US2596926A - Preparation of azine dye images - Google Patents
Preparation of azine dye images Download PDFInfo
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- US2596926A US2596926A US133464A US13346449A US2596926A US 2596926 A US2596926 A US 2596926A US 133464 A US133464 A US 133464A US 13346449 A US13346449 A US 13346449A US 2596926 A US2596926 A US 2596926A
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- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 title claims description 39
- 238000002360 preparation method Methods 0.000 title description 3
- -1 SILVER HALIDE Chemical class 0.000 claims description 36
- JSYBAZQQYCNZJE-UHFFFAOYSA-N 1,2,4-benzenetriamine Natural products NC1=CC=C(N)C(N)=C1 JSYBAZQQYCNZJE-UHFFFAOYSA-N 0.000 claims description 21
- 239000000839 emulsion Substances 0.000 claims description 17
- 229910052709 silver Inorganic materials 0.000 claims description 15
- 239000004332 silver Substances 0.000 claims description 15
- 238000000034 method Methods 0.000 claims description 13
- 230000008569 process Effects 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 2
- 230000003647 oxidation Effects 0.000 claims description 2
- 238000007254 oxidation reaction Methods 0.000 claims description 2
- 239000000975 dye Substances 0.000 description 31
- 150000003222 pyridines Chemical class 0.000 description 18
- 125000000217 alkyl group Chemical group 0.000 description 10
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 10
- 238000005859 coupling reaction Methods 0.000 description 9
- IOLCXVTUBQKXJR-UHFFFAOYSA-M potassium bromide Chemical compound [K+].[Br-] IOLCXVTUBQKXJR-UHFFFAOYSA-M 0.000 description 8
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 8
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 8
- 150000001875 compounds Chemical class 0.000 description 7
- 230000008878 coupling Effects 0.000 description 7
- 238000010168 coupling process Methods 0.000 description 7
- 239000002585 base Substances 0.000 description 6
- 230000015572 biosynthetic process Effects 0.000 description 6
- 238000005755 formation reaction Methods 0.000 description 6
- 229910052739 hydrogen Inorganic materials 0.000 description 6
- 239000001257 hydrogen Substances 0.000 description 6
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 6
- 230000001617 migratory effect Effects 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- 239000002253 acid Substances 0.000 description 5
- ZAJAQTYSTDTMCU-UHFFFAOYSA-N 3-aminobenzenesulfonic acid Chemical compound NC1=CC=CC(S(O)(=O)=O)=C1 ZAJAQTYSTDTMCU-UHFFFAOYSA-N 0.000 description 4
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 description 4
- NQRYJNQNLNOLGT-UHFFFAOYSA-N Piperidine Chemical compound C1CCNCC1 NQRYJNQNLNOLGT-UHFFFAOYSA-N 0.000 description 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- 235000010265 sodium sulphite Nutrition 0.000 description 4
- 230000001629 suppression Effects 0.000 description 4
- OISVCGZHLKNMSJ-UHFFFAOYSA-N 2,6-dimethylpyridine Chemical compound CC1=CC=CC(C)=N1 OISVCGZHLKNMSJ-UHFFFAOYSA-N 0.000 description 3
- 239000007844 bleaching agent Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- ICSNLGPSRYBMBD-UHFFFAOYSA-N 2-aminopyridine Chemical compound NC1=CC=CC=N1 ICSNLGPSRYBMBD-UHFFFAOYSA-N 0.000 description 2
- BSKHPKMHTQYZBB-UHFFFAOYSA-N 2-methylpyridine Chemical compound CC1=CC=CC=N1 BSKHPKMHTQYZBB-UHFFFAOYSA-N 0.000 description 2
- ORLGLBZRQYOWNA-UHFFFAOYSA-N 4-methylpyridin-2-amine Chemical compound CC1=CC=NC(N)=C1 ORLGLBZRQYOWNA-UHFFFAOYSA-N 0.000 description 2
- FKNQCJSGGFJEIZ-UHFFFAOYSA-N 4-methylpyridine Chemical compound CC1=CC=NC=C1 FKNQCJSGGFJEIZ-UHFFFAOYSA-N 0.000 description 2
- DLFVBJFMPXGRIB-UHFFFAOYSA-N Acetamide Chemical compound CC(N)=O DLFVBJFMPXGRIB-UHFFFAOYSA-N 0.000 description 2
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 2
- QUSNBJAOOMFDIB-UHFFFAOYSA-N Ethylamine Chemical compound CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 125000003277 amino group Chemical group 0.000 description 2
- 229940039407 aniline Drugs 0.000 description 2
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- DDVXXITYAVIOHO-UHFFFAOYSA-N n-ethyl-3-methylpyridin-2-amine Chemical compound CCNC1=NC=CC=C1C DDVXXITYAVIOHO-UHFFFAOYSA-N 0.000 description 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 2
