US2462270A - Method and apparatus for physicochemical analysis - Google Patents
Method and apparatus for physicochemical analysis Download PDFInfo
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- US2462270A US2462270A US501499A US50149943A US2462270A US 2462270 A US2462270 A US 2462270A US 501499 A US501499 A US 501499A US 50149943 A US50149943 A US 50149943A US 2462270 A US2462270 A US 2462270A
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N23/00—Investigating or analysing materials by the use of wave or particle radiation, e.g. X-rays or neutrons, not covered by groups G01N3/00 – G01N17/00, G01N21/00 or G01N22/00
- G01N23/22—Investigating or analysing materials by the use of wave or particle radiation, e.g. X-rays or neutrons, not covered by groups G01N3/00 – G01N17/00, G01N21/00 or G01N22/00 by measuring secondary emission from the material
- G01N23/221—Investigating or analysing materials by the use of wave or particle radiation, e.g. X-rays or neutrons, not covered by groups G01N3/00 – G01N17/00, G01N21/00 or G01N22/00 by measuring secondary emission from the material by activation analysis
- G01N23/222—Investigating or analysing materials by the use of wave or particle radiation, e.g. X-rays or neutrons, not covered by groups G01N3/00 – G01N17/00, G01N21/00 or G01N22/00 by measuring secondary emission from the material by activation analysis using neutron activation analysis [NAA]
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N2223/00—Investigating materials by wave or particle radiation
- G01N2223/07—Investigating materials by wave or particle radiation secondary emission
- G01N2223/074—Investigating materials by wave or particle radiation secondary emission activation analysis
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N2223/00—Investigating materials by wave or particle radiation
- G01N2223/60—Specific applications or type of materials
- G01N2223/616—Specific applications or type of materials earth materials
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- This invention relates in general to certain new mentally established, however, that materials which contain hydrogenous substances produce measurable nuclear reactions when bombarded by neutrons.
- Neutron particles are not decelerated or otherwise materially afiected by heavy inorganic molecules but even minute amounts of hydrogen atoms, however combined or chemically associated, will slow down the neutron particles.
- Figure 1 is a lengthwise sectional view of a chamber for bombarding a sample with fast neutrons and detecting the resultant quantity of slow neutrons.
- Figure 2 is a diagrammatic representation of a preferred form of apparatus for the analytical determination ofhydrogenous substances in accordance with the method of the present inven-v tion.
- Figure 3 is a diagrammatic representation of an alternative form of indicating mechanism associated with and forming part of my present invention.
- A designates a neutron bombardment chamber comprising a preferably rectilinear box I having walls formed of an inner relatively thick wooden ply or layer 2 and an outer ply or layer 3 of cadmium foil, cadmium plated metal, or other radiation absorbing material, the top wall t being centrally provided with aperture 4.
- the box I is substantially filled with paraflin wax p recessed to provide a central rectangular sample well 5 extending upwardly and opening to the aperture 4.
- the relation between external size of the chamber A and the size of the sample well 5, is such that there will be a substantially thick mass of paraffin surrounding the sample well 5, and consequently practically all of the neutrons which would otherwise escap from the chamber are absorbed.
- the few highly energized neutrons which succeed in passing through the paraflin are, of course, ab.- sorbed in the cadmium foil layer 3.
- a tapered recess 6 Extending laterally from one of the vertical walls of the sample well 5 is a tapered recess 6 provided at its apex with a preferably brass capsule 1 containing a beryllium-polonium mixture or other suitable material constituting a source of fast neutrons.
- a short connecting passage or channel 8 Extending laterally from the opposite wall of the sample well '5 is a short connecting passage or channel 8 preferably having the same cross sectional shape and area as the opening of the tapered recess 6, and communicating with a somewhat larger compartment 9, one of the side walls of which is provided with a relatively large removable section 10 held in position by means of screws H or other suitable fastening elements.
- a neutron counter tube 12 Suitably mounted within the compartment 9 is a neutron counter tube 12 having suitable leads l3, l3 extending through the walls of the box I.
- I employ a self-extinguishing tube of the Geiger-Mueller type suitably charged with a nuclear reactant, that is to say, a substance containing atoms of low atomic number capable of emitting alpha particles of relatively high energy when bombarded by neutrons.
- a nuclear reactant that is to say, a substance containing atoms of low atomic number capable of emitting alpha particles of relatively high energy when bombarded by neutrons.
