US2488488A - Method and apparatus for conversion of fluid hydrocarbons - Google Patents
Method and apparatus for conversion of fluid hydrocarbons Download PDFInfo
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- US2488488A US2488488A US685835A US68583546A US2488488A US 2488488 A US2488488 A US 2488488A US 685835 A US685835 A US 685835A US 68583546 A US68583546 A US 68583546A US 2488488 A US2488488 A US 2488488A
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/08—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with moving particles
- B01J8/12—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with moving particles moved by gravity in a downward flow
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- This invention has to do with a method and apparatus for conversion of high boiling liquid hydrocarbons or mixed phase hydrocarbons to lower boiling hydrocarbons in the presence of a moving particle-form contact mass material which may or may not exhibit catalytic properties with respect to the conversion reaction.
- Typical of such processes is the catalytic conversion of heated liquid hydrocarbons to lower boiling gasoline containing gaseous products by the contacting of a high boiling liquid charge at temperatures of the order of 850 F.'and upwards with a particle-form adsorbent catalytic material.
- Other exemplary processes are the thermal visbreaking, coking or cracking of liquid or mixed phase hydrocarbon charge by contact with heated particle-form inert contact materials.
- a major object of this invention is the provision in a process for conversion of high-boiling fluid hydrocarbons in the presence of a column of moving contact material particles of method and apparatus for supplying of contact material and fluid hydrocarbons onto the contact material col umn within the conversion zone which method and apparatus overcome the above described difficulties.
- Another object is the provision of a practical process for the simultaneous catalytic conversion of gaseous and liquid hydrocarbons in the presence of a moving mass of particle-form catalyst.
- Another object is the provision in-a continuous cyclic process for conversion of high boiling liquid or mixed phase hydrocarbons of an improved method and apparatus for hydrocarbon and contact material introduction into the conversion zone.
- gaseous as used herein, is intended to refer to a material existing in the gaseous phase under the particular operating conditions of pressure and temperature involved regardless of what may be the normal phase of that material under ordinary atmospheric conditions.
- contact material is employed herein in a broad sense as covering solid particles which are suitable as a contacting or heat carrying agent for the particular conversion involved regardless of whether such solid particles exhibit a catalytic effect towards the conversion or not.
- a substantially vertical conversion vessel II which may be of circular or of any other suitable cross-sectional shape.
- a mixing chamber ll having a jacket I2 around its walls.
- An inlet conduit I3 is connected into the jacket for cooling fluid introduction to the jacketed space.
- An outlet conduit i4 is provided for fluid withdrawal from the jacketed space.
- a seal chamber I5 is positioned at a level above the mixing chamber II.
- a conduit 5 extends downwardly from the seal chamber to a location within the mixing chamber below the upper end but above its lower end for flow of contact material from the seal chamber onto the bed of contact material I!
- a ring type manifold I8 provided with downwardly depending spray nozzles I9 is positioned within chamber I i above the surface level of bed ll. Liquid hydrocarbons may be introduced to this spray device through conduit 20 connecting into manifold IS.
- a plurality of conduits 2! having branches 22 at their lower ends extend downwardly from the bottom of cham- 3 ber II for flow of contact material into the upper section of conversion vessel It).
- the branch pipes 22 all terminate at a common level below the upper end of vessel l and are spaced to deliver contact material uniformly over the entire crosssectional area of vessel Ill.
- An outlet 24 for withdrawal of gaseous material connects into the lower section of vessel III.
- This outlet may communicatewith suitable gas collecting devices (not shown) such as inverted troughs positioned within the lower section of vessel In.
- suitable gas collecting devices such as inverted troughs positioned within the lower section of vessel In.
- An inlet 25 for purge gas introduction connected into vessel [0 below the level of conduit 24.
- a solid drain conduit bearing flow control valve 21 is provided at the lower end of vessel I0.
- Suitable baflies may be provided within the lower section of vessel Ill to insure withdrawal of contact material uniformly from all portions of the vessel horizontal cross-sectional area.
- heated contact material existing at a temperature suitable for supporting the desired hydrocarbon conversion is supplied from hopper 28 through elongated gravity feed leg 29 into seal chamber I5.
- the contact material passes as a substantially compact column downwardly from seal chamber l5 through conduit l6 onto the surface of the contact material bed I! within mixing chamber H.
- the zone 40 in chamber I l represents a zone wherein the contact material flow is very low or nil.
- a conical baffle may be provided in this zone if desired.
- Heated high boiling liquid hydrocarbons are introduced through conduit 20 to manifold l8 and spray nozzles l9 from which it is sprayed onto the surface of the bed ll so as to become mixed with the contact material in chamber II.
- the dimensions of chamber H and the level of the lower end of conduit IS in chamber II should be such that the depth of the flowing stream of contact material at its shallowest point in chamber II, which in the arrangement shown is just adjacent the end of conduit I6, is of the order of A to inches while the depth of the flowing contact material stream at its deepest point is of the order of 3 to 5 inches.
- the oil charge should be sprayed onto the contact material where its depth of stream is least.
- the mixed liquid and contact material pass as a plurality of compact streams downwardly from chamber ll onto the column of contact material 30 within the vessel l0.
- the contact material and liquid hydrocarbons pass downwardly within the column 30, so that the liquid hydrocarbons are converted ,to lower boiling gaseous hydrocarbon products.
- the particle-form catalyst bearing a carbonaceous contaminant may be subjected un- 4 der controlled elevated temperature to contact with air to burn ofi the contaminant.
- the hot regenerated catalyst is then supplied to hopper 28 through conduit 35.
- Gaseous hydrocarbons may be purged from the used contact material in the lower section of vessel II) by the introduction of an inert purging gas such as steam or.
- the entering contact material should exist at a temperature sufliciently high to provide the heat for the desired hydrocarbon conversion without the contact material temperature in vessel l0 falling below a level suitable for rapid hydrocarbon conversion.
- the catalyst may enter chamber II at temperatures of the order of 950-1150 F. These temperature levels are sufilciently high to cause rapid cracking conversion of the high boiling liquid hydrocarbon charge. During suchcracking conversion a substantial amount of coke may be formed. This coke, if deposited on the catalyst may be easily withdrawn from the conversion system and removed by burning. If,
- the cooling medium may take the form of a gas such as steam or it may preferably take the form of a liquid such as hot water under pressure or certain low melting point mixtures of fused inorganic salts or certain low melting metal alloys.
- the rate of flow and temperature of the cooling medium should be controlled such as to control the temperature of the walls of chamber ll, particularly at points above the level of bed I! below a level which would promote the substantial deposition of coke on the walls if they are contacted by the high boiling liquid hydrocarbon charge.