- VQMSRUREDGBWKT-UHFFFAOYSA-N quinoline-4-carboxylic acid Chemical compound C1=CC=C2C(C(=O)O)=CC=NC2=C1 VQMSRUREDGBWKT-UHFFFAOYSA-N 0.000 description 2
- 230000002441 reversible effect Effects 0.000 description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 description 2
- CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical compound NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 description 1
- GWXQTTKUYBEZBP-UHFFFAOYSA-N 1h-benzimidazol-1-ium-2-sulfonate Chemical compound C1=CC=C2NC(S(=O)(=O)O)=NC2=C1 GWXQTTKUYBEZBP-UHFFFAOYSA-N 0.000 description 1
- WVJHONXZLYKXFP-UHFFFAOYSA-N 2-amino-6-methylbenzenesulfonic acid Chemical compound CC1=CC=CC(N)=C1S(O)(=O)=O WVJHONXZLYKXFP-UHFFFAOYSA-N 0.000 description 1
- FVZXYJDGVYLMDB-UHFFFAOYSA-N 3-pyridin-2-ylpropan-1-ol Chemical compound OCCCC1=CC=CC=N1 FVZXYJDGVYLMDB-UHFFFAOYSA-N 0.000 description 1
- PZVZGDBCMQBRMA-UHFFFAOYSA-N 3-pyridin-4-ylpropan-1-ol Chemical compound OCCCC1=CC=NC=C1 PZVZGDBCMQBRMA-UHFFFAOYSA-N 0.000 description 1
- VXLKZBRLFFGAQT-UHFFFAOYSA-N 3h-benzimidazole-5-sulfonic acid Chemical compound OS(=O)(=O)C1=CC=C2N=CNC2=C1 VXLKZBRLFFGAQT-UHFFFAOYSA-N 0.000 description 1
- CMBSSVKZOPZBKW-UHFFFAOYSA-N 5-methylpyridin-2-amine Chemical compound CC1=CC=C(N)N=C1 CMBSSVKZOPZBKW-UHFFFAOYSA-N 0.000 description 1
- 239000005725 8-Hydroxyquinoline Substances 0.000 description 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
- GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 description 1
- 241001121515 Celes Species 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 1
- XOAAWQZATWQOTB-UHFFFAOYSA-N Taurine Natural products NCCS(O)(=O)=O XOAAWQZATWQOTB-UHFFFAOYSA-N 0.000 description 1
- 125000000738 acetamido group Chemical group [H]C([H])([H])C(=O)N([H])[*] 0.000 description 1
- DYRDKSSFIWVSNM-UHFFFAOYSA-N acetoacetanilide Chemical compound CC(=O)CC(=O)NC1=CC=CC=C1 DYRDKSSFIWVSNM-UHFFFAOYSA-N 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910001513 alkali metal bromide Inorganic materials 0.000 description 1
- 230000029936 alkylation Effects 0.000 description 1
- 238000005804 alkylation reaction Methods 0.000 description 1
- 125000002490 anilino group Chemical group [H]N(*)C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 125000001246 bromo group Chemical group Br* 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- MQRJBSHKWOFOGF-UHFFFAOYSA-L disodium;carbonate;hydrate Chemical compound O.[Na+].[Na+].[O-]C([O-])=O MQRJBSHKWOFOGF-UHFFFAOYSA-L 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 125000000031 ethylamino group Chemical group [H]C([H])([H])C([H])([H])N([H])[*] 0.000 description 1
- YAGKRVSRTSUGEY-UHFFFAOYSA-N ferricyanide Chemical compound [Fe+3].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-] YAGKRVSRTSUGEY-UHFFFAOYSA-N 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 231100001261 hazardous Toxicity 0.000 description 1
- 125000005191 hydroxyalkylamino group Chemical group 0.000 description 1
- 125000004029 hydroxymethyl group Chemical group [H]OC([H])([H])* 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- LKVXQCKDIYHFGZ-UHFFFAOYSA-N n-naphthalen-1-yl-3-oxobutanamide Chemical compound C1=CC=C2C(NC(=O)CC(=O)C)=CC=CC2=C1 LKVXQCKDIYHFGZ-UHFFFAOYSA-N 0.000 description 1
- DLMJDNNPONRGGS-UHFFFAOYSA-N n-naphthalen-2-yl-3-oxo-3-phenylpropanamide Chemical compound C=1C=C2C=CC=CC2=CC=1NC(=O)CC(=O)C1=CC=CC=C1 DLMJDNNPONRGGS-UHFFFAOYSA-N 0.000 description 1
- 229960003540 oxyquinoline Drugs 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000000837 restrainer Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 description 1
- 235000019345 sodium thiosulphate Nutrition 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229960003080 taurine Drugs 0.000 description 1
Images
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C7/00—Multicolour photographic processes or agents therefor; Regeneration of such processing agents; Photosensitive materials for multicolour processes
- G03C7/30—Colour processes using colour-coupling substances; Materials therefor; Preparing or processing such materials
- G03C7/407—Development processes or agents therefor
- G03C7/413—Developers
Definitions
- the present invention relates to the forma tion of azine dye images while using color developers insuring the formation of brilliant dye images of proper color rendition.
