US2515025A - Process for pretreating vegetable materials - Google Patents
Process for pretreating vegetable materials Download PDFInfo
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- US2515025A US2515025A US674702A US67470246A US2515025A US 2515025 A US2515025 A US 2515025A US 674702 A US674702 A US 674702A US 67470246 A US67470246 A US 67470246A US 2515025 A US2515025 A US 2515025A
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- 238000000034 method Methods 0.000 title description 15
- 239000005418 vegetable material Substances 0.000 title description 4
- 239000000463 material Substances 0.000 description 16
- 235000013311 vegetables Nutrition 0.000 description 11
- 239000000203 mixture Substances 0.000 description 10
- 244000000626 Daucus carota Species 0.000 description 8
- 235000002767 Daucus carota Nutrition 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- 206010033546 Pallor Diseases 0.000 description 6
- 240000004713 Pisum sativum Species 0.000 description 6
- 235000010582 Pisum sativum Nutrition 0.000 description 6
- 238000001816 cooling Methods 0.000 description 6
- 238000001035 drying Methods 0.000 description 4
- 235000013399 edible fruits Nutrition 0.000 description 4
- 238000007710 freezing Methods 0.000 description 3
- 230000008014 freezing Effects 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 230000001105 regulatory effect Effects 0.000 description 3
- 230000001627 detrimental effect Effects 0.000 description 2
- 238000004321 preservation Methods 0.000 description 2
- 230000001954 sterilising effect Effects 0.000 description 2
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- 241000447437 Gerreidae Species 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- 238000007791 dehumidification Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 208000020442 loss of weight Diseases 0.000 description 1
- 235000008935 nutritious Nutrition 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
Images
Classifications
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23B—PRESERVING, e.g. BY CANNING, MEAT, FISH, EGGS, FRUIT, VEGETABLES, EDIBLE SEEDS; CHEMICAL RIPENING OF FRUIT OR VEGETABLES; THE PRESERVED, RIPENED, OR CANNED PRODUCTS
- A23B7/00—Preservation or chemical ripening of fruit or vegetables
- A23B7/06—Blanching
Definitions
- This invention relates to a process and an apparatus for pretreating vegetables, fruits and like materials.
- the invention has for its object to replace said blanching-process by a pre-treatment, whereby the disadvantages of the heating with hot water are avoided and yet the treatment can be carried out at a temperature of less than 100 C.
- the material to be treated is subjected in a closed or substantially closed room to the action of a hot humid airor gas stream circulating through the material and of normal pressure and of such a humidity that the temperature of the cooling limit of the air or gas (corresponding to the temperature of a wet body placed in said airor gas stream) lies above 65 C.
- the material under treatment is thereby treated to such an extent that the conversion aimed at with the usual blanching process is here also obtained.
- the temperature of the humid airor gas stream may be maintained at the required degree by conducting the stream through an airheater.
- air or gas or air from another source may be supplied.
- steam or vapour may be introduced into the airor gas stream.
- the humidity of the airor gas stream may be maintained at the desired degree by evaporating moisture exclusively or nearly exclusively from the material under treatment.
- the generated vapour is then taken up by the heated air so that the humidity of the air is gradually increased.
- the material therefore, will during this pretreatment lose a certain amount of its moisture but the drying action is not continued to such an extent that a dried product is obtained by said treatment.
- the temperature of the cooling limit that is the temperature of a Wet body placed in the air-stream
- Said temperature is approximately indicated by a wet thermometer placed in the air-stream and the indications of said thermometer substantially correspond to the temperature of the outer layer of the humid material under treatment.
- an aperture having an adjustable area may be provided at a convenient point in the air- Or gas stream, where the pressure is be low atmospheric pressure, so that a certain quantity of fresh air is sucked in through said aperture.
- Said control of the humidity of the air or gas may be effected manually or automatically.
- the area of said supplyaperture is controlled by a valve and in the airstream a wet thermometer may be placed which Fig. 3 shows a side elevation of the'apparatus according to Fig. 2.
