US2451814A - Deicing composition for aircraft parts and surfaces - Google Patents

Deicing composition for aircraft parts and surfaces Download PDF

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Publication number
US2451814A
US2451814A US656536A US65653646A US2451814A US 2451814 A US2451814 A US 2451814A US 656536 A US656536 A US 656536A US 65653646 A US65653646 A US 65653646A US 2451814 A US2451814 A US 2451814A
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US
United States
Prior art keywords
ice
aircraft parts
deicing composition
weight
parts
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US656536A
Inventor
Dissel Theodore Augustine
Newell Isaac Laird
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Raytheon Technologies Corp
Original Assignee
United Aircraft Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by United Aircraft Corp filed Critical United Aircraft Corp
Priority to US656536A priority Critical patent/US2451814A/en
Application granted granted Critical
Publication of US2451814A publication Critical patent/US2451814A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K3/00Materials not provided for elsewhere
    • C09K3/18Materials not provided for elsewhere for application to surfaces to minimize adherence of ice, mist or water thereto; Thawing or antifreeze materials for application to surfaces
    • C09K3/185Thawing materials

Definitions

  • This invention relates to a composition and a process for preventing the formation or accretion of ice on solid surfaces. It is particularly useful in preventing th formation of ice on propeller domes, rods, guides, rails, or wires in such thickness or amounts as to become dangerous on ships or aircraft for example.
  • the formation of dangerous thicknesses of ice on metallic or nonmetallic articles is prevented by coating such articles or applying thereto a mixture of certain water-insoluble esters or partial esters and a water soluble salt or ester.
  • compositions containing-certain substantially water-insoluble long chain fatty acid esters or partial esters and strongly ionizable water-soluble inorganic salts or a strongly ionizing, relatively non-volatile salt of an alkyl group with an inorganic acid radical can be applied to the surfaces of metal and nonmetal structures or parts, thus lowering the adhesion of ice thereto so that the same can be safely used even at very low temperatures.
  • Theproportions of the materials used in forming the de-icing composition can be varied widely but we prefer to have a larger amount of the insoluble ester in the composition than of the ionizing material. Mixtures containing proportions between 99 parts by weight of ester to one part by weight of ionizing material and parts by weight of ester to 90 parts by weight of ionizing material have been found to be suitable.
  • compositions may be dissolved in suitable solvents or lacquer and paints so that they may be applied by spraying or brushing.
  • Example 2 Sorbitan monostearate and powdered anhydrous potassium acetate are thoroughly mixed in a, mill or by other mechanical mean in the proportion of about 10 to 1 by weight, thus forming a. stiff paste that can be applied to and will adhere to the surfaces that are to be protected, thus facilitating removal of the ice that may form thereon.
  • Example 3 Ten parts by weight of sorbitan monostearate polyoxyalkylene derivative and one part of finely divided anhydrous potassium ethyl phosphate are thoroughly mixed until a heavy or thick paste is formed which can be applied to surfaces exposed to ice accretion so that the ice can be easily removed from the objects for example by impact, vibration or shear.
  • Example 4 The following ingredients are mixed together, making a liquid medium which is suitable for application to surfaces to facilitate the removal of ice accretions:
  • a de-icing composition consisting essentially of a, long chain fatty acid partial ester of sorbitan, selected from th group consisting of THEODORE AUGUSTINE DISSEL. ISAAC LAIRD NEWELL.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)
  • Tires In General (AREA)