- the azine dyes produced by this method have unusual stability, particularly when compared with the quinom'mine or azomethine dyes formed while using the older developers of the p-phenylenediamine type.
- the conventional material employed at the present time in color photography is an integral tripack consisting essentially of three superimposed silver halide emulsion layers, the bottom layer being sensitized'to red, the middle layer to green, and the top layer to blue.
- the red densities of the picture are recorded in the bottom layer, the green densities in the middle layer, and the blue densities in the top layer.
- the image formed in the respective layers is complimentary in color to the light rays for which the particular layer is sensitized.
- tripacks One of the best modes of constructing such tripacks involves the utilization in each of the three silver halide emulsion layers of a color former which is rendered non-dlfiusing in the emulsions. Where such tripacks are of the reversible type, they are processed by developing first in a black and white developer, and finally in a color forming developer.
- the color developer reduces in any one layer the silver halide remaining after the first development and is itself oxidized to an active state capable of coupling with the color former present in that layer to form a positive dye image. Consequently in any one layer the amount of dye produced will be a function of the amount of residual silver halide in that layer and the resulting dye will be formed imagewise.
- one of the primary color densities blue in the top layer, green in the middle layer, and red in the bottom layer
- the coupling reaction between the migratory oxidized developer and the immobile color formers in each layer is normally rapid so that the oxidized developer travels only a very. short distance before encountering the color former molecule and coupling therewith. It often happens, however, that some dye may be produced in a particular layer by the coupling of a color former in that layer with an oxidized developer molecule that originated not in that particular layer but in one of the adjacent layers. Typically an oxidized developer molecule originating in the red sensitive layer may escape from this layer without coupling and migrate to the green sensitive layer to couple with the color former molecule in that layer.
- the use of the pyridine derivative in an amount of from 4 grams to 30 grams not only energizes the azine color developer so as to produce a maximum of dye in a minimum of time
- the improvement in color rendition obtained by the use of the pyridine derivatives is attributable primarily to a suppression of proximity development by the azine developer.
- Color formers to be used with the aforement oned de lope t v e w azine. dye ima es are also described in Gunther application Serial No. 101,913. These compounds are typified by the fact that they are open chain keto methylene compounds. Examples of such compounds are:
- Acetoacetanilide N-l-naphthylacetoacetamide. N,N .ethylenebisaceto acetamide. p,p'-Bi-o-acetoacetaniside. N-2-naphthylbenzoylacetamide.
- the color formers utilized contain a group'rehdering. them non-migratory in the emulsion. Examples of such compounds are:
- decyl taurine fi-decoxy-3-(2ephenyl 6 bromo 8, hyd-rexycinchoninoyl) -,a m;inob,enzene-sulfonic acid cinchoninic acid 2 stearoylamino 6 (6 chloro 8 hydroxy-e cinchoninoyl), aminotoluene-A-sulfonic acid, and the like.
- pyridine derivatives that may be utilized in the 2,4-diamino-aniline colordevelcpers are those of the following formulae:
- R1 is hydrogen or a lower. alkyl group, i. e., methyl, ethyl, propyl or butyl, or a. hydroxyalkyl group, such as hydroxymethyl, hydroxyethyl, hydroxypropyl, and the like
- R2 is lower alkyl or hydroxyalkyl as above
- R3, R4 and Rs are hydrogen, lower alkyl as above or hydroxyalkyl as'above.
- pyridine itself is excluded from the scope of the pyridine bases contemplated for use. This is attributable to the fact that pyridine itself is sufficiently volatile to produce toxically hazardous concentrations of its vapors in the confined areas usually used in carrying out photographic processes. Also pyridine is objectionable for use by reason of the peculiar odor which it possesses. I
- the pyridine bases are added to the developer in an amount ranging from 1 to about 40 grams per liter. The particular quantity will depend upon the developer employed, as well as upon the particular dye density required in the color development.
- the color. developers contemplated herein in addition to containing the aforementioned 2,4- diamino anilines and the pyridine derivative will also contain the usual adjuncts such as an alkali, i. e., sodium carbonate, a preservative, i. e., sodium sulfite, and a restrainer, i. e., an alkali metal bromide such as potassium bromide, and the like.
- an alkali i. e., sodium carbonate
- a preservative i. e., sodium sulfite
- a restrainer i. e., an alkali metal bromide such as potassium bromide, and the like.
- the invention may be carried into eifect by color development of an exposed silver halide emulsion with the 2,4-diamino anilines while using the color former either in the developer or preferably in non-diffusing form in the silver halide emulsions.
- the procedure is applicable to negative; positlve or reversible color film, and particularly to such film in the form of the conventional tripack previously described.
- Example II The procedure is the same as .in Example I excepting that the Pyridine, is replaced by 4- methyl- 2-aminopyridine. V
- Example IV Theprocedure is'the same as in Example III excepting that the 4-hydroxy-propylpyridlne is replaced 'by Z-aminopyridine.