- a tray 4 is introduced .filled with the material to be treated, e. g. with green stuff and subsequently the doors 5, 6 are closed.
- the pressure conduit in of the fan which'is connected to the upper end of the casing. I contains an airheater I l'. 1
- the mode of operation of said apparatus is as follows:
- the air circulating in the apparatus along the arrows is heated by the heater H and thereby obtains a relatively-large drying capacity so that it evaporates and takes up the water adhering to the vegetablesand eventually also the fruit-water'or cell-water.
- On account of the increasing humidity of the air also its cooling limittemperature will increase and accordingly also the temperature at the surface of the vegetables will increase. As more moisture is evaporated from the vegetables the temperature will increase until it reaches the desired level.
- Said temperature corresponds with non-hygroscopic material to the indication of the wet thermometer 9 situated in the suction conduit 8.
- the vegetables are supplied by the conveyor I2 and'delivered on an endless band l3 passing over rollers l4, l5, It, the roller l'5 of which is'driven.
- the band i 3 runs through a casing l! which contains two fans l8 each generating an air-stream directed transversally to the band according to the arrows indicated in Fig. 2 and passing along a heater H.
- the mixture of air and vapour is not heated above 150 C. in the heater in order to avoid detrimental influences on the material sensitive to strong heating such as vegetables and fruits.
- a quantity of fresh air is supplied through the aperture 20 which may be more or less closed by an adjustable valve [9.
- Example I- Scraped, washed and sliced carrots are spread in such a quantity in a loose layer on a grid which is permeable to air, that each square metre of the grid surface contains 20 kilogrammes sliced car-rots.
- Said layer of carrots is sub- J'e'ctedin' an apparatus according to Fig. l to the actionof' a mixture of steam and air circulating through the layer.
- the steam and air mixture is heated by the heater H and the temperature of the mixture when entering the layer of vegetables is 125 C, whereas the mixture contains0'.953'kilogramme steam for each kilogramme ofdry air, so that the temperature of the cooling'limit of the mixture is C.
- Example II For pre-treating peas which. are .to be preserved by freezing they are supplied to an apparatus according to Figures 2 and3 by the conveyor l2 in such a manner that on every square metre of the conveyor band [3 seven kilogrammes of peas are uniformly distributed.
- the band I3 has such a velocity that the peas stay in the treatment room I! forGOseconds.
- the steam and air mixture entering the layer of peas has a temperature of 95 C. and the humidity of said mixture hasv sucha value, thatthe temperatureof the coolinglimit of the mixture is 90 C.
- For maintaining said degree of humidity steam is'introducedinto the room I! and air is supplied therein by means of valve IS.
- the airheater For maintaining said degree of humidity steam, is'introducedinto the room I! and air is supplied therein by means of valve IS. The airheater.
- a .method of blanching humid vegetable materials prior to. their preservation comprising continuously circulating through the said materrials a closed humid air stream at anormal pressurewhichair stream has been heated to. eiTect its dehumidification, humidifying the said, air stream by the moisture evaporated, from the materials. under treatment. and controlling the heating and the humidification of'sa-idcontinu- 5 6 ous air stream to maintain its wet bulb tempera- Number Name Date ture at a, range between above 65 and below 1,259,637 King Mar. 19, 1918 100 C. 1,346,986 Stamm July 20, 1920 LASZLQ vA- 1,685,511 Thomas Sept. 25, 1928 I L 5 1,947,115 Skinner Feb.
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Food Science & Technology (AREA)
- Polymers & Plastics (AREA)
- Apparatuses For Bulk Treatment Of Fruits And Vegetables And Apparatuses For Preparing Feeds (AREA)
- Drying Of Solid Materials (AREA)
- Storage Of Fruits Or Vegetables (AREA)
Description
July 11, 1950 VAHL ET AL PROCESS FOR PRETREATING VEGETABLE MATERIALS Filed June 6, 3.946
Patented July 11, i950 UNITED STATES PATENT OFFICE PROCESS FOR PRETREATING VEGETABLE MATERIALS the Netherlands Application June 6, 1946, Serial No. 674,702 In the Netherlands May 30, 1941 Section 1, Public Law 690, August 8, 1946 .Patent expires May 30, 1961 1 Claim.
