US2586777A - Method of separating olefins from hydrocarbon mixtures - Google Patents
Method of separating olefins from hydrocarbon mixtures Download PDFInfo
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- US2586777A US2586777A US725725A US72572547A US2586777A US 2586777 A US2586777 A US 2586777A US 725725 A US725725 A US 725725A US 72572547 A US72572547 A US 72572547A US 2586777 A US2586777 A US 2586777A
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- 229930195733 hydrocarbon Natural products 0.000 title claims description 23
- 150000002430 hydrocarbons Chemical class 0.000 title claims description 23
- 150000001336 alkenes Chemical class 0.000 title claims description 17
- 239000004215 Carbon black (E152) Substances 0.000 title claims description 15
- 238000000034 method Methods 0.000 title claims description 10
- 239000000203 mixture Substances 0.000 title description 14
- WFPZPJSADLPSON-UHFFFAOYSA-N dinitrogen tetraoxide Chemical compound [O-][N+](=O)[N+]([O-])=O WFPZPJSADLPSON-UHFFFAOYSA-N 0.000 claims description 36
- 238000009835 boiling Methods 0.000 claims description 13
- 239000007788 liquid Substances 0.000 claims description 10
- 239000003518 caustics Substances 0.000 claims description 9
- 239000011541 reaction mixture Substances 0.000 claims description 5
- 238000004326 stimulated echo acquisition mode for imaging Methods 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 description 27
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 17
- 239000000463 material Substances 0.000 description 13
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 12
- 238000001256 steam distillation Methods 0.000 description 11
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 9
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Inorganic materials [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 8
- 239000000243 solution Substances 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 6
- 239000002253 acid Substances 0.000 description 6
- 239000007795 chemical reaction product Substances 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 6
- 239000002244 precipitate Substances 0.000 description 5
- 125000003118 aryl group Chemical group 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 150000001993 dienes Chemical class 0.000 description 4
- LZDSILRDTDCIQT-UHFFFAOYSA-N dinitrogen trioxide Inorganic materials [O-][N+](=O)N=O LZDSILRDTDCIQT-UHFFFAOYSA-N 0.000 description 4
- 238000006396 nitration reaction Methods 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 238000000926 separation method Methods 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- 230000001476 alcoholic effect Effects 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 3
- 229910052794 bromium Inorganic materials 0.000 description 3
- 238000010908 decantation Methods 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 3
- 239000003208 petroleum Substances 0.000 description 3
- 238000007086 side reaction Methods 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical class O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 2
- IOVCWXUNBOPUCH-UHFFFAOYSA-N Nitrous acid Chemical class ON=O IOVCWXUNBOPUCH-UHFFFAOYSA-N 0.000 description 2
- 241000779819 Syncarpia glomulifera Species 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- HUMNYLRZRPPJDN-UHFFFAOYSA-N benzaldehyde Chemical compound O=CC1=CC=CC=C1 HUMNYLRZRPPJDN-UHFFFAOYSA-N 0.000 description 2
- 239000001110 calcium chloride Substances 0.000 description 2
- 229910001628 calcium chloride Inorganic materials 0.000 description 2
- 239000003245 coal Substances 0.000 description 2
- RWGFKTVRMDUZSP-UHFFFAOYSA-N cumene Chemical compound CC(C)C1=CC=CC=C1 RWGFKTVRMDUZSP-UHFFFAOYSA-N 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 238000010790 dilution Methods 0.000 description 2
- 239000012895 dilution Substances 0.000 description 2
- 238000004821 distillation Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 239000003517 fume Substances 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- -1 ketones or aldehydes Chemical class 0.000 description 2
- 150000002832 nitroso derivatives Chemical class 0.000 description 2
- 125000000018 nitroso group Chemical group N(=O)* 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 239000001739 pinus spp. Substances 0.000 description 2