- Example VII wherein R1 is selected from the class consisting of hydrogen, lower alkyl and hydroxyalkyl, R2 is selected from the class consisting of lower alkyl and hydroxyalkyl, and R3, R4 and R5 are a member of the class consisting of hydrogen, hydroxyalkyl and lower alkyl.:
- a pyridine derivative selected from the class consisting of those of the following formulae:
- each silver halide emulsion layer 7 of which is sensitized to one of the primary colors the red sensitive layer containing an aryl- J -acid non-migratory in the emulsion as a color former, the green sensitive layer containing a.
- R1 is selected from the class consisting of hydrogen, lower alkyl and hydroxyalkyl
- R2 is selected from the class consisting of lower alkyl and hydroxyalkyl
- R3, R4 and R5 are a member of the class consisting of hydrogen, hydroxyalkyl and lower alkyl.
- a color forming developer for the production of brilliant azine dye images comprising an aqueous solution of a 2,4 diamino aniline and a small amount of pyridine derivative selected from the class consisting of those of the following formulae:
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- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Pyridine Compounds (AREA)
Description
Filed Dec. 16. 1949 R. C. GUNTHER ETAL PREPARATION OF AZINE DYE IMAGES May 13, 1952 Kusuaq wnwgxow INVENTORS Robert C. Gunthgr Vsevolod Tulogm ATTORNEYS Mgsuaq wnwgxow fatented May 13, 1952 PREPARATION OF AZINE DYE IMAGES Robert C. Gunther, Easton, Pa., and Vsevolod Tulagin, Phillipsburg, N. J assignors to General Aniline & Film Corporation, New York, N. Y., a corporation of Delaware Application December 16, 1949, Serial N 0. 133,464
8 Claims.
The present invention relates to the forma tion of azine dye images while using color developers insuring the formation of brilliant dye images of proper color rendition.
U. S. Patent 2,486,440 granted to Willy A. Schmidt and Vsevolod Tulagin on November 1, 1949, describes the basic method of producing azine dyestuif images by color developing silver halide emulsions with a 2,4-diamino-aniline in the presence of a color former.
The azine dyes produced by this method have unusual stability, particularly when compared with the quinom'mine or azomethine dyes formed while using the older developers of the p-phenylenediamine type.
Despite the many recognized advantages of the azine method, there are certain disadvantages to which considerable study has been given in aneffort to effect their elimination. One such disadvantage is the fact that the energy of de velopment and of color coupling is not all that could be desired. A more serious problem, which manifests itself particularly in the development of mutilayer film, is a loss of color rendition in the azine images formed in such material through the phenomenon known as proximity development.
As is known, the conventional material employed at the present time in color photography is an integral tripack consisting essentially of three superimposed silver halide emulsion layers, the bottom layer being sensitized'to red, the middle layer to green, and the top layer to blue. When such a tripack is exposed, the red densities of the picture are recorded in the bottom layer, the green densities in the middle layer, and the blue densities in the top layer. According to customary practice, the image formed in the respective layers is complimentary in color to the light rays for which the particular layer is sensitized.
One of the best modes of constructing such tripacks involves the utilization in each of the three silver halide emulsion layers of a color former which is rendered non-dlfiusing in the emulsions. Where such tripacks are of the reversible type, they are processed by developing first in a black and white developer, and finally in a color forming developer.
In the color development of such a tripack with a 2-,4-diamino-aniline, the color developer reduces in any one layer the silver halide remaining after the first development and is itself oxidized to an active state capable of coupling with the color former present in that layer to form a positive dye image. Consequently in any one layer the amount of dye produced will be a function of the amount of residual silver halide in that layer and the resulting dye will be formed imagewise. Thus in each of the'three layers of the tripack, one of the primary color densities (blue in the top layer, green in the middle layer, and red in the bottom layer) is accurately recorded in the form of a positive complimentary dye image.
The coupling reaction between the migratory oxidized developer and the immobile color formers in each layer is normally rapid so that the oxidized developer travels only a very. short distance before encountering the color former molecule and coupling therewith. It often happens, however, that some dye may be produced in a particular layer by the coupling of a color former in that layer with an oxidized developer molecule that originated not in that particular layer but in one of the adjacent layers. Typically an oxidized developer molecule originating in the red sensitive layer may escape from this layer without coupling and migrate to the green sensitive layer to couple with the color former molecule in that layer. As a result there will be produced in the green sensitive layer a certain amount ofmagenta dye which records not the green densities of the original picture, but red densities which should have been confined to the bottom or red sensitive layer. This migration of oxidized developer from one layer to an'adjacent' layer is the phenomenon known as proximity development.
We have now discovered that the development of silver halide emulsions with a 2,4-diamino de veloper in the presence of a color former may be effected while realizing the advantages of (1) more energetic development of positive silver halide; (2) more energetic color coupling with resultant increase in dye formation efliciency, and (3) more brilliant dye images through improved color rendition (suppression of proximity development), by adding to the 2,4'-diamino developer a small quantity of a pyridine derivative. Thus coupling reactions which proceed very slowly or not at all with an ordinary azine developing substance in the conventional carbonate, sulfite and bromide solution, are greatly accelerated by the addition of the pyridine derivative to the solution.