This invention relates to a process and an apparatus for pretreating vegetables, fruits and like materials.
When preserving vegetables, certain kinds of fruits, tubers etc. it is usual or advantageous to heat them to a definite temperature and to maintain said temperature during a certain time in order to destroy enzymes before the proper preservation takes place which may be obtained by freezing, sterilising or drying the material. Said preliminary treatment is known as blanching in preserving processes for vegetables, tubers and fruits by freezing or drying them and in sterilizing processes for vegetables etc. in tins.
Hitherto said blanching process was generally carried out by immerging the material in hot water. Said method, however, has the drawback that valuable constituents, such as nutritious matter, vitamines and colouring matter, are lixiviated.
It has also been proposed to blanch the material by means of steam. The blanching process is then usually carried out at atmospheric pressure so that the temperature of the steam is 100 C. Said temperature, however, has still a detrimental influence on many products so that they are deteriorated in quality by said treatment. If it is desired to lower the temperature of the treatment it is required to also decrease thepressure of the steam and to carry out the process in vacuo. Such a process, however, has the drawback that it requires an expensive installation as besides a steam boiler also a condenser is needed. Moreover the process cannot be carried out continuously as the treatment-room should be sealed 1 against the air.
The invention has for its object to replace said blanching-process by a pre-treatment, whereby the disadvantages of the heating with hot water are avoided and yet the treatment can be carried out at a temperature of less than 100 C.
According to the invention the material to be treated is subjected in a closed or substantially closed room to the action of a hot humid airor gas stream circulating through the material and of normal pressure and of such a humidity that the temperature of the cooling limit of the air or gas (corresponding to the temperature of a wet body placed in said airor gas stream) lies above 65 C. The material under treatment is thereby treated to such an extent that the conversion aimed at with the usual blanching process is here also obtained.
The temperature of the humid airor gas stream may be maintained at the required degree by conducting the stream through an airheater. For regulating the humidity of the airor gas stream atmospheric air or gas or air from another source may be supplied. Also steam or vapour may be introduced into the airor gas stream.
Experiments have shown that the humidity of the airor gas stream may be maintained at the desired degree by evaporating moisture exclusively or nearly exclusively from the material under treatment. During the treatment the generated vapour is then taken up by the heated air so that the humidity of the air is gradually increased. The material, therefore, will during this pretreatment lose a certain amount of its moisture but the drying action is not continued to such an extent that a dried product is obtained by said treatment. With the increase Of the humidity of the air also the temperature of the cooling limit (that is the temperature of a Wet body placed in the air-stream) of the air-stream is increased. Said temperature is approximately indicated by a wet thermometer placed in the air-stream and the indications of said thermometer substantially correspond to the temperature of the outer layer of the humid material under treatment. Hereby a simple control and regulation of the temperature of the treatment is obtained by regulating the temperature of the cooling limit of the airor gas stream in accordance with the indications of a wet thermometer or like body placed in said stream.
To this end an aperture having an adjustable area may be provided at a convenient point in the air- Or gas stream, where the pressure is be low atmospheric pressure, so that a certain quantity of fresh air is sucked in through said aperture. Said control of the humidity of the air or gas may be effected manually or automatically. In said latter instance the area of said supplyaperture is controlled by a valve and in the airstream a wet thermometer may be placed which Fig. 3 shows a side elevation of the'apparatus according to Fig. 2.
