US2449615A - Distillation of oil shale under fluidized conditions - Google Patents
Distillation of oil shale under fluidized conditions Download PDFInfo
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- US2449615A US2449615A US454756A US45475642A US2449615A US 2449615 A US2449615 A US 2449615A US 454756 A US454756 A US 454756A US 45475642 A US45475642 A US 45475642A US 2449615 A US2449615 A US 2449615A
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
- C10G1/02—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal by distillation
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S48/00—Gas: heating and illuminating
- Y10S48/04—Powdered fuel injection
Definitions
- I preferably employ two, or a multiple of two, distillation vesselsto maintain continuity of operation so that while one vessel is undergoing shale distillation, the other may undergo superheating by combustion of the iixed carbon and other combustibles of spent shale.
- I also supply during the combustion operation of the spent shale substantially sufficient heat to maintain the process during the distillation operation. If desired, however, I may inject a fuel, such as liquid hydrocarbon oil, into the spent shale just prior or during the combustion thereof, if morev heat is required than that obtained by burning olf the fixed carbon on the spent shale.
- a fuel such as liquid hydrocarbon oil
- A. further object of my invention is ⁇ to reduce raw shale to aggregates of appreciable size, say of about nut coal size, and to subject the ground shale to pyrolysis.
- a rough ground shale having an average size of say 1A inch in diameter is introduced into a hopper I and thence discharged into a distillation vessel 5 where it mixes with a quantity of hot spent shale which is maintained in a fluidized mass in the lower portion 6 of said distillation vessel 5.
- the mass is maintained in the iluidized condition by discharging a gasiform material such as steam from some suitable source thru a pipe l0, thence thru a pipe Il, thence thru a pipe i4 into the bottom portion of the lower compartment'l 6 of distillation vessel 5.
- a gasiform material such as steam from some suitable source thru a pipe l0, thence thru a pipe Il, thence thru a pipe i4 into the bottom portion of the lower compartment'l 6 of distillation vessel 5.
- valves l2l, 23 and 25 are closed and valve 21 is in open position.
- the condition prevailing within the distillation vessel 5 is that from the grid plate 30 to a substantial level corresponding to L there is a dense phase suspension or uidized mass of shale of varying size, the distillation causing some of the shale to disintegrate in situ to smaller aggregates, apparently by loss of adhesive material.
- the suspension residing in the compartment B i ⁇ snot the ordinary type of suspension in which a solid is supported in a gas, say a flowing stream of air, under such conditions that the solid material suspended in the air is swept along with the current of moving air and has no directional motion independent of the directional motion of the air stream. Rather the suspension in compartment 6 resembles a boiling liquid with some particles moving from the grid toward L and others descending from L toward the grid. 'I'his particular sort of suspension affords: very intimate and rapid mixing so that shale discharged from hopper 5 into compartment 6 is almost instantaneously mixed with spent shale or partly spent shale in compartment 6 prior to the introduction of fresh raw shale.
- a dip pipe 40 extending into compartment B is provided, and this pipe 40 carries a valve 42.
- valve 42 is open so that shale may be withdrawn thru said pipe 40 in amounts corresponding to that added thru standpipe 3 so that a considerable amount of shale may be maintained within the reaction vessel 5.
- large lumps of spent shale which collect in the vicinity of grids 30 and 30' are removed thru draw-oils 32 and 32 respectively.
- the steam and 4 45 During the discharge of hydrocarbon vapors from line 45 into cyclone separator 50, all valves except valve 14 are closed, the latter valve, of
- a temperature of about 1000 F. is maintained therein.
- 'I'his temperature is maintained by preheating the shale entering the distillation vessel 6 to a temperature of about 400 lil-500 F. in a manner which will be subsequently explained, and causing the spent shale andthe shale added to distillation vessel 5 to be so proportioned that there is present during the distillation about 2 lbs. of spent shale per pound of raw shale, the temperature of the spent shale immediately following the completion of the burning operation being within the range of about 1000 F.1300 F.