Further, the use of the pyridine derivative in an amount of from 4 grams to 30 grams not only energizes the azine color developer so as to produce a maximum of dye in a minimum of time,
but also produces dye images of exceptional clarity and brilliance.
The improvement in color rendition obtained by the use of the pyridine derivatives is attributable primarily to a suppression of proximity development by the azine developer.
We do not know, nor has it been possible to ascertain, the particular manner in which the pyridine derivative operates to promote this effect. It is known, however, that the action is peculiar to the pyridine derivatives, not even being shared by other heterocyclic nitrogenous bases. Thus we have also employed bases such as piperidine or morpholine, and while finding that these when present in the azine color deg veloper give satisfactory dye density, unlike the pyridine derivatives, the dye formation is accompanied by increased proximity development. The overall effect is a severe loss in color rendition which manifests itself in the final image as a loss in color brilliance.
Nor have We found any ther nitrcg'eno s bases capable of operating in the same manner as the pyridine derivatives. Attempts to sup: plant the pyridine derivatives by aliphatic amines such as ethylenediamine, ethylamine and hexa methylenediamine, led to an effective energizing of azine dye formation. However. as in the Case of morpholine, piperidine, and the "like, the in: creased dye formation in each instance was accompanied by a corresponding loss in color brilliance because of a markedly increased proximity development. The action which we have found to be portrayed by the pyridine derivatives are accordingly specific to these particular cornpounds, and this discovery constitutes a very im: portant part of the invention.
The utilization of pyridine derivatives in azine color developers of the 2,4-diamino-aniline class for the purpose of obtaining more energetic development, 'more energetic color coupling, and more brilliant dyes through suppression of 'p rox imity development, constitute the. purposes and.
objects of our invention.
The 2,4-diamino-ani1ines which may be en ployed as the color developers'for the contem: plated procedure are of the type described in the aforementioned Schmidt andTulagin Patent No. 2,486,440 and in Gunther application Serial No. 101,913, 'filed' June 28, 1949; and entitled Color Developers for the Production of .ezine ilpye Images, now Patent No. 2,570,116. i
"Specific exam es'e such de elepins agene are:
4 (B hydroxyeth lamino) 6 (4' carbcxymethoXy-phenylamino) metanilic acid.
4- (carboxymethylamino) -6- (4' methOXy phenylamino) {metanilic acid. L
2- (psulfoe'thylamino) -4-phenylamino-anil-ine.
4,6-di(fi hydroxyethylamino) -metanilic acid.
4 (,8 hydroxyethylamino) 6 phenylarninometanilic acid.
2 (p hydroxyethylamino) 4 -(-B sulfoethyl amino) -5-methyl aniline. v v l 4 (fi-hydroxy-fl-methyl-ethylaminoi -6-phenyl amino-metanilic acid. J
4-(a-dilhydroxyethyl) ethylamino) 6 -(3-eth oxyphenylamino) -metanilic acid.
4 (B hydroxy ethylamino) 6 'methylaminometanilic acid.
4 (sulfomethylamino) -6- (methylphenylamino)-- metanilic acid.
Color formers to be used with the aforement oned de lope t v e w azine. dye ima es are also described in Gunther application Serial No. 101,913. These compounds are typified by the fact that they are open chain keto methylene compounds. Examples of such compounds are:
Acetoacetanilide. N-l-naphthylacetoacetamide. N,N .ethylenebisaceto acetamide. p,p'-Bi-o-acetoacetaniside. N-2-naphthylbenzoylacetamide.
. p,p-Biacetoacetanilide.
can. Terephthaloylbis-(3chloro-4,6-dimethoxyacetanilide) -Benzoylacetanilide.
Preferably the color formers utilized contain a group'rehdering. them non-migratory in the emulsion. Examples of such compounds are:
2-(m-benzoylacetamidophenyl) 1 octadecy1-5- benzimidazolesulfonic acid.
3,3 ureylenebis 5 p benzoylacetamidobenzamide-benzene sulfonic acid.
2 oy eceta id ben em ee '6. s earqyh aminoep-toluenesulfonic acid.
2-(p-benzoylacetamidophenyl) 1 getadecyl- 5 -v benzimidazolesulfonic acid.
p-Cyanoacetyl-3-octadecenylsuccinalic acid.
Co r f m s sapeb e o roducin ma enta y s u f a es. a e also descri ed in the Mere:
mentioned ll l lhfi a ation 4$. WQll as n @111.
' I p at Serial o. 93 533. .filed December 234 19 by T lae n and Celes nd ent tl d "Ma enta o ed h n zon m Dyestufi; ma s. now- Rat:
enfi N .524. 41 Breierab these. colo formers ar fial ee -iie ydr quinol nes and pa ticularly those which are non-migratory in the emulsions. Ex m les of the 1.a.tter t pe compounds are:
fie in 2v phenyl :16. breniovfi'e hydrox cin hen noyl eaminotelu ne .-;4 sule fonic acid -p y 10 o18:hyd 2;v e nehonin yl cote! decyl taurine fi-decoxy-3-(2ephenyl 6 bromo 8, hyd-rexycinchoninoyl) -,a m;inob,enzene-sulfonic acid cinchoninic acid 2 stearoylamino 6 (6 chloro 8 hydroxy-e cinchoninoyl), aminotoluene-A-sulfonic acid, and the like.
