US25271A - Improvement in curing and treating caoutchouc - Google Patents
Improvement in curing and treating caoutchouc Download PDFInfo
- Publication number
- US25271A US25271A US25271DA US25271A US 25271 A US25271 A US 25271A US 25271D A US25271D A US 25271DA US 25271 A US25271 A US 25271A
- Authority
- US
- United States
- Prior art keywords
- curing
- caoutchouc
- treating
- rubber
- improvement
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 title description 9
- 229920001195 polyisoprene Polymers 0.000 title description 9
- 150000001875 compounds Chemical class 0.000 description 8
- 244000286663 Ficus elastica Species 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 229920001971 elastomer Polymers 0.000 description 4
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 3
- 239000004744 fabric Substances 0.000 description 3
- 229910000340 lead(II) sulfide Inorganic materials 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 239000005864 Sulphur Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Inorganic materials [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 1
- ZOMBKNNSYQHRCA-UHFFFAOYSA-J calcium sulfate hemihydrate Chemical compound O.[Ca+2].[Ca+2].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O ZOMBKNNSYQHRCA-UHFFFAOYSA-J 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000011507 gypsum plaster Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- KNXVOGGZOFOROK-UHFFFAOYSA-N trimagnesium;dioxido(oxo)silane;hydroxy-oxido-oxosilane Chemical compound [Mg+2].[Mg+2].[Mg+2].O[Si]([O-])=O.O[Si]([O-])=O.[O-][Si]([O-])=O.[O-][Si]([O-])=O KNXVOGGZOFOROK-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/34—Introducing sulfur atoms or sulfur-containing groups
Definitions
- my invention consists in the combination of sulphuret of lead and carbonate of lead with india-rubber or caoutchouc and submitting the compound thus formed to the action of heat.
- To two parts ofrubber I add one part of sulphuret of lead and one part of carbonate of lead, by weight, and mix or unite the compound by' passing the same through the heated rollers or grind ers now generally used in preparing and manufacturing india-rubber. After the mixture is thoroughly combined by grinding, it may be spread upon cloth, or rolled into sheets, or put into any other required form for use.
- the application of heat by means of steam or hot water may be made by any of the wellknown processes in the manufacture of india rubber, and must be made by such means, as the compound will not cure satisfactorily in dry air.
- French chalk or paris-white may be added to the compound for the purpose ofincreasing the bulk of the compound, and plaster-of-paris, for the purpose of'hardening it, may be added in small quantities.
- Other ingredients may also be added for the purpose of coloring the fabric or giving it peculiar properties, as is well known toindia-rubber manufacturers; but such articles have no effect in prcducing the result I have described.
Landscapes
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Description
UNITED STATES PATENT OFFICE.
E. E. MARGY, OF NEW YORK, N. Y.
IMPROVEMENT IN CURING AND TREATING CAOUTCHOUC.
Specification forming part of Letters Patent No. 25,271, dated August 30, 1859.
To all whom it may concern:
Be it known that I,E. E. MARCY, of the city of New York, have invented a new and Improved Method of Treating and Curing India- Rubber, which will cause it to retain permanent elasticity, and withstand changes of temperature, and emit no unpleasant odor; and I declare the following is a true description of the same.
The nature of my invention consists in the combination of sulphuret of lead and carbonate of lead with india-rubber or caoutchouc and submitting the compound thus formed to the action of heat. I combine these articles with india -rubber in the following proportions, which are the bestknown to me, although they may be varied with good results To two parts ofrubber I add one part of sulphuret of lead and one part of carbonate of lead, by weight, and mix or unite the compound by' passing the same through the heated rollers or grind ers now generally used in preparing and manufacturing india-rubber. After the mixture is thoroughly combined by grinding, it may be spread upon cloth, or rolled into sheets, or put into any other required form for use. It should then be subjected to the action of steam or water at a high temperature, by being placed in a vessel containing steam at a heat from 240 to 350 Fahrenheit, or containing water, or containing water and steam at the same high temperature. It may be necessary for thethorough curing ofsome articles to increase the temperature to 400 and upward butthe degree of temperature and the length of time that the compound must be submitted to the heat will depend, to a certain extent, upon the size and quality of the fabric, but the heat will in no case be carried so high as to liberate sulphur from the sulphuret of lead.
The application of heat by means of steam or hot water may be made by any of the wellknown processes in the manufacture of india rubber, and must be made by such means, as the compound will not cure satisfactorily in dry air.
French chalk or paris-white may be added to the compound for the purpose ofincreasing the bulk of the compound, and plaster-of-paris, for the purpose of'hardening it, may be added in small quantities. Other ingredients may also be added for the purpose of coloring the fabric or giving it peculiar properties, as is well known toindia-rubber manufacturers; but such articles have no effect in prcducing the result I have described.
I have sometimes dispensed with the ear-- bonate of lead, and used a quantity of sulphuret oflead nearly equal in weight to the rubber, and combined the same with about halt'the quantity ofprotoxide oflead orlitharge and chalk, with the addition of some of the above-named substances, for the purpose of giving body and color, with a good result.
I do not claim the curing ofindia-rubber as set forth in the patent of S. Moulton, August, 1847, (English), nor as set forth in the reissued patent of Charles Goodyear, June 15,1844, dated June, 1849; but
What I do claim as my invention, and desire to secure by Letters Patent, is-- The improved process of curing india-rubher by combining india-rubber with the sulphuret ot'lead and carbonate of lead, or the protoxide of lead, in the manner hereinbefore described, and without the use of free sulphur in combination with the rubber or with said compound, and the exposure of these compounds to steam or water at the temperature hereinbefore indicated, and in the mode point.- ed out.
E. E. MARGY,
In presence of- JAMES MARRINER, FREDERICK O. WAGNER.
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US25271A true US25271A (en) | 1859-08-30 |
Family
ID=2094010
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US25271D Expired - Lifetime US25271A (en) | Improvement in curing and treating caoutchouc |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US25271A (en) |
-
0
- US US25271D patent/US25271A/en not_active Expired - Lifetime
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