- the mixture By adding preheated raw shale to this spent shale in the proportions indicated, the mixture will have a temperature of about 1000 F. and this temperature gives good results. It is pointed out, however, that good results are also obtained by using a distillation range of from 800 F.-l200 F. and -by properly adjusting conditions within the reaction zone.
- each t-on of said shale will normally produce about 30 gallons of oil, and I have found that good results are obtainable by permitting the shale undergoing dis tillation to remain in the distillation zone for a period of 15 seconds to one minute.
- valve 14 is closed, valve 1I is closed, and valve 12 is in open position so that the ilue gaspasses into line 82 and then passes into cyclone separator 83 where any entrained shale is separated and withdrawn from the system thru line 84, the ue gases leaving or exiting from the separator thru line 88 and passing thru a waste heat boiler 90 where a portion of their sensible heat may be recovered ior use in some part of the system or for some extraneous purpose.
- a portion of the ue gas in line 45 may be discharged thru valvedlline 92 into the bottom of the hopper I where it serves to dry and preheat the shale therein, the gases then existing thru a valved line 9
- shale is continuously discharged from hopper I thru line 4 into a second distillation vessel 5' which may be identical in all respects with vessel 5, and where in order to maintain continuity of operation of the overall process, the distillation may be carried out in vessel 5' while the shale in 5 is undergoing burning.
- valve 25 is opened to permit air to ow thru line I1 into line I6 and -thence into the bottom of vessel 6' and shortly thereafter valve 21 is closed so that only air passes thru line I6 into the bottom of vessel 6.
- a continuous method of distilling shale to recover valuable hydrocarbons therefrom which comprises establishing a iluidized mass of ilnely divided spent shale to which has been imparted a heat content adequate for distillation of raw shale, maintaining the mass in iluidized condition 'by discharging into it a gasiform material', feeding into said iiuidized mass nely divided raw shale for rapid, intima-te -admixture therewith and distillation primarily by the heat already imparted to the spent shale, withdrawing spent shale in amount corresponding in general to the amount of raw shale added, withdrawing steam and .products of distillation derived from the raw shale by the distillation eiect of the hot spent shale, dlverting the feed of raw shale to another hot duidized mass of spent shale when the heat content of the fluidized mass of spent shale being used
- the finelydivided raw shale to be distilled being preheated by contact with hot gases from combustion ofthe spent shale, generated from the spent shale occupying its original place, said hot gases being passed into the nely divided raw shale so as to pass upwardly therethrough.
- the iluidized mass undergoing distillation is a dense phase suspension in which each cubic foot of gasiform material therein contains from 8 to 40 pounds oi' shale, and in which hot spent shale at a temperature of 1000 to 1300 F. and raw shale added to the distillation vessel are so proportioned that there is present during the distillation about 2 pounds of spent shale per pound of raw shale.
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- Chemical & Material Sciences (AREA)
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- Oil, Petroleum & Natural Gas (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Description
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DISTIILATION F OIL SHALE UNDER CONDITIGNS Edwardlli Peck, Elizabeth, N. L', asslgnor to Standard Oll Development Company, a corporation of Delaware Application August 14, 1942, Serial No. 454,756
z claimt (ci. 2oz-14) ously and in which operation the shale is subjected to a high degree of heat in the form of relatively large aggregates, thus obviating the necessity of line grinding of the shale; furthermore, I operate the process in such a manner that the pyrolysis is effected rapidly, so that valuable hydrocarbon oil released during pyrolysis of the shale is not exposed to high temperatures in the reaction zone for too long a time and hence deterioration and degradation of said products are avoided.
