US256108A - Daniel m - Google Patents
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- US256108A US256108A US256108DA US256108A US 256108 A US256108 A US 256108A US 256108D A US256108D A US 256108DA US 256108 A US256108 A US 256108A
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- solution
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- 239000007789 gas Substances 0.000 description 48
- 150000001875 compounds Chemical class 0.000 description 46
- 239000000203 mixture Substances 0.000 description 18
- 239000003921 oil Substances 0.000 description 14
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 12
- 239000002904 solvent Substances 0.000 description 12
- 235000011149 sulphuric acid Nutrition 0.000 description 12
- 239000001117 sulphuric acid Substances 0.000 description 12
- 239000004753 textile Substances 0.000 description 12
- VEXZGXHMUGYJMC-UHFFFAOYSA-M chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 10
- 239000000463 material Substances 0.000 description 10
- KEAYESYHFKHZAL-UHFFFAOYSA-N sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 10
- 239000011734 sodium Substances 0.000 description 10
- 229910052708 sodium Inorganic materials 0.000 description 10
- 239000002253 acid Substances 0.000 description 8
- 150000002430 hydrocarbons Chemical class 0.000 description 8
- 238000000034 method Methods 0.000 description 8
- 235000002639 sodium chloride Nutrition 0.000 description 8
- 239000011780 sodium chloride Substances 0.000 description 8
- 239000000126 substance Substances 0.000 description 8
- 239000004215 Carbon black (E152) Substances 0.000 description 6
- 210000003746 Feathers Anatomy 0.000 description 6
- 239000004744 fabric Substances 0.000 description 6
- 239000012535 impurity Substances 0.000 description 6
- 239000005871 repellent Substances 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 238000005406 washing Methods 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- UHOVQNZJYSORNB-UHFFFAOYSA-N benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 4
- 238000004061 bleaching Methods 0.000 description 4
- 239000004615 ingredient Substances 0.000 description 4
- 238000000746 purification Methods 0.000 description 4
- 238000009877 rendering Methods 0.000 description 4
- 230000002940 repellent Effects 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- FAPWRFPIFSIZLT-UHFFFAOYSA-M sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 239000004575 stone Substances 0.000 description 4
- 238000004078 waterproofing Methods 0.000 description 4
- 239000002023 wood Substances 0.000 description 4
- 206010022114 Injury Diseases 0.000 description 2
- 235000019687 Lamb Nutrition 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 230000003796 beauty Effects 0.000 description 2
- 239000007844 bleaching agent Substances 0.000 description 2
- 150000003841 chloride salts Chemical class 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 238000004040 coloring Methods 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 230000001877 deodorizing Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 238000005562 fading Methods 0.000 description 2
- 238000000855 fermentation Methods 0.000 description 2
- 230000004151 fermentation Effects 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000010985 leather Substances 0.000 description 2
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Inorganic materials O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 239000000123 paper Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000012466 permeate Substances 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 238000004321 preservation Methods 0.000 description 2
- 230000000717 retained Effects 0.000 description 2
- 239000002965 rope Substances 0.000 description 2
- 235000011121 sodium hydroxide Nutrition 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- 238000009834 vaporization Methods 0.000 description 2
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/02—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with hydrocarbons
Definitions
- This invention is an improvement on a similar invention granted to me in Patent No. 224,295, dated February 10, 1880.
- the object of this invention is to prepare a compound adapted to be applied to various kinds and qualities of goods or other articles, for the purposeof rendering them impervious to moisture or repellent to water or moisture.
- the articles intended to be treated by this compound embrace every variety of textile delicate-such as sails of vessels, carpets, tents, cordage rope, yarn, thread, clothing, &c., as well as feathers, flowers, furs, paper, wood, stone, or metal-and, in short, the compound is intended to be applied to any article Whatever the preservation of which from the humidity of the atmosphere or from amore complete saturation is a desirable object, and the compound used is such that it may be applied to the most delicate shades or tints of any textile goods, or ostrich-feathers, or any other feathers or fursthat claim the attention of the taxidermist,'or any beautiful specimens,
- The-nature and constituents of this compound are such that no delicacy of shade or coloring will be injured by the treatment therewith, but, on the contrary, the colors to which the compound shall be applied will become and remain more fixed and unfailing, for the reason that the humidity of the atmosphere will be excluded from every pore and fiber of the article treated, and hence all incipient decay or fermentation will be prohibited, and consequent decomposition or fading will thereby be prevented.