- the wall temperature should be controlled below about 750 F. and preferably within the range about 500-600 F.
- liquid hydrocarbon charge may be uniformly deposited on the contact material delivering onto the surface of column 30 in the conversion vessel, vaporized hydrocarbon charge may be introduced through conduit 36 above the level of column 30 and then passed downwardly through column 30 without any gas channeling difliculties arising.
- both liquid and gaseous hydrocarbon charges may be simultaneously con- Verted to lower boiling gaseous hydrocarbons in the system described hereinabove.
- the conversion may be a strictly high temperature thermal conversion in the presence of a heat carryingparticle-form inert material or it may be a catalytic cracking conversion.
- the operating conditions will, of course, vary widely depending upon the particular process and materials involved.
- a particle-form catalyst which may be of clay-type is introduced into the conversion chamber at a temperature within the range of about 900-1200" F. depending upon the desired conversion temperature, the clay to oil ratio and the particular hydrocarbon charge involved and the desired products.
- a liquid hydrocarbon charge which may consist principally of hydrocarbons boiling above the desired coverage conversion temperature is introduced through pipe 20.
- Such a charge may consist of a reduced crude which has been preferably preheated to a temperature of the order of 600-800 F.
- a gas oil fraction which may have been obtained from the same stock as the reduced crude, may be vaporized and heated to a temperature of the order of 800-950 F. in a conventional heater and introduced into the upper section of the convertor l through conduit 36.
- Gaseous products containing high yields of gasoline may be withdrawn from the conversion chamber through conduit 20.
- the pressure in the conversion chamber may be quite low, usually of the order of to 30 pounds per square inch gauge.
- the total oil space velocity may be within the range of about 0.5 to.
- a method for conversion of high boiling liquid hydrocarbons in the presence of a moving particle-form contact material which comprises:
- the r maintaining an accumulation of particle-form carbon charge onto said bed of contact material in said mixing zone, passing contact material and the liquid hydrocarbon charge mixed therewith as a plurality of substantially compact streams downwardly from said bed to a plurality of distributed locations on the surface of a'column of said contact material maintained in a confined conversion zone therebelow, withdrawing used contact material from the lower section of said column at a controlled rate and withdrawing gaseous hydrocarbon conversion products from the lower section of said conversion zone substantially separately of said contact material.
- a method for conversion of high boiling fluid hydrocarbons in the present of a moving particleformncontact material which comprises:. maintaining an accumulation of particle-form contact material in a confined seal zone, introducing a substantially inert gas into said zoneto maintain an inert gaseous atmosphere therein, supplying particle-form contact material at a suitable temperature for supporting conversion of said liquid hydrocarbons into said seal zone, passing contact material as a substantially compact, continuous stream downwardly from said seal zone onto the surface of a bed of said contact material maintained therebelow in a confined mixing zone, spraying a high boiling liquid hydrocarbon charge onto said bed of contact material in said mixing zone, passing contact material and the liquid hydrocarbon charge mixed therewith as a plurality of substantially compact streams downwardly from said bed to a plurality of distributed locations on the surface of a column of said contact material maintained in a confined conversion zone therebelow, introducing a heated gaseous hydrocarbon charge into the upper section of said conversion zone, passing said liquid and gaseous hydrocarbons downwardly within said column to efiect
- a method for conversion of high boiling fluid hydrocarbons in the presence of a particle-form contact material which comprises: maintaining a substantially compact column of particle-form contact material within a confined conversion zone, maintaining a separately confined bed of said contact material above said conversion zone, substantially continuously supplying contact material to said bed at a suitable hydrocarbon conversion supporting temperature, supplying a heated high boiling liquid hydrocarbon charge onto the surface of said bed, to become mixed with said contact material, passing mixed liquid hydrocarbons and contact material downwardly from said bed as a plurality of confined streams discharging at a plurality of points on the surface of said column in said conversion zone, said points being uniformly distributed across the horizontal cross section of said column, introducing a vaporized hydrocarbon charge into the upper section of said conversion zone above the surface of said column, passing the contact material and liquid and gaseous hydrocarbons downwardly within said column to effect conversion of said hydrocarbons to lower boiling gaseous hydrocarbon products, withdrawing used contact material from the lower section of said column at a controlled rate and withdrawing gaseous hydrocarbon conversion products from
- a method for conversion of high boiling liquid hydrocarbons to lower boiling gaseous hydrocarbons in the presence of a moving particle-form contact material comprises: maintaining a substantially compact column of particle-form contact material within a confined conversion zone, maintaining a separately confined bed of said contact material above said conversion zone, substantially continuously supplying contact material to said bed at a suitable hydrocarbon conversion supporting temperature,
- a method for conversion of high boilingv fluid hydrocarbons to lower boiling hydrocarbon products in the presence of a moving particle form contact material comprises: maintaining an accumulation of particle-form contact material in a confined seal zone, introducing a substantially inert gas into said zone to maintain an inert gaseous atmosphere therein, supplying particle-form contact material at a suitable temperature for supporting conversion of said liquid hydrocarbons into said seal zone, passing contact material as a substantially compact, continuous stream downwardly from said seal zone onto the surface of a bed of said contact material maintained therebelow in a confined mixing zone, spraying a high boiling liquid hydrocarbon charge onto said bed Of contact material in said mixing zone, passing a fluid cooling medium in contact with the walls of said seal zone to cool said walls below a temperature which will support substantial coking of said liquid hydrocarbon charge, passing said contact material and said liquid hydrocarbon charge mixed therewith as a substantially compact, confined stream downwardly from said bed onto the surface of a substantially compact column of said contact material maintained in a confined elongated conversion zone therebel-ow
- conduit means for contact material flow connected between said seal chamber and said mixing chamber, said conduit means terminating below the upper end of said mixing chamber but'substantially above the bottom thereof, a spray device positioned within the upper section of said mixing chamber and adapted to spray liquid hydrocarbons downwardly within said chamber, means to supply a high boiling liquid hydrocarbon charge to said spray device, a plurality of conduits extending downwardly from said mixing chamber for fiow of contact material into said conversion chamber, said conduits terminating on their lower ends at a plurality of uniformly, horizontally spaced locations within said conversion chamber, means to withdraw contact material fromthe lower section of said conversion chamber at a controlled rate, and a separate outlet for withdrawal of gaseous material from the lower section of said conversion chamber.
