US2442024A - Cleaning and polishing composition - Google Patents
Cleaning and polishing composition Download PDFInfo
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- US2442024A US2442024A US2442024DA US2442024A US 2442024 A US2442024 A US 2442024A US 2442024D A US2442024D A US 2442024DA US 2442024 A US2442024 A US 2442024A
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- water
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- 239000000203 mixture Substances 0.000 title description 22
- 238000004140 cleaning Methods 0.000 title description 9
- 238000005498 polishing Methods 0.000 title description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 17
- 239000002904 solvent Substances 0.000 description 14
- 239000006185 dispersion Substances 0.000 description 13
- 239000004215 Carbon black (E152) Substances 0.000 description 12
- 229930195733 hydrocarbon Natural products 0.000 description 12
- 150000002430 hydrocarbons Chemical class 0.000 description 12
- -1 2-ethyl-hexyl Chemical group 0.000 description 11
- 239000004615 ingredient Substances 0.000 description 10
- 150000003839 salts Chemical class 0.000 description 9
- 239000002689 soil Substances 0.000 description 8
- WCWLEIAMBPYRFJ-UHFFFAOYSA-N 3-methylbutyl dihydrogen phosphate Chemical compound CC(C)CCOP(O)(O)=O WCWLEIAMBPYRFJ-UHFFFAOYSA-N 0.000 description 7
- 229910052751 metal Inorganic materials 0.000 description 7
- 239000002184 metal Substances 0.000 description 7
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical class OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 6
- 239000004927 clay Substances 0.000 description 5
- 230000007797 corrosion Effects 0.000 description 5
- 238000005260 corrosion Methods 0.000 description 5
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- 239000005909 Kieselgur Substances 0.000 description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 239000001993 wax Substances 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- 150000001412 amines Chemical class 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- GPRLSGONYQIRFK-UHFFFAOYSA-N hydron Chemical compound [H+] GPRLSGONYQIRFK-UHFFFAOYSA-N 0.000 description 3
- 125000001972 isopentyl group Chemical class [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])C([H])([H])* 0.000 description 3
- 239000002480 mineral oil Substances 0.000 description 3
- 235000010446 mineral oil Nutrition 0.000 description 3
- 159000000000 sodium salts Chemical class 0.000 description 3
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 2
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 2
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 2
- QUSNBJAOOMFDIB-UHFFFAOYSA-N Ethylamine Chemical compound CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 description 2
- 239000000908 ammonium hydroxide Substances 0.000 description 2
- 230000000844 anti-bacterial effect Effects 0.000 description 2
- 239000003899 bactericide agent Substances 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 239000004203 carnauba wax Substances 0.000 description 2
- 235000013869 carnauba wax Nutrition 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- 239000004519 grease Substances 0.000 description 2
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 2
- 235000011007 phosphoric acid Nutrition 0.000 description 2
- 150000003139 primary aliphatic amines Chemical class 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 2
- 244000215068 Acacia senegal Species 0.000 description 1
- 235000006491 Acacia senegal Nutrition 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 241000416162 Astragalus gummifer Species 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
- 229920000084 Gum arabic Polymers 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 229920001615 Tragacanth Polymers 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 239000003082 abrasive agent Substances 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 125000002723 alicyclic group Chemical group 0.000 description 1
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000000337 buffer salt Substances 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 229940043237 diethanolamine Drugs 0.000 description 1
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical class CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- JRBPAEWTRLWTQC-UHFFFAOYSA-N dodecylamine Chemical compound CCCCCCCCCCCCN JRBPAEWTRLWTQC-UHFFFAOYSA-N 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 229940031098 ethanolamine Drugs 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 239000001048 orange dye Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- ARENMZZMCSLORU-UHFFFAOYSA-N propan-2-yl naphthalene-1-sulfonate Chemical compound C1=CC=C2C(S(=O)(=O)OC(C)C)=CC=CC2=C1 ARENMZZMCSLORU-UHFFFAOYSA-N 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 229910000406 trisodium phosphate Inorganic materials 0.000 description 1
- 235000019801 trisodium phosphate Nutrition 0.000 description 1
- 229960004418 trolamine Drugs 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/18—Hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/36—Organic compounds containing phosphorus
- C11D3/361—Phosphonates, phosphinates or phosphonites
Definitions
- This invention relates to new compositions of matter which are particularly useful for cleaning and polishing the coated metal surfaces of automobile bodies and the like.
