope of the invention as outlined above and as set forth in the appended claims.
1 I claim:
1. In a process for froth flotation the steps of preparing a mineral pulp of a sulfldic ore, incorporating therein a thiopyrimidine having the following structure:
OH: R
G N CH Hal in which the R's are the same radical selected from the class consisting of methyl and ethyl radicals and subjecting the pulp to froth flotation.
2. In a process for froth flotation the steps of preparing a mineral pulp of a sulfidic ore, incorporating therein 2mercapto-4,4,6-trimethyl-3,4- dihydropyrimidine and subjecting the pulp to froth flotation.
3. In a process for froth flotation the steps of preparing a mineral pulp of a sulfide ore contaminated with pyrite incorporating therein a thiopyrimidine having the following structure:
OH: R
in which the Rs are the same radical selected from a class consisting of methyl and ethyl radicals and subjecting the pulp to froth flotation.
4. In a process for froth flotation the steps of preparing a mineral pulp of a sulphide ore contaminated with pyrite incorporating therein 2.
7 mercapto 4,4,6-trimet y1-Bl4-dihydmpynmid ne and subjecting the pulp to froth flotation.
5.. The method of claim 4 in which the mineral is selected from the class consisting of sulphide copper-iron ores and sulphide zinc-iron ores.
6. In a method for selectively floating copper sulphide in a sulphide copper-iron ore the steps of preparing a mineral pulp of the ore, incorporating therein 2 mercapt-4,4,6-trimethyl-3,4- dihydropyrimidine and subjecting the pulp to froth flotation.
7. In a method for separating lead, zinc and iron sulphides in sulphide lead-zinc-iron ores by means of froth flotation comprising the steps of selectively floating lead sulphide leaving a lead tails containing the bulk of the zinc and iron-sulphides, and selectively floating zinc sulphide by subjecting said lead tails to froth flotation the improvement which comprises effecting said froth flotation of said lead tails in the presence ofa thiopyrimidine of the formula:
in which the Rs are the same radical selected;
from a class consisting of methyl andethyl radicals.
8. In a method for separating lead, zinc iron sulphides in sulphide .lead-zinc-iron. ores :by
means of froth flotation comprising, the steps of: selectively floating lead sulphide leaying; a lead, tails containing the bulk of the zinc. and iron.
REFERENCES CITED The following references are of record in the file of this patent:
UNITED STATES PATENTS Number Name Date 1,364,307 Perkins Jan. 4, 1921 1,364,308 Perkins Jan. 4, 1921 1,364,859 Perkins Jan. 4, 1921 1,610,217 Elley Dec. 7, 1926 1,652,060 Smith Dec, 6, 1927 1,801,317 Moses Apr. 21, 1931 1,801,318 Moses Apr. 21, 1931 1,801,319 Moses Apr. 21, 1931 1,801,320 Moses Apr. 21, 1931 1,933,962 Bogemann Nov. 7, 1933 2,126,269 Messer Aug. 9, 1938 2,234,848 Horst Mar. 11, 1941 OTHER REFERENCES Giudice, Collection in Flotation, Engineering and Mining Journal, May 1934, pages 213, to 215.
Guitzeit Technical Paper No. 2077 in Mining Technology, 1946, pages 2, 3, 15.
Perry, Chemical Engineers Handbook, second edit-gen, 1941, by McGraw-Hill Book (10., page 1 3 Geiser: Technical paper 401, American Inst. of
Mining and Met. Engineering-pages 1 to 9.