Description

Patented Oct. 19, 1948 2,451,814 g V DEICINGCOMPOSITION FOR AIRCRAFT raitrs AND summons Theodore Augustine Dissel, Hartford, and Isaac Laird Nowell, Wethersfield, Conn., assignors to United Aircraft Corporation, East Hartford, Conn, a corporation of Delaware No Drawing. Application March 22, 1946,
' Serial No. 656,536
3 Claims.
This invention relates to a composition and a process for preventing the formation or accretion of ice on solid surfaces. It is particularly useful in preventing th formation of ice on propeller domes, rods, guides, rails, or wires in such thickness or amounts as to become dangerous on ships or aircraft for example.
It is well known that it is difiicult to remove ice that has formed on either metal or non-metal bodies or objects such as cables, rods, guides, and rails, for example, that are provided on such structures as ships, cables, rods, guides, and propeller domes such as are provided on airplanes. It is especially difficult to remove ice when the temperature is quite low, with the result that the hazard of losing control of the craft arises.
With the present invention the formation of dangerous thicknesses of ice on metallic or nonmetallic articles is prevented by coating such articles or applying thereto a mixture of certain water-insoluble esters or partial esters and a water soluble salt or ester.
We have discovered that a composition containing-certain substantially water-insoluble long chain fatty acid esters or partial esters and strongly ionizable water-soluble inorganic salts or a strongly ionizing, relatively non-volatile salt of an alkyl group with an inorganic acid radical can be applied to the surfaces of metal and nonmetal structures or parts, thus lowering the adhesion of ice thereto so that the same can be safely used even at very low temperatures.
Theproportions of the materials used in forming the de-icing composition can be varied widely but we prefer to have a larger amount of the insoluble ester in the composition than of the ionizing material. Mixtures containing proportions between 99 parts by weight of ester to one part by weight of ionizing material and parts by weight of ester to 90 parts by weight of ionizing material have been found to be suitable.
These compositions may be dissolved in suitable solvents or lacquer and paints so that they may be applied by spraying or brushing.
The following specific example are given to illustrate the invention but it is to be understood that the proportions of the ingredients can be varied widely and still produce satisfactory results.
2 Example 1 Sorbitan monopalmitate and powdered anhydrous potassium acetate are thoroughly mixed in a mill or by other mechanical means in the proportion of about 10 to l by weight, thus forming a stiff paste that can be applied to and will adhere to the surfaces that are to be protected, thus facilitating removal of the ice that may form thereon,
Example 2 Sorbitan monostearate and powdered anhydrous potassium acetate are thoroughly mixed in a, mill or by other mechanical mean in the proportion of about 10 to 1 by weight, thus forming a. stiff paste that can be applied to and will adhere to the surfaces that are to be protected, thus facilitating removal of the ice that may form thereon.
Example 3 Ten parts by weight of sorbitan monostearate polyoxyalkylene derivative and one part of finely divided anhydrous potassium ethyl phosphate are thoroughly mixed until a heavy or thick paste is formed which can be applied to surfaces exposed to ice accretion so that the ice can be easily removed from the objects for example by impact, vibration or shear.
Example 4 The following ingredients are mixed together, making a liquid medium which is suitable for application to surfaces to facilitate the removal of ice accretions:
What is claimed is:
1. A de-icing composition, consisting essentially of a, long chain fatty acid partial ester of sorbitan, selected from th group consisting of THEODORE AUGUSTINE DISSEL. ISAAC LAIRD NEWELL.
4 REFERENCES CITED The following references are of record in the file of this patent:
UNITED STATES PATENTS Number Name Date 2,098,482 Bashford Nov. 9, 1937 2,322,822 Brown June 29, 1943 2,346,891 Adlin-gton Apr. 18, 1944 2,416,103 Lampton et a1 Feb. 18, 1947 OTHER REFERENCES National Paint Bulletin, Sept, 1943, pages 10, 11, 13, and 15.
Spans and Tweens, Nov. 1942, page 5, 6, 7, and 8.
US656536A 1946-03-22 1946-03-22 Deicing composition for aircraft parts and surfaces Expired - Lifetime US2451814A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US656536A US2451814A (en) 1946-03-22 1946-03-22 Deicing composition for aircraft parts and surfaces

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US656536A US2451814A (en) 1946-03-22 1946-03-22 Deicing composition for aircraft parts and surfaces

Publications (1)

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US2451814A true US2451814A (en) 1948-10-19

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2716067A (en) * 1952-09-26 1955-08-23 Jacob M Fain De-icing composition
US2726962A (en) * 1953-07-03 1955-12-13 Gabriella A Iorio Defogging compound
US2948625A (en) * 1959-07-23 1960-08-09 William E Mackenzie Anti-icing fluid for use in freezing rain

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2098482A (en) * 1934-04-25 1937-11-09 Atlas Powder Co Method of and means for preventing the formation of sleet on mobile bodies
US2322822A (en) * 1940-08-23 1943-06-29 Atlas Powder Co Oil and water emulsion containing electrolytes
US2346891A (en) * 1940-12-20 1944-04-18 Adlington George Stuart Prevention of ice accretion
US2416103A (en) * 1943-10-30 1947-02-18 United Aircraft Corp Deicing composition

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2098482A (en) * 1934-04-25 1937-11-09 Atlas Powder Co Method of and means for preventing the formation of sleet on mobile bodies
US2322822A (en) * 1940-08-23 1943-06-29 Atlas Powder Co Oil and water emulsion containing electrolytes
US2346891A (en) * 1940-12-20 1944-04-18 Adlington George Stuart Prevention of ice accretion
US2416103A (en) * 1943-10-30 1947-02-18 United Aircraft Corp Deicing composition

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2716067A (en) * 1952-09-26 1955-08-23 Jacob M Fain De-icing composition
US2726962A (en) * 1953-07-03 1955-12-13 Gabriella A Iorio Defogging compound
US2948625A (en) * 1959-07-23 1960-08-09 William E Mackenzie Anti-icing fluid for use in freezing rain

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