- One object of this invention is to prepare a cleaner and polish which will readily remove various kinds of soil from coated metal surfaces.
- a further object of this invention is to manufacmm a, cleaner and polish which will not corrode the metal surfaces of cans in which it is stored.
- a still further object is to make a cleaner and polish which will impart a. pleasing appearance to surfaces to which it is applied. Other objects will appear hereinafter.
- a cleaner and polish which comprises an aqueous dispersion having a pH in the range of 6 to 8 and containing a hydrocarbon solvent and an abrasive powder dispersed in the water and also containing a water-insoluble higher aliphatic amine salt of 2-ethyl-hexyl, 3-methyl-but.vl ortho-phosphoric acid and a water-soluble salt of Z-ethyl-hexyl, 3-methyl-butyl ortho-phosphoric acid.
- water is used in such quantities that it constitutes at least half by wei ht of the final composition of the dispersion. The water assists in removing water-soluble soil from the coated metal surfaces of an automobile or the like.
- the hydrocarbon solvent which is dispersed in the water may be a light hydrocarbon fraction such as Stoddard solvent although somewhat higher or lower boiling mineral oil fractions may be used if desired.
- hydrocarbon solvents of the aromatic and alicyclic series such as benzen and cyclohexane may be employed. in lieu of or in addition to Stoddard solvent.
- the hydrocarbon solvent functions in the prepared cleaner to aid in the removal from the coated metal surfaces of greases and similar types of soil that are soluble in hydrocarbon solvents,
- the abrasive powder that is dispersed in our new cleaning and polishing composition is usually powdered diatomaceous earth of about 325 mesh, although any suitable abrasive powder that will stay dispersed in water may be used in its place.
- a colloidal clay such as bentonite may be added to the dispersion along with the diatomaceous earth in order to help retain the diatomaceous earth in a dis ersed condition and keep it from settling out.
- the abrasive powder assists in mechanically removing soil that adheres to the coated metal surfaces that are being cleaned.
- the hydrogen ion concentrations of the dispersions are not too high or too low. If the hydrogen ion concentration of the dispersion is too low, the polish will leave an easily Elli markable surface. On the other hand, if the hydrogen ion concentration is too high, the polished surface is not protected from corrosion and any cracks in the paint surface are accentually pictured. It is therefore necessary to maintain the pH of the dispersion somewhere in the range 6 to 8 and preferably about 7.
- the pH of the dispersion can be suitably adjusted by adding small amounts of suitable acidic or alkaline substances such as trisodium phosphate, ammonium hydroxide or aluminum sulfate.
- the pH of the dispersion can obviously by suitably adjusted to a desired value by the addition of small amounts of suitable buffer salts.
- a scenting agent may be added toimpart the desired odor to the composition.
- a dye may be added to impart the desired color to the composition.
- Glycerine or ethylene glycol may be added to the composition to lower its freezing point and to help retain the proper moisture content upon the film of polish applied to a surface,
- a bactericide such as formaldehyde or phenol may be added to the composition to stop any bacterial action that might otherwise occur.
- Gums such as gum tragacanth and gum acacia may be used in preparing these dispersions to thicken them and thereby impede any breaking of the dispersions.
- Surface active agents such as sulfonated castor oil or isopropyl naphthalene sulfonate may also be used in preparing these dispersions since surface active agents will function to stabilize the dispersion.
- a thin water repellant film it is desirable to include a small amount of a high viscosity mineral oil and/or a wax such as paraffin wax, carnauba wax or a synthetic wax in the composition of the cleaner.
