US2473166A - Process for the production of photographic images by color development - Google Patents

Process for the production of photographic images by color development Download PDF

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Publication number
US2473166A
US2473166A US11324A US1132448A US2473166A US 2473166 A US2473166 A US 2473166A US 11324 A US11324 A US 11324A US 1132448 A US1132448 A US 1132448A US 2473166 A US2473166 A US 2473166A
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US
United States
Prior art keywords
color
group
production
developing
color development
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US11324A
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English (en)
Inventor
Merckx Philibert Raymond
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Gevaert Photo Producten NV
Original Assignee
Gevaert Photo Producten NV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Gevaert Photo Producten NV filed Critical Gevaert Photo Producten NV
Application granted granted Critical
Publication of US2473166A publication Critical patent/US2473166A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03CPHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C7/00Multicolour photographic processes or agents therefor; Regeneration of such processing agents; Photosensitive materials for multicolour processes
    • G03C7/30Colour processes using colour-coupling substances; Materials therefor; Preparing or processing such materials
    • G03C7/32Colour coupling substances
    • G03C7/36Couplers containing compounds with active methylene groups

Definitions

  • This invention relates to the production of photographic images by color development, and more particularly to a new group of color couplers.
  • R is amino, substituted by an arylor heterocyclic group.
  • X is an electro-negative organic radical, for instance CN, alkyl-CO, aryl-CO, Y is an organic radical, hydrogen.
  • Another object of my invention is to provide a new color developer.
  • Still another object of myinvention is to provide new light-sensitive silver halide emulsions.
  • a further object of my invention is to provide a colored photographic image.
  • Y is hydrogen, an aliphatic-, homoor heterocyclic group either substituted or not.
  • the reactive methylene group may also be substituted by atoms or groups which, on developing, easily spilt-off. such as for instance bromo.
  • the brown precipitate formed is purified by boiling with alcohol.
  • the new color couplers may either directly be added to the photographic colloid layer, either before or after coating so that the colored image is formed by developing with an aromatic developer, or the colored image may be obtained by developing the photographic image with an aromatic developer which contains one of the above-defined color couplers.
  • the colloid layer to which the color coupler is added may be a light-sensitive silver halide [2-p-nitrophenyl-1,3,4-oxodia-
  • a developing bath for obtaining color images according to my invention is "the following:
  • a N ,N-diethylparaphenylenegdiamine Z is a member selected from the group consisting of.0 ands,
  • Process for the production of photographic color images by coior development which comprises developing with a primary aromatic amino developing agent a reducible silver salt image in a light-sensitive silver salt emulsion containing a compound of the following general iormula:
  • Nr N H g 1-0 -CH2GN z "wherein Z is amember selected from the group consisting hydrochloride grams 5 Sodium sulphite (cryst.) do Sodium carbonate (cryst.) do 100 Sodium hydroxide do 1 Water cm'. 1000 B C n u NO 0 OCH:CN ..grams 1 Acetone cm. .30
  • My invention may be used for obtaining colored photographic images upon plates, ,paper or film, coated with a light-sensitive silver halide emulsion.
  • the color developing process may be used for developing photographic material with one or more light-sensitive layers coated on one side or on Jooth sides 26f the support.
  • the silver image-termed during the development can easily be removed by treatment in a bleach-bath.
  • the bleach-bath used is not allowed to exert anoxious influence upon the colored image.
  • A'bleach-hath of potassium ferricyanide and sodium thiosulphate removes the silver without damaging the color image.
  • Z is a member selected from the group consisting of O and S,
  • Y is a member selected from the group consisting of aliphatic-,homoandheterocyclic groups.
  • Y' is a member selected from the group consisting of aliphatic-, homoand heterocyclic groups.
  • Color photographic developer containing .a primary aromatic amino developing agent and 1a com-poundof thefol-lowing general formula:
  • Y is .a member selected .from the group nourishing of aliphatic-, homoand heterocirclicsgroups.

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  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Silver Salt Photography Or Processing Solution Therefor (AREA)
US11324A 1945-08-03 1948-02-26 Process for the production of photographic images by color development Expired - Lifetime US2473166A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
BE2473166X 1945-08-03

Publications (1)

Publication Number Publication Date
US2473166A true US2473166A (en) 1949-06-14

Family

ID=3895842

Family Applications (1)

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US11324A Expired - Lifetime US2473166A (en) 1945-08-03 1948-02-26 Process for the production of photographic images by color development

Country Status (3)

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US (1) US2473166A (US20080094685A1-20080424-C00004.png)
BE (1) BE459542A (US20080094685A1-20080424-C00004.png)
DE (1) DE806936C (US20080094685A1-20080424-C00004.png)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5066576A (en) * 1989-10-03 1991-11-19 Fuji Photo Film Co., Ltd. Silver halide color photographic material
US5104783A (en) * 1988-10-04 1992-04-14 Fuji Photo Film Co., Ltd. Silver halide color photographic material
US5162196A (en) * 1989-11-20 1992-11-10 Fuji Photo Film Co., Ltd. Color coupler for photography and silver halide photographic material comprising the same
WO2005120445A3 (de) * 2004-06-12 2006-04-13 Henkel Kgaa Mittel zum färben von keratinhaltigen fasern

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR836144A (fr) * 1935-03-21 1939-01-11 Kodak Pathe Perfectionnements aux procédés de photographie en couleurs et en particulier aux révélateurs chromogènes

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR836144A (fr) * 1935-03-21 1939-01-11 Kodak Pathe Perfectionnements aux procédés de photographie en couleurs et en particulier aux révélateurs chromogènes

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5104783A (en) * 1988-10-04 1992-04-14 Fuji Photo Film Co., Ltd. Silver halide color photographic material
US5066576A (en) * 1989-10-03 1991-11-19 Fuji Photo Film Co., Ltd. Silver halide color photographic material
US5162196A (en) * 1989-11-20 1992-11-10 Fuji Photo Film Co., Ltd. Color coupler for photography and silver halide photographic material comprising the same
WO2005120445A3 (de) * 2004-06-12 2006-04-13 Henkel Kgaa Mittel zum färben von keratinhaltigen fasern

Also Published As

Publication number Publication date
BE459542A (US20080094685A1-20080424-C00004.png)
DE806936C (de) 1951-06-21

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