- An apparatus for conversion of high boiling fluid hydrocarbons to lower boiling hydrocarbons which comprises in combinationz'an elongated conversion chamber, a seal chamber adapted to confine a bed of contact material positioned at a level above said conversion chamber, a conduit for inert seal gas supply connecting into said seal chamber, means to supply particle form contact material into said seal chamber, a mixing chamber positioned at a level between said seal chamber and said conversion chamber, a conduit for solid flow extending down from the bottom of said seal chamber to a level within and intermediate the upper and lower ends of said mixing chamber, a spray device positioned within the upper section of said mixing chamber with spray openings pointed downward, a conduit connected to said spray device for supply of liquid hydrocarbon charge, at least one conduit for solid flow extending downwardly from said mixing chamber into the upper section of said conversion chamber, said conduit terminating on its lower end at a level within the upper section of the conversion chamber spaced below its upper end, a conduit for gaseous hydrocarbon introduction connecting into said conversion chamber above the level of the lower end of said last named conduit
- An apparatus for conversion of high boiling fluid hydrocarbons to lower boiling hydrocarbons which comprises in combination an elongated conversion chamber adapted to confine an upright column of particle-form contact material, a closed seal chamber positioned at a level above said conversion chamber, an elongated conduit extending vertically upward from said seal chamber for gravity.
- a conduit for supply of an inert seal gas connected to said seal chamber, a closed mixing chamber positioned between said seal chamber and said conversion chamber, a conduit for solid flow extending from th bottom of said seal chamber into said mixing chamber and terminating on its lower end below the upper end of said mixing chamber but substantially above the bottom thereof, a spray device positioned within the upper section of said mixing chamber with spray openings pointed downwardly, a conduit connected to said spray device for supply of a high boiling liquid hydrocarbon charge, a jacket defining a jacketed space around at least the upwardly extending walls of said mixing chamber, conduit means for supply of a cooling fluid to said jacketed space and conduit means for withdrawal of cooling fluid therefrom, at least one conduit for solid flow extending downwardly from said mixing chamber into the upper section of said conversion chamber, said conduit terminating on its lower end at a level within the upper section of the conversion chamber spaced below its upper end, a conduit for gaseous hydrocarbon introduction connecting into said conversion chamber above the level of the lower end of said last named
- An apparatus for conversion of high boiling liquid hydrocarbons to lower boiling hydrocarbons in the presence of a moving particle-form contact material which comprises in combination: a substantially vertical, elongated conversion vessel closed on either end, a mixing chamber above said conversion vessel, adapted to confine a bed of contact material, a jacket defining a closed jacketed space around the vertical walls of said mixing chamber, a conduit associated with said jacket for cooling fluid introduction to said jacketed space and conduit means for fluid withdrawal therefrom, a contact material supply conduit extending upwardly through the top of said mixing chamber from an intermediate level therein, a spray device in the upper section of said mixing chamber adapted to spray liquid downwardly within said chamber, conduit means for supply of liquid hydrocarbons to said spray device, a plurality of conduits extending downwardly from said.
- mixing chamber for flow of contact material into said conversion cham her, said conduits terminating on their lower ends at a plurality of uniformly, horizontally spaced locations within said conversion chamber, means to withdraw contact material from the lower section of said conversion chamber at a controlled rate, and means to separately withdraw gaseous material from the lower section of said conversion chamber.
- a method for conversion of high boiling liquid hydrocarbons to lower boiling gaseous hydrocarbons in the presence of a moving particleform contact material which method comprises: maintaining a substantially compact column of particle-form contact material within a confined conversion zone, maintaining a separately confined bed of said contact material in a second confined zone, supplying heated contact material to said bed at a temperature sufficiently high to supply the heat required for said hydrocarbon conversion, supplying a high boiling liquid hydrocarbon charge onto the surface of said bed to become mixed with said contact material, passing mixed liquid hydrocarbons and contact material from said bed as a plurality of streams discharging at a plurality of points on the surface of said column in said conversion zone, said points being uniformly distributed across the horizontal cross-section of said column, withdrawing used contact material from the lower section of said column at a controlled rate to promote downward movement of said mixed liquid hydrocarbons and contact material within said conversion zone, thereby efiecting conversion of said hydrocarbons to lower boiling gasiform hydrocarbon products, and withdrawing gasiform hydrocarbon conversion products from said conversion zone.
- a method for conversion of high boiling liquid hydrocarbons to lower boiling gaseous hydrocarbons in the presence of a moving particleform contact material which method comprises: maintaining a substantially compact column of particle-form contact material within-a confined conversion zone, maintaining a separately confined bed of said contact material in a second confined zone, supplying heated contact material to said bed, supplying a high boiling liquid hydrocarbon charge onto the surface of said bed to become mixed with said contact material, passing a.
- suitable fluid cooling medium in contact with the walls confining said bed so as to maintain said walls at a temperature substantially below that of said contact material so as to prevent the substantial formation of coke on said walls, passing mixed liquid hydrocarbons and contact material from said bed onto the surface of said column in said conversion zone, withdrawing used contact material from the lower section of said column at a controlled rate to promote downward movement of said mixed liquid hydrocarbons and contact material within said conversion zone, thereby effecting conversion of said hydrocarbons to lower boiling gasiform hydrocarbon products, and withdrawing gasiform hydrocarbon conversion products from said conversion zone.
- a method for conversion of high boiling fluid hydrocarbons in the presence of a particleform contact material which comprises: maintaining a substantially compact column of partiole-form contact material within a confined conversion zone, maintaining a separately confined gravity flowing stream of varying depth of said contact material above said conversion zone, said stream being of a minimum depth of at least about one-quarter inch and of a maximum depth not greater than about 5 inches substantially continuouly supplying contact material to said stream at a suitable hydrocarbon conversion supporting temperature, supplying a heated high boiling liquid hydrocarbon charge onto the surface of said stream, to become mixed with said contact material, passing mixed liquid hydrocarbons and contact material downwardly from said stream as a plurality of confined streams discharging at a plurality of points on the surface of said column in said conversion zone, said points being uniformly distributed across the horizontal cross-section of said column, withdrawing used contact material from the lower section of said column at a controlled rate and withdrawing gaseous hydrocarbon conversion products from said conversion zone substantially separately of said contact material.
