US2600158A - Process for hydrocarbon gas mixture analysis - Google Patents
Process for hydrocarbon gas mixture analysis Download PDFInfo
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- US2600158A US2600158A US772561A US77256147A US2600158A US 2600158 A US2600158 A US 2600158A US 772561 A US772561 A US 772561A US 77256147 A US77256147 A US 77256147A US 2600158 A US2600158 A US 2600158A
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N25/00—Investigating or analyzing materials by the use of thermal means
- G01N25/14—Investigating or analyzing materials by the use of thermal means by using distillation, extraction, sublimation, condensation, freezing, or crystallisation
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T436/00—Chemistry: analytical and immunological testing
- Y10T436/21—Hydrocarbon
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T436/00—Chemistry: analytical and immunological testing
- Y10T436/25—Chemistry: analytical and immunological testing including sample preparation
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T436/00—Chemistry: analytical and immunological testing
- Y10T436/25—Chemistry: analytical and immunological testing including sample preparation
- Y10T436/25875—Gaseous sample or with change of physical state
Definitions
- the present invention is concerned with an improved process for analyzing light hydrocarbon gases.
- the invention is more particularly concerned with a method for determining the analysis and composition of petroleum gases wherein the concentration of various light constituents in the gas is relatively small.
- My method comprises removing the methane and segregating constituents boiling in the range of hydrocarbons containing from 2 to carbon atoms in the molecule. This latter fraction is then handled in a manner as hereinafter described.
- the amount of sample taken into the system from pipette l is determined by the pressure on manometer 4.
- the desired amount of sample is allowed to flow through valve 3 into the system.
- valve 3 is closed.
- the gas passes through ascarite and phosphorus pentoxide I3 and H! where the carbon dioxide and Water vapor are removed.
- the gas, free of undesirable carbon dioxide and Water vapor, is introduced into trap l 2 which is immersed in liquid nitrogen at a temperature of --196 C.
- gases boiling above the boiling point of methane are condensed.
- the system is controlled so that a mercury diffusion pump is withdrawing uncondensed gases comprising methane from the system through valve 1.
- Other gases which are removed from the system comprise relatively large quantities of uncondensed oxygen and nitrogen. Pumping is continued until the pressure on the system is below about 2 millimeters of mercury. At this point, valve 5 is closed and pumping is continued on the remainder of the system until the pressure is lowered to the vapor pressure of the mercury in the System.
- the sample contained in trap I2 is transferred to distillation trap l5.
- This is preferably accomplished by removing the nitrogen bath and substituting a Dry Ice-acetone bath, the temperature of which is about '80 C.
- the distillation trap I5 is cooled to 196 0., thus causing the sample to recondense in the distillation trap.
- the pressure changes involved in the transfer of the sample from zone 12 to zone l5 are watched by using the Pirani gauge [6. When the reading on the Pirani gauge is again approximately zero, the transfer is complete and valve 6 is closed.
- the cold loath around the distillation trap I5 is lowered until a slow rise in temperature is noted on the thermocouple IT.
- a rise in pressure shown by the Pirani gauge l 6 indicates that the distillation temperature for a compound has been reached.
- the cold bath is adjusted so that the temperature remains constant and the fraction is taken off by opening valve [0 and condensing it in combustion trap l8 which is maintained at a temperature of l96 C. by immersion in a liquid nitrogen bath.
- valve 9 is closed isolating the distillation trap.
- the volume of the fraction in zone I 8 is determined by bringing the temperature of zone l8 to about C. and opening valves I I1 and 8. The sample is allowed to expand into the McLeod gauge I9 where the pressure is determined. The volume of the system is known so that the volume of sample can be calculated.
- the sample is also allowed to expand into Langmuir viscosity gauge 20 by which the molecular weight of the sample is determined. (Procedure described in Procedures in Experimental Physics, by Strong, pages 146-147)
- the sample is next reconde'nsed into the burnin'g trap is and oxygen is added from bulb 2
- Valve I0 is closed, the burning trap I8 is brought to room temperatrue and the sample is burned for about one minute with either high voltage or radio frequency glow discharge. When burning is completed, the trap is again cooled to a temperature of -196 C. Valves 1 and [-0 are opened and the excess oxygen is pumped off.
