US2618537A - Process for briqueting combustible materials - Google Patents
Process for briqueting combustible materials Download PDFInfo
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- US2618537A US2618537A US88268A US8826849A US2618537A US 2618537 A US2618537 A US 2618537A US 88268 A US88268 A US 88268A US 8826849 A US8826849 A US 8826849A US 2618537 A US2618537 A US 2618537A
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- fuel
- water
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- briquette
- briqueting
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L5/00—Solid fuels
- C10L5/02—Solid fuels such as briquettes consisting mainly of carbonaceous materials of mineral or non-mineral origin
Definitions
- This invention relates to the briqueting of solid fuels such as coal in all its forms, gas coke dust, and metallurgical coke dust.
- the invention also relates to new briquettes, to a new briqueting dough, and to apparatus employed in the making of such briquettes.
- Pulverized combustible materials such as coal have heretofore been briqueted by mixing such materials, for instance pulverized coal, with 6 to 8% of molten pitch at a temperature about 120 C. That process requires equipment for heating the tar, and equipment for drying the fuel particles, which must be as thoroughly desiccated as possible. The drying equipment is of necessity, large, and the relative proportion of tar employed increases the cost of the product.
- An object of this invention is to briquette solid combustible materials without desiccation and with a reduced quantity of binder. Another object of the invention is to produce apparatus capable of briqueting water-wet products. Another object of they invention is to briquette wet fuels and to produce a novel watery dough capable of being briqueted.
- the objects of the invention are accomplished generally speaking by mixing a wetted pulverized fuel with a water emulsion of a colloidal combustible, deaerating the wet mass, preferably under light vacuum, and producing the briquettes by extrusion of the dough and division of the p extruded mass.
- the extruded mass is preferably compressed before division.
- the dough need not contain over 2% of the colloidal emulsion.
- This water emulsion contains acombustible divided to colloidal fineness. Such combustibles are illustratedby bitumen, petroleum pitch, and
- Figure 1 is a vertical sectional view through apparatus for making such briquettes and Figure 2 is a plan view, also partly in section, of the apparatus of Figure 1.
- Figure 3 is a perspective View of a briquette.
- a solid fuel is reduced to particles having a maximum dimension on the order of 2 mm. This constitutes preferred practice although the briqueting process can be employed on larger particles.
- the pulverized fuel is then mixed with Water. These fuels are usually carbonaceous and hydrophobic so that it is advisable to use a wetting agent in the water. Ordinary wetting agents are useful,
- An emulsion is now made up of water and a colloidal combustible.
- colloidal combustibles may be named sludges, bitumen, petroleum pitch from the distillation or cracking of oil, and coal tar from gas works, coke works, or from the distillation of coal at low, medium or high temperature.
- One said emulsion contains water and 50% bitumen.
- Another contains 30% petroleum pitch, or coal tar, 40% water and 30% of an emulsifier or plasticizer such as bentonite or oleine. 2% or less of this emulsion is all that is required for the making of said dough, and it will be observed that of 2% only about V2 is combustible and expensive.
- the dough When the dough has been prepared it is deaerated in order to eliminate occluded gases such as air.
- the de-aerating can be carried out satisfactorily at normal or slightly elevated temperature under a mere 5 to 10 mm. of water vacuum pressure.
- the temperatureused in mixing and de-aerating need not exceed C. Employment of this temperature facilitates the hardening of the product after extrusion and moulding.
- the product is preferably maintained under vacuum until extrusion has been completed.
- a supporting pan 16 receives the extruded material [2 and carries it to the cooperating rotating rollers H, I8 which are provided with cooperating circular knives [9 which cut the dough into longitudinal strips, and by coperating transverse ridges 20, 2
- the pockets between adjacent ridges and adjacent knives in the two rollers compress and shape the dough to the required size.
- the pressure employed upon the dough may be on the order of 1,000 kilos per sq. cm.
- the products discharged are preferably dried rapidly at about 40 C. either in a drier or exposed to the air.
- An ordinary briqueting press can be used by cutting the dough to appropriate sizes for filling the press.
- Example I Appr. 87% dry pulverized coal.
- Example II Appr. 94% crushed coal containing about 6 to 8% water.
- the method of making a fuel briquette that comprises wetting solid carbonaceous fuel particles with an aqueous solution of a wetting agent for carbonaceous materials, mixing the wet particles with circa 1-2% by weight of an aqueous emulsion of a bituminous combustible divided to colloidal fineness, the total Water in the fuel at this stage approximating 10-12% by weight, deaerating the mixture under light vacuum at a temperature in the range from atmospheric to about C., extruding the deaerated mass, forming the extrusion mass into a sheet of uniform thickness With pressure, molding the said sheet thereby dividing it into sections of briquette shape under heavy pressure, and drying it with moderate and sustained heat.