According to my present invention, I have provided means forcausing the shale to undergo distillation rapidly to produce valuable hydrocarbon oils, such as oils boiling within the gasoline motor fuel range, and in brief compass, my improvements in oil shale distillation involve subjecting the shale to pyrolysis in the form of a roughly ground fiuldized mass admixed with hot spent shale, which latter material provides heat useful in the distillation of the fresh shale. In my operation I preferably employ two, or a multiple of two, distillation vesselsto maintain continuity of operation so that while one vessel is undergoing shale distillation, the other may undergo superheating by combustion of the iixed carbon and other combustibles of spent shale. By thus operating the process in what might be termed a blow and run" type of manipulation,
I maintain continuity of the overall process, as
indicated, and I also supply during the combustion operation of the spent shale substantially sufficient heat to maintain the process during the distillation operation. If desired, however, I may inject a fuel, such as liquid hydrocarbon oil, into the spent shale just prior or during the combustion thereof, if morev heat is required than that obtained by burning olf the fixed carbon on the spent shale.
It is therefore an object of my present invention to perform shale pyrolysis rapidly and under conditions where excessive deterioration of the product is avoided.
A. further object of my invention is `to reduce raw shale to aggregates of appreciable size, say of about nut coal size, and to subject the ground shale to pyrolysis.
Other and further objects of my present inven- 2 tion will appear from the following more detailed description and claims.
Referring in detail to the drawing, a rough ground shale having an average size of say 1A inch in diameter is introduced into a hopper I and thence discharged into a distillation vessel 5 where it mixes with a quantity of hot spent shale which is maintained in a fluidized mass in the lower portion 6 of said distillation vessel 5. The mass is maintained in the iluidized condition by discharging a gasiform material such as steam from some suitable source thru a pipe l0, thence thru a pipe Il, thence thru a pipe i4 into the bottom portion of the lower compartment'l 6 of distillation vessel 5. Obviously during this particular ow of steam fromv line Il) into vessel 5,'
valves l2l, 23 and 25 are closed and valve 21 is in open position. Located near the bottom of vessel 5 is a grid plate 3U thru which the incoming steam passes upwardly and by maintaining the linear velocity of the up-owing steam in compartment 6 of vessel 5 withinw the range of from 2e8 it. per second with the particle size specified, a sort of dense phase suspension is maintained within the said compartment 6, that is to say, each cubic foot of steam and gas released during the distillation contains from 8-40 lbs. of shale perI cubic foot of total gas and vapors. Therefore, the condition prevailing within the distillation vessel 5 is that from the grid plate 30 to a substantial level corresponding to L there is a dense phase suspension or uidized mass of shale of varying size, the distillation causing some of the shale to disintegrate in situ to smaller aggregates, apparently by loss of adhesive material. Above L there is a solid-disengaging space where the greater internal diameter of the distillation vessel in this region causes the gas and vapor velocity to slow down so that the main bulk, at least, of the shale remains in the compartment 6, so that the vapors eventually exiting thru 35 are substantially free of entrained powdered material, or at most, contain small amounts of shale. It should be pointed out that the suspension residing in the compartment B i`snot the ordinary type of suspension in which a solid is supported in a gas, say a flowing stream of air, under such conditions that the solid material suspended in the air is swept along with the current of moving air and has no directional motion independent of the directional motion of the air stream. Rather the suspension in compartment 6 resembles a boiling liquid with some particles moving from the grid toward L and others descending from L toward the grid. 'I'his particular sort of suspension affords: very intimate and rapid mixing so that shale discharged from hopper 5 into compartment 6 is almost instantaneously mixed with spent shale or partly spent shale in compartment 6 prior to the introduction of fresh raw shale.