- the after-burning read ing is taken on the McLeod gauge [9 by closing valve 1, opening valves '8'and Ill and raising the temperature of trap [8 to a temperature of -80 C.
- the after-burning reading gives a measure of the carbon dioxide formed during the combustion of the sample.
- the ratio of the afterburning reading to the before-burning reading shows the number of carbon atomsper molecule in the fraction.
- valves 1, 8, H! and II The system is thoroughly evacuated by opening valves 1, 8, H! and II and pumpinguntil the system is completely degassed. Valves 1, 8, l0 and H are closed and valve 9 is opened. The temperature is adjusted and the procedure is repeated for the next fraction.
- Distillation temperatures are reproducible within 2 C. and by calibrating the apparatus with known gases, a method of identification is obtained.
- Molecular weight determination is accurate within 2 molecular weight units on compounds having molecular weights up to 72. Heavier compounds suffer loss of accuracy due to dilution with traces of lighter gases.
- My invention is directly applicable in the analysis of petroleum gases comprising lig-ht hydrocarbon constituents. It is especially applicable when these light hydrocarbon constituents contain appreciable quantities of methane, oxygen and nitrogen and relatively small quantities of constituents having from 2 to carbon atoms in the molecule.
- the general procedure used in my process is to segregate hydrocarbon constituents having 2 and more carbon atoms in the molecule from the methane, oxygen and nitrogen as described. I then segregate a fraction containing from 2 to 5 carbon atoms in the molecule in a distillation zone. My next step is to progressively segregrate the lowest boiling constituent from the remaining constituents by cooling the fraction to a temperature of 196 C. 1 then allow the temperature to rise until a rise in pressure is indicated on the gauge. This rise in pressure indicates that the distillation temperature for the particular compound has been reached. I hold the temperature constant until the pressure on the gauge again drops to zero indicating that the particular compound has been removed.
- This operation consists in distilling the lowest boiling constituent, condensing the same in a segregated zone, revaporizing the segregated constituent and determining the molecular weight.
- the vaporized constituent is recondensed and expanded into a McLeod gauge and a pressure reading taken.
- a determined quantity of oxygen is added and the sample burned and condensed.
- Oxygen is removed from the burnt sample and the amount of CO2 determined.
- Process for analyzing a gas mixture for its content of hydrocarbons of two to five carbon atoms wherein such hydrocarbons are present in minute quantities in admixture with methane and with relatively large quantities of oxygen and nitrogen which comprises placing said mixture in a separation zone at a temperature of about 196 C. and at a pressure below about 2 millimeters of mercury, whereby hydrocarbons boiling above methane are condensed while methane, oxygen and nitrogen remain uncondensed, removing methane, oxygen and nitrogen from the condensed hydrocarbon gases, transferring the remaining condensed gases comprising a hydro- 4 carbon fraction of 2 to 5 carbon atoms from said separating zone into a distillation zone maintained at a temperature of about -196 C.
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- General Physics & Mathematics (AREA)
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- Investigating Or Analyzing Non-Biological Materials By The Use Of Chemical Means (AREA)
Description
June 10, 1952 A. T. CLOTHIER PROCESS FOR HYDROCARBON GAS MIXTURE ANALYSIS Filed Sept. 6, 1947 mm J \rd JUNE .2
m p b CZr'ckzL'eTCZothier Savant/or g e n r o b b a Patented June 10, 1952 2,600,158 ICE PROCESS FOR HYDROCARBON GAS lVIIXTURE ANALYSIS Archie T. Clothier, Tulsa, Okla., assignor to Standard Oil Development Company, a corporation of Delaware Application September 6, 1947, Serial No. 772,561
1 Claim.
The present invention is concerned with an improved process for analyzing light hydrocarbon gases. The invention is more particularly concerned with a method for determining the analysis and composition of petroleum gases wherein the concentration of various light constituents in the gas is relatively small. My method comprises removing the methane and segregating constituents boiling in the range of hydrocarbons containing from 2 to carbon atoms in the molecule. This latter fraction is then handled in a manner as hereinafter described.