- a fuel briquette that comprises wetting solid carbonaceous fuel particles having a maximum dimension on the order of 2 mm. with an aqueous solution of a wetting agent, mixing the wet particles with circa 1-2% by weight of a water emulsion of which about half is a bituminous colloidal combustible, the total water in the fuel at this stage approximating 10-12% by weight, deaerating the mixture under light vacuum of 5-10 mm. water at temperatures from atmospheric to 90 C., extruding the mass under continued vacuum, rolling it into a sheet, subdividing this sheet and molding the di visions under heavy pressure of about 1,000 kilos per sq. cm., and drying the mass.
- a fuel briquette that comprises wetting solid carbonaceous fuel particles with an aqueous solution of a wetting agent for carbonaceous materials, mixing the wet particles with circa 1-2% by weight of an aqueous emulsion of a bituminous combustible divided to colloidal fineness, the total water in the fuel at this stage approximating 10-12% by weight, deaerating the mixture under light vacuum at a temperature in the range from atmospheric to about 90 C., extruding the deaerated mass, rolling and flattening the plastic extrusion mass, molding the flattened mass under heavy pressure, thereby dividing it into sections imparting density and briquette shape to said sections, and drying the briquettes at about 40 C.
Description
Nov. 18, 1952 RABU PROCESS FOR BRIQUETING COMBUSTIBLE MATERIALS Filed April 19, 1949 TEL INVENTOR. M0055 Lows 74A= P950 qrraP/vzy Patented Nov. 18, 1952 PROCESS FOR BRIQUETING COMBUSTEBLE I MATERIALS dudes Louis Marie Rabu, Grenoble, France Application April 19, 1949, Serial No. 88,268 In France April 27, 1948 3 Claims.
This invention relates to the briqueting of solid fuels such as coal in all its forms, gas coke dust, and metallurgical coke dust. The invention also relates to new briquettes, to a new briqueting dough, and to apparatus employed in the making of such briquettes.
Pulverized combustible materials such as coal have heretofore been briqueted by mixing such materials, for instance pulverized coal, with 6 to 8% of molten pitch at a temperature about 120 C. That process requires equipment for heating the tar, and equipment for drying the fuel particles, which must be as thoroughly desiccated as possible. The drying equipment is of necessity, large, and the relative proportion of tar employed increases the cost of the product.
An object of this invention is to briquette solid combustible materials without desiccation and with a reduced quantity of binder. Another object of the invention is to produce apparatus capable of briqueting water-wet products. Another object of they invention is to briquette wet fuels and to produce a novel watery dough capable of being briqueted.
The objects of the invention are accomplished generally speaking by mixing a wetted pulverized fuel with a water emulsion of a colloidal combustible, deaerating the wet mass, preferably under light vacuum, and producing the briquettes by extrusion of the dough and division of the p extruded mass. The extruded mass is preferably compressed before division.
In the practice of the invention the dough need not contain over 2% of the colloidal emulsion. This water emulsion contains acombustible divided to colloidal fineness. Such combustibles are illustratedby bitumen, petroleum pitch, and
coal tar.
The invention will be better understood by reference to the accompanyin drawings, wherein Figure 1 is a vertical sectional view through apparatus for making such briquettes and Figure 2 is a plan view, also partly in section, of the apparatus of Figure 1. Figure 3 is a perspective View of a briquette.
In carrying out the invention a solid fuel is reduced to particles having a maximum dimension on the order of 2 mm. This constitutes preferred practice although the briqueting process can be employed on larger particles. The pulverized fuel is then mixed with Water. These fuels are usually carbonaceous and hydrophobic so that it is advisable to use a wetting agent in the water. Ordinary wetting agents are useful,
p ularly hos t t eretofore have been used for wetting coal. Examples are the sulfonated fatty alcohols. The percentage of water in the extrusion mass, the dough, should approximate 10 to 12% as this produces a very homogeneous and satisfactory extrusion mass. When the pulverized fuel is dried the entire quantity of water may be added but when the fuel is wet only that Water is added which is needed to bring the water content to approximately 10 to 12%.
