US2563447A - Flotation of hematite - Google Patents
Flotation of hematite Download PDFInfo
- Publication number
- US2563447A US2563447A US2563447DA US2563447A US 2563447 A US2563447 A US 2563447A US 2563447D A US2563447D A US 2563447DA US 2563447 A US2563447 A US 2563447A
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- US
- United States
- Prior art keywords
- flotation
- pulp
- soap
- ore
- hematite
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000005188 flotation Methods 0.000 title claims description 64
- 229910052595 hematite Inorganic materials 0.000 title description 34
- 239000011019 hematite Substances 0.000 title description 34
- 239000000344 soap Substances 0.000 claims description 52
- 239000003153 chemical reaction reagent Substances 0.000 claims description 32
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 28
- 235000012343 cottonseed oil Nutrition 0.000 claims description 26
- 239000000839 emulsion Substances 0.000 claims description 20
- 239000000203 mixture Substances 0.000 claims description 20
- 229910052742 iron Inorganic materials 0.000 claims description 14
- 239000008149 soap solution Substances 0.000 claims description 14
- 238000009291 froth flotation Methods 0.000 claims description 12
- 239000002480 mineral oil Substances 0.000 claims description 8
- 235000010446 mineral oil Nutrition 0.000 claims description 8
- 210000002683 Foot Anatomy 0.000 description 26
- 238000000034 method Methods 0.000 description 24
- 239000003921 oil Substances 0.000 description 22
- 235000019198 oils Nutrition 0.000 description 22
- 238000011084 recovery Methods 0.000 description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 14
- 239000003795 chemical substances by application Substances 0.000 description 12
- 239000000463 material Substances 0.000 description 12
- CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 12
- BVDRUCCQKHGCRX-UHFFFAOYSA-N 2,3-dihydroxypropyl formate Chemical compound OCC(O)COC=O BVDRUCCQKHGCRX-UHFFFAOYSA-N 0.000 description 8
- 241000196324 Embryophyta Species 0.000 description 8
- 230000003750 conditioning Effects 0.000 description 8
- 239000002245 particle Substances 0.000 description 8
- QAOWNCQODCNURD-UHFFFAOYSA-L sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 8
- 239000001187 sodium carbonate Substances 0.000 description 6
- 229910000029 sodium carbonate Inorganic materials 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 239000007787 solid Substances 0.000 description 6
- VTYYLEPIZMXCLO-UHFFFAOYSA-L calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
- 235000019864 coconut oil Nutrition 0.000 description 4
- 239000003240 coconut oil Substances 0.000 description 4
- 239000012535 impurity Substances 0.000 description 4
- 229910052500 inorganic mineral Inorganic materials 0.000 description 4
- 229910000460 iron oxide Inorganic materials 0.000 description 4
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 4
- 239000011707 mineral Substances 0.000 description 4
- 230000001264 neutralization Effects 0.000 description 4
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 4
- 159000000000 sodium salts Chemical class 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- PRKQVKDSMLBJBJ-UHFFFAOYSA-N Ammonium carbonate Chemical compound N.N.OC(O)=O PRKQVKDSMLBJBJ-UHFFFAOYSA-N 0.000 description 2
- 229960003563 Calcium Carbonate Drugs 0.000 description 2
- 229940013317 Fish Oils Drugs 0.000 description 2
- 229940059904 Light Mineral Oil Drugs 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M NaHCO3 Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- 239000001099 ammonium carbonate Substances 0.000 description 2
- 235000012501 ammonium carbonate Nutrition 0.000 description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 description 2
- 238000001246 colloidal dispersion Methods 0.000 description 2
- 239000012141 concentrate Substances 0.000 description 2
- 230000001143 conditioned Effects 0.000 description 2
- 235000005687 corn oil Nutrition 0.000 description 2
- 239000002285 corn oil Substances 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 239000003995 emulsifying agent Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000003925 fat Substances 0.000 description 2
- 235000019197 fats Nutrition 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 238000007667 floating Methods 0.000 description 2
- 230000005484 gravity Effects 0.000 description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 2
- 150000004668 long chain fatty acids Chemical class 0.000 description 2
- 239000010687 lubricating oil Substances 0.000 description 2
- 238000005065 mining Methods 0.000 description 2
- 239000007764 o/w emulsion Substances 0.000 description 2
- 229910052592 oxide mineral Inorganic materials 0.000 description 2