- 238000000197 pyrolysis Methods 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 229940036248 turpentine Drugs 0.000 description 2
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 1
- DRHABPMHZRIRAH-UHFFFAOYSA-N 2,4,4,6,6-pentamethylhept-2-ene Chemical group CC(C)=CC(C)(C)CC(C)(C)C DRHABPMHZRIRAH-UHFFFAOYSA-N 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000010306 acid treatment Methods 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 1
- 229910052977 alkali metal sulfide Inorganic materials 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- 239000000987 azo dye Substances 0.000 description 1
- DALDUXIBIKGWTK-UHFFFAOYSA-N benzene;toluene Chemical compound C1=CC=CC=C1.CC1=CC=CC=C1 DALDUXIBIKGWTK-UHFFFAOYSA-N 0.000 description 1
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 150000001728 carbonyl compounds Chemical class 0.000 description 1
- 239000011280 coal tar Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 125000002534 ethynyl group Chemical class [H]C#C* 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 238000005194 fractionation Methods 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 239000000543 intermediate Substances 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 150000005673 monoalkenes Chemical class 0.000 description 1
- LNOPIUAQISRISI-UHFFFAOYSA-N n'-hydroxy-2-propan-2-ylsulfonylethanimidamide Chemical compound CC(C)S(=O)(=O)CC(N)=NO LNOPIUAQISRISI-UHFFFAOYSA-N 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- GQPLMRYTRLFLPF-UHFFFAOYSA-N nitrous oxide Inorganic materials [O-][N+]#N GQPLMRYTRLFLPF-UHFFFAOYSA-N 0.000 description 1
- QNGNSVIICDLXHT-UHFFFAOYSA-N para-ethylbenzaldehyde Natural products CCC1=CC=C(C=O)C=C1 QNGNSVIICDLXHT-UHFFFAOYSA-N 0.000 description 1
- DPLVEEXVKBWGHE-UHFFFAOYSA-N potassium sulfide Chemical compound [S-2].[K+].[K+] DPLVEEXVKBWGHE-UHFFFAOYSA-N 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 229930195734 saturated hydrocarbon Natural products 0.000 description 1
- 150000003505 terpenes Chemical class 0.000 description 1
- 235000007586 terpenes Nutrition 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 229930195735 unsaturated hydrocarbon Natural products 0.000 description 1
- 239000012808 vapor phase Substances 0.000 description 1
- 238000009834 vaporization Methods 0.000 description 1
- 230000008016 vaporization Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G17/00—Refining of hydrocarbon oils in the absence of hydrogen, with acids, acid-forming compounds or acid-containing liquids, e.g. acid sludge
- C10G17/09—Refining of hydrocarbon oils in the absence of hydrogen, with acids, acid-forming compounds or acid-containing liquids, e.g. acid sludge with acid salts
Definitions
- the unreacted material present in the liquid hydrocarbon fraction which may contain parafllns, naphthenes and aromatics, can then be readily separated by simple steam distillation.
- nitrogen tetroxide vapor is run into the liquid-hydrocarbon fraction at temperatures below that of thermal decomposition and in quantity at least suificient to react with olefins present.
- the nitrogenous addition compounds of the olefins are then separated from the unreacted products, preferably by subjecting the entire mixture to steam distillation and recovering the distillate of unreacted products by condensation.
- the hydrocarbons in the condensed distillate are readily separable from the water layer; by decantation; any nitroso compounds that may have been entrained or dissolved by the steam vapors are easily separated, for instance by an alkaline wash.
- reaction will also take place in vapor phase.
- the reaction is strongly exothermic and it is preferred to control the temperature of the reaction so as to maintain the same at 80 to 100 R, which may be readily accomplished by controlling the rate of introduction of the nitrogen tetroxide, or if desired, provision may be made for heat exchange.
- the nitrogen tetroxide in vapor form may be obtained from any suitable source such as by vaporization of liquid nitrogen tetroxide at apdirectly into the body of the hydrocarbon liquid and thorough contact of the reactants may be enhanced by agitation during treatment.
- the completion of the reaction is readily ascertained by the cessation of the exothermic phenomenon (significant temperature decline) and by the marked formation of brown fumes above the surface of the liquid being treated.