An emulsion is now made up of water and a colloidal combustible. Among the colloidal combustibles may be named sludges, bitumen, petroleum pitch from the distillation or cracking of oil, and coal tar from gas works, coke works, or from the distillation of coal at low, medium or high temperature. One said emulsion contains water and 50% bitumen. Another contains 30% petroleum pitch, or coal tar, 40% water and 30% of an emulsifier or plasticizer such as bentonite or oleine. 2% or less of this emulsion is all that is required for the making of said dough, and it will be observed that of 2% only about V2 is combustible and expensive.
When the dough has been prepared it is deaerated in order to eliminate occluded gases such as air. The de-aerating can be carried out satisfactorily at normal or slightly elevated temperature under a mere 5 to 10 mm. of water vacuum pressure. The temperatureused in mixing and de-aerating need not exceed C. Employment of this temperature facilitates the hardening of the product after extrusion and moulding. The product is preferably maintained under vacuum until extrusion has been completed.
The extrusion and moulding is conveniently in the novel apparatus shown in the accompanying drawing wherein Hi is an extrusion nozzle having an orifice Ii through'which the plastic mass 12 is extruded, being caught between two press rollers l3, M which expand the width in the mass at the expense of its thickness and produce close contact between all portions of the binder and the fuel particles. After issuing from the rollers l3, l4, the plastic mass maybe slit lengthwise into ribbons, the ribbons being cut off from time to time, each strip thus produced being perforated so that they can be strung on wire with out'packaging'. In Figure 3 is sh-own a briquet l5 having a perforation 15' which can be used for stringingf This briquette has been formed by the process which has-been hereinabov described. I
'Cc'a'l products are sold in standard sizes to fit the grates of standard furnaces and are known by names such as buckwheat, pea, chestnut, stove and eg and it is desired to prepare the briquettes in sizes conforming to these established wants. The apparatus shown in Figures 1 and 2 accomplishes this. A supporting pan 16 receives the extruded material [2 and carries it to the cooperating rotating rollers H, I8 which are provided with cooperating circular knives [9 which cut the dough into longitudinal strips, and by coperating transverse ridges 20, 2| which cut the dough transversely. The pockets between adjacent ridges and adjacent knives in the two rollers compress and shape the dough to the required size. The pressure employed upon the dough may be on the order of 1,000 kilos per sq. cm. The products discharged are preferably dried rapidly at about 40 C. either in a drier or exposed to the air.
The agglomerated products hold together perfectly, although the proportion of binders in the dry product is less than 2%. On the other hand, when molten pitch is used for briqueting it is necessary to use 6 to 8% and to heat the dough to 120 C. Furthermore the screenings must be dried prior to mingling with the pitch, in the molten pitch process. Consequently, this process eliminates the use of driers for the powdered fuel and reduces the amount of binder to a new and lower order of magnitude. The process also affects savings in heat because of the difierence in drying temperatures employed.
These advantages do not come wholly from any one step of the process alone but are a product of the combination. For instance, if de-aerating is eliminated the amount of colloidal binder employed must be increased. On the other hand, if de-aerating is used alone for a mixture of coal and molten pitch the amount of water added for pugging is 18 to 20%, producing a very soft dough which cannot be shaped in the moulding rollers. Consequently, this invention eliminates the evaporation of an additional 8 to 10% of water which otherwise would have to be removed.
An ordinary briqueting press can be used by cutting the dough to appropriate sizes for filling the press.
The following examples illustrate some of the doughs.
Example I Appr. 87% dry pulverized coal.
Appr. 11% water mixed with wetting materials.
Appr. 2% of an emulsion composed of 50% water and 50% bitumen.
Example II Appr. 94% crushed coal containing about 6 to 8% water.
Appr. 4% water mixed with Wetting materials.
Appr. 2% of an emulsion composed of 50% Water and 50% bitumen.
In the first example mixing was carried out in the cold. In the second example it was carried out at 90 C. In both cases de-aeration was carried out under a vacuum of to mm. of water pressure.
As many apparently widely different embodiments of the present invention may be made without departing from the spirit and scope thereon, it is to be understood that the invention is not limited to the specific embodiments.
What is claimed is:
1. The method of making a fuel briquette that comprises wetting solid carbonaceous fuel particles with an aqueous solution of a wetting agent for carbonaceous materials, mixing the wet particles with circa 1-2% by weight of an aqueous emulsion of a bituminous combustible divided to colloidal fineness, the total Water in the fuel at this stage approximating 10-12% by weight, deaerating the mixture under light vacuum at a temperature in the range from atmospheric to about C., extruding the deaerated mass, forming the extrusion mass into a sheet of uniform thickness With pressure, molding the said sheet thereby dividing it into sections of briquette shape under heavy pressure, and drying it with moderate and sustained heat.