- 239000003208 petroleum Substances 0.000 description 2
- 239000001184 potassium carbonate Substances 0.000 description 2
- 229910000027 potassium carbonate Inorganic materials 0.000 description 2
- 230000000630 rising Effects 0.000 description 2
- 230000000087 stabilizing Effects 0.000 description 2
- 238000010408 sweeping Methods 0.000 description 2
- 239000010723 turbine oil Substances 0.000 description 2
- 235000015112 vegetable and seed oil Nutrition 0.000 description 2
- 239000008158 vegetable oil Substances 0.000 description 2
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/02—Froth-flotation processes
- B03D1/06—Froth-flotation processes differential
Definitions
- Flotation processes for separating mineral ores from gangue materials generally comprise a series of integrated steps, for example reducing ore particles in size to substantially free the ore from the gangue, preparing a pulp by the addition of water to the ore, adding and dispersing in the pulp reagents which have the desired selectivity for the ore, floating the ore, dewatering the concentrate and disposing of the tailings.
- the pulp is usually formed in an agitating mixing device called a condition, and the necessary reagents added at the conditioner.
- a condition agitating mixing device
- the pulp completely mixed, enters a flotation cell, and upon the addition of air bubbles during agitation in the cell the ore adheres to the bubbles, rising with them to the surface, where it is held by a more or less stable froth.
- the froth and the ore are then mechanically withdrawn from the cell.
- Flotation reagents are not always readily miscible with pulps, and lack of homogeneity of the mass entering a flotation cell can result in excessive need for reagents in achieving a given result, or can limit the grade and recovery of the floated material so as to render the process clumsy and impractical of eflicient operation.
- This invention comprises subjecting an ore containing hematite to a flotation process wherein a collector and a, frother are used, in. which process the collector is an oil carried in a soapstabilized oil-in-water emulsion, and the frother is a soap.
- particles of impure ore are introduced into a conditioner, where water is added with agitation to produce a pulp.
- a conditioning reagent is added to the pulp in the conditioner, the reagent preferred being sodium carbonate, although other agents such as potassium carbonate, sodium acid carbonate, calcium carbonate, ammonium carbonate, sodium hydroxide, etc., may be used.
- a collecting reagent comprising an oil is added to the conditioned pulp, the oil being emulsified in water and the emulsion stabilized by a small proportion of a suitable soap.
- the oil employed may be a refined petroleum lube oil fraction of 3 turbine oil, spindle oil, etc., may be used.
- the soap used for stabilizing the emulsion may be any suitable soap, for example cottonseed foots soap, others generally known as good emulsifying agents being equally suitable, including soaps made from animal fats, vegetable oils, and fish oils. 1 Afterfdispersion oi the emulsion throughout the pulp, a fr'othing agent comprising a poor soap is added to the mixture. Cottonseed foots soap has been found excellently adapted for use in the process. Other agents may be used for this purpose including corn oil foots soap and other soaps and soap mixtures having approximately the same fatty radicals, i. e. approximately the same proportions of saturated and unsaturated,
- the pulp is passed into a flotation cell where air bubbles are introduced during further violent agitation, the ore floated and the froth containing the ore removed from the cell.
- the process makes possible the recovery of a large proportion of high-grade hematite from low-grade ore, and results in adequate flotation when pulps of high solid content are used, thereby achieving a high rate of recovery for each cell employed.
- a small proportion of a solution of a neutral monoglyceride sulfate added in the pulp before the frothing agent serves to improve the grade of the material recovered, and such an agent is particularly applicable where rougher and cleaner cells are used in series, for use in the cleaner cells toward removing impurities in the last stage of concentration.
- Removal of the froth with the ore particles 1 may be accomplished in conventional manner, for example by overflow or through the use of sweeping vanes.
- the process does not require flne grinding for successful operation, and has been found to operate satisfactorily when performed with ore of minus 20 mesh size 1. e., which is sufficiently reduced in size that all particles thereof can be passed through a 20 mesh screen.