- boron trifiuoride is a preferable type of nuclear reactant.
- a closure plug l4 consisting of a two-ply wood-cadmium member [5 matching the wall in thickness and materials and provided at its outer face with a semi-circular handle "5.
- the member I5 On its under face the member I5 is provided with a, parafiin wax plug I1 having a length sufiicient to extend down through the sample well 5 almost to the level of the upper marginsof the tapered recess 6 and the channel 8.
- a rectilinear sample container I 8 formed preferably of brass or other suitable neutron-transparent material, all as best seen in Figure 1.
- the lead 13 issuing from the chamber A is connected to one input lead of a high-gain linear amplifier B and to ground.
- the lead I3 is connected through the resistor l'9 to a source of high voltage and is also connectedt'hroughthe capacitor to the other input lead of the linear amplifier B.
- This source of high voltage is maintained below the threshold voltageof-the counter tube l2 so that such tube 12 will countdnlyheutrons and will not be affectedby extraneousra diations such as cosmic rays, gamma rays and the like.
- the output leads'ofthe linear ampli bomb B are connected to the input leads-of the multi-vibrator C and the output leads of the latter are in turn connected to an electro-mefchanical recorder D preferably of the recording typefan as shown in Figure 2.
- an instantaneousrecordingsystem may be employed by substituting, along the line I I; in the circuit shown in Figure 2, a pulse 'intgra'torE and any suitable type of directreading instantaneous recorder F connected as shown diagrammatically in' Figure 3.
- the stream of fast neutrons issuing from the neutron source 7 will pass through the sample and, depending upon the presence of hydrogenous material, a certain number of the neutrons will be slowed down and the composite stream of fast andslow neutrons ,will pass through the channel '8 into the compartment 9.
- the neutrons will register upon the counter tube i2 and create impulses which will pass'throug'h thelinear amplifier B, the multi-Vibrator C and be recorded by the recorder D. It is of course obvious that where the instantaneous recordingsystem shown in Figure 3 is used the impulses from the counter will be visually noted rather than per.- manently recorded.
- Thesampies arethena'nalyz'e'd to determine the presence of hydrocarbon materials for the reason that "there'is a directrlation'between thefquai'itity'of hydrocarbon materials and the presence of setroleum products in the underlying strata; In fact it has been round that 'by taking a fairly large number of samples and plotting the relative quantities ofhydrocarbons "present'in the various samples it is-possible to delineate the boundary lines of subterranean .oil deposits.
- the methods and apparatus of the present invention make it possible to run geophysical surveys of the type above described quickly andat comparatively small cost. Be cause of the rapidity and accuracy with which results maybe obtained it is [possible to send a survey crevvdnto the fieldto take samples over an initial gridpattern in which the samples are widely spaced and thus .rc'iugh-in1 the geophysical characteristics o'ffth'e area. Thereupon the crew while still in the field can be directed to certainselected areas in which a finergrid-worl pattern will'b'e employed 'an'dia greater number of more closely spaced samples taken. this secondary phase of the operation the 's'peedkan'cl simplicity of the present methods and apparatus are highly important.
- the method of determining the amount of hydrogenous material in a selected sample which comprises completelydrying the sample, interposing the dried sample in a path of fast neutrons, and measuring the reaction between fast neutrons and the hydrogenous material in the sample by imposing the slow neutrons resulting from such reaction upon a Geiger-Muller counter.
- Analytical apparatus for the determination of the amount of hydrogenous material in a selected sample, comprising in combination a wax filled box having an internal chamber for receiving a sample to be analyzed, a lateral recess opening into the chamber, a source of fast neutrons within the recess, and means for counting the number of slow neutrons resulting from the reaction between the fast neutrons and the hydrogenous material.
- Analytical apparatus for the determination of the amount of hydrogenous material in a selected sample, comprising in combination, a wax filled box provided with an outer layer formed of radiation-absorptive material and having an internal chamber for receiving a sample to be analyzed, a lateral recess opening into the chamber, a source of fast neutrons within the recess, and means for counting the number of slow neutrons resulting from the reaction between the fast neutrons and the hydrogenous material.
- Analytical apparatus for the determination of the amount of hydrogenous material in a selected sample, comprising in combination, a wax filled box having a chamber for receiving a sample to be analyzed, a recess opening into the chamber, a source of fast neutrons within the recess, a channel extending outwardly from the opposite side of the chamber with respect to the recess, a compartment communicating with the channel, means in the compartment for converting into electrical impulses, the slow neutrons resulting from the reaction between the fast neutrons and the hydrogenous material, and means for recording said electrical impulses.