- the materials used for this purpose are so compounded and manipulated and the elements of the compound are such that goods treated therewith will retain all their ordinary beauty and style of finish, remain as entirely pliable and soft as in the natural or untreated state, be as perfectly inodorous as before the treatment, and no injury whatever will result from the treatment.
- the materials used for this purpose, the manner of compounding them, and the process of treating the goods are as follows:
- the mixture may be made in any suitable quantities, and will preferably be compounded in such a vessel as is usuallyemployed as and called an agitator in coal-oil-retlnin g operations.
- the mixture or solution will be treated with a gas or gases in substantially the following manner: Itake about one pound (more or less) of common salt, or chloride of sodium, for each gallon of the solution above described, and put it directly into the solution, preferably distributing the salt pretty evenly over the bottom of the vessel containing the solution, and immediately thereafter I add to the mixture for each gallon thereof about one pound (more or less) of sulphuric acid, which will settle down directly upon the salt and decompose it, thereby setting free a gas or gases, which will rise up through the solution or com pound under treatment and attack the mucilaginous and sedimentary portions thereof, and precipitate them to the bottom of the vessel, the whole operation of the gaseous treatment IOO z I aselee upon the solution being to whiten or bleach it, as well
- the compound or solution will be allowed to remain standing quietly, subject to the gaseous treatmentabove described, for from three to ten days, (more or less,) and the sediment will be drawn off from the bottom of the vessel, or the purified compound from the top of the vessel. After the sedimentshall have been drawn off or removed from the purified solution, the remaining gas will be eliminated from the compound by any suitable means. This may be accomplished by allowing the mixture to stand a sufficient length of time to discharge the gas; or the mixture may be agitated by any suitable mechanical appliance; or it could best be done by a powerful current of air driven through 'the compound from the bottom to the top, using for this purpose some suitable air compressor.
- blower conveniently located with reference to the fabricating-vessel and connected therewith by means of suitable piping, so arranged within the fabricating-vessel as to deliver the air-currentat or near the bottom of the same, in order that the air-current may be driven up through the mass of the compound, so as to carry off any gases, impurities, or other foreign substances that may be held in suspension in the solution.
- This agitation will be continued for from five to thirty minutes, or until the gas is removed from the compound,along with all foreign substances or impurities that may be carried with it.
- a process of treatment somewhat similar to that above described has been employed heretofore by me in the treatment of crude or distilled oils, such oils having been subject to the gaseous treatment, and afterward agitated with air; but the application of the gaseous treatment and air-agitation in the present instance is to a compound, as hereinbefore described, of an essentially different character to the oils to which I have heretofore applied it, and for which I obtained Letters Patent No. 183,401 in 1.876.
- the gas for the purification and bleaching of the solution under treatment maybe generated within the mass of the compound under treatment, and it will be best to so generate it, and from the materials hereinbefore described, as by doing so a cheap and efficient gas may be produced and used in its nascent form, which will be most efficacious; but it will be equally within the scope of this invention to generate the gas within a contiguous vessel and condnetit into the fabricating-vessel by means of suitable piping, so arranged as to deliver the gas at or near the bottom of the solution, so that it may rise up through and permeate the entire mass under treatment.
- the gas or gases may also be generated from other chlorides and other acids than those mentioned above, or an efficient gas or gases may be generated by mixing the black oxide of manganese with the chloride of sodium and then causing the mixture to be acted upon by sulphuric acid, muriatie acid, or any other suitable acid, and all of these forms of generating the gas or gases and the elements for fabricating the same are clearly within the scope of this invention, as I find them to produce equivalent results; but I prefer the use of the chloride of sodium and sulphuric acid, and the application of the same, substantially as first hereinbefore described.