2. The method of making a fuel briquette that comprises wetting solid carbonaceous fuel particles having a maximum dimension on the order of 2 mm. with an aqueous solution of a wetting agent, mixing the wet particles with circa 1-2% by weight of a water emulsion of which about half is a bituminous colloidal combustible, the total water in the fuel at this stage approximating 10-12% by weight, deaerating the mixture under light vacuum of 5-10 mm. water at temperatures from atmospheric to 90 C., extruding the mass under continued vacuum, rolling it into a sheet, subdividing this sheet and molding the di visions under heavy pressure of about 1,000 kilos per sq. cm., and drying the mass.
3. The method of making a fuel briquette that comprises wetting solid carbonaceous fuel particles with an aqueous solution of a wetting agent for carbonaceous materials, mixing the wet particles with circa 1-2% by weight of an aqueous emulsion of a bituminous combustible divided to colloidal fineness, the total water in the fuel at this stage approximating 10-12% by weight, deaerating the mixture under light vacuum at a temperature in the range from atmospheric to about 90 C., extruding the deaerated mass, rolling and flattening the plastic extrusion mass, molding the flattened mass under heavy pressure, thereby dividing it into sections imparting density and briquette shape to said sections, and drying the briquettes at about 40 C.
RABU, JUDES LOUIS MARIE.
REFERENCES CITED The following references are of record in the file of this patent:
UNITED STATES PATENTS Number Name Date 66,277 Ames July 2, 1867 209,069 Norris Oct. 15, 1878 257,985 Siffken May 16, 1882 790,918 Du Pont May 30, 1905 946,745 Wadsworth Jan. 18, 1910 1,2 2,291 Vogel Jan. 16, 1917 1,549,436 Billinghame Aug. 11, 1925 1,596,218 Wagel Aug. 17, 1926 1,780,205 Maurel Nov. 4, 1930 1,790,356 Smith Jan. 27, 1931 1,811,935 Hue June 30, 1931 2,008,147 Morrell July 16, 1935 2,207,459 Futo July 9, 1940 2,253,699 Goss Aug. 26, 1941 OTHER REFERENCES Hackhs "Chem. Dictionary, The Blakeston 00., 2nd ed, Philadelphia, 1944.
Claims (1)
1. THE METHOD OF MAKING A FUEL BRIQUETTE THAT COMPRISES WETTING SOLID CARBONACEOUS FUEL PARTICLES WITH AN AQUEOUS SOLUTION OF A WETTING AGENT FOR CARBONACEOUS MATERIALS, MIXING THE WET PARTICLES WITH CIRCA 1-2% BY WEIGHT OF AN AQUEOUS. EMULSION OF THE BITUMINOUS COMBUSTIBLE DIVIDED TO COLLOIDAL FINENESS, THE TOTAL WATER IN THE FUEL AT THIS STAGE APPPROXIMATING 10-12% BY WEIGHT, DEAERATING THE MIXTURE UNDER LIGHT VACUUM AT A TEMPERATURE IN THE RANGE FROM ATMOSPHERIC TO ABOUT 90* C., EXTRUDING THE DEAERATED MASS, FORMING THE EXTRUSION MASS INTO A SHEET OF UNIFORM THICKNESS WITH PRESSURE, MOLDING THE SAID SHEET THEREBY DIVIDED IT INTO SECTIONS OF BRIQUETTE SHAPE UNDER HEAVY PRESSURE, AND DRYING IT WITH MODERATE AND SUSTAINED HEAT.