- Analytical apparatus for the determination of the amount of hydrogenous material in a selected sample, comprising in combination, a. wax
- a filled box having a chamber for receiving a samrecess, a compartment communicating with the channel, means in the compartment for converting into electrical impulses, the slow neutrons resulting from the reaction between the fast neutrons and the hydrogenous material, a high gain linear amplifier connected to said means for strengthening said impulses, a multi-vibrator connected to the amplifier for lengthening said impulses, and means connected to the multi vibrator for recording said impulses.
- Analytical apparatus for the determination of the amount of hydrogenous material in a Selected sample, comprising in combination, a wax filled box having a chamber for receiving a sample to be analyzed, a recess opening into the chamber, a source of fast neutrons within the recess, a channel extending outwardly from the opposite side of the chamber with respect to the recess, a compartment communicating with the channel, means in the compartment for converting into electrical impulses, the slow neutrons resulting from the reaction between the fast neutrons and the hydrogenous material, a high gain linear amplifier connected to said means for strengthening said impulses, a multi-vibrator connected to the amplifier for lengthening said impulses, and an electro-mechanical recorder for recording said impulses.
- Analytical apparatus for the determination of the amount of hydrogenous material in a selected sample, comprising in combination, a wax filled box having a chamber for receiving a sample to be analyzed, a recess opening into the chamber, asource of fast neutrons within the recess, a channel extending outwardly from the opposite side of the chamber with respect to the recess, a compartment communicating with the channel, means in the compartment for converting into electrical impulses, the slow neutrons resulting from the reaction between the fast neutrons and the hydrogenous material, a high gain linear amplifier connected to said means for strengthening said impulses, a multi-vibrator connected to the amplifier for lengthening said impulses, a pulse integrator connected to the multi-vibrator, and an instantaneous recorder connected to the pulse integrator for indicating said impulses.
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Description
Feb. 22, 1949.
| B. LIPSON 2,462,270
METHOD AND APPARATUS FOR PHYSICOCHEMICAL ANALYSIS Filed Sept. '7, 1943 A .0 a 7 2 i a LINEAR MULTI RECORDER AMPLIFIER VIBRATOR FIG.2.
\ F L PULSE 7 'I INTEGRATOR F I G. 3. INVENTOR Patented Feb. 22, 1949 METHOD AND APPARATUS FOR rnYsIoo- CHEMICAL ANALYSIS Leonard B. Lipson, Arlington County, Va.
Application September '7, 1943-, Serial No. 501,499
7 Claims.
This invention relates in general to certain new mentally established, however, that materials which contain hydrogenous substances produce measurable nuclear reactions when bombarded by neutrons. Neutron particles are not decelerated or otherwise materially afiected by heavy inorganic molecules but even minute amounts of hydrogen atoms, however combined or chemically associated, will slow down the neutron particles.
The number of such slow neutrons bears a statistically direct ratio to the amount of hydrogenous I:
material present. Thus by bombarding a sample with fast neutrons and measuring the quantity of slow neutrons resulting from inelastic collision with hydrogen nuclei it is possible to determine within desirable limits of precision, the
- amount of hydrogenous material present. Such analytical procedure has been found to be entirely reliable and definitive as well as being exceedingly rapid, simple, and eflicient.
It is therefore a principal object of the present invention to provide a simple rapid and definitive method for the analytical determination of hydrogenous substances and apparatus for carrying out the same.
It is also an object of the present invention to provide compact and economical apparatus for bombarding a sample containinghydrogenous material with fast neutrons and measuring the resultant quantity of slow neutrons. In the drawings (one sheet) Figure 1 is a lengthwise sectional view of a chamber for bombarding a sample with fast neutrons and detecting the resultant quantity of slow neutrons.
Figure 2 is a diagrammatic representation of a preferred form of apparatus for the analytical determination ofhydrogenous substances in accordance with the method of the present inven-v tion.
Figure 3 is a diagrammatic representation of an alternative form of indicating mechanism associated with and forming part of my present invention.