It is well known in the art to analyze various gas compositions by many types of gas analysis a paratus. While these methods are generally satisfactory for ordinary gases they are not particularly adaptable for determining the actual composition of gas mixtures secured in the production of petroleum oils. These latter gas compositions for example may contain relatively large quantities of certain constituents and relatively minor quantities of other constituents. In accordance with my process, I am able to accurately analyze gas compositions, particularly those compositions containing from 2 to 5 carbon atoms in the molecule and resulting from the production of petroleum oils.
My invention may be readily understood by reference to the drawing illustrating one embodiment of the same. Referring specifically to the drawing, the gas sample to be analyzed is collected inpipette I. This entire system is evacuated and is of a known capacity. Stopcock or valve 3 is closed and stopcock 2 is opened. The sample is allowed to expand into the mercury manometer 4 where the pressure of the sample can be read.
The amount of sample taken into the system from pipette l is determined by the pressure on manometer 4. The desired amount of sample is allowed to flow through valve 3 into the system. When the desired amount of sample has passed into the system, valve 3 is closed. The gas passes through ascarite and phosphorus pentoxide I3 and H! where the carbon dioxide and Water vapor are removed.
The gas, free of undesirable carbon dioxide and Water vapor, is introduced into trap l 2 which is immersed in liquid nitrogen at a temperature of --196 C. In this unit gases boiling above the boiling point of methane are condensed. During this operation the system is controlled so that a mercury diffusion pump is withdrawing uncondensed gases comprising methane from the system through valve 1. Other gases which are removed from the system comprise relatively large quantities of uncondensed oxygen and nitrogen. Pumping is continued until the pressure on the system is below about 2 millimeters of mercury. At this point, valve 5 is closed and pumping is continued on the remainder of the system until the pressure is lowered to the vapor pressure of the mercury in the System.
At this point, the sample contained in trap I2 is transferred to distillation trap l5. This is preferably accomplished by removing the nitrogen bath and substituting a Dry Ice-acetone bath, the temperature of which is about '80 C. The distillation trap I5 is cooled to 196 0., thus causing the sample to recondense in the distillation trap. The pressure changes involved in the transfer of the sample from zone 12 to zone l5 are watched by using the Pirani gauge [6. When the reading on the Pirani gauge is again approximately zero, the transfer is complete and valve 6 is closed.
The cold loath around the distillation trap I5 is lowered until a slow rise in temperature is noted on the thermocouple IT. A rise in pressure shown by the Pirani gauge l 6 indicates that the distillation temperature for a compound has been reached. The cold bath is adjusted so that the temperature remains constant and the fraction is taken off by opening valve [0 and condensing it in combustion trap l8 which is maintained at a temperature of l96 C. by immersion in a liquid nitrogen bath. When the pressure no longer goes up with valve I 0 closed, the fraction has all been distilled oil and valve 9 is closed isolating the distillation trap.
The volume of the fraction in zone I 8 is determined by bringing the temperature of zone l8 to about C. and opening valves I I1 and 8. The sample is allowed to expand into the McLeod gauge I9 where the pressure is determined. The volume of the system is known so that the volume of sample can be calculated.
The sample is also allowed to expand into Langmuir viscosity gauge 20 by which the molecular weight of the sample is determined. (Procedure described in Procedures in Experimental Physics, by Strong, pages 146-147) The sample is next reconde'nsed into the burnin'g trap is and oxygen is added from bulb 2| by opening stopcock 22 slightly until the pressure in the system is about 2 millimeters of mercury as shown by manometer 23. Valve I0 is closed, the burning trap I8 is brought to room temperatrue and the sample is burned for about one minute with either high voltage or radio frequency glow discharge. When burning is completed, the trap is again cooled to a temperature of -196 C. Valves 1 and [-0 are opened and the excess oxygen is pumped off. The after-burning read ing is taken on the McLeod gauge [9 by closing valve 1, opening valves '8'and Ill and raising the temperature of trap [8 to a temperature of -80 C. The after-burning reading gives a measure of the carbon dioxide formed during the combustion of the sample. The ratio of the afterburning reading to the before-burning reading shows the number of carbon atomsper molecule in the fraction.