- the solution will be retained in a tightly-closed vessel, if it is desired to retain it in the form of a solution, and to do this, it left in the agitator or fabricating-vessel, a cover should be provided therefor, which said cover will set into a water-chamber, or arranged in any similar manner so as to tightly seal it and prevent the evaporation of the solvent, which is exceedingly volatile; but if it is desired to restore the solids contained in the solution to a solidified form, the compound should be placed in shallow tanks, and the vaporization of the solvent be accelerated by raising the temperature of the apartment in which it is placed to, say, 150 Fahrenheit.
- the usual manner, however, of storing the purified material will be in the solution, as it will be principally adapted to application to textile or other goods or materials for the purpose of rendering them water-' repellent or proof against oxidization in any form.
- the class of goods which may be so treated and preserved embraces an exceedingly wide range of subjects, among which are wood, stone, metal, textile goods, leather, furs, feathers, artificial flowers, human-hair goods, &c. a
- the application of the compound to the goods or articles to be treated may be by means of a brush or sponge; but I prefer in ordinary cases for all articles where it is practicable to immerse the goods to be treated in a bath but in either case the articles treated (if they be textile or other light and portable goods) will have all adhering moisture drained off from or pressed out of them, andthen gently dried in a closed room kept at a temperature of about Fahrenheit, and after the goods shall have been so dried the compound will be fixed into and upon the goods by heat, (preferably in the same room in which they were dried but durin g the fixing or curing process the temperature must be kept at about 180 Fahrenheit (more or less) by means of steam pipes or radiators.
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Detergent Compositions (AREA)
Description
, NITED STATES ATENT O FICE.
DANIEL M. LAMB, OF NEW YORK, N. Y.
COMPOUND FOR TREATING GOODS TO RENDER THEM WATER-REPELLENT SPECIFICATION forming part of Letters Patent No. 256,108, dated. April 4, 1882. Application filed December 29, 1880. Renewed March I, 1882. (No specimens.)
To all whom it may concern:
Be it known that I, DANIEL MARTAIN LAMB, of the city, county, and State of New York, have invented a new and useful Oompound for Treating Goods or other Articles to Render them Water-Repellent; and I hereby declare the following specification to be a full and clear description of the same.
This invention is an improvement on a similar invention granted to me in Patent No. 224,295, dated February 10, 1880.
The object of this invention is to prepare a compound adapted to be applied to various kinds and qualities of goods or other articles, for the purposeof rendering them impervious to moisture or repellent to water or moisture.
fabrics, from the heaviest goods to the most The articles intended to be treated by this compound embrace every variety of textile delicate-such as sails of vessels, carpets, tents, cordage rope, yarn, thread, clothing, &c., as well as feathers, flowers, furs, paper, wood, stone, or metal-and, in short, the compound is intended to be applied to any article Whatever the preservation of which from the humidity of the atmosphere or from amore complete saturation is a desirable object, and the compound used is such that it may be applied to the most delicate shades or tints of any textile goods, or ostrich-feathers, or any other feathers or fursthat claim the attention of the taxidermist,'or any beautiful specimens,
either in color or texture, that are intended to adorn the museum of the entomologist, and for all of these uses, or any others where moisture is to be excluded, the compound hereinafter more fully described isequally as well adapted as to the textile fabrics.
The-nature and constituents of this compound are such that no delicacy of shade or coloring will be injured by the treatment therewith, but, on the contrary, the colors to which the compound shall be applied will become and remain more fixed and unfailing, for the reason that the humidity of the atmosphere will be excluded from every pore and fiber of the article treated, and hence all incipient decay or fermentation will be prohibited, and consequent decomposition or fading will thereby be prevented. The materials used for this purpose are so compounded and manipulated and the elements of the compound are such that goods treated therewith will retain all their ordinary beauty and style of finish, remain as entirely pliable and soft as in the natural or untreated state, be as perfectly inodorous as before the treatment, and no injury whatever will result from the treatment. The materials used for this purpose, the manner of compounding them, and the process of treating the goods are as follows:
In the first place, I take solidified paraffiue and dissolve it in any of the lighter hydrocarbons-such as naphtha, benzine, benzole, gasoline, 850.; but I take only such hydrocarbons as are .72 Baume, (more or less,) using for this mixture, say, from one-quarter of an ounce to two ounces, (more or less,) or for ordinary cases, say, about one ounce of the paraffine to one gallon of the solvent; The proportions in which these ingredients are mixed will vary of course with the kind and quality of the goods to which the mixture is to be applied and the purpose for which the goods are to be employed.