- Any excess of N204 in the reaction mix may be destroyed by the addition of water to convert the same to nitric and nitrous acids, or by other well known methods such as the addition of aqueous solutions of sulfamic acid, as is done in the azo dye industry, or by the addition of aqueous solution of urea to destroy nitrous acid.
- a crude naphtha fraction produced for instance by high temperature cracking of a petroleum stock, may be selectively solvent extracted to obtain an extract containing aromatic materials including styrene; olefins, and diolefins.
- aromatic materials including styrene; olefins, and diolefins.
- N204 nitrosates of the unsaturated materials are formed which are then readily separated from the unreacted substantially pure saturated aromatics.
- the separation may be carried out in two stages.
- the solvent extract of naphtha may be initially treated with nitrogen trloxide (N202), under conditions substantially similar to that employed with the nitrogen tetroxide, whereby nitrosites are formed of the aralkenes and conjugated diolefins present, leaving substantially unreacted the mono-olefin content of the naphtha.
- N202 nitrogen trloxide
- the aromatics may then be purified by the removal of these remaining olefins by treatment with N204 forming the nitrosates which can be separated by distillation.
- the unreacted hydrocarbons are preferably separated from the-nitrosites or nitrosates by steam distillation. If desired, separation may be effected by precipitation of the nitrosates or nitrosites on dilution of the treated naphtha with petroleum ether or the like, the precipitate being removed by filtration or decantation. Any desired narrow aromatic cut may be removed before or after formation of the nitroso compound. For instance by taking out a toluene cut, a pure enough toluene is obtained to meet the required standards for nitration grade toluene.
- Steam distillation is preferably effected by r-un-, ning steam directly into the nitrogen tetroxidetreated mix, but if desired the mix may be diluted with at least an equal volume of water and then boiled, collecting the vapors in a cooled receiver to condense the same.
- the reaction products are heavier than water.
- the unreacted material being lighter than water collects above the surface of the water in the distillate and completion of the separation is indicated when distillate material heavier than water distills over and collects at the bottom of the water layer.
- reaction products as are carried over during the steam distillation may be removed from the unreacted portion of the oil distillate by reaction with aqueous or alcoholic alkali metal hydroxide such as sodium or potassium hydroxide.
- aqueous or alcoholic alkali metal sulfide such as sodium or potassium sulfide.
- Reaction of N204 with olefinic hydrocarbons in hydrocarbon mixtures boiling above 430 F. is readily effected with, however, increased tendency to side reactions such as nitration or oxidation and increasing difflculty of separation by steam distillation of the reacted from the unreacted portions as the boiling point-of the material increases.
- the oily reaction products of olefins and Nfloi may be hydrolyzed to nitro-alcohols or rearranged to nitrooximes during steam distillation. No serious decomposition of these compounds, however, has been observed at temperatures up to 212 F., with the possible exception in cases of certain terpenes, which if present in high concentrations, should be substantially diluted with any desired saturated hydrocarbons, before distillation.
- the nitrosate in the admixture may be further treated or converted to other chemical 4 compounds, provided that such compounds are easily separable from the unreacted hydrocarbons by conventional methods. For instance, if the reaction mass of nitrosates and unreacted hydrocarbons is treated with aqueous alkaline solutions, before subjecting the mass to steam distillation, the nitrosates are converted to carbonyl compounds, such as ketones or aldehydes, which can then be separated from the unreacted hydrocarbons by fractionation or selective extraction.
- carbonyl compounds such as ketones or aldehydes
- Example I A sample of 115-200 F. boiling range coal-tar reformer naphtha from destructive distillation of coal was reacted with N204 (at 70-100 F.) until excess N204 fumes indicated completion of the reaction, then washed with water and steam distilled. The distillate was washed with about 5 volume per cent of 10% caustic solution, water washed caustic free, and redistilled substantially to dryness. The distillate, amounting to 85.2% by volume of the original sample, had a density of 0.8730, a bromine number of 0.2 (ASTM) and was absorbed practically completely by concentrated sulfuric acid, showing that the composition of the distillate was practically pure aromatic in nature.