Referring now in more detail and by reference characters to the drawings, A designates a neutron bombardment chamber comprising a preferably rectilinear box I having walls formed of an inner relatively thick wooden ply or layer 2 and an outer ply or layer 3 of cadmium foil, cadmium plated metal, or other radiation absorbing material, the top wall t being centrally provided with aperture 4. Interiorly the box I is substantially filled with paraflin wax p recessed to provide a central rectangular sample well 5 extending upwardly and opening to the aperture 4. The relation between external size of the chamber A and the size of the sample well 5, is such that there will be a substantially thick mass of paraffin surrounding the sample well 5, and consequently practically all of the neutrons which would otherwise escap from the chamber are absorbed. The few highly energized neutrons which succeed in passing through the paraflin are, of course, ab.- sorbed in the cadmium foil layer 3.
Extending laterally from one of the vertical walls of the sample well 5 is a tapered recess 6 provided at its apex with a preferably brass capsule 1 containing a beryllium-polonium mixture or other suitable material constituting a source of fast neutrons. Extending laterally from the opposite wall of the sample well '5 is a short connecting passage or channel 8 preferably having the same cross sectional shape and area as the opening of the tapered recess 6, and communicating with a somewhat larger compartment 9, one of the side walls of which is provided with a relatively large removable section 10 held in position by means of screws H or other suitable fastening elements.
Suitably mounted within the compartment 9 is a neutron counter tube 12 having suitable leads l3, l3 extending through the walls of the box I. For this purpose I employ a self-extinguishing tube of the Geiger-Mueller type suitably charged with a nuclear reactant, that is to say, a substance containing atoms of low atomic number capable of emitting alpha particles of relatively high energy when bombarded by neutrons. I have found that boron trifiuoride is a preferable type of nuclear reactant.
Shaped for snug fitting disposition within the upper portion of the sample well 5 is a closure plug l4 consisting of a two-ply wood-cadmium member [5 matching the wall in thickness and materials and provided at its outer face with a semi-circular handle "5. On its under face the member I5 is provided with a, parafiin wax plug I1 having a length sufiicient to extend down through the sample well 5 almost to the level of the upper marginsof the tapered recess 6 and the channel 8. Sized for removable disposition within the sample well is a rectilinear sample container I 8 formed preferably of brass or other suitable neutron-transparent material, all as best seen in Figure 1.
The lead 13 issuing from the chamber A is connected to one input lead of a high-gain linear amplifier B and to ground. The lead I3 is connected through the resistor l'9 to a source of high voltage and is also connectedt'hroughthe capacitor to the other input lead of the linear amplifier B. This source of high voltage is maintained below the threshold voltageof-the counter tube l2 so that such tube 12 will countdnlyheutrons and will not be affectedby extraneousra diations such as cosmic rays, gamma rays and the like. The output leads'ofthe linear ampli fier B are connected to the input leads-of the multi-vibrator C and the output leads of the latter are in turn connected to an electro-mefchanical recorder D preferably of the recording typefan as shown in Figure 2.
" fI'f desired an instantaneousrecordingsystem may be employed by substituting, along the line I I; in the circuit shown in Figure 2, a pulse 'intgra'torE and any suitable type of directreading instantaneous recorder F connected as shown diagrammatically in'Figure 3.
In performing an analysis a sample of soil or other material "containing hydrogenous substances is carefullymulled or ground to a substantially miiform state of fineness and dried under carefully controlled moderate temperature so as'tofr'e'move'alltraces of moisture. It'is essential' that the sample be thoroughly dried inasmuch as water isitself an hydrogenous substance'and would "introduce substantial errors int'o the analytical result. Either before or after dryingthe sample is packed firmly but not tightly into-the sample container i 8. Because of the danger of contaminating the sample with water vapor picked up from the atmosphere, it is preferable that the sample be packed into the container E8 prior to ,drying. ,Whe'n ,dry the sample is weighed and then placed within the sample well 5.