The mixture may be made in any suitable quantities, and will preferably be compounded in such a vessel as is usuallyemployed as and called an agitator in coal-oil-retlnin g operations.
To facilitate the solution of the pa'raffine, it should be cut up into small pieces before it is put in the solvent, and the mixture should be allowed to stand until the paratfiue is fully desolved, and then the mixture or solution will be treated with a gas or gases in substantially the following manner: Itake about one pound (more or less) of common salt, or chloride of sodium, for each gallon of the solution above described, and put it directly into the solution, preferably distributing the salt pretty evenly over the bottom of the vessel containing the solution, and immediately thereafter I add to the mixture for each gallon thereof about one pound (more or less) of sulphuric acid, which will settle down directly upon the salt and decompose it, thereby setting free a gas or gases, which will rise up through the solution or com pound under treatment and attack the mucilaginous and sedimentary portions thereof, and precipitate them to the bottom of the vessel, the whole operation of the gaseous treatment IOO z I aselee upon the solution being to whiten or bleach it, as well as to remove all foreign substances or impurities, and also to effect a complete chemical change in the compound. The compound or solution will be allowed to remain standing quietly, subject to the gaseous treatmentabove described, for from three to ten days, (more or less,) and the sediment will be drawn off from the bottom of the vessel, or the purified compound from the top of the vessel. After the sedimentshall have been drawn off or removed from the purified solution, the remaining gas will be eliminated from the compound by any suitable means. This may be accomplished by allowing the mixture to stand a sufficient length of time to discharge the gas; or the mixture may be agitated by any suitable mechanical appliance; or it could best be done by a powerful current of air driven through 'the compound from the bottom to the top, using for this purpose some suitable air compressor.
or blower conveniently located with reference to the fabricating-vessel and connected therewith by means of suitable piping, so arranged within the fabricating-vessel as to deliver the air-currentat or near the bottom of the same, in order that the air-current may be driven up through the mass of the compound, so as to carry off any gases, impurities, or other foreign substances that may be held in suspension in the solution. This agitation will be continued for from five to thirty minutes, or until the gas is removed from the compound,along with all foreign substances or impurities that may be carried with it.
A process of treatment somewhat similar to that above described has been employed heretofore by me in the treatment of crude or distilled oils, such oils having been subject to the gaseous treatment, and afterward agitated with air; but the application of the gaseous treatment and air-agitation in the present instance is to a compound, as hereinbefore described, of an essentially different character to the oils to which I have heretofore applied it, and for which I obtained Letters Patent No. 183,401 in 1.876. After the air-agitation of the compound, as above described, a small quantity of caustic soda or ammonia, or both, or any other suitable alkaline, will be added to it, and the agitation continued, as hereinafter described, so as to remove any trace of gas or acid, and this washing or purifying is accompanied by water, and it must be accompanied by a mechanical agitation, so as to throw the alkaline solution up into and through the mass of the compound, so as to act upon the particles thereof.
As has been described, the gas for the purification and bleaching of the solution under treatment maybe generated within the mass of the compound under treatment, and it will be best to so generate it, and from the materials hereinbefore described, as by doing so a cheap and efficient gas may be produced and used in its nascent form, which will be most efficacious; but it will be equally within the scope of this invention to generate the gas within a contiguous vessel and condnetit into the fabricating-vessel by means of suitable piping, so arranged as to deliver the gas at or near the bottom of the solution, so that it may rise up through and permeate the entire mass under treatment. This form of applying the gas, however, would takemore timethan would the application of the nascent gas fabricated in the vessel in which thecompound was made. The gas or gases may also be generated from other chlorides and other acids than those mentioned above, or an efficient gas or gases may be generated by mixing the black oxide of manganese with the chloride of sodium and then causing the mixture to be acted upon by sulphuric acid, muriatie acid, or any other suitable acid, and all of these forms of generating the gas or gases and the elements for fabricating the same are clearly within the scope of this invention, as I find them to produce equivalent results; but I prefer the use of the chloride of sodium and sulphuric acid, and the application of the same, substantially as first hereinbefore described.