- Example I 2000 parts by weight of low-grade, impure hematite ore, containing 18.2% F620: and of minus 20 mesh size are mixed together and agitated with 3000 parts of water to form a pulp. To the pulp is added 1 part of sodium carbonate, followed by further agitation and the addition of 1.5 parts of an emulsion containing of a lighter pale oil and 1% of cottonseed foots soap. During still further agitation 2.0 parts of cottonseed foots soap are added and the mixture then passed into a flotation cell where in the presence of violent agitation and air bubbles the ore is floated off in a surface froth and the froth removed from the cell. The hematite recovered from the froth represents 86.1% of the total iron oxide present in the impure ore and is of 80.2% purity.
- Example II 2000 parts by weight of impure, minus 20 mesh hematite ore containing 18.2% Fe2O3 are mixed and dispersed with 3000 parts of water in a. conditioning tank. 1.5 parts of sodium carbonate are added and the mixture is continuously agitated in the entire conditioning step during which are added, separately and in or- 5 der, 1.5 parts of the emulsion described in Example I, a, solution containing 0.02 part of a sodium salt of a monoglyceride sulfate made from coconut oil and 1.5 parts of cottonseed foots soap. The mixture is then transferred to a flotation cell where air bubbles are introduced into the pulp during agitation, the ore floated off, and the froth containing the ore removed from the cell. The hematite recovered is of 84% purity and represents 84.5% of the iron oxide present in the impure ore.
- I claim 1 The method of concentrating iron ores by flotation which comprises forming a flotation pulp of the desired density, incorporating with the pulp a proportion of a flotation reagent comprising a, mineral oil in emulsion in a soap solution, adding to the mixture a proportion of a poor soap having approximately the same fatty radicals as cottonseed foots soap and thereafter 25 subjecting the pulp to froth flotation.
- the method of concentrating iron ores by flotation which comprises forming a flotation pul of the desired density, incorporating with the pulp a proportion of a flotation reagent comprising a mineral oil in emulsion in a soap solution, adding to the mixture a proportion of a neutral monoglyceride sulfate, adding a proportion of a poor soap having approximately the same fatty radicals as cottonseed foots soap and thereafter subjecting the pulp to froth flotation.
- the method of concentrating iron ores by flotation which comprises forming a flotation pulp of the desired density, incorporating with the pulp a proportion of a flotation reagent comprising a refined, light mineral oil of the type known as pale oil, the oil being emulsified in an aqueous soap solution, adding to the mixture a proportion of a poor soap having approximately the same fatty radicals as cottonseed foots soap and thereafter subjecting the pulp to froth flotation.
- the method of concentrating iron ores which comprises forming a flotation pulp of the desired density, incorporating with the pulp a. proportion of a flotation reagent comprising a mineral oil in emulsion in an aqueous soap solution, adding to the mixture a proportion of cottonseed foots soap and thereafter subjecting the pulp to froth flotation.
- the method of concentrating non-magnetic iron ores which comprises addin water to a powdered ore of minus 20 mesh to form a pulp of the desired density, adding and dispersing in the pulp flotation reagents including a colloidal dispersion of a light pale oil in aqueous soap solution, a relatively small proportion of a sodium salt of a monoglyceride sulfate made from long chain fatty acids such as coconut oil and a larger proportion of cottonseed foots soap, passing air bubbles through the pulp during agitation Number to float the ore in a froth, and removing the 2,014,405 froth containing the ore from the surface of the 2,014,406 pulp.
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- Paper (AREA)
- Manufacture And Refinement Of Metals (AREA)
Description
Patented Aug. 7, 1951 FLOTATION F HEMATITE William Godfrey Alsop, New York, N. Y., assignor to Colgate-Palmolive-Peet Company, Jersey City, N. J a corporation of Delaware No Drawing. Application November 29, 1946, Serial No. 713,097
6 Claims. (Cl. 209-166) This invention relates to the recovery of hematite by flotation.
Previously, high-grade hematite ores available near the surface in some parts of this country have been mined, concentrated in washing plants or by other gravity methods and marketed. The low-grade ores, such as those found in washing plant tailings and in a natural state near sources of high-grade ore, have been accordingly discarded. In many places the high-grade ores have now become practically exhausted, and in obtaining them it is necessary to dig shafts. Greater attention is therefore directed to the recovery of hematite from the previously rejected low-grade ores.