Into the casing I (Fig. 1) whichatthe entrance and the outlet side is provided withasluice 2 and 3 respectively, a tray 4 is introduced .filled with the material to be treated, e. g. with green stuff and subsequently the doors 5, 6 are closed. With the casing l a fan I is connected, the suction conduit 8 of which comprises a wet thermometer 9. The pressure conduit in of the fan which'is connected to the upper end of the casing. I contains an airheater I l'. 1
The mode of operation of said apparatus is as follows: The air circulating in the apparatus along the arrows is heated by the heater H and thereby obtains a relatively-large drying capacity so that it evaporates and takes up the water adhering to the vegetablesand eventually also the fruit-water'or cell-water. On account of the increasing humidity of the air also its cooling limittemperature will increase and accordingly also the temperature at the surface of the vegetables will increase. As more moisture is evaporated from the vegetables the temperature will increase until it reaches the desired level. Said temperature corresponds with non-hygroscopic material to the indication of the wet thermometer 9 situated in the suction conduit 8. When the vegetables have been subjected to said temperature for the required lapse of time, the tray 4 is removed by opening the door 6 and a next tray is introduced into the apparatus through the door 5.
In the apparatus shown in Figures 2 and 3 the vegetables are supplied by the conveyor I2 and'delivered on an endless band l3 passing over rollers l4, l5, It, the roller l'5 of which is'driven. The band i 3 runs through a casing l! which contains two fans l8 each generating an air-stream directed transversally to the band according to the arrows indicated in Fig. 2 and passing along a heater H. The mixture of air and vapour is not heated above 150 C. in the heater in order to avoid detrimental influences on the material sensitive to strong heating such as vegetables and fruits. For regulating the humidity of the air and thus the temperature of the treatment a quantity of fresh air is supplied through the aperture 20 which may be more or less closed by an adjustable valve [9.
The loose run of the conveyor band [3 is dragged through a receptacle 2i filledwith'water in order to keep the band clean.
At the entrance opening 22 of the "casing underneath the band 13 where the pressure 'is below atmospheric pressure air from the outside can enter the casing. In order to prevent said leakage of air the space at the underside of the band I3 is at the entranceopening'22 and at the outlet opening 24 by means of conduit 23 connected to a part of the treatment-room where the pressure is above atmospheric, The air flowing through conduit" 23 for the greater 4 part will then again be sucked into the casing so that only a small quantity of air is lost. Above the band 13 the pressure in the casing l1 exceeds the atmospheric pressure a little so that here the entrance opening and the outlet opening may be mainly sealed. by the vegetables themselves.
Example I- Scraped, washed and sliced carrots are spread in such a quantity in a loose layer on a grid which is permeable to air, that each square metre of the grid surface contains 20 kilogrammes sliced car-rots. Said layer of carrots is sub- J'e'ctedin' an apparatus according to Fig. l to the actionof' a mixture of steam and air circulating through the layer. The steam and air mixture is heated by the heater H and the temperature of the mixture when entering the layer of vegetables is 125 C, whereas the mixture contains0'.953'kilogramme steam for each kilogramme ofdry air, so that the temperature of the cooling'limit of the mixture is C. After a period of action of 3 minutes and 20 seconds the mass of'carrots has been heated to 86 C. The sliced material does not obtain a higher temperature as itssurface isstill humid. From the -massof greenstuii lfikilogrammes. of moisture are. then withdrawn for every 100 kilogrammesof material, so thatper 100 kilogrammes of carrots under treatmentat mostdfikilogrammes, of air together with the vapours generated from the. carrots should be withdrawn. from the treatment-room and an equivalent quantityof air, should be supplied to said room. For maintaining the required degree: of humidity of the. air exclusivelythe moisture evaporated from the carrots iscemployed. The so pre-treated carrots are suitable fort-being dried .in a drier.
. Example II For pre-treating peas which. are .to be preserved by freezing they are supplied to an apparatus according to Figures 2 and3 by the conveyor l2 in such a manner that on every square metre of the conveyor band [3 seven kilogrammes of peas are uniformly distributed. The band I3 has such a velocity that the peas stay in the treatment room I! forGOseconds. The steam and air mixture entering the layer of peas has a temperature of 95 C. and the humidity of said mixture hasv sucha value, thatthe temperatureof the coolinglimit of the mixture is 90 C. For maintaining said degree of humidity steam, is'introducedinto the room I! and air is supplied therein by means of valve IS. The airheater. ll only supplies such a quantity of heat as isrequired for maintaining the temperature of C. .for the steam and air mixture at the desired cooling limit temperature of 90". C. There is practically no loss of weight to, the peas;. the surfaces of. the treated peas, however, feel .dry as the superficial water (Wash-Water) has been evaporated.