After the purification of the compound shall have been fully completed, as above described, the solution will be retained in a tightly-closed vessel, if it is desired to retain it in the form of a solution, and to do this, it left in the agitator or fabricating-vessel, a cover should be provided therefor, which said cover will set into a water-chamber, or arranged in any similar manner so as to tightly seal it and prevent the evaporation of the solvent, which is exceedingly volatile; but if it is desired to restore the solids contained in the solution to a solidified form, the compound should be placed in shallow tanks, and the vaporization of the solvent be accelerated by raising the temperature of the apartment in which it is placed to, say, 150 Fahrenheit. The usual manner, however, of storing the purified material will be in the solution, as it will be principally adapted to application to textile or other goods or materials for the purpose of rendering them water-' repellent or proof against oxidization in any form. The class of goods which may be so treated and preserved embraces an exceedingly wide range of subjects, among which are wood, stone, metal, textile goods, leather, furs, feathers, artificial flowers, human-hair goods, &c. a
The application of the compound to the goods or articles to be treated may be by means of a brush or sponge; but I prefer in ordinary cases for all articles where it is practicable to immerse the goods to be treated in a bath but in either case the articles treated (if they be textile or other light and portable goods) will have all adhering moisture drained off from or pressed out of them, andthen gently dried in a closed room kept at a temperature of about Fahrenheit, and after the goods shall have been so dried the compound will be fixed into and upon the goods by heat, (preferably in the same room in which they were dried but durin g the fixing or curing process the temperature must be kept at about 180 Fahrenheit (more or less) by means of steam pipes or radiators. I have discovered that gas generated as described (from common salt and sulphuric acid) under hydrocarbon oils and paraffine acts directly upon the oils and parafline, bleaching, deodorizing, and curing the oils and parafiine; and it also combines with the hydrogen ot' the oil and paraffine and forms solids to the amount of three-quarters of an ounce per galion, or more.
Having described my invention,l claim- 1. The process of preparing a waterproofing componnd,consisting in first dissolving parafline innaphtha or other light hydrocarbon solvent, then subjecting the solution so formed 7 for a period of from three to ten days to the action of a gas formed by the union of sulphuric acid and chloride of sodium, in the proportion of about one pound of each ingredient to each gallon of the solution, then subjecting the solution to a powerful agitation of a current of air, and then washing said solution with water and an alkaline solution, substantially as described.
2. A waterproofing solution formed by dissolving paraffine in any suitable light hydrocarbon solvent, then subjecting the solution so formed for a period of from three to ten days to the action of gas formed by the union of sulphuric acid and chloride of sodium in the proportions mentioned, and then subjecting the-solution to the action of air and a washing process, substantially as described.
3. As a new article of manufacture, a fabric having an invisible water-proof coating composed of the solution of paraftine treated as herein described, fixed thereto by heat, substantially asdescribed.
DANIEL M. LAMB.
Witnesses:
J. B. THURSTON, M. RANDOLPH.
Publications (1)
Publication Number | Publication Date |
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US256108A true US256108A (en) | 1882-04-04 |
Family
ID=2325397
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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US256108D Expired - Lifetime US256108A (en) | Daniel m |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2820719A (en) * | 1952-08-27 | 1958-01-21 | Davies Young Soap Company | Process for rendering fabrics water repellent |
-
0
- US US256108D patent/US256108A/en not_active Expired - Lifetime
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2820719A (en) * | 1952-08-27 | 1958-01-21 | Davies Young Soap Company | Process for rendering fabrics water repellent |
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