Earlier eiiorts have been made toward developing a satisfactory process for recovering hematite from low-grade ores by flotation, however, these processes have so far been somewhat unsuccessful because of the low proportion of the ore treated which is recovered in usable form, and the costly fine grinding which is necessary in carrying them out.
It is known that certain oils, fatty acids and similar materials can be made to develop selectivity for oxide minerals. Agents of these and similar types have been used in the past in the process of froth flotation as applied in separating mineral ores from accompanying gangue materials.
Flotation processes for separating mineral ores from gangue materials generally comprise a series of integrated steps, for example reducing ore particles in size to substantially free the ore from the gangue, preparing a pulp by the addition of water to the ore, adding and dispersing in the pulp reagents which have the desired selectivity for the ore, floating the ore, dewatering the concentrate and disposing of the tailings.
The pulp is usually formed in an agitating mixing device called a condition, and the necessary reagents added at the conditioner. Generally the pulp, completely mixed, enters a flotation cell, and upon the addition of air bubbles during agitation in the cell the ore adheres to the bubbles, rising with them to the surface, where it is held by a more or less stable froth. The froth and the ore are then mechanically withdrawn from the cell.
In the past, numerous difiiculties have at- -tended the concentration of hematite ores by flotation, for example, prior processes require fine grinding for selective flotation. Portions of the hematite contained in the ore are found present in the tailings, while the ore recovered contains a substantial proportion of impurities. Low solid content in the pulp is requisite, as high concentrations result in entrainment of slimes by a r18- ing mat of floated material.
Flotation reagents are not always readily miscible with pulps, and lack of homogeneity of the mass entering a flotation cell can result in excessive need for reagents in achieving a given result, or can limit the grade and recovery of the floated material so as to render the process clumsy and impractical of eflicient operation.
It is an object of this invention to provide a method for the recovery of hematite ores, and particularly low-grade hematite ores by flotation in which appropriate reagents may be uniformly dispersed throughout a pulp of high solid content, to eifect an efficient recovery of high grade hematite without fine grinding of the ore.
Further objects and advantages of this invention will be apparent from the following description.
This invention comprises subjecting an ore containing hematite to a flotation process wherein a collector and a, frother are used, in. which process the collector is an oil carried in a soapstabilized oil-in-water emulsion, and the frother is a soap.
In carrying out the process, particles of impure ore are introduced into a conditioner, where water is added with agitation to produce a pulp. A conditioning reagent is added to the pulp in the conditioner, the reagent preferred being sodium carbonate, although other agents such as potassium carbonate, sodium acid carbonate, calcium carbonate, ammonium carbonate, sodium hydroxide, etc., may be used.
A collecting reagent comprising an oil is added to the conditioned pulp, the oil being emulsified in water and the emulsion stabilized by a small proportion of a suitable soap. The oil employed may be a refined petroleum lube oil fraction of 3 turbine oil, spindle oil, etc., may be used. The soap used for stabilizing the emulsion may be any suitable soap, for example cottonseed foots soap, others generally known as good emulsifying agents being equally suitable, including soaps made from animal fats, vegetable oils, and fish oils. 1 Afterfdispersion oi the emulsion throughout the pulp, a fr'othing agent comprising a poor soap is added to the mixture. Cottonseed foots soap has been found excellently adapted for use in the process. Other agents may be used for this purpose including corn oil foots soap and other soaps and soap mixtures having approximately the same fatty radicals, i. e. approximately the same proportions of saturated and unsaturated,
long and short chain molecules, as cottonseed foots soap.
After the conditioning reagent, collector and frother have been added to the pulp and the mass made substantially homogeneous by agitation, the pulp is passed into a flotation cell where air bubbles are introduced during further violent agitation, the ore floated and the froth containing the ore removed from the cell.