- Two of the more important ingredients of the cleaning and polishing compositions of this invention are a water-insoluble higher aliphatic amine salt of 2-ethyl-hexyl, 3-methyl-butyl ortho-phosphoric acid and a Water-soluble salt of 2-ethyl hexyl, 3-methyl butyl ortho phosphoric acid,
- higher aliphatic amine salt we intend to denote a salt prepared from a primary aliphatic amine containing at least 8 carbon atoms.
- these higher aliphatic amine salts are made from primary aliphatic amines containing from 10 to 18 carbon atoms such as the normal primary decyl, dodecyl.
- cocoamlne which is a commercial mi ture of higher aliphatic amines prepared from coconut oil fatty acids. Cocoamine contains a major amount of primary dodecyl amine, and
- compositions of this invention function as corrosion inhibitors, They prevent corrosion of the cans in which the compositions of the present invention are packaged for commerce.
- the first step is to dissolve all of the water-soluble ingredients except the bactericide in the water. Then while agitating the solution the powdered abrasive and colloidal clay are slowly added thereto. Meanwhile all of the water-insoluble ingredients that are soluble in the hydrocarbon solvent are dissolved in said solvent. After all of the powdered abrasive and colloidal clay have been added to the water solution, the hydrocarbon solution of dissolved ingredients is slowly run into the water solution containing dispersed abrasive material while vigorously agitating the water solution in order to cause the hydrocarbon solvent to become emulsified in the water phase. After all of the hydrocarbon solvent has been added to the of 2-ethyl-hexyl,
- compositionofthis example has a specific Water 52-75 152 Formaldehyde, 40% solution 0. 15-0. 25 0.
- a composition of matter suitable for cleaning the coated metal surfaces of automobile bodies which comprises a major amount of water, Stoddard solvent dispersed in the water in an amount suillcient to assist in removal of grease and other hydrocarbon soluble soil, powdered diatomaceous earth dispersed in the water in an amount sufllcient to assist in mechanically removing soil, and small amounts, suflicient t inhibit corrosion, of the cocoamine salt of2-ethylhexyl, 3-methyl-butyl .ortho phosphoric acid and the sodium salt of 2-ethyl-hexyl, 3-methylbutyl ortho-phosphoric acid, said composition having a pH of about 7.
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Description
Patented May 25, 1948 CLEANING: AND POLISHING COMPOSITION Herschel G. Smith, Wallingford, Mark L. Hill, Yeadon, and Troy L. Cantrell, Lansdowne, Pa., assignors to Gulf Oil Corporation, Pittsburgh, Pa., a corporation of Pennsylvania No Drawing. ApplicationFebruai-y 15, 1946, Serial No. 648,010
2 Claims. (Cl. 252-166) This invention relates to new compositions of matter which are particularly useful for cleaning and polishing the coated metal surfaces of automobile bodies and the like.
One object of this invention is to prepare a cleaner and polish which will readily remove various kinds of soil from coated metal surfaces. A further object of this invention is to manufacmm a, cleaner and polish which will not corrode the metal surfaces of cans in which it is stored. A still further object is to make a cleaner and polish which will impart a. pleasing appearance to surfaces to which it is applied. Other objects will appear hereinafter.
These objects are accomplished in accordance with the present invention by manufacturing a cleaner and polish which comprises an aqueous dispersion having a pH in the range of 6 to 8 and containing a hydrocarbon solvent and an abrasive powder dispersed in the water and also containing a water-insoluble higher aliphatic amine salt of 2-ethyl-hexyl, 3-methyl-but.vl ortho-phosphoric acid and a water-soluble salt of Z-ethyl-hexyl, 3-methyl-butyl ortho-phosphoric acid. In formulating such a dispersion, water is used in such quantities that it constitutes at least half by wei ht of the final composition of the dispersion. The water assists in removing water-soluble soil from the coated metal surfaces of an automobile or the like.