The system is thoroughly evacuated by opening valves 1, 8, H! and II and pumpinguntil the system is completely degassed. Valves 1, 8, l0 and H are closed and valve 9 is opened. The temperature is adjusted and the procedure is repeated for the next fraction.
Distillation temperatures are reproducible within 2 C. and by calibrating the apparatus with known gases, a method of identification is obtained. Molecular weight determination is accurate within 2 molecular weight units on compounds having molecular weights up to 72. Heavier compounds suffer loss of accuracy due to dilution with traces of lighter gases.
My invention is directly applicable in the analysis of petroleum gases comprising lig-ht hydrocarbon constituents. It is especially applicable when these light hydrocarbon constituents contain appreciable quantities of methane, oxygen and nitrogen and relatively small quantities of constituents having from 2 to carbon atoms in the molecule.
The general procedure used in my process is to segregate hydrocarbon constituents having 2 and more carbon atoms in the molecule from the methane, oxygen and nitrogen as described. I then segregate a fraction containing from 2 to 5 carbon atoms in the molecule in a distillation zone. My next step is to progressively segregrate the lowest boiling constituent from the remaining constituents by cooling the fraction to a temperature of 196 C. 1 then allow the temperature to rise until a rise in pressure is indicated on the gauge. This rise in pressure indicates that the distillation temperature for the particular compound has been reached. I hold the temperature constant until the pressure on the gauge again drops to zero indicating that the particular compound has been removed.
This operation consists in distilling the lowest boiling constituent, condensing the same in a segregated zone, revaporizing the segregated constituent and determining the molecular weight. The vaporized constituent is recondensed and expanded into a McLeod gauge and a pressure reading taken. A determined quantity of oxygen is added and the sample burned and condensed. Oxygen is removed from the burnt sample and the amount of CO2 determined. By this procedure I am able to accurately analyze a light hy drocarbon fraction to a high degree of accuracy.
The terms "Langmuir viscosity gauge, Pirani gauge and McLeod gauge as used in the specification and claims refer to these types of gauges and apparatus as they are known and described in standard textbooks, such as for example in Strong, Procedures in Experimental Physics, pages 138-148 (Prentice-Hall, Inc., 1946).
The process of my invention is not to be limited by any theory as to mode of operation, but only in and by the following claims in which it is desired to obtain all novelty insofar as the prior art permits.
What is claimed is:
Process for analyzing a gas mixture for its content of hydrocarbons of two to five carbon atoms wherein such hydrocarbons are present in minute quantities in admixture with methane and with relatively large quantities of oxygen and nitrogen which comprises placing said mixture in a separation zone at a temperature of about 196 C. and at a pressure below about 2 millimeters of mercury, whereby hydrocarbons boiling above methane are condensed while methane, oxygen and nitrogen remain uncondensed, removing methane, oxygen and nitrogen from the condensed hydrocarbon gases, transferring the remaining condensed gases comprising a hydro- 4 carbon fraction of 2 to 5 carbon atoms from said separating zone into a distillation zone maintained at a temperature of about -196 C. and at a pressure of about that of the vapor pressure of mercury, bringing said distillation zone into communication with an evacuated combustion zone cooled to a temperature of about 196 (3., raising the temperature of said distillation zone sufliciently to cause a measurable increase in pressure in said zone, maintaining said increased temperature until the completion of distillation of the hydrocarbon exhibiting the lowest boiling