- N204 at 70-100 F.
- Example II A sample of a synthetic mixture of paraffinnaphthene base (acid treated gasoline range material) containing about 10% styrene was treated with N203 until excess of nitrous fumes showed completion of reaction. The precipitate formed during the reaction was separated by filtration and the residual oil, by volume of the original, was washed with about 5 volume per cent of 10% caustic solution, washed with sodium bisulflte (small amount) to remove traces of benzaldehyde, and again with a small Y amount of 10% caustic solution; then water washed to remove excess caustic, dried over calcium chloride, and distilled to 294 F. cut point. The distillate had the following properties, whichshowcomplete removal of styrene.
- Example III One part of a synthetic mixture containing 23.1% turpentine, 38.45% benzene and 38.45% acid treated naphtha was treated with N20 at 70100 F. until the reaction was completeas evidenced by the presence of excess N204. The excess N204 was destroyed by the addition of 0.3 part 20% NaOH solution in 50% alcohol. The reaction products were dissolved by mixing this mixture with one part of 25% alcoholic K23 and separated by centrifuging the mixture after dilution with aqueous alcohol. The residual unreacted oil was found to equal 77.0% by volume of the original, indicating complete removal of the turpentine since previous tests have shown no significant reaction occurring with either benzene or the acid treated naphtha.
- Example IV A crude benzene-toluene fraction from the destructive distillation of coal was treated with N204 until the persistant presence of unreacted N204 showed substantial completion of the treatment.
- the solution, new dark red in color and -with a slight gummy precipitate was washed with water and then steam distilled.
- the distillate was washed with about 2 to 3 volume per cent of caustic solution and then with water until it tested neutral to litmus, and then freed of water by drying over calcium chloride.
- Example V A hydrocarbon fraction containing a major amount of isopropyl benzene and minor amounts of similar boiling range material was subjected to dehydrogention conditions and then treated at room temperature with N203 until the presence of unreacted N: showed completion of reaction; the nitrosite precipitate thus formed was separated from the unreacted oil by decantation. The unreacted oil, amounting to 52.8% by volume of the original sample, was treated with N204 at room temperature until the reaction was complete. The remaining unreacted oil was then separated by steam distillation and purified by caustic wash of the distillate. The purified distillate amounted to 25.6% by volume of the original sample.
- the method of the invention is also applicable to the treatment of higher boiling hydrocarbons, such as those boiling in a range up to about 600 F.
- higher boiling hydrocarbons such as those boiling in a range up to about 600 F.
- complications may be encountered if substantial amounts of di-cyclic compounds are present, due to the greater facility of nitration taking place.
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- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Description
Patented Feb. 26, 195i METHOD OF SEPARATING OLEFINS FROM HYDROCARBON MIXTURES George R. Bond, Jr., Paulsbo'ro,
Houdry Process Corporation,
N. J., assignor to Wilmington, DeL,
a corporation of Delaware No Drawing. Application January 31, 1947, Serial No. 125,725
2 claims. 01. 260-666) all commonly available olefinic compounds present in liquid hydrocarbon fractions to convert the same to nitroso addition compounds which are but slightly, if at all, volatile with steam.
The unreacted material present in the liquid hydrocarbon fraction, which may contain parafllns, naphthenes and aromatics, can then be readily separated by simple steam distillation.
In accordance with the invention, nitrogen tetroxide vapor is run into the liquid-hydrocarbon fraction at temperatures below that of thermal decomposition and in quantity at least suificient to react with olefins present. The nitrogenous addition compounds of the olefins are then separated from the unreacted products, preferably by subjecting the entire mixture to steam distillation and recovering the distillate of unreacted products by condensation. The hydrocarbons in the condensed distillate are readily separable from the water layer; by decantation; any nitroso compounds that may have been entrained or dissolved by the steam vapors are easily separated, for instance by an alkaline wash.