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Application Number | Priority Date | Filing Date | Title |
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FR2618537X | 1948-04-27 |
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US2618537A true US2618537A (en) | 1952-11-18 |
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US88268A Expired - Lifetime US2618537A (en) | 1948-04-27 | 1949-04-19 | Process for briqueting combustible materials |
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2501636A1 (en) * | 1974-01-18 | 1975-07-24 | Shell Int Research | PROCESS FOR THE PRODUCTION OF BRIQUETTES |
US4153419A (en) * | 1976-12-03 | 1979-05-08 | Shell Oil Company | Agglomeration of coal fines |
US4243393A (en) * | 1977-10-13 | 1981-01-06 | Banner Energy Corporation | Coal article |
US4412840A (en) * | 1979-10-09 | 1983-11-01 | Goksel Mehmet A | Pelletizing lignite |
US4548615A (en) * | 1983-06-30 | 1985-10-22 | Institut Francais Du Petrole | Process for manufacturing solid fuels from heavy hydrocarbon oils and vegetable materials |
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US209069A (en) * | 1878-10-15 | Improvement in fire-kindlers | ||
US257985A (en) * | 1882-05-16 | Canada | ||
US790918A (en) * | 1903-06-10 | 1905-05-30 | Francis I Du Pont | Apparatus for the manufacture of strips of explosive powder. |
US946745A (en) * | 1908-01-06 | 1910-01-18 | Schultze Gunpowder Company Ltd | Machinery or apparatus for dividing gelatinous gunpowder into particles or grains. |
US1212291A (en) * | 1916-07-22 | 1917-01-16 | Gen Briquetting Company | Manufacture of briquets. |
US1549436A (en) * | 1925-05-15 | 1925-08-11 | Billinghame Wilfred Ernest | Emulsive agent and the manufacture thereof |
US1596218A (en) * | 1924-11-08 | 1926-08-17 | Lehigh Coal And Navigation Com | Briquette and process of making the same |
US1780205A (en) * | 1928-03-24 | 1930-11-04 | Maurel Invest Corp | Process of manufacturing fuel briquettes |
US1790356A (en) * | 1931-01-27 | Solid fttel | ||
US1811935A (en) * | 1929-03-18 | 1931-06-30 | Hue Marcel Hippolyte | Process for manufacturing agglomerated products |
US2008147A (en) * | 1934-07-11 | 1935-07-16 | Jacque C Morrell | Manufacture of compressed carbonaceous materials and activated carbon |
US2207459A (en) * | 1938-03-16 | 1940-07-09 | Ellis Corp Patents & Invest Lt | Method of making fuel briquettes, and binding agent suitable therefor |
US2253699A (en) * | 1937-12-17 | 1941-08-26 | Carlisle Lumber Company | Method and apparatus for making fuel briquettes |
-
1949
- 1949-04-19 US US88268A patent/US2618537A/en not_active Expired - Lifetime
Patent Citations (14)
Publication number | Priority date | Publication date | Assignee | Title |
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US1790356A (en) * | 1931-01-27 | Solid fttel | ||
US209069A (en) * | 1878-10-15 | Improvement in fire-kindlers | ||
US257985A (en) * | 1882-05-16 | Canada | ||
US66277A (en) * | 1867-07-02 | Improved machine foe peepaeing peat foe fuel | ||
US790918A (en) * | 1903-06-10 | 1905-05-30 | Francis I Du Pont | Apparatus for the manufacture of strips of explosive powder. |
US946745A (en) * | 1908-01-06 | 1910-01-18 | Schultze Gunpowder Company Ltd | Machinery or apparatus for dividing gelatinous gunpowder into particles or grains. |
US1212291A (en) * | 1916-07-22 | 1917-01-16 | Gen Briquetting Company | Manufacture of briquets. |
US1596218A (en) * | 1924-11-08 | 1926-08-17 | Lehigh Coal And Navigation Com | Briquette and process of making the same |
US1549436A (en) * | 1925-05-15 | 1925-08-11 | Billinghame Wilfred Ernest | Emulsive agent and the manufacture thereof |
US1780205A (en) * | 1928-03-24 | 1930-11-04 | Maurel Invest Corp | Process of manufacturing fuel briquettes |
US1811935A (en) * | 1929-03-18 | 1931-06-30 | Hue Marcel Hippolyte | Process for manufacturing agglomerated products |
US2008147A (en) * | 1934-07-11 | 1935-07-16 | Jacque C Morrell | Manufacture of compressed carbonaceous materials and activated carbon |
US2253699A (en) * | 1937-12-17 | 1941-08-26 | Carlisle Lumber Company | Method and apparatus for making fuel briquettes |
US2207459A (en) * | 1938-03-16 | 1940-07-09 | Ellis Corp Patents & Invest Lt | Method of making fuel briquettes, and binding agent suitable therefor |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2501636A1 (en) * | 1974-01-18 | 1975-07-24 | Shell Int Research | PROCESS FOR THE PRODUCTION OF BRIQUETTES |
US3966427A (en) * | 1974-01-18 | 1976-06-29 | Shell Oil Company | Production of briquettes |
US4153419A (en) * | 1976-12-03 | 1979-05-08 | Shell Oil Company | Agglomeration of coal fines |
US4243393A (en) * | 1977-10-13 | 1981-01-06 | Banner Energy Corporation | Coal article |
US4412840A (en) * | 1979-10-09 | 1983-11-01 | Goksel Mehmet A | Pelletizing lignite |
US4548615A (en) * | 1983-06-30 | 1985-10-22 | Institut Francais Du Petrole | Process for manufacturing solid fuels from heavy hydrocarbon oils and vegetable materials |
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