It will be noted that a dip pipe 40 extending into compartment B is provided, and this pipe 40 carries a valve 42. Normally, during the distillation operation valve 42 is open so that shale may be withdrawn thru said pipe 40 in amounts corresponding to that added thru standpipe 3 so that a considerable amount of shale may be maintained within the reaction vessel 5. However, large lumps of spent shale which collect in the vicinity of grids 30 and 30' are removed thru draw- oils 32 and 32 respectively. The steam and 4 45. During the discharge of hydrocarbon vapors from line 45 into cyclone separator 50, all valves except valve 14 are closed, the latter valve, of
course, being open. When, however, ilue gas is products oi' distillation are withdrawn overheadl thru line 45 and thence discharged by line 41 and line 48 into a cyclone separator 50' where the last traces of shale may be removed from the vapors rejected from the system thru draw-of! pipe 52. The gases and vapors, on the other hand, are withdrawn from the cyclone separator thru line 55 and delivered to fractionating and distillation equipment to recover desired products. The fractionating and recovering of desired products may be carried out in a conventional manner and is not shown in the drawing.
Referring again to reaction vessel 5, and particularly with respect to the conditions maintained therein, it is pointed out that a temperature of about 1000 F. is maintained therein. 'I'his temperature is maintained by preheating the shale entering the distillation vessel 6 to a temperature of about 400 lil-500 F. in a manner which will be subsequently explained, and causing the spent shale andthe shale added to distillation vessel 5 to be so proportioned that there is present during the distillation about 2 lbs. of spent shale per pound of raw shale, the temperature of the spent shale immediately following the completion of the burning operation being within the range of about 1000 F.1300 F. By adding preheated raw shale to this spent shale in the proportions indicated, the mixture will have a temperature of about 1000 F. and this temperature gives good results. It is pointed out, however, that good results are also obtained by using a distillation range of from 800 F.-l200 F. and -by properly adjusting conditions within the reaction zone.
Employing an Australian shale, each t-on of said shale will normally produce about 30 gallons of oil, and I have found that good results are obtainable by permitting the shale undergoing dis tillation to remain in the distillation zone for a period of 15 seconds to one minute.
During the operation described there normally comes a time when due to temperature drops, the operation in vessel 5 must be discontinued and this is accomplished by closing the valve in line 3 and, at the same time, closing valve 42 in line 40. A minute or so later, or after permitting suilicient time to complete the distillation and to remove recoverable hydrocarbons, air is admitted from line 60 to line 6I by opening valve 23. This air flows with the steam from line I I into line I4 and thence into the bottom of the reaction vessel 5. Shortly thereafter valve 21 is closed so that only air is discharged into the bottom of vessel 5. This air, which may be at ordinary atmospheric temperature as its enters thru line 60, causes a combustion of the combustibles remaining in the spent shale which are carbonaceous in nature, and
the combustion products flow upwardly thru line discharged from line 45 into line 41, valve 14 is closed, valve 1I is closed, and valve 12 is in open position so that the ilue gaspasses into line 82 and then passes into cyclone separator 83 where any entrained shale is separated and withdrawn from the system thru line 84, the ue gases leaving or exiting from the separator thru line 88 and passing thru a waste heat boiler 90 where a portion of their sensible heat may be recovered ior use in some part of the system or for some extraneous purpose. However, a portion of the ue gas in line 45 may be discharged thru valvedlline 92 into the bottom of the hopper I where it serves to dry and preheat the shale therein, the gases then existing thru a valved line 9|.
During the combustion of the spent shale in vessel 5, shale is continuously discharged from hopper I thru line 4 into a second distillation vessel 5' which may be identical in all respects with vessel 5, and where in order to maintain continuity of operation of the overall process, the distillation may be carried out in vessel 5' while the shale in 5 is undergoing burning.
In the drawing, I have shown the corresponding parts of vessel 5 and have indicated them by employing the same reference characters carrying a prime mark. It is believed unnecessary to repeat the operation carried out in vessel 5 because it is substantially identical in all particulars to that previously described as carried out in vessel 5. In supplying steam to vessel E', however, it should be pointed out that ste-am entering thru line I0 passes xthru line I5 and then-ce thru a line I6 into the bottom of the reactor. This ow is accomplished by opening valve 2| and closing valves 23, 25 and 21. At the conclusion of the distillation operation in vessel 6', valve 25 is opened to permit air to ow thru line I1 into line I6 and -thence into the bottom of vessel 6' and shortly thereafter valve 21 is closed so that only air passes thru line I6 into the bottom of vessel 6.