What we claim. is:
A .method of blanching humid vegetable materials prior to. their preservation comprising continuously circulating through the said materrials a closed humid air stream at anormal pressurewhichair stream has been heated to. eiTect its dehumidification, humidifying the said, air stream by the moisture evaporated, from the materials. under treatment. and controlling the heating and the humidification of'sa-idcontinu- 5 6 ous air stream to maintain its wet bulb tempera- Number Name Date ture at a, range between above 65 and below 1,259,637 King Mar. 19, 1918 100 C. 1,346,986 Stamm July 20, 1920 LASZLQ vA- 1,685,511 Thomas Sept. 25, 1928 I L 5 1,947,115 Skinner Feb. 13, 1934 ANDRES JANSEN' 1,982,944 Anderson Dec. 4, 1934 REFERENCES CITED 2,097,198 Lesley et a1 Oct. 26, 1937 The following references are of record in the 2312339 Jones 1943 file of this patent: 1o FOREIGN PATENTS UNITED STATES PATENTS Number Country Date 339,859 Italy Apr. 29, 1936 Number Name Date 648,248 Edwards Apr. 24, 1900
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
NL2515025X | 1941-05-30 |
Publications (1)
Publication Number | Publication Date |
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US2515025A true US2515025A (en) | 1950-07-11 |
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US674702A Expired - Lifetime US2515025A (en) | 1941-05-30 | 1946-06-06 | Process for pretreating vegetable materials |
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Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2581484A (en) * | 1946-08-24 | 1952-01-08 | Helgerud Oyvind | Process in pretreating vegetables and fruits before freezing |
US2910392A (en) * | 1953-08-17 | 1959-10-27 | California Packing Corp | Method of removing the skin of fruit and vegetable articles |
US2910393A (en) * | 1953-11-30 | 1959-10-27 | California Packing Corp | Process for loosening the skins of fruits and vegetables |
US2936012A (en) * | 1953-11-30 | 1960-05-10 | California Packing Corp | Apparatus for loosening the skins of fruits and vegetables |
US2985210A (en) * | 1958-01-20 | 1961-05-23 | Genevieve I Magnuson | Treating apparatus for fruit and vegetable articles |
US2997085A (en) * | 1953-08-17 | 1961-08-22 | California Packing Corp | Peeling machine for fruit and vegetables |
US4670275A (en) * | 1984-09-13 | 1987-06-02 | Dna Plant Technology Corporation | Prolonging the shelf life of fresh root vegetables |
US4808420A (en) * | 1984-09-13 | 1989-02-28 | Dna Plant Technology Corporation | Fresh root vegetables with prolonged shelf life |
US4855153A (en) * | 1984-09-13 | 1989-08-08 | Dna Plant Technology Corporation | Prolonging the shelf life of fresh root vegetables |
WO2010091803A2 (en) | 2009-02-13 | 2010-08-19 | Bayer Cropscience Ag | Use of succinate dehydrogenase inhibitors for extending shelf life of fruits and vegetables |
WO2012022706A1 (en) | 2010-08-17 | 2012-02-23 | Bayer Cropscience Ag | Use of n-phenylethylpyrazole carboxamide derivatives or salts thereof for extending shelf life of fruits and vegetables |
Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US648248A (en) * | 1899-12-18 | 1900-04-24 | George H Edwards | Apparatus for treating sweet potatoes. |
US1259637A (en) * | 1917-06-29 | 1918-03-19 | Pacific Evaporator Company | Evaporated fruits. |
US1346986A (en) * | 1915-11-29 | 1920-07-20 | Fred Stebler | Apparatus for drying fruit |
US1685511A (en) * | 1927-09-27 | 1928-09-25 | William E Thomas | Process for preparing spinach and the like for canning |