Claims (1)
1. IN A PROCESS FOR FROTH FLOTATION THE STEPS OF PREPARING A MINERAL PULP OF SULFIDIC ORE, INCORPORATING THEREIN A THIOPYRIMIDINE HAVING THE FOLLOWING STRUCTURE:
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US654817A US2628716A (en) | 1946-03-15 | 1946-03-15 | Flotation process |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US654817A US2628716A (en) | 1946-03-15 | 1946-03-15 | Flotation process |
Publications (1)
Publication Number | Publication Date |
---|---|
US2628716A true US2628716A (en) | 1953-02-17 |
Family
ID=24626356
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US654817A Expired - Lifetime US2628716A (en) | 1946-03-15 | 1946-03-15 | Flotation process |
Country Status (1)
Country | Link |
---|---|
US (1) | US2628716A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3901450A (en) * | 1969-11-03 | 1975-08-26 | David Weston | Flotation with xanthate |
Citations (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1364307A (en) * | 1919-03-25 | 1921-01-04 | Metals Recovery Co | Flotation of minerals |
US1364859A (en) * | 1920-07-13 | 1921-01-04 | Metals Recovery Co | Flotation of minerals |
US1610217A (en) * | 1925-04-24 | 1926-12-07 | Du Pont | Process of concentrating ores by flotation |
US1652060A (en) * | 1927-01-10 | 1927-12-06 | Du Pont | Process of concentrating ores and minerals by flotation |
US1801320A (en) * | 1927-05-20 | 1931-04-21 | Barrett Co | Concentration of ores |
US1801318A (en) * | 1927-05-20 | 1931-04-21 | Barrett Co | Concentration of ores |
US1801317A (en) * | 1927-05-20 | 1931-04-21 | Barrett Co | Separation of minerals by flotation |
US1801319A (en) * | 1927-05-20 | 1931-04-21 | Barrett Co | Flotation of minerals |
US1933962A (en) * | 1931-01-01 | 1933-11-07 | Ig Farbenindustrie Ag | Preserving of rubber |
US2126269A (en) * | 1937-01-16 | 1938-08-09 | Us Rubber Prod Inc | Process for treating rubber and product obtained thereby |
US2234848A (en) * | 1938-03-18 | 1941-03-11 | Us Rubber Co | Treatment of rubber |
-
1946
- 1946-03-15 US US654817A patent/US2628716A/en not_active Expired - Lifetime
Patent Citations (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1364307A (en) * | 1919-03-25 | 1921-01-04 | Metals Recovery Co | Flotation of minerals |
US1364308A (en) * | 1919-03-25 | 1921-01-04 | Metals Recovery Co | Flotation of minerals |
US1364859A (en) * | 1920-07-13 | 1921-01-04 | Metals Recovery Co | Flotation of minerals |
US1610217A (en) * | 1925-04-24 | 1926-12-07 | Du Pont | Process of concentrating ores by flotation |
US1652060A (en) * | 1927-01-10 | 1927-12-06 | Du Pont | Process of concentrating ores and minerals by flotation |
US1801320A (en) * | 1927-05-20 | 1931-04-21 | Barrett Co | Concentration of ores |
US1801318A (en) * | 1927-05-20 | 1931-04-21 | Barrett Co | Concentration of ores |
US1801317A (en) * | 1927-05-20 | 1931-04-21 | Barrett Co | Separation of minerals by flotation |
US1801319A (en) * | 1927-05-20 | 1931-04-21 | Barrett Co | Flotation of minerals |
US1933962A (en) * | 1931-01-01 | 1933-11-07 | Ig Farbenindustrie Ag | Preserving of rubber |
US2126269A (en) * | 1937-01-16 | 1938-08-09 | Us Rubber Prod Inc | Process for treating rubber and product obtained thereby |
US2234848A (en) * | 1938-03-18 | 1941-03-11 | Us Rubber Co | Treatment of rubber |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3901450A (en) * | 1969-11-03 | 1975-08-26 | David Weston | Flotation with xanthate |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
AU646295B2 (en) | Sequential and selective flotation of sulfide ores | |
US5411148A (en) | Selective flotation process for separation of sulphide minerals | |
US5049612A (en) | Depressant for flotation separation of polymetallic sulphidic ores | |
US4880529A (en) | Separation of polymetallic sulphides by froth flotation | |
US2695101A (en) | Frothing agents for the flotation of ores and coal | |
US3464551A (en) | Dialkyl dithiocarbamates as collectors in froth flotation | |
US4929344A (en) | Metals recovery by flotation | |
US2471384A (en) | Froth flotatation of sulfide ores | |
US5232581A (en) | Recovery of platinum group metals and gold by synergistic reaction between allylalkyl thionocarbamates and dithiophosphates | |
US4584097A (en) | Neutral hydrocarboxycarbonyl thionocarbamate sulfide collectors | |
US4208487A (en) | Novel frother composition for beneficiation of mineral ores | |
US4595493A (en) | Process for the flotation of base metal sulfide minerals in acid, neutral or mildly alkaline circuits | |
US4904374A (en) | Froth flotation | |
US4587013A (en) | Monothiophosphinates as acid, neutral, or mildly alkaline circuit sulfide collectors and process for using same | |
US4128475A (en) | Process for beneficiation of mineral values | |
US2310240A (en) | Flotation of ores | |
US5126038A (en) | Process for improved precious metals recovery from ores with the use of alkylhydroxamate collectors | |
US3827557A (en) | Method of copper sulfide ore flotation | |
US2485083A (en) | Froth flotation of copper sulfide ores with lignin sulfonates | |
US3355017A (en) | Method for effecting ore flotation | |
US3469692A (en) | Use of organic dithiols as flotation reagents | |
US2628716A (en) | Flotation process | |
US4159943A (en) | Froth flotation of ores using hydrocarbyl bicarbonates | |
US3309029A (en) | Activation of sulfide ores for froth flotation | |
US3667690A (en) | Flotation of copper-nickel sulfide ores |