With respect to the distillation products resulting from the distillation operation in distillation vessel 5', the same are withdrawn thru line 45 and discharged into cyclone separator 50 by opening valve 13, valves 1I and 14 being' in closed .posicontinuity of operation in a process of the type herein described, two or more reactors are required so that while one or more are undergoing burning of the spent shale, the other may be employed in the productive phase. It is possible, according to the operation which I have shown. to provide sufficient heat within the process itself to support the ydistillation of the shale, although in.
44ans that more than simple distillation is involved. In the appended claims I have referred to the operation as being pyrolytic, and by that term I mean toI imply that the operation may-be simple distillation, destructive distillation. metathetical or effected in some other manner caused by the application of heat.
Many modifications of my invention will readily suggest themselves to those who are familiar with this art.
What I claim is:
1. A continuous method of distilling shale to recover valuable hydrocarbons therefrom, which comprises establishing a iluidized mass of ilnely divided spent shale to which has been imparted a heat content adequate for distillation of raw shale, maintaining the mass in iluidized condition 'by discharging into it a gasiform material', feeding into said iiuidized mass nely divided raw shale for rapid, intima-te -admixture therewith and distillation primarily by the heat already imparted to the spent shale, withdrawing spent shale in amount corresponding in general to the amount of raw shale added, withdrawing steam and .products of distillation derived from the raw shale by the distillation eiect of the hot spent shale, dlverting the feed of raw shale to another hot duidized mass of spent shale when the heat content of the fluidized mass of spent shale being used for distillation has dropped to a point where it is no longer effective for such purpose, passing an oxygen-containing gas intothe mass of spent shale from which the feed of raw shale has been diverted, whereby the iluidized state is maintained and combustion of residual carbonaceous com- Iponents of the spent shale is caused to take place,
'withdrawing products of combustion, and again feeding raw shale into the iluidized mass of spent shale when it has reached the proper temperature for further use in distillation, the finelydivided raw shale to be distilled being preheated by contact with hot gases from combustion ofthe spent shale, generated from the spent shale occupying its original place, said hot gases being passed into the nely divided raw shale so as to pass upwardly therethrough.
2. Process according to claim 1, in which the iluidized mass undergoing distillation is a dense phase suspension in which each cubic foot of gasiform material therein contains from 8 to 40 pounds oi' shale, and in which hot spent shale at a temperature of 1000 to 1300 F. and raw shale added to the distillation vessel are so proportioned that there is present during the distillation about 2 pounds of spent shale per pound of raw shale.
EDWARD B. PECK.