- a method for conversion of high boiling fluid hydrocarbons in the presence of a moving partiole-form contact material which comprises: maintaining an accumulation of particle-form contact material in a confined seal zone, introducing a substantially inert gas into said zone to maintain an inert gaseous atmosphere therein, supplying particle-form contact material at a suitable temperature for supporting conversion of said liquid hydrocarbons intosaid seal zone, passing contact material from said seal zone onto the surface of a bed of said contact material maintained in a separate confined mixing zone, supplying a high boiling liquid hydrocarbon charge onto said bed of contact material in said mixing zone, passing contact material and the liquid hydrocarbon charge mixed therewith as a plurality of substantially compact streams downwardly from said bed to a plurality of distributed locations on the surface of a column of said contact material maintained in a confined conversion zone therebelow, passing said liquid hydrocarbons and said contact material downwardly within said conversion zone to effect conversion of said liquid hydrocarbons to lower boiling g-asiform hydrocarbon praducts, withdrawing used contact material from the lower section
- An apparatus for conversion of high boiling fluid hydrocarbons to lower boiling hydrocarbons comprising, an elongated vertical conversion chamber closed on its ends, a closed seal chamber positioned above said conversion chamher, a conduit for inert gas supply connecting into the upper section of said seal chamber, an
- a closed mixingchamber positioned between said seal chamber and said conversion chamber, a conduit for solid flow extending downwardly from the bottom of said seal chamber and terminating within said mixing chamber at a level spaced substantially above its bottom, a spray device having downwardly facing spray openings positioned within said mixing chamber near the lower end of said last named conduit, a conduit connected to said spray device for supply of liquid hydrocarbon charge thereto, a plurality of conduits extending downwardly from said mixing chamber 'for flow of contact material into said conversion chamber, said conduits terminating on their lower ends at a plurality of uniformly, horizontally spaced locations within said conversion chamber, means to withdraw contact material from the lower section of said conversion chamber at a controlled rate, and a separate outlet for withdrawal of gaseous material from the lower section of said conversion chamber.
Description
Nov. 15, 1949 2,488,488
- METHOD AND APPARATUS FOR CONVERSION 5 N. 0% Rw TCI 5mm GD m m B .Md vmm EF 0 Patented Nov. 15, 1949 IWETHOD AND APPARATUS FOR CONVER- SION OF FLUID HYDROCARBONS Eric V. Bergstrom, Short Hills, N. J., assignor to Socony-Vacuum Oil Company, Incorporated, a
corporation of New York Application July 24, l946, Serial No. 685,835 7 14 Claims.
This invention has to do with a method and apparatus for conversion of high boiling liquid hydrocarbons or mixed phase hydrocarbons to lower boiling hydrocarbons in the presence of a moving particle-form contact mass material which may or may not exhibit catalytic properties with respect to the conversion reaction. Typical of such processes is the catalytic conversion of heated liquid hydrocarbons to lower boiling gasoline containing gaseous products by the contacting of a high boiling liquid charge at temperatures of the order of 850 F.'and upwards with a particle-form adsorbent catalytic material. Other exemplary processes are the thermal visbreaking, coking or cracking of liquid or mixed phase hydrocarbon charge by contact with heated particle-form inert contact materials.
Another difficulty arising in systems for the conversion of high boiling liquid hydrocarbons is the tendency for the liquid charge to form coke on hot metal surfaces at the inlet end of the convertor. In cyclic conversion systems used for conversion of vaporized hydrocarbons it has been customary to supply the contact material into the conversion chamber through one or more tubes extending downwardly through a short upper sec tion of said chamber and terminating at the surface of the column of contact material within said chamber. When a liquid or mixed phase hydrocarbon charge is to be converted it is desirable to supply all or a large part of the heat required for conversion in the incoming contact material. This means that the incoming contact material and the tubes through which it enters and other metal surfaces in the upper section of the conversion vessel exist at temperatures sufiiciently high to cause, upon contact by the liquid hydrocarbon charge, rapid conversion of said charge. As a result there is a marked tendency for coke to form on the hot tubes and metal surfaces in the upper section of the conversion vessel. This coke eventually breaks off from the metal surfaces in large chunks which pass downwardly through the convertor and plug up restricted passages for solid flow near the lower end of the convertor and in other portions of the cyclic system.
A major object of this invention is the provision in a process for conversion of high-boiling fluid hydrocarbons in the presence of a column of moving contact material particles of method and apparatus for supplying of contact material and fluid hydrocarbons onto the contact material col umn within the conversion zone which method and apparatus overcome the above described difficulties.
Another object is the provision of a practical process for the simultaneous catalytic conversion of gaseous and liquid hydrocarbons in the presence of a moving mass of particle-form catalyst.
Another object is the provision in-a continuous cyclic process for conversion of high boiling liquid or mixed phase hydrocarbons of an improved method and apparatus for hydrocarbon and contact material introduction into the conversion zone.
These and other objects of this invention will become apparent from the following discussion of the invention. Before proceeding with this discussion certains terms used in describing and in claiming this invention will be defined. The term "gaseous, as used herein, is intended to refer to a material existing in the gaseous phase under the particular operating conditions of pressure and temperature involved regardless of what may be the normal phase of that material under ordinary atmospheric conditions. The expression contact material is employed herein in a broad sense as covering solid particles which are suitable as a contacting or heat carrying agent for the particular conversion involved regardless of whether such solid particles exhibit a catalytic effect towards the conversion or not.
The invention may be best understood by reference to the single drawing attached hereto which is an elevational View, partially in section of an apparatus combination constructed according to this invention. In the drawing, there is shown a substantially vertical conversion vessel II] which may be of circular or of any other suitable cross-sectional shape. Above the reactor is provided a mixing chamber ll having a jacket I2 around its walls. An inlet conduit I3 is connected into the jacket for cooling fluid introduction to the jacketed space. An outlet conduit i4 is provided for fluid withdrawal from the jacketed space. A seal chamber I5 is positioned at a level above the mixing chamber II. A conduit 5 extends downwardly from the seal chamber to a location within the mixing chamber below the upper end but above its lower end for flow of contact material from the seal chamber onto the bed of contact material I! maintained in the mixing chamber. A ring type manifold I8 provided with downwardly depending spray nozzles I9 is positioned within chamber I i above the surface level of bed ll. Liquid hydrocarbons may be introduced to this spray device through conduit 20 connecting into manifold IS. A plurality of conduits 2! having branches 22 at their lower ends extend downwardly from the bottom of cham- 3 ber II for flow of contact material into the upper section of conversion vessel It). The branch pipes 22 all terminate at a common level below the upper end of vessel l and are spaced to deliver contact material uniformly over the entire crosssectional area of vessel Ill. An outlet 24 for withdrawal of gaseous material connects into the lower section of vessel III. This outlet may communicatewith suitable gas collecting devices (not shown) such as inverted troughs positioned within the lower section of vessel In. An inlet 25 for purge gas introduction connected into vessel [0 below the level of conduit 24. A solid drain conduit bearing flow control valve 21 is provided at the lower end of vessel I0. Suitable baflies (not shown) may be provided within the lower section of vessel Ill to insure withdrawal of contact material uniformly from all portions of the vessel horizontal cross-sectional area.
