US2620286A - Removing carbonaceous deposits from still tubes - Google Patents

Removing carbonaceous deposits from still tubes Download PDF

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US2620286A
US2620286A US47651A US4765148A US2620286A US 2620286 A US2620286 A US 2620286A US 47651 A US47651 A US 47651A US 4765148 A US4765148 A US 4765148A US 2620286 A US2620286 A US 2620286A
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tube
tubes
deposits
still
carbonaceous deposits
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Morris R Shaw
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G9/00Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G9/14Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils in pipes or coils with or without auxiliary means, e.g. digesters, soaking drums, expansion means
    • C10G9/16Preventing or removing incrustation

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  • the invention relates to a method of removing depositsv from tubes, and in particular to a method of removing sedimentary deposits from petroleum refinery still tubes.
  • Another object of th invention is to provide a refinery still tube cleaning method which cleans the tube in situ in a relatively short time with a minimum of trouble.
  • a section of a refinery still tube is shown at 2 which has accumulated therein over a period of time the deposits 3 on the inner surface 4 thereof.
  • the effects of these deposits are well known to those versed in the art. For example, such deposits tend to cut down greatly the operating efliciency of the still, due to heat transfer problems and the like, and also lessen the life of the tubes in which such deposits accumulate. Other deleterious effects are directly related to the accumulation of these deposits within the still tubes.
  • the tubes be cleaned from time to time in order to maintain a high operating efiiciency of the still and in order to increase the life of the tubes.
  • the present invention is therefore particularly directed to a method and apparatus for applying an even heat throughout the length of a refinery still tube to burn the carbonaceous deposits therefrom.
  • an induction type heater 5 is of elongated construction so that it can fit within varying size still tubes.
  • a plurality of spacers 0 are arranged about the heater 5 so that it is maintained in spaced relation with respect to the interior wall 4 of the tube 2. In this manner an even heat may be applied about the inner wall of the tube, thereby avoiding hot spots or undue heating of any particular portion of the tube.
  • the spacers 6 may be of any suitable construction and configuration, and are preferably somewhat fiexible so that they may be inserted into the tube to conform with the internal diameter thereof and still maintain a substantially even spacing between the inner surface of the tube 2 and such heater.
  • Electrical conduits l and 8 may be connected to the ends of the induction heater whereby a suitable amount of electrical energy may be supplied to the heater to elevate the temperature within the tube 2.
  • the temperature maintained within the tube 2 by the heater 5 will depend upon varying circumstances. However, as a matter of necessity, such temperature will be below the fusion point of the tubes 2 but will be at a high enough point so as to efiect combustion of the deposits within the tube 2.
  • the elongated induction heater 5 may be of any suitable length so that it can clean a complete section of tube in one operation, or it may be maintained in shorter sections so that it can be moved longitudinally along the interior of the tube so as to stepwise remove sedimentary deposits therefrom.
  • a whole battery of tubes within one particular piece of equipment may be supplied each with a heater so that each tube in the battery is simultaneously cleaned.
  • maintaining the temperature between 1500 and 2000 Fahrenheit for a period of from five to fifteen minutes will thoroughly clean, or effect combustion of the deposits within the tube 2,
  • a method of removing carbonaceous deposits from still tubes in situ comprising the steps of, producing a uniform fiameless heat by induction heating in the walls of a, tube simultaneously throughout its whole length and of a sufiiciently high temperature to destroy the deposits in the tube but not sufficiently high to adversely affect the tube.
  • the steps including inducing a uniform heat of about 1,500 F. to 2,000 F. substantially throughout the whole length of the tube to destroy said deposits, and maintaining the induced temperature in the tube between about 1500 F. and 2,000 F. which is below its fusion temperature to inhibit damage thereto.