The pyridine derivatives that may be utilized in the 2,4-diamino-aniline colordevelcpers are those of the following formulae:
and
wherein R1 is hydrogen or a lower. alkyl group, i. e., methyl, ethyl, propyl or butyl, or a. hydroxyalkyl group, such as hydroxymethyl, hydroxyethyl, hydroxypropyl, and the like, R2 is lower alkyl or hydroxyalkyl as above and R3, R4 and Rs are hydrogen, lower alkyl as above or hydroxyalkyl as'above.
Examples of such compounds which we have found to be effective for our purpose are the following:
2 methylpyridine (a-picollne) N 4-methylpyridine. (qr-picoline) on on;
2,6-dimethylpyridine (2,6-1lltidil18) cmomon 2-B-hydroxyethylpyrldine 2-y-hydroxypropylpyridine 4-'y-hydroxypropylpyridine N NH:
Z-amlnopyrldlne NHCHrCHzOH NH, \N V fi-mcthyLZ-aminopyridiue 3-methyl-2-ethylaminopyridine Most of the above compounds are commercially available with the possibleexception ofwthose in which the amino group in 2-position is substituted by alkyl or hydroxyalkyl, such as,for example, 3-methyl-2-ethylaminopyridine. These compounds, however, are readily obtained by alkylation of the amino group in 2-position.
It will be observed that pyridine itself is excluded from the scope of the pyridine bases contemplated for use. This is attributable to the fact that pyridine itself is sufficiently volatile to produce toxically hazardous concentrations of its vapors in the confined areas usually used in carrying out photographic processes. Also pyridine is objectionable for use by reason of the peculiar odor which it possesses. I
The pyridine bases are added to the developer in an amount ranging from 1 to about 40 grams per liter. The particular quantity will depend upon the developer employed, as well as upon the particular dye density required in the color development.
The color. developers contemplated herein in addition to containing the aforementioned 2,4- diamino anilines and the pyridine derivative will also contain the usual adjuncts such as an alkali, i. e., sodium carbonate, a preservative, i. e., sodium sulfite, and a restrainer, i. e., an alkali metal bromide such as potassium bromide, and the like.
The invention may be carried into eifect by color development of an exposed silver halide emulsion with the 2,4-diamino anilines while using the color former either in the developer or preferably in non-diffusing form in the silver halide emulsions.
The procedure is applicable to negative; positlve or reversible color film, and particularly to such film in the form of the conventional tripack previously described.
The invention is further illustrated by the accompanying self-explanatory drawings, Figures 1 and 2 of which show the eifecton the maximum dye density of an azine multilayer type film as described in Examples VI and VII of varying the concentration of z-aminopyridine and 4-methyl-2-aminopyridine respectively in the color developer employed.
It will be observed that as the concentration of the pyridine base in the color developer is increased from 0 to 20 grams per liter, the maximum dye density increases from about .1 to over 2 units.
The invention is further explained by the following examples but it is to be understood that 4,6-di- (phenylamino) metanilic acid grams 4.0
p-Anisyl-J-acid do 1.5
Sodium carbonate, monohydrate do 20 Sodium sulfite do 30 Potassium bromide do 2 5-methyl-2-aminopyridine do 12 :Water to... ...cc... 1000 7 Th film was washed, bleached in a ferrioyanide bleach and fixed in an acid-hardening hypo. There was obtained an azine cyan dye image of exceptional density and brilliance.
Example II The procedure is the same as .in Example I excepting that the Pyridine, is replaced by 4- methyl- 2-aminopyridine. V
.EmampleJlI A multilayer film composed of a red-sensitive bottom layer containing (:i-c'stearoylaminophenyl) -J-acid and a green-sensitive middleilayer containing 2 stearoylamino-fi-(6=]oromo-8ehy droxyclnchoninoyl).aminotoluene--sulfonic acid was exposed through a sharp cutting yellow filter, developedin a black and white developer,',reexposed, and the residual silver "halide "developed for :16 minutes in a solution of the following. composition:
amino metanilicacidgmqr g sgramsm 610 Sodium. carbonate "PPR-"H. do v 40 Sodium sulfite -l m doc u 40 Potassium bromide s m m,e t .do g g 4 hydroxypropylpyridine dog, 16 Water o. A cc" 1000 After development the film was washedand bleached "in 'aferricyanide bleach. After fixing in anacid-hardeninghypo, there remained a multi-colored dye image of excellent saturation and "brilliance.
Example IV Theprocedure is'the same as in Example III excepting that the 4-hydroxy-propylpyridlne is replaced 'by Z-aminopyridine.