(The stream of fast neutrons issuing from the neutron source 7 will pass through the sample and, depending upon the presence of hydrogenous material, a certain number of the neutrons will be slowed down and the composite stream of fast andslow neutrons ,will pass through the channel '8 into the compartment 9. The neutrons will register upon the counter tube i2 and create impulses which will pass'throug'h thelinear amplifier B, the multi-Vibrator C and be recorded by the recorder D. It is of course obvious that where the instantaneous recordingsystem shown in Figure 3 is used the impulses from the counter will be visually noted rather than per.- manently recorded. By reason of the fact that the statistical probability of a nuclear reaction between a neutron and the atoms of the nuclear reactant such as the boron atoms of boron trifiuoride, .for instance, is, many thousand times greater in the case of slow neutrons than in the case of ,fast neutrons, thenumber of fast neutrons which will aifect the counter tube 12 "will represent only a few-thousandths of one percent. However, the apparatusfmust be. initially calibrated against carefully standardized samples since eachneutron source willliproduce a neutron stream, "of unique intensity. Furthermore the counting of. neutrons isstatistical rather than absolute and therefore'is measurable only in terms of ratios. Once the particular ratios and other constants for a given piece of apparatus have been established against absolute standards and the apparatus accordingly calibrated it is thereafter possible to interpret readings or recordings so as to obtain accurate and positive analytical results. It will of course be recognized that the methods andalpparatus of the present finventlon -are applicable to it wide range of analytic'al problems. However, there are certain types of analyses to which such apparatus and methods are uniquely well suited, such as for example, the-analysis of soil samples in geophysical exploration.
In the course of exploring a particular section of the earths surface to determine the character "an'dty-pe dfpetroleum deposits Which may exist in theunderlying strata it has become a recognized technique to takes]. multiplicity of soil samples at uniformly spaced selected points over the 'area'in a sort of grid-work pattern. Thesampies arethena'nalyz'e'd to determine the presence of hydrocarbon materials for the reason that "there'is a directrlation'between thefquai'itity'of hydrocarbon materials and the presence of setroleum products in the underlying strata; In fact it has been round that 'by taking a fairly large number of samples and plotting the relative quantities ofhydrocarbons "present'in the various samples it is-possible to delineate the boundary lines of subterranean .oil deposits.
Although these principles and geophysical relationships have been established in practice, suchgeophysical surveys and explorations have been hampered by diificulties in available-ana- 'lytical methods and apparatus with which the soil samples can be analysed. The hydrocarboncontent of any 'given sample is very minute and beyond the limits of accuracy or ordinary laboratory methods of chemical analysis. Inaddition to this the hydrocarbons which are present take the form of complex wax-like polymerization products, which are not readily susceptible to analysis by the usual -acidimetric-alkilimetric or oxidation-reduction methods. of a relatively small section of territory will result in many hundreds of samples so as to require rather extensive analytical facilities ifthe samples must be analys'edby usual routine methods. For 'this'reason such geophysical exploration and surveys "are extremely costly and relatively slow.
The methods and apparatus of the present invention however make it possible to run geophysical surveys of the type above described quickly andat comparatively small cost. Be cause of the rapidity and accuracy with which results maybe obtained it is [possible to send a survey crevvdnto the fieldto take samples over an initial gridpattern in which the samples are widely spaced and thus .rc'iugh-in1 the geophysical characteristics o'ffth'e area. Thereupon the crew while still in the field can be directed to certainselected areas in which a finergrid-worl pattern will'b'e employed 'an'dia greater number of more closely spaced samples taken. this secondary phase of the operation the 's'peedkan'cl simplicity of the present methods and apparatus are highly important. Not only will-the, results of the survey be known alinost .as soon asthe sampling crew is finished'faking'thsamfplesbut any strikin deviations wiii's'how'up. "'rhe egde viationsmay result from actual geophysical'idio syn'crasie's m tres. or: iiiaymsjiiltfiforn "som error in 'sampletalhng. In either case itis'p'os Finally a survey sible to have new samples taken in such instance so that the results may be checked or corrected without the great expense of sending men back into the field many weeks after the original survey has been run.
Although the previously described use of the methods and apparatus of my present invention in the analysis of soil samples as an incident of geophysical exploration has been described above it should nevertheless be understood that such use is merely illustrative and that my invention is not limited strictly to the geophysical field but is applicable with equal speed and precision to practically any type of analytical situation where it is necessary to determine the amount of hydrogenous material present in a sample and various changes and modifications may be made where different types of hydrogenous materials or different operating conditions are encountered without departin from the spirit of my invention.
Having thus described my invention, what I claim and desire to secure by these Letters Patent is as follows:
1. The method of determining the amount of hydrogenous material in a selected sample which comprises completelydrying the sample, interposing the dried sample in a path of fast neutrons, and measuring the reaction between fast neutrons and the hydrogenous material in the sample by imposing the slow neutrons resulting from such reaction upon a Geiger-Muller counter.