Description

Dec. 2, 1952 M. R. SHAW 2,620,286
REMOVING CARBONACEOUS DEPOSITS FROM STILL TUBES Filed Sept. 3, 1948 Morris R. Shaw INVENTOR.
ATTORNEYS Patented Dec. 2, 1952 UNITED STATES PATENT OFFICE REMOVING CARBONACEOUS DEPOSITS FROM STILL TUBES 2 Claims.
The invention relates to a method of removing depositsv from tubes, and in particular to a method of removing sedimentary deposits from petroleum refinery still tubes.
In present day practice a great deal of dimculty is encountered in cleaning sedimentary deposits from tubes such as those used in stills around refineries. Various mechanical scrapers have been devised, but these are unsatisfactory in that a great deal of time is consumed in tearing the still down and subjecting it to the cleaning operation.
It is, therefore, an object of the instant invention to find a method which can remove sedimentary deposits from refinery still tubes and the like without entailing a great deal of diificulty.
Another object of th invention is to provide a refinery still tube cleaning method which cleans the tube in situ in a relatively short time with a minimum of trouble.
Other objects of the invention will become more readily apparent from a consideration of the following description and drawing, wherein the single figure schematically illustrates a method and apparatus for practicing the instant invention.
A section of a refinery still tube is shown at 2 which has accumulated therein over a period of time the deposits 3 on the inner surface 4 thereof. The effects of these deposits are well known to those versed in the art. For example, such deposits tend to cut down greatly the operating efliciency of the still, due to heat transfer problems and the like, and also lessen the life of the tubes in which such deposits accumulate. Other deleterious effects are directly related to the accumulation of these deposits within the still tubes.
It is, therefore, desirable that the tubes be cleaned from time to time in order to maintain a high operating efiiciency of the still and in order to increase the life of the tubes.
Heretofore a common practice has been to subject each tube in a battery of tubes in a still to a cleaning, such as by a mechanical scraper. This is particularly disadvantageous in that such operation consumes several hours, during which, of course, that particular piece of equipment can not be maintained in operation. With the instant invention it is possible to remove the sedimentary deposits from the interior of the tubes while they are retained in situ in the piece of equipment, such cleaning operation consuming only a matter of five to fifteen minutes, depending upon the condition of the tubes being cleaned.
Another common practice in cleaning the tubes is to burn the deposits from the interior of the tubes by a mixture of oxygen and a gas. This is disadvantageous in that it is difiicult to control the mixing and burning of the gases throughout the tube so that some parts of the tube become distorted because of differences in temperature in parts of the tube. Additionally, lack of control of the burning of the gases causes hot spots in the tubes, which in turn shortens the life of such tubes and necessitates replacement quicker.
The present invention is therefore particularly directed to a method and apparatus for applying an even heat throughout the length of a refinery still tube to burn the carbonaceous deposits therefrom.
As shown in the drawing, an induction type heater 5 is of elongated construction so that it can fit within varying size still tubes. A plurality of spacers 0 are arranged about the heater 5 so that it is maintained in spaced relation with respect to the interior wall 4 of the tube 2. In this manner an even heat may be applied about the inner wall of the tube, thereby avoiding hot spots or undue heating of any particular portion of the tube.
The spacers 6 may be of any suitable construction and configuration, and are preferably somewhat fiexible so that they may be inserted into the tube to conform with the internal diameter thereof and still maintain a substantially even spacing between the inner surface of the tube 2 and such heater.
Electrical conduits l and 8 may be connected to the ends of the induction heater whereby a suitable amount of electrical energy may be supplied to the heater to elevate the temperature within the tube 2.
Of course, the temperature maintained within the tube 2 by the heater 5 will depend upon varying circumstances. However, as a matter of necessity, such temperature will be below the fusion point of the tubes 2 but will be at a high enough point so as to efiect combustion of the deposits within the tube 2.
As a practical matter, it has been found that a temperature of from 1500 to 2000 Fahrenheit efficiently effects combustion of the deposits, which are primarily carbonaceous in nature, on the interior wall of the tube 2.
The elongated induction heater 5 may be of any suitable length so that it can clean a complete section of tube in one operation, or it may be maintained in shorter sections so that it can be moved longitudinally along the interior of the tube so as to stepwise remove sedimentary deposits therefrom. Preferably a whole battery of tubes within one particular piece of equipment may be supplied each with a heater so that each tube in the battery is simultaneously cleaned. As a practical matter, it has been found that maintaining the temperature between 1500 and 2000 Fahrenheit for a period of from five to fifteen minutes will thoroughly clean, or effect combustion of the deposits within the tube 2,
What is claimed is:
1. A method of removing carbonaceous deposits from still tubes in situ comprising the steps of, producing a uniform fiameless heat by induction heating in the walls of a, tube simultaneously throughout its whole length and of a sufiiciently high temperature to destroy the deposits in the tube but not sufficiently high to adversely affect the tube.
2. In a method of removing carbonaceous deposits from the interior of a still tube by the combustion of said deposits,the steps including inducing a uniform heat of about 1,500 F. to 2,000 F. substantially throughout the whole length of the tube to destroy said deposits, and maintaining the induced temperature in the tube between about 1500 F. and 2,000 F. which is below its fusion temperature to inhibit damage thereto.
MORRIS R. SHAW.
REFERENCES CITED The following references are of record in the file of this patent:
UNITED STATES PATENTS

Claims (1)

1. A METHOD OF REMOVING CARBONACEOUS DEPOSITS FROM STILL TUBES IN SITU COMPRISING THE STEPS OF, PRODUCING A UNIFORM FLAMELESS HEAT BY INDUCTION HEATING IN THE WALLS OF A TUBE SIMULTANEOUSLY THROUGHOUT ITS WHOLE LENGTH AND OF A SUFFICIENTLY HIGH TEMPERATURE TO DESTROY THE DEPOSITS IN THE TUBE BUT NOT SUFFICIENTLY HIGH TO ADVERSELY AFFECT THE TUBE.
US47651A 1948-09-03 1948-09-03 Removing carbonaceous deposits from still tubes Expired - Lifetime US2620286A (en)