The hydrocarbon solvent which is dispersed in the water may be a light hydrocarbon fraction such as Stoddard solvent although somewhat higher or lower boiling mineral oil fractions may be used if desired. Likewise, hydrocarbon solvents of the aromatic and alicyclic series such as benzen and cyclohexane may be employed. in lieu of or in addition to Stoddard solvent. The hydrocarbon solvent functions in the prepared cleaner to aid in the removal from the coated metal surfaces of greases and similar types of soil that are soluble in hydrocarbon solvents,
The abrasive powder that is dispersed in our new cleaning and polishing composition is usually powdered diatomaceous earth of about 325 mesh, although any suitable abrasive powder that will stay dispersed in water may be used in its place. A colloidal clay such as bentonite may be added to the dispersion along with the diatomaceous earth in order to help retain the diatomaceous earth in a dis ersed condition and keep it from settling out. The abrasive powder assists in mechanically removing soil that adheres to the coated metal surfaces that are being cleaned.
In preparing the cleaning and polishing compositions of the present invention it is important to take care that the hydrogen ion concentrations of the dispersions are not too high or too low. If the hydrogen ion concentration of the dispersion is too low, the polish will leave an easily Elli markable surface. On the other hand, if the hydrogen ion concentration is too high, the polished surface is not protected from corrosion and any cracks in the paint surface are accentually pictured. It is therefore necessary to maintain the pH of the dispersion somewhere in the range 6 to 8 and preferably about 7. The pH of the dispersion can be suitably adjusted by adding small amounts of suitable acidic or alkaline substances such as trisodium phosphate, ammonium hydroxide or aluminum sulfate. The pH of the dispersion can obviously by suitably adjusted to a desired value by the addition of small amounts of suitable buffer salts.
Various miscellaneous ingredients may be included in the cleaning and polishing compositions of the present invention to accomplish certain particular objectives. A scenting agent may be added toimpart the desired odor to the composition. A dye may be added to impart the desired color to the composition. Glycerine or ethylene glycol may be added to the composition to lower its freezing point and to help retain the proper moisture content upon the film of polish applied to a surface, A bactericide such as formaldehyde or phenol may be added to the composition to stop any bacterial action that might otherwise occur. Gums such as gum tragacanth and gum acacia may be used in preparing these dispersions to thicken them and thereby impede any breaking of the dispersions. Surface active agents such as sulfonated castor oil or isopropyl naphthalene sulfonate may also be used in preparing these dispersions since surface active agents will function to stabilize the dispersion.
In order that the surface being cleaned will at the same time be coated with a thin water repellant film it is desirable to include a small amount of a high viscosity mineral oil and/or a wax such as paraffin wax, carnauba wax or a synthetic wax in the composition of the cleaner.
Two of the more important ingredients of the cleaning and polishing compositions of this invention are a water-insoluble higher aliphatic amine salt of 2-ethyl-hexyl, 3-methyl-butyl ortho-phosphoric acid and a Water-soluble salt of 2-ethyl hexyl, 3-methyl butyl ortho phosphoric acid, By the term higher aliphatic amine salt we intend to denote a salt prepared from a primary aliphatic amine containing at least 8 carbon atoms. Preferably these higher aliphatic amine salts are made from primary aliphatic amines containing from 10 to 18 carbon atoms such as the normal primary decyl, dodecyl. tetradecyl, hexadecyl and octadecyl amines. Mixtures of these amines may be used such as cocoamlne which is a commercial mi ture of higher aliphatic amines prepared from coconut oil fatty acids. Cocoamine contains a major amount of primary dodecyl amine, and
typical samples thereof have been found to have average molecular weights ranging from 200 to 210. Among the various water-soluble salts of 2- ethyl-hexyl, 3-methyl-butyl orth -phosph0ric acid which may be'usedin these compositions there may be mentioned the sodium, potassium, ammonium, and substituted ammonium salts prepared from such amines as -methyl amine, dimethyl amine, trimethyl amine, ethyl amine,
ethanol amine, diethanol amine, triethanol amine,,propano1 amine, etc. Both the water-insoluble higher ialiphatic amine salts and the water-soluble salts oi Z-ethyl-hexyl, 3-methylbutyl ortho-phosphoric acid which are used in. the compositions of this invention function as corrosion inhibitors, They prevent corrosion of the cans in which the compositions of the present invention are packaged for commerce.