The extreme selectivity of the reaction between the nitrogen tetroxide and olefins has been successfully demonstrated b extensive preliminary experimentationparticularly on known and synthetic mixtures containing various parafllns, naphthenes, olefins, diolefins, acetylenes, aromatics, etc. in compositions boiling up to 450 F. In all instances it was found that the olefins (including conjugated and non-conjugated diolefins and aromatics having an olefinic side-chain) reacted completely, while aromatics (free from side chain unsaturation), parafilns and naphthenes remained substantially unchanged.
Although it is preferred to carry out the described reaction with the hydrocarbon fraction in liquid phase, the reaction will also take place in vapor phase. The reaction is strongly exothermic and it is preferred to control the temperature of the reaction so as to maintain the same at 80 to 100 R, which may be readily accomplished by controlling the rate of introduction of the nitrogen tetroxide, or if desired, provision may be made for heat exchange.
The nitrogen tetroxide in vapor form may be obtained from any suitable source such as by vaporization of liquid nitrogen tetroxide at apdirectly into the body of the hydrocarbon liquid and thorough contact of the reactants may be enhanced by agitation during treatment. The completion of the reaction is readily ascertained by the cessation of the exothermic phenomenon (significant temperature decline) and by the marked formation of brown fumes above the surface of the liquid being treated. When it is observed from these indications that the reaction has gone to completion, further addition of N204 should be stopped. Any excess of N204 in the reaction mix may be destroyed by the addition of water to convert the same to nitric and nitrous acids, or by other well known methods such as the addition of aqueous solutions of sulfamic acid, as is done in the azo dye industry, or by the addition of aqueous solution of urea to destroy nitrous acid.
In accordance with one embodiment of the invention, a crude naphtha fraction, produced for instance by high temperature cracking of a petroleum stock, may be selectively solvent extracted to obtain an extract containing aromatic materials including styrene; olefins, and diolefins. By treatment with N204, nitrosates of the unsaturated materials are formed which are then readily separated from the unreacted substantially pure saturated aromatics. These purified aromatics find important uses as solvents and intermediates in the chemical industries.
Alternatively, the separation may be carried out in two stages. Thus, the solvent extract of naphtha may be initially treated with nitrogen trloxide (N202), under conditions substantially similar to that employed with the nitrogen tetroxide, whereby nitrosites are formed of the aralkenes and conjugated diolefins present, leaving substantially unreacted the mono-olefin content of the naphtha. The aromatics may then be purified by the removal of these remaining olefins by treatment with N204 forming the nitrosates which can be separated by distillation.
In either the one-stage or two-stage treatment above described, the unreacted hydrocarbons are preferably separated from the-nitrosites or nitrosates by steam distillation. If desired, separation may be effected by precipitation of the nitrosates or nitrosites on dilution of the treated naphtha with petroleum ether or the like, the precipitate being removed by filtration or decantation. Any desired narrow aromatic cut may be removed before or after formation of the nitroso compound. For instance by taking out a toluene cut, a pure enough toluene is obtained to meet the required standards for nitration grade toluene.
In the reaction of the N204 with an olefincontaining fraction, a wide range of temperatures is available; formation of nitroso compropriate temperature. The vapor is introduced an pounds has been obtained at temperatures rang- ,ing from below 32 F. (with liquid butene) to somewhat above 130 F. It is preferred, however, to carry out the reaction at about room temperature or slightly above as in the range of 80 to 100 F. At low temperatures the rate of reaction is slower and in some instances less stable reaction products may be formed, while at temperatures above 100 F. complicated side reactions may take place to form less easily separated products. The use of super-atmospheric pressure is unnecessary and it is preferred to carry out the reaction at atmospheric or subatmospheric pressures. Higher pressure may be used when it is not extended to the point of causing undesirable side reactions such as oxidation, nitration, and others which may occur. The reaction of the nitrogen oxides with the unsaturated hydrocarbons proceeds rapidly so that time limitations are imposed only by operating conditions to assure completeness of the reaction. For complete reaction the amount of nitrogen oxide, whether it be N203 or,N204, should be at least one mol of the oxide for each bond of olefinic unsaturation. Excess nitrogen oxide should be destroyed, as described.