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3092514A (en) * 1959-05-25 1963-06-04 Petro Electronics Corp Method and apparatus for cleaning and thawing flow lines and the like
US3437714A (en) * 1965-05-21 1969-04-08 Lummus Co Process for the production of ethylene
US4304609A (en) * 1980-02-28 1981-12-08 Morris James B N Drill cuttings treatment apparatus and method
US4351678A (en) * 1980-08-06 1982-09-28 Usines A Cuivre Et A Zinc De Liege Method of making corrosion resistant phosphorous copper or phosphorous copper alloy pipes
US4377420A (en) * 1980-03-06 1983-03-22 United Technologies Corporation Removal of carbonaceous material from gas turbine cavities
US4453319A (en) * 1980-02-28 1984-06-12 Morris James B N Aqueous drill cutting treatment apparatus and method
US4988367A (en) * 1987-12-29 1991-01-29 Shell Oil Company Process for removal of flyash deposits

Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US855210A (en) * 1906-09-26 1907-05-28 Archibald Stewart Boiler-tube cleaner.
US1872410A (en) * 1930-04-15 1932-08-16 Kore Inc Method of controlling scale in gas cutting of metals
US1901803A (en) * 1930-07-01 1933-03-14 William T Davis Method of decarbonizing oil refining apparatus
US2060663A (en) * 1934-03-17 1936-11-10 Gen Electric Processing graphite
US2118480A (en) * 1934-11-08 1938-05-24 Howard E Somes Method of treating metals or metallic articles
US2289351A (en) * 1939-04-06 1942-07-14 Texas Co Method of cleaning heater tubes
US2293047A (en) * 1935-12-31 1942-08-18 Ohio Crankshaft Co Apparatus for zone hardening
US2397629A (en) * 1943-06-18 1946-04-02 Induction Heating Corp Induction heating
GB585921A (en) * 1943-11-22 1947-02-28 Birmingham Electr Furnaces Ltd Improvements in, or relating to, the decarburisation of iron or iron alloy castings
US2432868A (en) * 1944-04-04 1947-12-16 Western Electric Co Method of removing insulation
US2472445A (en) * 1945-02-02 1949-06-07 Thermactor Company Apparatus for treating oil and gas bearing strata

Patent Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US855210A (en) * 1906-09-26 1907-05-28 Archibald Stewart Boiler-tube cleaner.
US1872410A (en) * 1930-04-15 1932-08-16 Kore Inc Method of controlling scale in gas cutting of metals
US1901803A (en) * 1930-07-01 1933-03-14 William T Davis Method of decarbonizing oil refining apparatus
US2060663A (en) * 1934-03-17 1936-11-10 Gen Electric Processing graphite
US2118480A (en) * 1934-11-08 1938-05-24 Howard E Somes Method of treating metals or metallic articles
US2293047A (en) * 1935-12-31 1942-08-18 Ohio Crankshaft Co Apparatus for zone hardening
US2289351A (en) * 1939-04-06 1942-07-14 Texas Co Method of cleaning heater tubes
US2397629A (en) * 1943-06-18 1946-04-02 Induction Heating Corp Induction heating
GB585921A (en) * 1943-11-22 1947-02-28 Birmingham Electr Furnaces Ltd Improvements in, or relating to, the decarburisation of iron or iron alloy castings
US2432868A (en) * 1944-04-04 1947-12-16 Western Electric Co Method of removing insulation
US2472445A (en) * 1945-02-02 1949-06-07 Thermactor Company Apparatus for treating oil and gas bearing strata

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3092514A (en) * 1959-05-25 1963-06-04 Petro Electronics Corp Method and apparatus for cleaning and thawing flow lines and the like
US3437714A (en) * 1965-05-21 1969-04-08 Lummus Co Process for the production of ethylene
US4304609A (en) * 1980-02-28 1981-12-08 Morris James B N Drill cuttings treatment apparatus and method
US4453319A (en) * 1980-02-28 1984-06-12 Morris James B N Aqueous drill cutting treatment apparatus and method
US4377420A (en) * 1980-03-06 1983-03-22 United Technologies Corporation Removal of carbonaceous material from gas turbine cavities
US4351678A (en) * 1980-08-06 1982-09-28 Usines A Cuivre Et A Zinc De Liege Method of making corrosion resistant phosphorous copper or phosphorous copper alloy pipes
US4988367A (en) * 1987-12-29 1991-01-29 Shell Oil Company Process for removal of flyash deposits

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