2. Analytical apparatus for the determination of the amount of hydrogenous material in a selected sample, comprising in combination a wax filled box having an internal chamber for receiving a sample to be analyzed, a lateral recess opening into the chamber, a source of fast neutrons within the recess, and means for counting the number of slow neutrons resulting from the reaction between the fast neutrons and the hydrogenous material.
3. Analytical apparatus for the determination of the amount of hydrogenous material in a selected sample, comprising in combination, a wax filled box provided with an outer layer formed of radiation-absorptive material and having an internal chamber for receiving a sample to be analyzed, a lateral recess opening into the chamber, a source of fast neutrons within the recess, and means for counting the number of slow neutrons resulting from the reaction between the fast neutrons and the hydrogenous material.
4. Analytical apparatus for the determination of the amount of hydrogenous material in a selected sample, comprising in combination, a wax filled box having a chamber for receiving a sample to be analyzed, a recess opening into the chamber, a source of fast neutrons within the recess, a channel extending outwardly from the opposite side of the chamber with respect to the recess, a compartment communicating with the channel, means in the compartment for converting into electrical impulses, the slow neutrons resulting from the reaction between the fast neutrons and the hydrogenous material, and means for recording said electrical impulses.
5. Analytical apparatus for the determination of the amount of hydrogenous material in a selected sample, comprising in combination, a. wax
filled box having a chamber for receiving a samrecess, a compartment communicating with the channel, means in the compartment for converting into electrical impulses, the slow neutrons resulting from the reaction between the fast neutrons and the hydrogenous material, a high gain linear amplifier connected to said means for strengthening said impulses, a multi-vibrator connected to the amplifier for lengthening said impulses, and means connected to the multi vibrator for recording said impulses.
6. Analytical apparatus for the determination of the amount of hydrogenous material in a Selected sample, comprising in combination, a wax filled box having a chamber for receiving a sample to be analyzed, a recess opening into the chamber, a source of fast neutrons within the recess, a channel extending outwardly from the opposite side of the chamber with respect to the recess, a compartment communicating with the channel, means in the compartment for converting into electrical impulses, the slow neutrons resulting from the reaction between the fast neutrons and the hydrogenous material, a high gain linear amplifier connected to said means for strengthening said impulses, a multi-vibrator connected to the amplifier for lengthening said impulses, and an electro-mechanical recorder for recording said impulses.
7. Analytical apparatus for the determination of the amount of hydrogenous material in a selected sample, comprising in combination, a wax filled box having a chamber for receiving a sample to be analyzed, a recess opening into the chamber, asource of fast neutrons within the recess, a channel extending outwardly from the opposite side of the chamber with respect to the recess, a compartment communicating with the channel, means in the compartment for converting into electrical impulses, the slow neutrons resulting from the reaction between the fast neutrons and the hydrogenous material, a high gain linear amplifier connected to said means for strengthening said impulses, a multi-vibrator connected to the amplifier for lengthening said impulses, a pulse integrator connected to the multi-vibrator, and an instantaneous recorder connected to the pulse integrator for indicating said impulses.
LEONARD B. LIPSON.