Steam distillation is preferably effected by r-un-, ning steam directly into the nitrogen tetroxidetreated mix, but if desired the mix may be diluted with at least an equal volume of water and then boiled, collecting the vapors in a cooled receiver to condense the same. Usually in the case of hydrocarbons boiling below 430 F., the reaction products are heavier than water. Thus when steam distillation is efiected, the unreacted material being lighter than water collects above the surface of the water in the distillate and completion of the separation is indicated when distillate material heavier than water distills over and collects at the bottom of the water layer. However, in certain instances, as for example, in the case of tri-isobutylene nitrosate and some other reaction products which are lighter than water, it is desirable to stop the steam distillation when the ratio of oil to water in fresh portions of the distillate decreases to about 1 to 4. Such reaction products as are carried over during the steam distillation may be removed from the unreacted portion of the oil distillate by reaction with aqueous or alcoholic alkali metal hydroxide such as sodium or potassium hydroxide. Instead of or in addition to the hydroxide, removal of impurities may be effected with aqueous or alcoholic alkali metal sulfide such as sodium or potassium sulfide. Reaction of N204 with olefinic hydrocarbons in hydrocarbon mixtures boiling above 430 F. is readily effected with, however, increased tendency to side reactions such as nitration or oxidation and increasing difflculty of separation by steam distillation of the reacted from the unreacted portions as the boiling point-of the material increases.
The oily reaction products of olefins and Nfloi, composed chiefly of nitrosates, may be hydrolyzed to nitro-alcohols or rearranged to nitrooximes during steam distillation. No serious decomposition of these compounds, however, has been observed at temperatures up to 212 F., with the possible exception in cases of certain terpenes, which if present in high concentrations, should be substantially diluted with any desired saturated hydrocarbons, before distillation.
Instead of separating the nitrosate formed from the unreacted hydrocarbons in a treated fraction, the nitrosate in the admixture may be further treated or converted to other chemical 4 compounds, provided that such compounds are easily separable from the unreacted hydrocarbons by conventional methods. For instance, if the reaction mass of nitrosates and unreacted hydrocarbons is treated with aqueous alkaline solutions, before subjecting the mass to steam distillation, the nitrosates are converted to carbonyl compounds, such as ketones or aldehydes, which can then be separated from the unreacted hydrocarbons by fractionation or selective extraction.
The formation of aromatic carbonyl compounds from certain oleflns is more fully described and claimed in my copending application Serial No. 725,726 filed of even date herewith, and now Patent No. 2,542,985.
Example I A sample of 115-200 F. boiling range coal-tar reformer naphtha from destructive distillation of coal was reacted with N204 (at 70-100 F.) until excess N204 fumes indicated completion of the reaction, then washed with water and steam distilled. The distillate was washed with about 5 volume per cent of 10% caustic solution, water washed caustic free, and redistilled substantially to dryness. The distillate, amounting to 85.2% by volume of the original sample, had a density of 0.8730, a bromine number of 0.2 (ASTM) and was absorbed practically completely by concentrated sulfuric acid, showing that the composition of the distillate was practically pure aromatic in nature.
A similar treat was made on a 1l5200 F. fraction of a high temperature thermal reformer naphtha from petroleum. The distilled unreacted oil, amounting to about one-third of the original sample, had a density of 0.8685, a bromine number of 0.2 and was absorbed to the extent of about 94% by concentrated sulfuric acid. showing that practically all olefinic materials had been removed successfully and that most of the residue was aromatic in nature.
Example II A sample of a synthetic mixture of paraffinnaphthene base (acid treated gasoline range material) containing about 10% styrene was treated with N203 until excess of nitrous fumes showed completion of reaction. The precipitate formed during the reaction was separated by filtration and the residual oil, by volume of the original, was washed with about 5 volume per cent of 10% caustic solution, washed with sodium bisulflte (small amount) to remove traces of benzaldehyde, and again with a small Y amount of 10% caustic solution; then water washed to remove excess caustic, dried over calcium chloride, and distilled to 294 F. cut point. The distillate had the following properties, whichshowcomplete removal of styrene.
