US2580801A - Method of making lustrous steel music wire - Google Patents

Method of making lustrous steel music wire Download PDF

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US2580801A
US2580801A US660963A US66096346A US2580801A US 2580801 A US2580801 A US 2580801A US 660963 A US660963 A US 660963A US 66096346 A US66096346 A US 66096346A US 2580801 A US2580801 A US 2580801A
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wire
tin
drum
die
anode
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US660963A
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William E Leonard
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American Steel and Wire Company of New Jersey
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American Steel and Wire Company of New Jersey
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    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D7/00Electroplating characterised by the article coated
    • C25D7/06Wires; Strips; Foils
    • C25D7/0607Wires
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S205/00Electrolysis: processes, compositions used therein, and methods of preparing the compositions
    • Y10S205/917Treatment of workpiece between coating steps

Definitions

  • invention relates to improvements in wire drawing and provides a novel procedure which makes possible the mass production of smooth brIght finish wire having an exceptionally hi luster. Whilenot limited thereto, the method is peculiarly well suited for the manufacture of music wire.
  • music wire made according to conventional prior practice has required costly and time consuming special cleaning usually accomplished by immersing coils or bundles of ferrous wire in sulphuric or hydrochloric acid and then dipping at the cleaning crane into a vat containing tin sulphate or copper sulphate or a combination of them thereby chemically coating the ferrous stock with a film or layer of a dissimilar metal.
  • Such chemically cleaned and metallic coated wire was then taken to the wire drawing room and wet drawn 7 drafts continuously from .030" to .015 in diameter.
  • This .015 diameter wire was then taken to the cleaning house again and a metallic coating again applied by dipping the coils of wire in the metallic coating solution as referred to above.
  • the finished wire made according to the conventional practice above described lacks the smooth, white and lustrous coating obtained on wire when it is treated and drawn by the new process hereinafter disclosed and claimed.
  • Figure 1 is a. plan of a layout of apparatus for carrying out the invention. 2
  • Figure 2 may be considered as a sectional elevation taken on either of lines 2-2 shown on Figure 1.
  • Figures 3 and 4 are respectively a plan and sec ti'ona'l'elevatlon illustrating a modification of the method.
  • I start with a wire that has been drawn dry on continuous machines from the hot rolled rod, to a process size which may be approximately 2 drafts from the finished sizein "which the wire is to be sold to the customer.
  • a dr hdrawn wire for example, may vary irom .0305" to-.070" in diameter and even (CL. 204-28l and lustrous as desired.
  • This. yrawn. wire has on. its surface the soap. and lime lubricant used in the drawin process.
  • This wire w is placed on a floor reel Illand passed from there into an electroplating tub l2, as shown in Figures 1 and 2, in which the wire is made the cathodein an electroplating circuit.
  • the electric current is supplied by a generator i as indicated or from any other conventional plating current source.
  • the wire is passed through a wire drawing die i4 using a paste type of lubricant [5, after which it is wound up on a block 56 driven by any suitable or conventional power means.
  • the wire thus treated and drawn has abright luster, but not as bright
  • this drawn wire is given a furth r e ectrolytic treatment as set forth in steps recited below.
  • the wire from the block it is placed on the floor reel Illa and passed into a tub lZa in which the wire is again'made the cathode in theelectroplating circuitpowered, for examp e, by the generator as diagrammatically shown.
  • the electrolyte contained in the two tubs l 2 and lZc may be the same kind, for'example, H2604 of a corn centration'of approximately 2% to 4% by volume, but that contained in tub lzc is cleaner since the electrolytic action taking place in the first tub [2 effects a cl aning off of some of the lime and-e other lubricating substances carried over on the wire from its initial drawing treatments.
  • the wire is given a draft through a die [4a using a. paste lubricant [5a after which it is wound up on a second block 86a driven by any suitable power drive.
  • Metal anodes l8 and l8a, for example, of pig tin are suitably supported in the tubs, respectively.
  • the electroplating circuit in each tub is such that the wire to. in. process is maintainedas a cathode and the.
  • the starting material is patented wire which therefore has no lubricant on it whatsoever, that having been burnt off by the heat of the patenting furnace.
  • the patented wire is passed through two electroplating tubs 24 an 24a arranged in tandem as shown and the process differs slightly from that of Figures 1 and 2 in that, in this modification of Figures 3 and 4 there is no wire drawing step between the two e ectroplating steps and in the latter modification the wire is subjected to multiple drafts in a continuous wet wire drawing machine 26 which may be considered as a conventional wet wire drawing apparatus effective to subject the wire from 6 to 14 drafts or reductions in sectional area.
  • the wire while in process of being drawn is also maintained as a cathode in the electroplating circuit and thus has metal from'the tin anodes 28 and 28a'electroplated thereon while enroute to the ultimate take-up block 30. 4
  • safety pin wire and the like which generally have a carbon content from .65 to .90.
  • Both examples of the treatment described involve thesteps of cathodically treating the wire by passing it successively through two dilute acid electrolytic baths containing metallic'ions and subjecting the thus cleaned and plated wire to, at least, one draft through a wire drawing die whereby the combined action of the steps produces a greatly improved drawn electroplated smooth wire having a highly lustrous finish far superior than that attainable by prior known methods.
  • the wire drawer simply is required to make up, at the wire drawing bench, his tubs of acid and water solution which he does'once every one or two weeks depending upon whether the tub is the first tub or the second tub.
  • the electrolyte in the first tub generally becomes contaminated with the sludge which comes from the lubricant and lime on the wire so that it has to be dumped once a week.
  • the electrolyte in the second tub becomes less contaminated and only needs to be dumped every two weeks. This indicates that the treatment in the first tub is principally electrolytic cleaning accompanied by some electrodeposition while the treatment in the second tub is principally electrodeposition with some secondary cleaning.
  • the plant electrician places the metal anodes in the electroplating tubs and connects the circuits as shown, so that the wire drawer does not have to concern himself about that part of the apparatus. This saving in cleaning cost in the cleaning house is very substantial.
  • the labor conditions have been improved.
  • the wire drawer has less physical labor in treating and drawing the wire than he had when he used the old conventional practice.
  • each wire drawer was required to immerse coils of wire to be drawn in his metallic coating tub. This was done by means of hooks which he held in his hands to dip or swish the coils in the metallic coating solution in order to coat the wire. None of that laborious immersion treatment is now required.
  • the wire had tobe passed through the tinning bath twice in order to prevent the copper color of the original metallic coating thereon from showing through'the tin coating.
  • a method of making lustrous steel music wire including drawing steel wire rod dry through dies, thereby reducing it to a size at least two drafts larger than the desired finished size, 1. e., between .0305" and .070" in diameter, then passing the wire around a drum at least partly immersed in a first dilute sulphuric acid bath of approximately 2 to 4% concentration containing a tin anode, maintaining the wire on the drum as the cathode in a circuit including said bath, said anode and a current source, thereby efiecting principally an electrolytic cleaning of the wire accompanied by some electrodeposition of tin on the wire, drawing the coated wire through a die and thereby reducing it to smaller size and smoothing the coating, then passing the wire around a drum at least partly immersed in a second dilute sulphuric acid bath of approximately 2 to 4% concentration separate 6 from the first and containing a tin anode, maintaining the wire on the second-mentioned