In operation heated contact material existing at a temperature suitable for supporting the desired hydrocarbon conversion is supplied from hopper 28 through elongated gravity feed leg 29 into seal chamber I5. The contact material passes as a substantially compact column downwardly from seal chamber l5 through conduit l6 onto the surface of the contact material bed I! within mixing chamber H. The zone 40 in chamber I l represents a zone wherein the contact material flow is very low or nil. A conical baffle may be provided in this zone if desired. Heated high boiling liquid hydrocarbons are introduced through conduit 20 to manifold l8 and spray nozzles l9 from which it is sprayed onto the surface of the bed ll so as to become mixed with the contact material in chamber II. In order to insure uniform mixing of the liquid and the contact material in chamber II, the dimensions of chamber H and the level of the lower end of conduit IS in chamber II should be such that the depth of the flowing stream of contact material at its shallowest point in chamber II, which in the arrangement shown is just adjacent the end of conduit I6, is of the order of A to inches while the depth of the flowing contact material stream at its deepest point is of the order of 3 to 5 inches. The oil charge should be sprayed onto the contact material where its depth of stream is least. The mixed liquid and contact material pass as a plurality of compact streams downwardly from chamber ll onto the column of contact material 30 within the vessel l0. The contact material and liquid hydrocarbons pass downwardly within the column 30, so that the liquid hydrocarbons are converted ,to lower boiling gaseous hydrocarbon products.
These gaseous products are withdrawn from the lower section of the conversion zone through conduit 24 and are passed to a conventional fractionation system (not shown). The used contact material is withdrawn from the lower end of vessel I0 through conduit 26 at a rate controlled by'means of valve 21. By throttling the flow with valve 21 continuity of compact contact material body is maintained unbroken upwardly from the point of throttling through the conversion zone, pipes 22 and 2|, bed I! in chamber ll, conduit ii, the bed in chamber I5, and feed leg 29 to the accumulation in hopper 28. The used contact material may be passed through a reconditioning chamber (not shown) to condition it for re-use in the conversion chamber. For example, if the process involved is a catalytic conversion operation, the particle-form catalyst bearing a carbonaceous contaminant may be subjected un- 4 der controlled elevated temperature to contact with air to burn ofi the contaminant. The hot regenerated catalyst is then supplied to hopper 28 through conduit 35. Gaseous hydrocarbons may be purged from the used contact material in the lower section of vessel II) by the introduction of an inert purging gas such as steam or.
fiue' gas through conduit 25. The escape of hydrocarbons from chamber ll through the contact material feed system may be prevented by the introduction of a suitable inert seal gas such as steam or flue gas into seal chamber [5 through conduit 3| at a rate controlled by diaphragm actuated valve 32 and differential pressure control instrument 33 such as will maintain the seal gas pressure in chamber l5 slightly above the gaseous pressure .in chamber II. For example, the pressure in chamber l5 may be maintained about A to pound per square inch above that in chamber ll.
In the above described operation, the entering contact material should exist at a temperature sufliciently high to provide the heat for the desired hydrocarbon conversion without the contact material temperature in vessel l0 falling below a level suitable for rapid hydrocarbon conversion. For example, in catalytic cracking operations, the catalyst may enter chamber II at temperatures of the order of 950-1150 F. These temperature levels are sufilciently high to cause rapid cracking conversion of the high boiling liquid hydrocarbon charge. During suchcracking conversion a substantial amount of coke may be formed. This coke, if deposited on the catalyst may be easily withdrawn from the conversion system and removed by burning. If,
however, it deposits on metal walls such as the walls above the catalyst level in chamber II, it may accumulate in large chunks. These chunks may eventually break off from the chamber walls and join the catalyst stream. Soon the chunks plug up the system at some restricted point and prevent further catalyst flow. To avoid this a suitable cooling medium is introduced into the jacketed space around chamber ll through inlet I3. The cooling medium is withdrawn through pipe Id. The cooling medium may take the form of a gas such as steam or it may preferably take the form of a liquid such as hot water under pressure or certain low melting point mixtures of fused inorganic salts or certain low melting metal alloys. The rate of flow and temperature of the cooling medium should be controlled such as to control the temperature of the walls of chamber ll, particularly at points above the level of bed I! below a level which would promote the substantial deposition of coke on the walls if they are contacted by the high boiling liquid hydrocarbon charge. In general, the wall temperature should be controlled below about 750 F. and preferably within the range about 500-600 F.
Inasmuch as the liquid hydrocarbon charge is uniformly deposited on the contact material delivering onto the surface of column 30 in the conversion vessel, vaporized hydrocarbon charge may be introduced through conduit 36 above the level of column 30 and then passed downwardly through column 30 without any gas channeling difliculties arising. Thus both liquid and gaseous hydrocarbon charges may be simultaneously con- Verted to lower boiling gaseous hydrocarbons in the system described hereinabove.
The method and apparatus described hereinabove may be applied to a number of different processes for conversion or liquid or mixed phase petroleum stocks. For example, the conversion may be a strictly high temperature thermal conversion in the presence of a heat carryingparticle-form inert material or it may be a catalytic cracking conversion. The operating conditions will, of course, vary widely depending upon the particular process and materials involved. As an example of the application of this invention its use in the catalytic cracking conversion of high boiling fluid hydrocarbons may be considered. In such an operation, a particle-form catalyst which may be of clay-type is introduced into the conversion chamber at a temperature within the range of about 900-1200" F. depending upon the desired conversion temperature, the clay to oil ratio and the particular hydrocarbon charge involved and the desired products. A liquid hydrocarbon charge which may consist principally of hydrocarbons boiling above the desired coverage conversion temperature is introduced through pipe 20. Such a charge may consist of a reduced crude which has been preferably preheated to a temperature of the order of 600-800 F. A gas oil fraction which may have been obtained from the same stock as the reduced crude, may be vaporized and heated to a temperature of the order of 800-950 F. in a conventional heater and introduced into the upper section of the convertor l through conduit 36. Gaseous products containing high yields of gasoline may be withdrawn from the conversion chamber through conduit 20. The pressure in the conversion chamber may be quite low, usually of the order of to 30 pounds per square inch gauge. The total oil space velocity may be within the range of about 0.5 to. volumes of oil (measured as a liquid at 60 F.) per hour per volume of flowing catalyst in the conversion zone. The relative ratio of liquid to gaseous hydrocarbon charge may vary widely depending upon the specific refinery stock conditions. The catalyst to oil ratio on the weight basis may be within the range about 2.0 to parts of catalyst charged per part of oil. In the regeneration zone, air may be employed to burn from the catalyst the carbon across contaminant formed thereon in the conversion zone. Sufficient heat should be withdrawn from the catalyst during regeneration to prevent it from reaching a heat damaging temperature. heat damaging level is of the order of about 1200 F.