Refractive index ('n 1.4189 Specific gravity (d?) 0.7523 Bromine number (ASTM) 0.0
Specific dispersionW- 99 In the above example and in several of the examples following, reference is made to acid treated gasoline range material or to "acid treated naphtha" or "paraffln-naphthene base stock. These designations have reference to various samples of gasolines and light naphthas (as the case may be) that were subjected to the type of acid treatment used in determining analytically the amounts of aromatics and olefins by their absorption in the treating acid. The residue, comprised mainly of paramns and naphthenes, was washed and neutralized, and after drying constituted a material which showed no reaction with the nitrogen oxides and was therefore satisfactory as a diluent or carrier for the oleflnic materials being tested.
Example III One part of a synthetic mixture containing 23.1% turpentine, 38.45% benzene and 38.45% acid treated naphtha was treated with N20 at 70100 F. until the reaction was completeas evidenced by the presence of excess N204. The excess N204 was destroyed by the addition of 0.3 part 20% NaOH solution in 50% alcohol. The reaction products were dissolved by mixing this mixture with one part of 25% alcoholic K23 and separated by centrifuging the mixture after dilution with aqueous alcohol. The residual unreacted oil was found to equal 77.0% by volume of the original, indicating complete removal of the turpentine since previous tests have shown no significant reaction occurring with either benzene or the acid treated naphtha.
Example IV A crude benzene-toluene fraction from the destructive distillation of coal was treated with N204 until the persistant presence of unreacted N204 showed substantial completion of the treatment. The solution, new dark red in color and -with a slight gummy precipitate was washed with water and then steam distilled. The distillate was washed with about 2 to 3 volume per cent of caustic solution and then with water until it tested neutral to litmus, and then freed of water by drying over calcium chloride.
Other polymerizable impurities were then removed by treating the fraction with approximately 0.5% by volume of 96-98% H2804, washing with water, washing with 0.2% by weight of NaOH in 10% aqueous solution and then steam distilling the treated oil. The thus purified hydrocarbon distillate fraction, amounting to 91.2 was colorless, sweet smelling, and distilled completely between 176 F. and 235 F. A satisfactory H2804 wash test (did not turn black) indicated complete removal of olefinic materials.
Example V A hydrocarbon fraction containing a major amount of isopropyl benzene and minor amounts of similar boiling range material was subjected to dehydrogention conditions and then treated at room temperature with N203 until the presence of unreacted N: showed completion of reaction; the nitrosite precipitate thus formed was separated from the unreacted oil by decantation. The unreacted oil, amounting to 52.8% by volume of the original sample, was treated with N204 at room temperature until the reaction was complete. The remaining unreacted oil was then separated by steam distillation and purified by caustic wash of the distillate. The purified distillate amounted to 25.6% by volume of the original sample.
The described method of removal of olefins from mixtures containing the same is adapted to be employed as a direct volumetric measure of olefinic unsaturation in a hydrocarbon sample, as described by me in Determination of Olefinic Unsaturation," Industrial and Engineering Chemistry, Analytical Edition, (1946) vol. 18, p. 692.
The method of the invention is also applicable to the treatment of higher boiling hydrocarbons, such as those boiling in a range up to about 600 F. In the use of the described method with higher boiling hydrocarbon in this range, as above 450 F., complications may be encountered if substantial amounts of di-cyclic compounds are present, due to the greater facility of nitration taking place.
Obviously many modifications and variations of the invention as hereinbefore set forth may be made without departing from the spirit and scope thereof and therefore only such limitations should be imposed as are indicated in the appended claims.
The present application is a continuation-inpart of my application Serial No. 528,948, filed March 31, 1944, now abandoned.