E mplev The procedure is the same as in EXamplelII xcepting th the -hydr ypropylpyrid ne jis replaced by -methyl 2ep hydroxyethylaminm pyridine.
Example VI in three layenfilm composed of a red, sensitive bottomlayer containing:
6-p- -N tad cy acetamido 5 :sulfophenylcarbamyl) N-acetylanilino-l-naphthol-B-sulfonic acid, and a green sensitive middle layer containingb 2-r-- stearoylamino-fi (6 lohloro ea hydroxyv zsf x and phenylcinchoninyl) 2(p-benzoylacetaminophenyl) 1 octadeoyl 5-benzimidazole sulfonic acid was exposed, developed in a black and white developer, reexposed, and the residual silver halide developed for 18 minutes in a solution of the following composition;
4- (B-hydroxyethylamino) -6-phenylamino metanilic acid g 5 Sodium carbonate g 40 Sodium sulfite g 40 Potassium bromide g 3 2 aminopyridine g 15 Water to cc 1000 After development the film was washed, bleached in a ferricyanide bleach. After fixing in a 20 per cent sodium thiosulfate solution there remainedva tri -colored dye image of superior brilliance and saturation,
Example VII wherein R1 is selected from the class consisting of hydrogen, lower alkyl and hydroxyalkyl, R2 is selected from the class consisting of lower alkyl and hydroxyalkyl, and R3, R4 and R5 are a member of the class consisting of hydrogen, hydroxyalkyl and lower alkyl.:
2. The process as defined in claim 1 in which the pyridine derivative is added in an amount of 7 from 1 to 40 grams per liter of *solution.
3. In the process of producing subtractively colored azine dye images in a tripack, each silver halide emulsion layer of which is sensitized to one of the primarycolorsandeach silver halide emulsion layer of which contains a color former capable of reacting with the oxidation products of a 2,4-diaminoani-line to yield an azine dye image complimentary in color to the light for which the layer is sensitized by exposing the tripack and developing the same with a color developer containing astheefiective de- 1 amino. "tOhICHB-A SUHOHi-C acid, and a blue sensitive emulsion containing:
veloping agent a 2,4-diamino aniline, the improvement which involves the suppression of proximity development by incorporating in the color developer a pyridine derivative selected from the class consisting of those of the following formulae:
and
in a tripack, each silver halide emulsion layer 7 of which is sensitized to one of the primary colors, the red sensitive layer containing an aryl- J -acid non-migratory in the emulsion as a color former, the green sensitive layer containing a.
6-halogen-8-hydroxy quinoline non-migratory in the emulsion as a color former, and the blue sensitive layer containing an open chain keto methylene compound non-migratory in the emulsion as a color former. which comprises exposing the tripack and color developing the same with a developer containing a 2,4-diamino aniline and a pyridine derivative selected from the class consisting of those of the following formulae:
and
RI R| N/ 10 wherein R1 is selected from the class consisting of hydrogen, lower alkyl and hydroxyalkyl, R2 is selected from the class consisting of lower alkyl and hydroxyalkyl, and R3, R4 and R5 are a member of the class consisting of hydrogen, hydroxyalkyl and lower alkyl.
6. The process as defined in claim 5 wherein the pyridine derivative is present in the color developer in an amount of from about 1 to 40 grams per liter.
'7. The process as defined in claim 5 wherein the 2,4-diamino aniline is a metanilic acid derivative containing an hydroxyalkylamino group in the 4-position.
8. A color forming developer for the production of brilliant azine dye images comprising an aqueous solution of a 2,4 diamino aniline and a small amount of pyridine derivative selected from the class consisting of those of the following formulae:
and
REFERENCES CITED The following references are of record in the file of this patent:
UNITED STATES PATENTS Name Date Schmidt Nov. 1, 1949 Number
Claims (1)
1. IN THE PROCESS OF PRODUCING BRILLIANT AZINE DYE IMAGES THROUGH IMPROVED COLR RENDITION WHICH COMPRISES DEVELOPING AN EXPOSED SILVER HALIDE EMULSION IN THE PRESENCE OF A COLOR FORMER CAPABLE OF REACTING WITH THE OXIDATION PRODUCTS OF A 2,4-DIAMINOANILINE TO YIELD AN AZINE DYE IMAGE WITH A DEVELOPING AGENT CONTAINING A 2,4DIAMINO ANILINE AND A SMALL QUANTITY OF A PYRIDINE DERIVATIVE SELECTED FROM THE CLASS CONSISTING OF THOSE OF THE FOLLOWING FORMULAE:
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US133464A US2596926A (en) | 1949-12-16 | 1949-12-16 | Preparation of azine dye images |
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US133464A US2596926A (en) | 1949-12-16 | 1949-12-16 | Preparation of azine dye images |
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Cited By (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4268593A (en) * | 1978-11-06 | 1981-05-19 | Ciba-Geigy Ag | Recording material for color photography |