point in the hydrocarbon fraction is indicated by a drop in pressure, cutting off communication between said distillation zone and said combustion zone, raising the temperature in said combustion zone to about -80 C., measuring the pressure exerted by the resultant expanded hydrocarbon gas in a zone of known volume whereby the quantity of said lowest boiling hydrocarbon is determined, determining the molecular weight of said lowest boiling hydrocarbon by measuring its viscosiity at the indicated pressure, recondensing said hydrocarbon gas in said combustion zone by recooling said zone to about 196 C., introducing oxygen into said combustion zone under a pressure of about 2 millimeters of mercury, isolating said combustion zone and raising its temperature to ordinary room temperature, burning the mixture of hydrocarbon gas and oxygen by means of an electrical discharge, condensing the combustion products by recooling said combustion zone to about -196 C., removing excess oxygen, raising the temperature of the combustion zone to about 80 C., measuring the pressure exerted by the resultant expanded gas in a zone of known volume and determining the amount of carbon dioxide produced by said burning by comparing said last named pressure with the pressure exerted by said particular hydrocarbon when the temperature of said combustion chamber was previously raised to about -80 C. prior to said burning, and successively distilling each higher boiling hydrocarbon in said distillation zone and subjecting the thus separated hydrocarbon to the viscosity measuring, burning and associated steps in the manner aforesaid whereby each hydrocarbon of from 2 to 5 carbon atoms and the composite concentration of hydrocarbons of two to five carbon atoms in the gas sample are determined' ARCHIE T. CLOTHIER.
REFERENCES CITED The following references are of record in the file of this patent:
UNITED STATES PATENTS Number Name Date 2,389,706 Williams et a1. Nov. 27, 1945 2,414,876 Horvitz Jan. 28, 1947 2,427,261 Crawford Sept. 9, 1947 2,429,555 Langford et a1. Oct. 21, 1947 OTHER REFERENCES Strong, Procedures in Experimental Physics, pages -148, Prentice Hall, Inc., 1946.
Kriegel, Geophysics, vol. 9, No. 4, pages 447- 450. Presented at 14th annual meeting, Dallas, Texas, March 1944.
Davis et al., Ind. and Eng. Chem., Anal. Ed, vol. 4, No. 2, pages 193-197, April 15, 1932.
Harpel et al., Ind. and Eng. Chem, Anal. Ed, vol. 6, No. 5, pages 323-326, Sept. 15, 1934.
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US772561A US2600158A (en) | 1947-09-06 | 1947-09-06 | Process for hydrocarbon gas mixture analysis |
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US772561A US2600158A (en) | 1947-09-06 | 1947-09-06 | Process for hydrocarbon gas mixture analysis |
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Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2866691A (en) * | 1954-08-21 | 1958-12-30 | Geraetebau Anstalt | Apparatus for gas analysis |
US2888331A (en) * | 1954-12-27 | 1959-05-26 | Virginia C Carpenter | Testing device |
US3345137A (en) * | 1965-09-24 | 1967-10-03 | Chevron Res | Geochemical method of prospecting for petroleum |
US3953171A (en) * | 1973-04-27 | 1976-04-27 | Institut Francais Du Petrole, Des Carburants Et Lubrifiants | Method and apparatus for rapidly evaluating the hydrocarbon production capacity of sediments, using small samples thereof |
US4340391A (en) * | 1980-03-28 | 1982-07-20 | Chevron Research Company | Predicting hydrocarbon potential of an earth formation underlying a body of water by analysis of seeps containing low concentrations of methane |
US4444889A (en) * | 1980-03-28 | 1984-04-24 | Chevron Research Company | Predicting hydrocarbon potential of an earth formation underlying a body of water by analysis of seeps containing low concentrations of carbonaceous gases |
US4560664A (en) * | 1980-03-28 | 1985-12-24 | Chevron Research Company | Predicting hydrocarbon potential of an earth formation underlying a body of water by analysis of seeps containing low concentrations of carbonaceous gases |