I claim as my invention:
1. The method of removing olefins from low boiling liquid hydrocarbon fractions containing the same, said fractions boiling in the range of up to about 600 R, which comprises contacting such a fraction with vapors of nitrogen tetroxide in quantity approximately suflicient to react with all olefins present in such fraction and at a temperature in the range of -100" F. until excess nitrogenous vapors appear, destroying any excess nitrogen tetroxide in the reaction mixture, thereafter steam distilling the reaction mixture, and washing the oil in the distillate with caustic solution to remove therefrom any nitrogenous products present.
2. The method of separating olefins from crude liquid hydrocarbon fractions containing the same, which comprises treating such fraction with nitrogen trioxide at approximately room temperature until no further reaction occurs, separat the formed precipitate, treating the residual liquid fraction with nitrogen tetroxide at approximately room temperature until no further reaction occurs; steam distilling the nitrogen tetroxidetreated fraction, and washing the oil in the distillate with alkali.
GEORGE R. BOND. JR.
REFERENCES CITED The following references are of record in the file of this patent:
Taylor and Baker, pages 225-6 (1937) Sohaarsohmidt Untersuchungen mit Stickstofitetroxyd Zeitschrift fu: Angewandte Chemie, Nov. 27, 1924 (No. 48) pages 933 to 938.
Claims (1)
1. THE METHOD OF REMOVING OLEFINS FROM LOW BOILING LIQUID HYDROCARBON FRACTIONS CONTAINING THE SAME, SAID FRACTIONS BOILING IN THE RANGE OF UP TO ABOUT 600* F., WHICH COMPRISES CONTACTING SUCH A FRACTION WITH VAPORS OF NITROGEN TETROXIDE IN QUANTITY APPROXIMATELY SUFFICIENT TO REACT WITH ALL OLEFINS PRESENT IN SUCH FRACTION AND AT A TEMPERATURE IN THE RANGE OF 70-100* F. UNTIL EXCESS NITROGENOUS VAPORS APPEAR, DESTROYING ANY EXCESS NITROGEN TETROXIDE IN THE REACTION MIXTURE, AND AFTER STEAM DISTILLING THE REACTION MIXTURE, AND WASING THE OIL IN THE DISTILLATE WITH CAUSTIC SOLUTION TO REMOVE THEREFORM ANY NITROGENOUS PRODUCTS PRESENT.
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
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US2745843A (en) * | 1952-05-07 | 1956-05-15 | Leonard S Levitt | Process for the purification of thiophene |
US3347873A (en) * | 1960-12-21 | 1967-10-17 | Exxon Research Engineering Co | Separation of organic compounds |
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US1962181A (en) * | 1930-06-28 | 1934-06-12 | Universal Oil Prod Co | Treatment of hydrocarbon oils |
US2175437A (en) * | 1936-01-24 | 1939-10-10 | Tide Water Associated Oil Comp | Treatment of light petroleum distillates |
US2313719A (en) * | 1942-01-19 | 1943-03-16 | Solvay Process Co | Manufacture of organic sulphitation products |
US2402315A (en) * | 1944-01-04 | 1946-06-18 | Solvay Process Co | Preparation of nitrogen tetroxide addition products |
US2472550A (en) * | 1949-06-07 | Manufacture of organic nitro |
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- 1947-01-31 US US725725A patent/US2586777A/en not_active Expired - Lifetime
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
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US2472550A (en) * | 1949-06-07 | Manufacture of organic nitro | ||
US1962181A (en) * | 1930-06-28 | 1934-06-12 | Universal Oil Prod Co | Treatment of hydrocarbon oils |
US2175437A (en) * | 1936-01-24 | 1939-10-10 | Tide Water Associated Oil Comp | Treatment of light petroleum distillates |
US2313719A (en) * | 1942-01-19 | 1943-03-16 | Solvay Process Co | Manufacture of organic sulphitation products |
US2402315A (en) * | 1944-01-04 | 1946-06-18 | Solvay Process Co | Preparation of nitrogen tetroxide addition products |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2745843A (en) * | 1952-05-07 | 1956-05-15 | Leonard S Levitt | Process for the purification of thiophene |
US3347873A (en) * | 1960-12-21 | 1967-10-17 | Exxon Research Engineering Co | Separation of organic compounds |
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