REFERNCES CITED The following references are of record in the file of this patent:
UNITED STATES PATENTS Y Number Name Date 1,432,101' Danckwardt Oct. 17, 1922 1,484,256 Fenton Feb. 19, 1924 1,732,219 Bierregaard Oct. 22, 1929 1,774,391 McKee Aug. .26, 1930 1,899,887 'Thiele Feb. 28, 1933 1,972,833 Subkow Sept. 4, 1934 1,983,943 Odell Dec. 11, 1934 1,984,380 Odell Dec. 18, 1934 2,327,175
Conn Aug. 17, 1943
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US454756A US2449615A (en) | 1942-08-14 | 1942-08-14 | Distillation of oil shale under fluidized conditions |
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US454756A US2449615A (en) | 1942-08-14 | 1942-08-14 | Distillation of oil shale under fluidized conditions |
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Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2544912A (en) * | 1946-05-29 | 1951-03-13 | Texas Co | Shale distillation with fluidized residue treatment |
US2586703A (en) * | 1946-11-01 | 1952-02-19 | Standard Oil Dev Co | Shale distillation |
US2626234A (en) * | 1949-06-11 | 1953-01-20 | Standard Oil Dev Co | Heat exchange of fluidized solids with gases and vapors |
US2664338A (en) * | 1950-08-25 | 1953-12-29 | Gulf Oil Corp | Line and valve system for fluidized particle handling |
US2738315A (en) * | 1951-10-31 | 1956-03-13 | Esso Res And Eugineering Compa | Shale distillation |
US3505201A (en) * | 1967-01-27 | 1970-04-07 | Alberta Res Council | Separation of coal-oil suspensions |
US3972801A (en) * | 1974-10-29 | 1976-08-03 | Cities Service Research & Development Co. | Oil shale retorting |
Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1432101A (en) * | 1922-10-17 | dangkwardt | ||
US1484256A (en) * | 1922-08-24 | 1924-02-19 | James T Fenton | Intermittent system for treatment of coal |
US1732219A (en) * | 1924-11-18 | 1929-10-22 | Doherty Res Co | Production of hydrocarbons from oil shale |
US1774391A (en) * | 1922-02-14 | 1930-08-26 | Ralph H Mckee | Method and apparatus for distilling shale |
US1899887A (en) * | 1928-05-14 | 1933-02-28 | Ernest w | |
US1972833A (en) * | 1925-10-17 | 1934-09-04 | Subkow Philip | Continuous process for making carbureted water gas |
US1983943A (en) * | 1929-12-17 | 1934-12-11 | William W Odell | Process for carbonizing carbonaceous materials |
US1984380A (en) * | 1929-12-17 | 1934-12-18 | William W Odell | Process of producing chemical reactions |
US2327175A (en) * | 1941-10-31 | 1943-08-17 | Standard Oil Co | Catalyst control in hydrocarbon conversion |
-
1942
- 1942-08-14 US US454756A patent/US2449615A/en not_active Expired - Lifetime
Patent Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1432101A (en) * | 1922-10-17 | dangkwardt | ||
US1774391A (en) * | 1922-02-14 | 1930-08-26 | Ralph H Mckee | Method and apparatus for distilling shale |
US1484256A (en) * | 1922-08-24 | 1924-02-19 | James T Fenton | Intermittent system for treatment of coal |
US1732219A (en) * | 1924-11-18 | 1929-10-22 | Doherty Res Co | Production of hydrocarbons from oil shale |
US1972833A (en) * | 1925-10-17 | 1934-09-04 | Subkow Philip | Continuous process for making carbureted water gas |
US1899887A (en) * | 1928-05-14 | 1933-02-28 | Ernest w | |
US1983943A (en) * | 1929-12-17 | 1934-12-11 | William W Odell | Process for carbonizing carbonaceous materials |
US1984380A (en) * | 1929-12-17 | 1934-12-18 | William W Odell | Process of producing chemical reactions |
US2327175A (en) * | 1941-10-31 | 1943-08-17 | Standard Oil Co | Catalyst control in hydrocarbon conversion |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2544912A (en) * | 1946-05-29 | 1951-03-13 | Texas Co | Shale distillation with fluidized residue treatment |
US2586703A (en) * | 1946-11-01 | 1952-02-19 | Standard Oil Dev Co | Shale distillation |
US2626234A (en) * | 1949-06-11 | 1953-01-20 | Standard Oil Dev Co | Heat exchange of fluidized solids with gases and vapors |
US2664338A (en) * | 1950-08-25 | 1953-12-29 | Gulf Oil Corp | Line and valve system for fluidized particle handling |
US2738315A (en) * | 1951-10-31 | 1956-03-13 | Esso Res And Eugineering Compa | Shale distillation |
US3505201A (en) * | 1967-01-27 | 1970-04-07 | Alberta Res Council | Separation of coal-oil suspensions |
US3972801A (en) * | 1974-10-29 | 1976-08-03 | Cities Service Research & Development Co. | Oil shale retorting |
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