US1947115A (en) * | 1929-12-24 | 1934-02-13 | Brogdex Co | Treatment of insect-infested fruit in preparation for market |
US1982944A (en) * | 1931-11-02 | 1934-12-04 | Fmc Corp | Method for preparing spinach for canning |
US2097198A (en) * | 1934-02-09 | 1937-10-26 | California Packing Corp | Process of preparing spinach or the like for canning |
US2312339A (en) * | 1938-12-23 | 1943-03-02 | Carrier Corp | Smokehouse apparatus |
-
1946
- 1946-06-06 US US674702A patent/US2515025A/en not_active Expired - Lifetime
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US648248A (en) * | 1899-12-18 | 1900-04-24 | George H Edwards | Apparatus for treating sweet potatoes. |
US1346986A (en) * | 1915-11-29 | 1920-07-20 | Fred Stebler | Apparatus for drying fruit |
US1259637A (en) * | 1917-06-29 | 1918-03-19 | Pacific Evaporator Company | Evaporated fruits. |
US1685511A (en) * | 1927-09-27 | 1928-09-25 | William E Thomas | Process for preparing spinach and the like for canning |
US1947115A (en) * | 1929-12-24 | 1934-02-13 | Brogdex Co | Treatment of insect-infested fruit in preparation for market |
US1982944A (en) * | 1931-11-02 | 1934-12-04 | Fmc Corp | Method for preparing spinach for canning |
US2097198A (en) * | 1934-02-09 | 1937-10-26 | California Packing Corp | Process of preparing spinach or the like for canning |
US2312339A (en) * | 1938-12-23 | 1943-03-02 | Carrier Corp | Smokehouse apparatus |
Cited By (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2581484A (en) * | 1946-08-24 | 1952-01-08 | Helgerud Oyvind | Process in pretreating vegetables and fruits before freezing |
US2910392A (en) * | 1953-08-17 | 1959-10-27 | California Packing Corp | Method of removing the skin of fruit and vegetable articles |
US2997085A (en) * | 1953-08-17 | 1961-08-22 | California Packing Corp | Peeling machine for fruit and vegetables |
US2910393A (en) * | 1953-11-30 | 1959-10-27 | California Packing Corp | Process for loosening the skins of fruits and vegetables |
US2936012A (en) * | 1953-11-30 | 1960-05-10 | California Packing Corp | Apparatus for loosening the skins of fruits and vegetables |
US2985210A (en) * | 1958-01-20 | 1961-05-23 | Genevieve I Magnuson | Treating apparatus for fruit and vegetable articles |
US4670275A (en) * | 1984-09-13 | 1987-06-02 | Dna Plant Technology Corporation | Prolonging the shelf life of fresh root vegetables |
US4808420A (en) * | 1984-09-13 | 1989-02-28 | Dna Plant Technology Corporation | Fresh root vegetables with prolonged shelf life |
US4855153A (en) * | 1984-09-13 | 1989-08-08 | Dna Plant Technology Corporation | Prolonging the shelf life of fresh root vegetables |
WO2010091803A2 (en) | 2009-02-13 | 2010-08-19 | Bayer Cropscience Ag | Use of succinate dehydrogenase inhibitors for extending shelf life of fruits and vegetables |
US10548315B2 (en) | 2009-02-13 | 2020-02-04 | Bayer Intellectual Property Gmbh | Use of succinate dehydrogenase inhibitors for extending shelf life of fruits and vegetables |
US11241010B2 (en) | 2009-02-13 | 2022-02-08 | Bayer Intellectual Property Gmbh | Use of succinate dehydrogenase inhibitors for extending shelf life of fruits and vegetables |
WO2012022706A1 (en) | 2010-08-17 | 2012-02-23 | Bayer Cropscience Ag | Use of n-phenylethylpyrazole carboxamide derivatives or salts thereof for extending shelf life of fruits and vegetables |
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