Description

Jan. 1, 1952 W. E. LEONARD METHOD OF MAKING LUSTROUS STEEL MUSIC WIRE Filed April 10, 1946 3 Sheets-Sheet l INVENTOR. /4 Will/0 g? 5. Leonard Jan. 1, 1952 we. LEONARD 3 MEIHQD 01 MAKING LUSTROUS STEEL MUSIC WIRE Filed April 10, 1946 3 Sheets-Sheet 2 W. E. LEONARD METHOD OF MAKING LUSTROUS STEEL MUSIC WIRE Jan. 1, 1952 3 Sheets-Sheet 3 Filed April 10, 1946 INVENTOR. Wll/lam E. Leonard Patented Jan. 1, 1952 UNITED STATES METHOD OF MAKING LUSTROUS STEEL MUSIC WIRE William E. Leonard, Worcester, Mass, assignor to The American Steel and Wire Company of New Jersey, a. corporation of New Jersey Application April 10, 1946, Serial No. 660,963
2 Claims.
invention relates to improvements in wire drawing and provides a novel procedure which makes possible the mass production of smooth brIght finish wire having an exceptionally hi luster. Whilenot limited thereto, the method is peculiarly well suited for the manufacture of music wire.
Heretofore, music wire made according to conventional prior practice has required costly and time consuming special cleaning usually accomplished by immersing coils or bundles of ferrous wire in sulphuric or hydrochloric acid and then dipping at the cleaning crane into a vat containing tin sulphate or copper sulphate or a combination of them thereby chemically coating the ferrous stock with a film or layer of a dissimilar metal. Such chemically cleaned and metallic coated wire was then taken to the wire drawing room and wet drawn 7 drafts continuously from .030" to .015 in diameter.
This .015 diameter wire was then taken to the cleaning house again and a metallic coating again applied by dipping the coils of wire in the metallic coating solution as referred to above.
Thereafter, the wire was taken to the wire drawing room where it was again drawn 7 drafts continuously from .015" to .008" in diameter which was the finished size. In these continuous wet-drawing steps, the usual soap lubricant was used and the wire was drawn at a speed of about 240 feet per minute. The finished wire made according to the conventional practice above described lacks the smooth, white and lustrous coating obtained on wire when it is treated and drawn by the new process hereinafter disclosed and claimed.
My improved method will be apparent from the following detailed disclosure and the appended claims when read in connection with the accompanying drawings in which:
Figure 1 is a. plan of a layout of apparatus for carrying out the invention. 2
Figure 2 may be considered as a sectional elevation taken on either of lines 2-2 shown on Figure 1. Figures 3 and 4 are respectively a plan and sec ti'ona'l'elevatlon illustrating a modification of the method.
Referring in detail to the preferred method as illustrated in Figures 1 and 2, I start with a wire that has been drawn dry on continuous machines from the hot rolled rod, to a process size which may be approximately 2 drafts from the finished sizein "which the wire is to be sold to the customer. Such a dr hdrawn wire, for example, may vary irom .0305" to-.070" in diameter and even (CL. 204-28l and lustrous as desired.
larger depending on the finished size of wire desired. This. yrawn. wire has on. its surface the soap. and lime lubricant used in the drawin process.
This wire w is placed on a floor reel Illand passed from there into an electroplating tub l2, as shown in Figures 1 and 2, in which the wire is made the cathodein an electroplating circuit. The electric current is supplied by a generator i as indicated or from any other conventional plating current source.
From the electroplating tub I2 the wire is passed through a wire drawing die i4 using a paste type of lubricant [5, after which it is wound up on a block 56 driven by any suitable or conventional power means. The wire thus treated and drawn has abright luster, but not as bright In view of the fact that the wire produced by the above treatment'does not have the desired brightness and luster, this drawn wire is given a furth r e ectrolytic treatment as set forth in steps recited below.
The wire from the block it is placed on the floor reel Illa and passed into a tub lZa in which the wire is again'made the cathode in theelectroplating circuitpowered, for examp e, by the generator as diagrammatically shown. The electrolyte contained in the two tubs l 2 and lZc may be the same kind, for'example, H2604 of a corn centration'of approximately 2% to 4% by volume, but that contained in tub lzc is cleaner since the electrolytic action taking place in the first tub [2 effects a cl aning off of some of the lime and-e other lubricating substances carried over on the wire from its initial drawing treatments.