It will be understood that the particular details of apparatus design and operating conditions and the examples of application of this invention given hereinabove are intended as illustrative and should not be construed as limiting the scope of this invention except as it maybe limited by the following claims.
I claim:
1. A method for conversion of high boiling liquid hydrocarbons in the presence of a moving particle-form contact material which comprises:
For clay type catalysts the r maintaining an accumulation of particle-form carbon charge onto said bed of contact material in said mixing zone, passing contact material and the liquid hydrocarbon charge mixed therewith as a plurality of substantially compact streams downwardly from said bed to a plurality of distributed locations on the surface of a'column of said contact material maintained in a confined conversion zone therebelow, withdrawing used contact material from the lower section of said column at a controlled rate and withdrawing gaseous hydrocarbon conversion products from the lower section of said conversion zone substantially separately of said contact material.
2. A method for conversion of high boiling fluid hydrocarbons in the present of a moving particleformncontact material which comprises:. maintaining an accumulation of particle-form contact material in a confined seal zone, introducing a substantially inert gas into said zoneto maintain an inert gaseous atmosphere therein, supplying particle-form contact material at a suitable temperature for supporting conversion of said liquid hydrocarbons into said seal zone, passing contact material as a substantially compact, continuous stream downwardly from said seal zone onto the surface of a bed of said contact material maintained therebelow in a confined mixing zone, spraying a high boiling liquid hydrocarbon charge onto said bed of contact material in said mixing zone, passing contact material and the liquid hydrocarbon charge mixed therewith as a plurality of substantially compact streams downwardly from said bed to a plurality of distributed locations on the surface of a column of said contact material maintained in a confined conversion zone therebelow, introducing a heated gaseous hydrocarbon charge into the upper section of said conversion zone, passing said liquid and gaseous hydrocarbons downwardly within said column to efiect their conversion to lower boiling gaseous hydrocarbon products, withdrawing used contact material from the lower section of said column at a controlled rate and withdrawing gaseous hydrocarbon conversion products from the lower section of said conversion zone substantially separately of said contact material.
3. A method for conversion of high boiling fluid hydrocarbons in the presence of a particle-form contact material which comprises: maintaining a substantially compact column of particle-form contact material within a confined conversion zone, maintaining a separately confined bed of said contact material above said conversion zone, substantially continuously supplying contact material to said bed at a suitable hydrocarbon conversion supporting temperature, supplying a heated high boiling liquid hydrocarbon charge onto the surface of said bed, to become mixed with said contact material, passing mixed liquid hydrocarbons and contact material downwardly from said bed as a plurality of confined streams discharging at a plurality of points on the surface of said column in said conversion zone, said points being uniformly distributed across the horizontal cross section of said column, introducing a vaporized hydrocarbon charge into the upper section of said conversion zone above the surface of said column, passing the contact material and liquid and gaseous hydrocarbons downwardly within said column to effect conversion of said hydrocarbons to lower boiling gaseous hydrocarbon products, withdrawing used contact material from the lower section of said column at a controlled rate and withdrawing gaseous hydrocarbon conversion products from the lower section of said conversion zone substantially separately or said contact material.
4. A method for conversion of high boiling liquid hydrocarbons to lower boiling gaseous hydrocarbons in the presence of a moving particle-form contact material which method comprises: maintaining a substantially compact column of particle-form contact material within a confined conversion zone, maintaining a separately confined bed of said contact material above said conversion zone, substantially continuously supplying contact material to said bed at a suitable hydrocarbon conversion supporting temperature,
supplying a heated high boiling liquid hydrocarbon charge onto the surface of said bed to become mixed with said contact material, passing a suitable i'iuid cooling medium in contact with the walls confining said bed so as to maintain said walls at a temperature substantially below that of said contact material so as to prevent the substantial formation of coke on said walls, passing mixed liquid hydrocarbons and contact material downwardly from said bed as a plurality of confined streams discharging at a plurality of points on the surface of said column in said conversion zone, said points being uniformly distributed across the horizontal cross section Of said column, passing liquid hydrocarbons and contact material downwardly within said column to effect conversion of said hydrocarbons to lower boiling gaseous hydrocarbon products, withdrawing used contact material from the lower section of said column at a controlled rate and withdrawing gaseous hydrocarbon conversion products from the lower section of said conversion zone substantially separately of said contact material.
5. A method for conversion of high boilingv fluid hydrocarbons to lower boiling hydrocarbon products in the presence of a moving particle form contact material which method comprises: maintaining an accumulation of particle-form contact material in a confined seal zone, introducing a substantially inert gas into said zone to maintain an inert gaseous atmosphere therein, supplying particle-form contact material at a suitable temperature for supporting conversion of said liquid hydrocarbons into said seal zone, passing contact material as a substantially compact, continuous stream downwardly from said seal zone onto the surface of a bed of said contact material maintained therebelow in a confined mixing zone, spraying a high boiling liquid hydrocarbon charge onto said bed Of contact material in said mixing zone, passing a fluid cooling medium in contact with the walls of said seal zone to cool said walls below a temperature which will support substantial coking of said liquid hydrocarbon charge, passing said contact material and said liquid hydrocarbon charge mixed therewith as a substantially compact, confined stream downwardly from said bed onto the surface of a substantially compact column of said contact material maintained in a confined elongated conversion zone therebel-ow, introducing a vaporized hydrocarbon charge into the upper section of said conversion zone, passing said contact material and the liquid and vaporized hydrocarbons downwardly within said column to effect conversion of said hydrocarbons to lower boiling hydrocarbons, withdrawing used contact material from the lower section of said column at a controlled rate and withdrawing gaseous hydrocarbon conversion products from the lower section of said conversion zone substantially separately of said contact material.
chamber and said conversion chamber, conduit means for contact material flow connected between said seal chamber and said mixing chamber, said conduit means terminating below the upper end of said mixing chamber but'substantially above the bottom thereof, a spray device positioned within the upper section of said mixing chamber and adapted to spray liquid hydrocarbons downwardly within said chamber, means to supply a high boiling liquid hydrocarbon charge to said spray device, a plurality of conduits extending downwardly from said mixing chamber for fiow of contact material into said conversion chamber, said conduits terminating on their lower ends at a plurality of uniformly, horizontally spaced locations within said conversion chamber, means to withdraw contact material fromthe lower section of said conversion chamber at a controlled rate, and a separate outlet for withdrawal of gaseous material from the lower section of said conversion chamber.