The process makes possible the recovery of a large proportion of high-grade hematite from low-grade ore, and results in adequate flotation when pulps of high solid content are used, thereby achieving a high rate of recovery for each cell employed.
A small proportion of a solution of a neutral monoglyceride sulfate added in the pulp before the frothing agent serves to improve the grade of the material recovered, and such an agent is particularly applicable where rougher and cleaner cells are used in series, for use in the cleaner cells toward removing impurities in the last stage of concentration.
Removal of the froth with the ore particles 1 may be accomplished in conventional manner, for example by overflow or through the use of sweeping vanes.
The process does not require flne grinding for successful operation, and has been found to operate satisfactorily when performed with ore of minus 20 mesh size 1. e., which is sufficiently reduced in size that all particles thereof can be passed through a 20 mesh screen.
The following examples are included to illustrate but not to limit the invention:
Example I 2000 parts by weight of low-grade, impure hematite ore, containing 18.2% F620: and of minus 20 mesh size are mixed together and agitated with 3000 parts of water to form a pulp. To the pulp is added 1 part of sodium carbonate, followed by further agitation and the addition of 1.5 parts of an emulsion containing of a lighter pale oil and 1% of cottonseed foots soap. During still further agitation 2.0 parts of cottonseed foots soap are added and the mixture then passed into a flotation cell where in the presence of violent agitation and air bubbles the ore is floated off in a surface froth and the froth removed from the cell. The hematite recovered from the froth represents 86.1% of the total iron oxide present in the impure ore and is of 80.2% purity.
Example II 2000 parts by weight of impure, minus 20 mesh hematite ore containing 18.2% Fe2O3 are mixed and dispersed with 3000 parts of water in a. conditioning tank. 1.5 parts of sodium carbonate are added and the mixture is continuously agitated in the entire conditioning step during which are added, separately and in or- 5 der, 1.5 parts of the emulsion described in Example I, a, solution containing 0.02 part of a sodium salt of a monoglyceride sulfate made from coconut oil and 1.5 parts of cottonseed foots soap. The mixture is then transferred to a flotation cell where air bubbles are introduced into the pulp during agitation, the ore floated off, and the froth containing the ore removed from the cell. The hematite recovered is of 84% purity and represents 84.5% of the iron oxide present in the impure ore.
I claim 1. The method of concentrating iron ores by flotation which comprises forming a flotation pulp of the desired density, incorporating with the pulp a proportion of a flotation reagent comprising a, mineral oil in emulsion in a soap solution, adding to the mixture a proportion of a poor soap having approximately the same fatty radicals as cottonseed foots soap and thereafter 25 subjecting the pulp to froth flotation.
2. The method of concentrating iron ores by flotation which comprises forming a flotation pul of the desired density, incorporating with the pulp a proportion of a flotation reagent comprising a mineral oil in emulsion in a soap solution, adding to the mixture a proportion of a neutral monoglyceride sulfate, adding a proportion of a poor soap having approximately the same fatty radicals as cottonseed foots soap and thereafter subjecting the pulp to froth flotation.
3. The method of concentrating iron ores by flotation which comprises forming a flotation pulp of the desired density, incorporating with the pulp a proportion of a flotation reagent comprising a refined, light mineral oil of the type known as pale oil, the oil being emulsified in an aqueous soap solution, adding to the mixture a proportion of a poor soap having approximately the same fatty radicals as cottonseed foots soap and thereafter subjecting the pulp to froth flotation.
4. The method of concentrating iron ores which comprises forming a flotation pulp of the desired density, incorporating with the pulp a. proportion of a flotation reagent comprising a mineral oil in emulsion in an aqueous soap solution, adding to the mixture a proportion of cottonseed foots soap and thereafter subjecting the pulp to froth flotation.
5. The method of concentrating non-magnetic iron ores which comprises adding water to a powdered ore of minus 20 mesh to form a pulp of the desired density, adding and dispersing in the pulp flotation reagents, including an emulsion of a light, refined pale oil in aqueous soap solution as a collector and cottonseed foots soap as a frother, passing air bubbles through the pulp during agitation to float the ore in a froth, and removing the froth containing the ore from the surface of the pulp.