From the second tub l2a, the wire is given a draft through a die [4a using a. paste lubricant [5a after which it is wound up on a second block 86a driven by any suitable power drive. Metal anodes l8 and l8a, for example, of pig tin are suitably supported in the tubs, respectively. The electroplating circuit in each tub is such that the wire to. in. process is maintainedas a cathode and the. metal from the anode is electrolytically deposited on'the continuously advancing wire while it is enroute to the wire drawing blocks lB'and In practice it has been found advantageous to connect the electric circuit to the cathode wire in two places, one where the wire enters the tub and the other where it leaves the tub. The electric connectioncan-convenientlybe made by se curing theconductor leads to'the metal guide eyes and 20a and 22, 22a as shown. The wire under treatment makes several wraps around spools l1 and Ila which are rotatably supported in the tubs as shown.
In the modification illustrated in Figures 3 and 4, the starting material is patented wire which therefore has no lubricant on it whatsoever, that having been burnt off by the heat of the patenting furnace. In this modified process, the patented wire is passed through two electroplating tubs 24 an 24a arranged in tandem as shown and the process differs slightly from that of Figures 1 and 2 in that, in this modification of Figures 3 and 4 there is no wire drawing step between the two e ectroplating steps and in the latter modification the wire is subjected to multiple drafts in a continuous wet wire drawing machine 26 which may be considered as a conventional wet wire drawing apparatus effective to subject the wire from 6 to 14 drafts or reductions in sectional area. In this modification, the wire while in process of being drawn is also maintained as a cathode in the electroplating circuit and thus has metal from'the tin anodes 28 and 28a'electroplated thereon while enroute to the ultimate take-up block 30. 4
While the amount of tin deposited on the wire in ounces per square foot is very small, it is nevertheless sufficient to impart to the wire a smooth bright whitish finish of high luster required for so-called music wire such as used for pianos and various other types of stringed in- 'struments.
While the method has been demonstrated to be of great utility in the production of music wire, it is also used in the manufacture of reed wire and stapling wire which is generally lowcarbon .10 to .16 carbon as well as for other highcarbon wire, such as heddle wire, needle wire,
safety pin wire and the like which generally have a carbon content from .65 to .90.
Both examples of the treatment described involve thesteps of cathodically treating the wire by passing it successively through two dilute acid electrolytic baths containing metallic'ions and subjecting the thus cleaned and plated wire to, at least, one draft through a wire drawing die whereby the combined action of the steps produces a greatly improved drawn electroplated smooth wire having a highly lustrous finish far superior than that attainable by prior known methods.
As a result of the adoption and use of the herein claimed novel process a uniform color and finish are now being obtained on all wire produced in the department under my supervision and no rejection is now being experiencedwhereas formerly, rejections went as high as and over. Thus my new process makes possible-a considerable increase in production and accordingly, constitutes an important economic advance in the art. Among other new and improved results that are made available by the present invention are the following: I
a. It has eliminated the step of cleansingand coating the wire previously performed in the cleaning house at the cleaning crane. The wire drawer simply is required to make up, at the wire drawing bench, his tubs of acid and water solution which he does'once every one or two weeks depending upon whether the tub is the first tub or the second tub. The electrolyte in the first tub generally becomes contaminated with the sludge which comes from the lubricant and lime on the wire so that it has to be dumped once a week.
The electrolyte in the second tub becomes less contaminated and only needs to be dumped every two weeks. This indicates that the treatment in the first tub is principally electrolytic cleaning accompanied by some electrodeposition while the treatment in the second tub is principally electrodeposition with some secondary cleaning. The plant electrician places the metal anodes in the electroplating tubs and connects the circuits as shown, so that the wire drawer does not have to concern himself about that part of the apparatus. This saving in cleaning cost in the cleaning house is very substantial.
b. An increased die life has resulted. The wire drawer does not have to go to the storekeeper for new dies as often as he did before. This has been particularly noticed by the die-tool man who has a smaller number of replacements and repairing or redrilling of wire drawing dies. I ascribe this improvement in die life to the fact that the wire is cleaner as it goes into the die than was the case by the old prior art practice. c. There has been a very marked increase in the total production of music wire. No time is now required by the wire drawer in preparing the coils of wire on the fioor ree's which are to be drawn. Wire cleaned and coated by the conventional practice often came to the wire drawer in a snarled condition which required the wire drawer to spend about three-quarters of an hour each day to straighten it out. It has been found that the music wire production has been practically doubled. By the new method, production in the music Wire department has been increased to an amount greater than could be handled by the existing cleaning equipment for music wire.