US4452884A (en) * | 1981-12-17 | 1984-06-05 | Ciba-Geigy Ag | Color-photographic recording material |
US4465757A (en) * | 1982-09-21 | 1984-08-14 | Ciba-Geigy A.G. | Recording material for color photography |
US4465765A (en) * | 1982-08-18 | 1984-08-14 | Ciba-Geigy A.G. | Colorphotographic recording material |
EP0266797A2 (en) | 1986-11-07 | 1988-05-11 | Fuji Photo Film Co., Ltd. | Method of processing silver halide color photographic material and photographic color developing composition |
EP0452886A2 (en) | 1990-04-17 | 1991-10-23 | Fuji Photo Film Co., Ltd. | Method of processing a silver halide color photographic material |
US5310633A (en) * | 1992-05-13 | 1994-05-10 | Fuji Photo Film Co., Ltd. | Bleach-fixing composition for color photographic material and method for processing a color photographic material with the same |
US5362610A (en) * | 1991-10-28 | 1994-11-08 | Konica Corporation | Photographic processing agent |
US5366853A (en) * | 1991-11-06 | 1994-11-22 | Konica Corporation | Tablet-shaped processing agent and method for processing silver halide photographic light sensitive materials |
EP0631185A1 (en) | 1993-06-11 | 1994-12-28 | Fuji Photo Film Co., Ltd. | Method for continuously processing silver halide color photosensitive material |
US5409805A (en) * | 1993-07-29 | 1995-04-25 | Konica Corporation | Solid processing agent for silver halide photographic light-sensitive materials |
US5452045A (en) * | 1992-10-30 | 1995-09-19 | Konica Corporation | Apparatus for processing a light-sensitive silver halide photographic material |
EP0686875A1 (en) | 1994-06-09 | 1995-12-13 | Fuji Photo Film Co., Ltd. | Method of processing silver halide color photographic materials |
EP0720049A2 (en) | 1990-05-09 | 1996-07-03 | Fuji Photo Film Co., Ltd. | Photographic processing composition and processing method using the same |
US5576161A (en) * | 1994-08-12 | 1996-11-19 | Konica Corporation | Silver halide light-sensitive photographic material and method of processing thereof |
US5766830A (en) * | 1994-09-09 | 1998-06-16 | Konica Corporation | Photographic processing method for processing a silver halide photographic light-sensitive material |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2486440A (en) * | 1946-01-10 | 1949-11-01 | Gen Aniline & Film Corp | Production of phenazonium dyestuff images |
-
1949
- 1949-12-16 US US133464A patent/US2596926A/en not_active Expired - Lifetime
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2486440A (en) * | 1946-01-10 | 1949-11-01 | Gen Aniline & Film Corp | Production of phenazonium dyestuff images |
Cited By (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4268593A (en) * | 1978-11-06 | 1981-05-19 | Ciba-Geigy Ag | Recording material for color photography |
US4452884A (en) * | 1981-12-17 | 1984-06-05 | Ciba-Geigy Ag | Color-photographic recording material |
US4465765A (en) * | 1982-08-18 | 1984-08-14 | Ciba-Geigy A.G. | Colorphotographic recording material |
US4465757A (en) * | 1982-09-21 | 1984-08-14 | Ciba-Geigy A.G. | Recording material for color photography |
EP0266797A2 (en) | 1986-11-07 | 1988-05-11 | Fuji Photo Film Co., Ltd. | Method of processing silver halide color photographic material and photographic color developing composition |
EP0452886A2 (en) | 1990-04-17 | 1991-10-23 | Fuji Photo Film Co., Ltd. | Method of processing a silver halide color photographic material |
EP0720049A2 (en) | 1990-05-09 | 1996-07-03 | Fuji Photo Film Co., Ltd. | Photographic processing composition and processing method using the same |
US5362610A (en) * | 1991-10-28 | 1994-11-08 | Konica Corporation | Photographic processing agent |
US5366853A (en) * | 1991-11-06 | 1994-11-22 | Konica Corporation | Tablet-shaped processing agent and method for processing silver halide photographic light sensitive materials |
US5310633A (en) * | 1992-05-13 | 1994-05-10 | Fuji Photo Film Co., Ltd. | Bleach-fixing composition for color photographic material and method for processing a color photographic material with the same |
US5452045A (en) * | 1992-10-30 | 1995-09-19 | Konica Corporation | Apparatus for processing a light-sensitive silver halide photographic material |
EP0631185A1 (en) | 1993-06-11 | 1994-12-28 | Fuji Photo Film Co., Ltd. | Method for continuously processing silver halide color photosensitive material |
US5409805A (en) * | 1993-07-29 | 1995-04-25 | Konica Corporation | Solid processing agent for silver halide photographic light-sensitive materials |
EP0686875A1 (en) | 1994-06-09 | 1995-12-13 | Fuji Photo Film Co., Ltd. | Method of processing silver halide color photographic materials |
US5576161A (en) * | 1994-08-12 | 1996-11-19 | Konica Corporation | Silver halide light-sensitive photographic material and method of processing thereof |
US5766830A (en) * | 1994-09-09 | 1998-06-16 | Konica Corporation | Photographic processing method for processing a silver halide photographic light-sensitive material |
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