'7. An apparatus for conversion of high boiling fluid hydrocarbons to lower boiling hydrocarbons which comprises in combinationz'an elongated conversion chamber, a seal chamber adapted to confine a bed of contact material positioned at a level above said conversion chamber, a conduit for inert seal gas supply connecting into said seal chamber, means to supply particle form contact material into said seal chamber, a mixing chamber positioned at a level between said seal chamber and said conversion chamber, a conduit for solid flow extending down from the bottom of said seal chamber to a level within and intermediate the upper and lower ends of said mixing chamber, a spray device positioned within the upper section of said mixing chamber with spray openings pointed downward, a conduit connected to said spray device for supply of liquid hydrocarbon charge, at least one conduit for solid flow extending downwardly from said mixing chamber into the upper section of said conversion chamber, said conduit terminating on its lower end at a level within the upper section of the conversion chamber spaced below its upper end, a conduit for gaseous hydrocarbon introduction connecting into said conversion chamber above the level of the lower end of said last named conduit, means to withdraw contact material from the lower section of said conversion chamber, and flow throttling means associated therewith, and means to substantially separately withdraw gaseous material from the lower section of said conversion chamber.
8. An apparatus for conversion of high boiling fluid hydrocarbons to lower boiling hydrocarbons which comprises in combination an elongated conversion chamber adapted to confine an upright column of particle-form contact material, a closed seal chamber positioned at a level above said conversion chamber, an elongated conduit extending vertically upward from said seal chamber for gravity. flow of contact material into said seal chamber, a conduit for supply of an inert seal gas connected to said seal chamber, a closed mixing chamber positioned between said seal chamber and said conversion chamber, a conduit for solid flow extending from th bottom of said seal chamber into said mixing chamber and terminating on its lower end below the upper end of said mixing chamber but substantially above the bottom thereof, a spray device positioned within the upper section of said mixing chamber with spray openings pointed downwardly, a conduit connected to said spray device for supply of a high boiling liquid hydrocarbon charge, a jacket defining a jacketed space around at least the upwardly extending walls of said mixing chamber, conduit means for supply of a cooling fluid to said jacketed space and conduit means for withdrawal of cooling fluid therefrom, at least one conduit for solid flow extending downwardly from said mixing chamber into the upper section of said conversion chamber, said conduit terminating on its lower end at a level within the upper section of the conversion chamber spaced below its upper end, a conduit for gaseous hydrocarbon introduction connecting into said conversion chamber above the level of the lower end of said last named conduit, means to withdraw contact material from the lower section of said conversion chamber, and flow throttling means associated therewith, and means to substantially separately withdraw gaseous material from the lower section of said conversion chamber.
9. An apparatus for conversion of high boiling liquid hydrocarbons to lower boiling hydrocarbons in the presence ofa moving particle-form contact material which comprises in combination: a substantially vertical, elongated conversion vessel closed on either end, a mixing chamber above said conversion vessel, adapted to confine a bed of contact material, a jacket defining a closed jacketed space around the vertical walls of said mixing chamber, a conduit associated with said jacket for cooling fluid introduction to said jacketed space and conduit means for fluid withdrawal therefrom, a contact material supply conduit extending upwardly through the top of said mixing chamber from an intermediate level therein, a spray device in the upper section of said mixing chamber adapted to spray liquid downwardly within said chamber, conduit means for supply of liquid hydrocarbons to said spray device, a plurality of conduits extending downwardly from said. mixing chamber for flow of contact material into said conversion cham her, said conduits terminating on their lower ends at a plurality of uniformly, horizontally spaced locations within said conversion chamber, means to withdraw contact material from the lower section of said conversion chamber at a controlled rate, and means to separately withdraw gaseous material from the lower section of said conversion chamber.
10. A method for conversion of high boiling liquid hydrocarbons to lower boiling gaseous hydrocarbons in the presence of a moving particleform contact material which method comprises: maintaining a substantially compact column of particle-form contact material within a confined conversion zone, maintaining a separately confined bed of said contact material in a second confined zone, supplying heated contact material to said bed at a temperature sufficiently high to supply the heat required for said hydrocarbon conversion, supplying a high boiling liquid hydrocarbon charge onto the surface of said bed to become mixed with said contact material, passing mixed liquid hydrocarbons and contact material from said bed as a plurality of streams discharging at a plurality of points on the surface of said column in said conversion zone, said points being uniformly distributed across the horizontal cross-section of said column, withdrawing used contact material from the lower section of said column at a controlled rate to promote downward movement of said mixed liquid hydrocarbons and contact material within said conversion zone, thereby efiecting conversion of said hydrocarbons to lower boiling gasiform hydrocarbon products, and withdrawing gasiform hydrocarbon conversion products from said conversion zone.
11. A method for conversion of high boiling liquid hydrocarbons to lower boiling gaseous hydrocarbons in the presence of a moving particleform contact material which method comprises: maintaining a substantially compact column of particle-form contact material within-a confined conversion zone, maintaining a separately confined bed of said contact material in a second confined zone, supplying heated contact material to said bed, supplying a high boiling liquid hydrocarbon charge onto the surface of said bed to become mixed with said contact material, passing a. suitable fluid cooling medium in contact with the walls confining said bed so as to maintain said walls at a temperature substantially below that of said contact material so as to prevent the substantial formation of coke on said walls, passing mixed liquid hydrocarbons and contact material from said bed onto the surface of said column in said conversion zone, withdrawing used contact material from the lower section of said column at a controlled rate to promote downward movement of said mixed liquid hydrocarbons and contact material within said conversion zone, thereby effecting conversion of said hydrocarbons to lower boiling gasiform hydrocarbon products, and withdrawing gasiform hydrocarbon conversion products from said conversion zone.
12. A method for conversion of high boiling fluid hydrocarbons in the presence of a particleform contact material which comprises: maintaining a substantially compact column of partiole-form contact material within a confined conversion zone, maintaining a separately confined gravity flowing stream of varying depth of said contact material above said conversion zone, said stream being of a minimum depth of at least about one-quarter inch and of a maximum depth not greater than about 5 inches substantially continuouly supplying contact material to said stream at a suitable hydrocarbon conversion supporting temperature, supplying a heated high boiling liquid hydrocarbon charge onto the surface of said stream, to become mixed with said contact material, passing mixed liquid hydrocarbons and contact material downwardly from said stream as a plurality of confined streams discharging at a plurality of points on the surface of said column in said conversion zone, said points being uniformly distributed across the horizontal cross-section of said column, withdrawing used contact material from the lower section of said column at a controlled rate and withdrawing gaseous hydrocarbon conversion products from said conversion zone substantially separately of said contact material.