d. By the new practice, there is now being obtained twice as much good wire as previously. Wire produced by the old conventional practice of batch cleaning and batch coating and then drawing often had to be returned to the cleaning house to be recoated so that it thereafter could be drawn to the proper color and finish. While the wire could be drawn to the required size, and tensile strength, generally that was done at the expense of the finish so that, therefore, it frequently had to be sent back to be metallic coated again and then drawn to obtain the required finish. By the new practice, as herein claimed, none of the wire produced is rejected nor has it been required to be sent back to be metallic coated again to obtain the required finish.
e. The labor conditions have been improved. The wire drawer has less physical labor in treating and drawing the wire than he had when he used the old conventional practice. By that old practice, each wire drawer was required to immerse coils of wire to be drawn in his metallic coating tub. This was done by means of hooks which he held in his hands to dip or swish the coils in the metallic coating solution in order to coat the wire. None of that laborious immersion treatment is now required.
f. There is also a saving in the hot tinning operation where this is necessary as a final operation to meet customers requirements. In that case, the liquor-finished wire as made heretofore was taken to another department for coating by the hot-tinning process. With the conventional practice of producing liquor-finished wire, it was impossible to avoid, as an inevitable result of the chemical deposition, some copper color in the finish. When the wire was taken to the hot-tinning department and a coating of tin was applied,
the wire had tobe passed through the tinning bath twice in order to prevent the copper color of the original metallic coating thereon from showing through'the tin coating.
By the present improved practice where a white, smooth and lustrous finish is obtained, when that wire is to be coated with another coating of tin by the hot tinning process, it is only necessary to pass it through the tinning bath once in order to produce the desired color. It is not necessary to pass it through twice as was heretofore required.
While in the foregoing, I have described features which have been demonstrated by an actual reduction to practice to be highly desirable, it is to be understood that the drawings and description are to be construed in an illustrative sense and that various modifications may be made without departing from the scope of the invention as defined in the appended claims.
I claim:
1. In a method of making lustrous steel music wire, the steps including drawing steel wire rod dry through dies, thereby reducing it to a size at least two drafts larger than the desired finished size, 1. e., between .0305" and .070" in diameter, then passing the wire around a drum at least partly immersed in a first dilute sulphuric acid bath of approximately 2 to 4% concentration containing a tin anode, maintaining the wire on the drum as the cathode in a circuit including said bath, said anode and a current source, thereby efiecting principally an electrolytic cleaning of the wire accompanied by some electrodeposition of tin on the wire, drawing the coated wire through a die and thereby reducing it to smaller size and smoothing the coating, then passing the wire around a drum at least partly immersed in a second dilute sulphuric acid bath of approximately 2 to 4% concentration separate 6 from the first and containing a tin anode, maintaining the wire on the second-mentioned drum as the cathode in a circuit including said second bath, the anode therein and a current source, thereby efiecting principally the electrodeposition of a final continuous tin coating on the wire, and then drawing the Wire through a die having a hole smaller than that of said first-mentioned die thereby reducing it to finished size and increasing the luster of its surface.
2. The method defined by claim 1 characterized by winding the wire on a drawing block after its passage through each die.
WILLIAM E. LEONARD.
REFERENCES CITED The following references are of record in the file of this patent:
UNITED STATES PATENTS Number Name Date 488,499 Hollingshead Dec. 20, 1892 1,058,048 Gibbs Apr. 8, 1913 1,120,191 Gibbs Dec. 8, 1914 1,466,126 Fink Aug. 28, 1923 1,766,201 Thormann June 24, 1930 1,902,493 Dantslzen Mar. 21, 1933 2,288,762 Winkler July 7, 1942 2,338,049 Murray Dec. 28, 1943 2,370,973 Lang Mar. 6, 1945 2,384,086 Glock Sept. 4, 1945 2,420,291 Adler May 13, 1947 FOREIGN PATENTS Number Country Date 14,591 Great Britain of 1890 OTHER REFERENCES Journal of the Electrodepositors Technical Society 12, 113-128 (1937).