US4574118A (en) * | 1980-03-28 | 1986-03-04 | Chevron Research Company | Predicting hydrocarbon potential of an earth formation underlying a body of water by analysis of seeps containing low concentrations of carbonaceous gases |
US4600559A (en) * | 1982-03-26 | 1986-07-15 | The United States Of America As Represented By The Administrator Environmental Protection Agency | Vacuum extractor with cryogenic concentration and capillary interface |
US20090314158A1 (en) * | 2008-06-23 | 2009-12-24 | Siemens Medical Solutions Usa, Inc. | Room Temperature Chemical Trap for the Purification of Gaseous Methane |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2389706A (en) * | 1943-01-07 | 1945-11-27 | Standard Oil Dev Co | Apparatus for gas analysis |
US2414876A (en) * | 1941-03-10 | 1947-01-28 | Esme E Rosaire | Gas analysis |
US2427261A (en) * | 1939-09-30 | 1947-09-09 | Phillips Petroleum Co | Method for analyzing gas |
US2429555A (en) * | 1942-08-08 | 1947-10-21 | Cecil T Langford | Method of and apparatus for analyzing gases and vapors absorbed in materials |
-
1947
- 1947-09-06 US US772561A patent/US2600158A/en not_active Expired - Lifetime
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2427261A (en) * | 1939-09-30 | 1947-09-09 | Phillips Petroleum Co | Method for analyzing gas |
US2414876A (en) * | 1941-03-10 | 1947-01-28 | Esme E Rosaire | Gas analysis |
US2429555A (en) * | 1942-08-08 | 1947-10-21 | Cecil T Langford | Method of and apparatus for analyzing gases and vapors absorbed in materials |
US2389706A (en) * | 1943-01-07 | 1945-11-27 | Standard Oil Dev Co | Apparatus for gas analysis |
Cited By (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2866691A (en) * | 1954-08-21 | 1958-12-30 | Geraetebau Anstalt | Apparatus for gas analysis |
US2888331A (en) * | 1954-12-27 | 1959-05-26 | Virginia C Carpenter | Testing device |
US3345137A (en) * | 1965-09-24 | 1967-10-03 | Chevron Res | Geochemical method of prospecting for petroleum |
US3953171A (en) * | 1973-04-27 | 1976-04-27 | Institut Francais Du Petrole, Des Carburants Et Lubrifiants | Method and apparatus for rapidly evaluating the hydrocarbon production capacity of sediments, using small samples thereof |
US4340391A (en) * | 1980-03-28 | 1982-07-20 | Chevron Research Company | Predicting hydrocarbon potential of an earth formation underlying a body of water by analysis of seeps containing low concentrations of methane |
US4444889A (en) * | 1980-03-28 | 1984-04-24 | Chevron Research Company | Predicting hydrocarbon potential of an earth formation underlying a body of water by analysis of seeps containing low concentrations of carbonaceous gases |
US4560664A (en) * | 1980-03-28 | 1985-12-24 | Chevron Research Company | Predicting hydrocarbon potential of an earth formation underlying a body of water by analysis of seeps containing low concentrations of carbonaceous gases |
US4574118A (en) * | 1980-03-28 | 1986-03-04 | Chevron Research Company | Predicting hydrocarbon potential of an earth formation underlying a body of water by analysis of seeps containing low concentrations of carbonaceous gases |
US4600559A (en) * | 1982-03-26 | 1986-07-15 | The United States Of America As Represented By The Administrator Environmental Protection Agency | Vacuum extractor with cryogenic concentration and capillary interface |
US20090314158A1 (en) * | 2008-06-23 | 2009-12-24 | Siemens Medical Solutions Usa, Inc. | Room Temperature Chemical Trap for the Purification of Gaseous Methane |
US8021468B2 (en) * | 2008-06-23 | 2011-09-20 | Siemens Medical Solutions Usa, Inc. | Room temperature chemical trap for the purification of gaseous methane |
US20120017761A1 (en) * | 2008-06-23 | 2012-01-26 | Siemens Medical Solutions Usa, Inc. | Room Temperature Chemical Trap for the Purification of Gaseous Methane |
US8500863B2 (en) * | 2008-06-23 | 2013-08-06 | Siemens Medical Solutions Usa, Inc. | Room temperature chemical trap for the purification of gaseous methane |
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