REFERENCES CITED The following references are of record in the file of this patent:
UNITED STATES PATENTS
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US501499A US2462270A (en) | 1943-09-07 | 1943-09-07 | Method and apparatus for physicochemical analysis |
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| Application Number | Priority Date | Filing Date | Title |
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| US501499A US2462270A (en) | 1943-09-07 | 1943-09-07 | Method and apparatus for physicochemical analysis |
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| US2462270A true US2462270A (en) | 1949-02-22 |
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| US2567057A (en) * | 1948-08-02 | 1951-09-04 | Texas Co | Chemical analysis using neutrons |
| US2597535A (en) * | 1946-07-23 | 1952-05-20 | Atomic Energy Commission | Radioactive assay apparatus |
| US2665153A (en) * | 1945-05-30 | 1954-01-05 | Texaco Development Corp | Control system for locking means |
| US2700593A (en) * | 1949-12-01 | 1955-01-25 | Standard Oil Dev Co | Correlation of crude oils |
| US2716705A (en) * | 1945-03-27 | 1955-08-30 | Walter H Zinn | Radiation shield |
| US2790087A (en) * | 1953-09-08 | 1957-04-23 | Molins Machine Co Ltd | Screening device for beta-ray scanning units |
| US2796411A (en) * | 1947-01-29 | 1957-06-18 | Raymond E Zirkle | Radiation shield |
| US2830944A (en) * | 1945-08-28 | 1958-04-15 | Eugene P Wigner | Neutronic reactor |
| US2872400A (en) * | 1946-03-28 | 1959-02-03 | Stnart J Bugbee | Reactor monitoring |
| US2876360A (en) * | 1953-11-16 | 1959-03-03 | John A Victoreen | Apparatus for the comparison of sources of radiation |
| US2992332A (en) * | 1956-10-31 | 1961-07-11 | John J Madigan | Method and apparatus for determining the quantitative relationship of components in products by measurement of gamma ray penetration thereof |
| US3050624A (en) * | 1958-03-14 | 1962-08-21 | Siemens Ag | Neutron-flux gage for nuclear reactors |
| US3124679A (en) * | 1964-03-10 | Nuclear determination of |
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| US2220509A (en) * | 1939-02-09 | 1940-11-05 | Shell Dev | Process and apparatus for exploring georlogical strata |
| US2269889A (en) * | 1939-02-27 | 1942-01-13 | Standard Oil Dev Co | Process for locating valuable subterranean deposits |
| US2316329A (en) * | 1940-06-18 | 1943-04-13 | Texaco Development Corp | Subsurface prospecting |
| US2316239A (en) * | 1941-08-20 | 1943-04-13 | Texas Co | Method and apparatus for determining density of fluids |
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| US2337306A (en) * | 1942-03-28 | 1943-12-21 | American Cyanamid Co | Method and apparatus for quantitative analysis of radioactive substances |
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| US2220509A (en) * | 1939-02-09 | 1940-11-05 | Shell Dev | Process and apparatus for exploring georlogical strata |
| US2269889A (en) * | 1939-02-27 | 1942-01-13 | Standard Oil Dev Co | Process for locating valuable subterranean deposits |
| US2378219A (en) * | 1940-05-29 | 1945-06-12 | Texas Co | Method and apparatus for determining liquid level |
| US2316329A (en) * | 1940-06-18 | 1943-04-13 | Texaco Development Corp | Subsurface prospecting |
| US2316239A (en) * | 1941-08-20 | 1943-04-13 | Texas Co | Method and apparatus for determining density of fluids |
| US2323128A (en) * | 1941-09-10 | 1943-06-29 | Texas Co | Method and apparatus for determining liquid level |
| US2370163A (en) * | 1941-10-16 | 1945-02-27 | Texas Co | Method and apparatus for examining opaque material |
| US2337306A (en) * | 1942-03-28 | 1943-12-21 | American Cyanamid Co | Method and apparatus for quantitative analysis of radioactive substances |
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3124679A (en) * | 1964-03-10 | Nuclear determination of | ||
| US2716705A (en) * | 1945-03-27 | 1955-08-30 | Walter H Zinn | Radiation shield |
| US2665153A (en) * | 1945-05-30 | 1954-01-05 | Texaco Development Corp | Control system for locking means |
| US2830944A (en) * | 1945-08-28 | 1958-04-15 | Eugene P Wigner | Neutronic reactor |
| US2872400A (en) * | 1946-03-28 | 1959-02-03 | Stnart J Bugbee | Reactor monitoring |
| US2597535A (en) * | 1946-07-23 | 1952-05-20 | Atomic Energy Commission | Radioactive assay apparatus |
| US2796411A (en) * | 1947-01-29 | 1957-06-18 | Raymond E Zirkle | Radiation shield |
| US2567057A (en) * | 1948-08-02 | 1951-09-04 | Texas Co | Chemical analysis using neutrons |
| US2700593A (en) * | 1949-12-01 | 1955-01-25 | Standard Oil Dev Co | Correlation of crude oils |
| US2790087A (en) * | 1953-09-08 | 1957-04-23 | Molins Machine Co Ltd | Screening device for beta-ray scanning units |
| US2876360A (en) * | 1953-11-16 | 1959-03-03 | John A Victoreen | Apparatus for the comparison of sources of radiation |
| US2992332A (en) * | 1956-10-31 | 1961-07-11 | John J Madigan | Method and apparatus for determining the quantitative relationship of components in products by measurement of gamma ray penetration thereof |
| US3050624A (en) * | 1958-03-14 | 1962-08-21 | Siemens Ag | Neutron-flux gage for nuclear reactors |
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