Claims (1)

1. IN A METHOD OF MAKING LUSTROUS STEEL MUSIC WIRE, THE STEPS INCLUDING DRAWING STEEL WIRE ROD DRY THROUGH DIES, THEREBY REDUCING IT TO A SIZE AT ZIZE, I.E., BETWEEN .0305'''' AND .070'''' IN DIAMETER, THEN PASSING THE WIRE AROUND A DRUM AT LEAST PARTLY IMMERSED IN A FIRST DILUTE SULPHURIC ACID BATH OF APPROXIMATELY 2 TO 4% CONCENTRATION CONTAINING A TIN ANODE, MAINTAINING THE WIRE ON THE DRUM AS THE CATHODE IN A CIRCUIT INCLUDING SAID BATH, SAID ANODE AND A CURRENT SOURCE, THEREBY EFFECTING PRINCIPALLY AN ELECTROLYTIC CLEANING OF THE WIRE ACCOMPANINED BY SOME ELECTRODEPOSITON OF TIN ON THE WIRE, DRAWING THE COATED WIRE THROUGH A DIE AND THEREBY REDUCING IT TO SMALLER SIZE AND SMOOTHING THE COATING, THEN PASSING THE WIRE AROUND A DRUM AT LEAST PARTLY IMMERSED IN A SECOND DILUTE SULPHURIC ACID BATH OF APPROXIMATELY 2 TO 4% CONCENTRATION SEPARATE FROM THE FIRST AND CONTAINING A TIN ANODE, MAINTAINING THE WIRE ON THE SECOND-MENTIONED DRUM AS THE CATHODE IN A CIRCUIT INCLUDING SAID SECOND BATH, THE ANODE THEREIN AND A CURRENT SOURCE, THEREBY EFFECTING PRINCIPALLY THE ELECTRODEPOSITION OF A FINAL CONTINUOUS TIN COATING ON THE WIRE, AND THEN DRAWING THE WIRE THROUGH A DIE HAVING A HOLE SMALLER THAN THAT OF SAID FIRST-MENTIONED DIE THEREBY REDUCING IT TO FINISHED SIZE AND INCREASING THE LUSTER OF ITS SURFACE.
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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2844529A (en) * 1955-01-17 1958-07-22 Reynolds Metals Co Process and apparatus for rapidly anodizing aluminum
US3669866A (en) * 1969-04-03 1972-06-13 Honeywell Bull Soc Ind Apparatus for obtaining wires for magnetic memories
WO1991014024A1 (en) * 1990-03-16 1991-09-19 Norsk Hydro A.S Method and device for surface treatment of elongated, metallic articles
US5622612A (en) * 1993-06-02 1997-04-22 Duracell Inc. Method of preparing current collectors for electrochemical cells
US5667661A (en) * 1993-05-08 1997-09-16 United Wire Limited Wire plating

Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US488499A (en) * 1892-12-20 William b
US1058048A (en) * 1910-08-30 1913-04-08 Gibbs Company Method of and apparatus for producing copper wire.
US1120191A (en) * 1912-04-04 1914-12-08 Gibbs Company Apparatus for electrolytic production of wire.
US1466126A (en) * 1922-02-01 1923-08-28 Guggenheim Brothers Electrolytic refining or depositing of tin
US1766201A (en) * 1927-07-25 1930-06-24 Albert F W Thormann Copper-coated wire rope
US1902493A (en) * 1931-06-22 1933-03-21 Gen Electric Wire making process
US2288762A (en) * 1938-02-07 1942-07-07 Bethlehem Steel Corp Zinc coated ferrous article
US2338049A (en) * 1939-07-20 1943-12-28 Continental Can Co Method of coating base metal withtin
US2370973A (en) * 1941-11-22 1945-03-06 William C Lang Method and apparatus for producing coated wire
US2384086A (en) * 1939-12-22 1945-09-04 Crown Cork & Seal Co Method of making tin plate
US2420291A (en) * 1940-07-22 1947-05-13 Nat Standard Co Electrodepositing copper upon steel wire

Patent Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US488499A (en) * 1892-12-20 William b
US1058048A (en) * 1910-08-30 1913-04-08 Gibbs Company Method of and apparatus for producing copper wire.
US1120191A (en) * 1912-04-04 1914-12-08 Gibbs Company Apparatus for electrolytic production of wire.
US1466126A (en) * 1922-02-01 1923-08-28 Guggenheim Brothers Electrolytic refining or depositing of tin
US1766201A (en) * 1927-07-25 1930-06-24 Albert F W Thormann Copper-coated wire rope
US1902493A (en) * 1931-06-22 1933-03-21 Gen Electric Wire making process
US2288762A (en) * 1938-02-07 1942-07-07 Bethlehem Steel Corp Zinc coated ferrous article
US2338049A (en) * 1939-07-20 1943-12-28 Continental Can Co Method of coating base metal withtin
US2384086A (en) * 1939-12-22 1945-09-04 Crown Cork & Seal Co Method of making tin plate
US2420291A (en) * 1940-07-22 1947-05-13 Nat Standard Co Electrodepositing copper upon steel wire
US2370973A (en) * 1941-11-22 1945-03-06 William C Lang Method and apparatus for producing coated wire

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2844529A (en) * 1955-01-17 1958-07-22 Reynolds Metals Co Process and apparatus for rapidly anodizing aluminum
US3669866A (en) * 1969-04-03 1972-06-13 Honeywell Bull Soc Ind Apparatus for obtaining wires for magnetic memories
WO1991014024A1 (en) * 1990-03-16 1991-09-19 Norsk Hydro A.S Method and device for surface treatment of elongated, metallic articles
US5667661A (en) * 1993-05-08 1997-09-16 United Wire Limited Wire plating
US5622612A (en) * 1993-06-02 1997-04-22 Duracell Inc. Method of preparing current collectors for electrochemical cells

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