13. A method for conversion of high boiling fluid hydrocarbons in the presence of a moving partiole-form contact material which comprises: maintaining an accumulation of particle-form contact material in a confined seal zone, introducing a substantially inert gas into said zone to maintain an inert gaseous atmosphere therein, supplying particle-form contact material at a suitable temperature for supporting conversion of said liquid hydrocarbons intosaid seal zone, passing contact material from said seal zone onto the surface of a bed of said contact material maintained in a separate confined mixing zone, supplying a high boiling liquid hydrocarbon charge onto said bed of contact material in said mixing zone, passing contact material and the liquid hydrocarbon charge mixed therewith as a plurality of substantially compact streams downwardly from said bed to a plurality of distributed locations on the surface of a column of said contact material maintained in a confined conversion zone therebelow, passing said liquid hydrocarbons and said contact material downwardly within said conversion zone to effect conversion of said liquid hydrocarbons to lower boiling g-asiform hydrocarbon praducts, withdrawing used contact material from the lower section of said column at a controlled rate and withdrawing gasiform hydrocarbon products from said conversion zone.
14. An apparatus for conversion of high boiling fluid hydrocarbons to lower boiling hydrocarbons comprising, an elongated vertical conversion chamber closed on its ends, a closed seal chamber positioned above said conversion chamher, a conduit for inert gas supply connecting into the upper section of said seal chamber, an
12 of said conduit, a closed mixingchamber positioned between said seal chamber and said conversion chamber, a conduit for solid flow extending downwardly from the bottom of said seal chamber and terminating within said mixing chamber at a level spaced substantially above its bottom, a spray device having downwardly facing spray openings positioned within said mixing chamber near the lower end of said last named conduit, a conduit connected to said spray device for supply of liquid hydrocarbon charge thereto, a plurality of conduits extending downwardly from said mixing chamber 'for flow of contact material into said conversion chamber, said conduits terminating on their lower ends at a plurality of uniformly, horizontally spaced locations within said conversion chamber, means to withdraw contact material from the lower section of said conversion chamber at a controlled rate, and a separate outlet for withdrawal of gaseous material from the lower section of said conversion chamber.
ERIC V. BERGSTROM.
REFERENCES CITED The following references are of record in the file of this patent:
UNITED STATES PATENTS Number Name Date 469.849 Borgarelli Mar. 1, 1892 1,568 018 Forrest et al Dec. 29, 1925 2,419,519 Evans Apr. 22, 1947 2,432,344 Sinclair Dec. 9, 1947 OTHER REFERENCES Oil and Gas Journal, May 12, 1945, pp. 88-90.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US685835A US2488488A (en) | 1946-07-24 | 1946-07-24 | Method and apparatus for conversion of fluid hydrocarbons |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US685835A US2488488A (en) | 1946-07-24 | 1946-07-24 | Method and apparatus for conversion of fluid hydrocarbons |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US2488488A true US2488488A (en) | 1949-11-15 |
Family
ID=24753870
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US685835A Expired - Lifetime US2488488A (en) | 1946-07-24 | 1946-07-24 | Method and apparatus for conversion of fluid hydrocarbons |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US2488488A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2767129A (en) * | 1950-07-27 | 1956-10-16 | Sinclair Refining Co | Process and apparatus for contacting hydrocarbons and catalysts particles in a moving bed |
| US2837467A (en) * | 1953-09-21 | 1958-06-03 | Sun Oil Co | Hydrocarbon conversion systems |
| US2848378A (en) * | 1953-01-30 | 1958-08-19 | Socony Mobil Oil Co Inc | Catalytic hydrocarbon conversion process |
| US2875146A (en) * | 1954-04-15 | 1959-02-24 | Phillips Petrolcum Company | Prevention of coke depositions in a hydrocarbon coking zone |
| US2885099A (en) * | 1954-10-13 | 1959-05-05 | Socony Mobil Oil Co Inc | Hydrocarbon conversion |
| US2925378A (en) * | 1958-04-29 | 1960-02-16 | Socony Mobil Oil Co Inc | Hydrocarbon conversion process and apparatus |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US469849A (en) * | 1892-03-01 | Hihihih | ||
| US1568018A (en) * | 1920-06-15 | 1925-12-29 | Barber Asphalt Co | Treatment of hydrocarbons |
| US2419519A (en) * | 1945-07-27 | 1947-04-22 | Socony Vacuum Oil Co Inc | Conversion of hydrocarbons |
| US2432344A (en) * | 1946-02-08 | 1947-12-09 | Socony Vacuum Oil Co Inc | Method and apparatus for hydrocarbon conversion |
-
1946
- 1946-07-24 US US685835A patent/US2488488A/en not_active Expired - Lifetime
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US469849A (en) * | 1892-03-01 | Hihihih | ||
| US1568018A (en) * | 1920-06-15 | 1925-12-29 | Barber Asphalt Co | Treatment of hydrocarbons |
| US2419519A (en) * | 1945-07-27 | 1947-04-22 | Socony Vacuum Oil Co Inc | Conversion of hydrocarbons |
| US2432344A (en) * | 1946-02-08 | 1947-12-09 | Socony Vacuum Oil Co Inc | Method and apparatus for hydrocarbon conversion |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2767129A (en) * | 1950-07-27 | 1956-10-16 | Sinclair Refining Co | Process and apparatus for contacting hydrocarbons and catalysts particles in a moving bed |
| US2848378A (en) * | 1953-01-30 | 1958-08-19 | Socony Mobil Oil Co Inc | Catalytic hydrocarbon conversion process |
| US2837467A (en) * | 1953-09-21 | 1958-06-03 | Sun Oil Co | Hydrocarbon conversion systems |
| US2875146A (en) * | 1954-04-15 | 1959-02-24 | Phillips Petrolcum Company | Prevention of coke depositions in a hydrocarbon coking zone |
| US2885099A (en) * | 1954-10-13 | 1959-05-05 | Socony Mobil Oil Co Inc | Hydrocarbon conversion |
| US2925378A (en) * | 1958-04-29 | 1960-02-16 | Socony Mobil Oil Co Inc | Hydrocarbon conversion process and apparatus |
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