6. The method of concentrating non-magnetic iron ores which comprises addin water to a powdered ore of minus 20 mesh to form a pulp of the desired density, adding and dispersing in the pulp flotation reagents including a colloidal dispersion of a light pale oil in aqueous soap solution, a relatively small proportion of a sodium salt of a monoglyceride sulfate made from long chain fatty acids such as coconut oil and a larger proportion of cottonseed foots soap, passing air bubbles through the pulp during agitation Number to float the ore in a froth, and removing the 2,014,405 froth containing the ore from the surface of the 2,014,406 pulp. 2,163,701 WILLIAM GODFREY ALSOP. 2,163,702 2,164,063 REFERENCES CITED 2,410,37
The following references are of record in the file of this patent:
UNITED STATES PATENTS 10 Number Name Date 1,939,119 Holt Dec. 12, 1933 6 Name Date Weed Sept. 17, 1935 Weed Sept. 17, 1935 Ried June 27, 1939 Riecl June 27, 1939 Handy June 27, 1939 Booth Oct. 29, 1946 OTHER REFERENCES A. I. M. E. Tech. Paper 1675, pages 14, 15, 17, la, in Mining Technology, vol. 8, January 1944.
Claims (1)
1. THE METHOD OF CONCENTRATING IRON ORES BY FLOTATION WHICH COMPRISES FORMING A FLOTATION PULP OF THE DESIRED DENSITY, INCORPORATING WITH THE PULP A PROPORTION OF A FLOTATION REAGENT COMPRISING A MINERAL OIL IN EMULSION IN A SOAP SOLUTION, ADDING TO THE MIXTURE A PROPORTION OF A POOR SOAP HAVING APPROXIMATELY THE SAME FATTY RADICALS AS COTTONSEED FOOTS SOAP AND THEREAFTER SUBJECTING THE PULP TO FROTH FLOTATION.
Publications (1)
Publication Number | Publication Date |
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US2563447A true US2563447A (en) | 1951-08-07 |
Family
ID=3438178
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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US2563447D Expired - Lifetime US2563447A (en) | Flotation of hematite |
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Country | Link |
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US (1) | US2563447A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2944666A (en) * | 1956-04-04 | 1960-07-12 | Hanna Mining Co | Ore beneficiation |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1939119A (en) * | 1930-05-21 | 1933-12-12 | Grover J Holt | Ore conditioning process |
US2014406A (en) * | 1932-10-12 | 1935-09-17 | Weed Floyd | Method of concentrating nonsulphide minerals by froth flotation |
US2014405A (en) * | 1932-10-12 | 1935-09-17 | Weed Floyd | Concentrating iron ores by froth flotation |
US2164063A (en) * | 1938-03-07 | 1939-06-27 | Royal S Handy | Flotation reagent |
US2163702A (en) * | 1937-09-10 | 1939-06-27 | Separation Process Company | Flotation process |
US2163701A (en) * | 1937-09-10 | 1939-06-27 | Separation Process Company | Flotation process |
US2410376A (en) * | 1943-04-05 | 1946-10-29 | American Cyanamid Co | Beneficiation of iron ores |
-
0
- US US2563447D patent/US2563447A/en not_active Expired - Lifetime
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1939119A (en) * | 1930-05-21 | 1933-12-12 | Grover J Holt | Ore conditioning process |
US2014406A (en) * | 1932-10-12 | 1935-09-17 | Weed Floyd | Method of concentrating nonsulphide minerals by froth flotation |
US2014405A (en) * | 1932-10-12 | 1935-09-17 | Weed Floyd | Concentrating iron ores by froth flotation |
US2163702A (en) * | 1937-09-10 | 1939-06-27 | Separation Process Company | Flotation process |
US2163701A (en) * | 1937-09-10 | 1939-06-27 | Separation Process Company | Flotation process |
US2164063A (en) * | 1938-03-07 | 1939-06-27 | Royal S Handy | Flotation reagent |
US2410376A (en) * | 1943-04-05 | 1946-10-29 | American Cyanamid Co | Beneficiation of iron ores |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2944666A (en) * | 1956-04-04 | 1960-07-12 | Hanna Mining Co | Ore beneficiation |
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