In preparing the cleaning and polishing com positions of the present invention the first step is to dissolve all of the water-soluble ingredients except the bactericide in the water. Then while agitating the solution the powdered abrasive and colloidal clay are slowly added thereto. Meanwhile all of the water-insoluble ingredients that are soluble in the hydrocarbon solvent are dissolved in said solvent. After all of the powdered abrasive and colloidal clay have been added to the water solution, the hydrocarbon solution of dissolved ingredients is slowly run into the water solution containing dispersed abrasive material while vigorously agitating the water solution in order to cause the hydrocarbon solvent to become emulsified in the water phase. After all of the hydrocarbon solvent has been added to the of 2-ethyl-hexyl,
hended by the present invention. 'These examples also indicate tolerable limits within which the amount of any ingredient in the composition may be varied. If the limit of any ingredient to be used is indicated to 'be "q. s., that means that only enough of this ingredient is to be used to produce the desired efl'ect such as odor, color or pH. The preferred amount and tolerable limits of any ingredient are stated in the following examples in terms of its percentage by weight of the entire composition.
Example I Tolerable Preferred ingredients Limits Amount A Water 52-75 64. Glycerine 0-4 4. Formaldehyde, 40% solution 0. 15-0. 25 0. Sodium salt of Z-ethyl-hexyl, 3-methylbutyl ortho-phosphorle acid 0. 001-1. 0 0. Trlsodium phosphate q. s 0. Diatomaoeous earth, 325 mesh 3-20 10. Colloidal clay, 300mesh 0 1-i0.0 2. Stoddard solvent 5-20 9. Mineral oil, 50 S U; S. at F 5-15 7. Scouting agent q. s. 0. Cocoamine salt of 2-ethyl-hexyl, a-methylbutyl ortho-phosphorlc acid 0. 001-1. 0 0.
The compositionofthis example has a specific Water 52-75 152 Formaldehyde, 40% solution 0. 15-0. 25 0.
Sodium salt 0! il-ethyl-hexyl, B-methylbutyl ortho-phosphorlc acid. 0. 001-1. 0 0. 200 Ammonium hydroxide q. s. 0. 023 Gum tragacanth-. 0.1-0.5 0.150 Sullonated caster o 0. 1-0. 5 0. 300 Diatomaoeons earth, 325 mesh 3-7 5. 000 Colloidal clay, 300 mesh... 0 1-10. 0. 1. 000 S derd solvent 4-.. 5-15 11. 800 Paraflln Type Naphths, B. R. 400-500 F. 2-10 8.000. Carnauba wax, No. 3N Country Refined. 1-4 2.000 Paraflln wax, melting at 122 F 0. 5-2.0 1. 000 V. G. Synthetic wax 0. 5-1. 5 1.000 Gasoline-soluble orange dye. q. s 0. 005 Scent 1 agent q. s 0. 020
C n 1 e salt of Z-ethyl-hexgl, a-methylbutyl ortho-phosplioric aci 0. 001-1 0 0. 200
an amount suificient to assist in, removal of grease and other hydrocarbon soluble soil, an abrasive powder-dispersed in the water in an amount sufflclent to assist in mechanically removing soil, and small amounts, suflicient to inhibit corrosion, of a water-insoluble higher aliphatic amine salt 3-methyl-butyl ortho-phosphoric acid and a water-soluble salt of 2-ethylhexyl, 3-methyl-butyl ortho-phosphoric acid, said composition having a pH in the range 6 to 8.
2. A composition of matter suitable for cleaning the coated metal surfaces of automobile bodies which comprises a major amount of water, Stoddard solvent dispersed in the water in an amount suillcient to assist in removal of grease and other hydrocarbon soluble soil, powdered diatomaceous earth dispersed in the water in an amount sufllcient to assist in mechanically removing soil, and small amounts, suflicient t inhibit corrosion, of the cocoamine salt of2-ethylhexyl, 3-methyl-butyl .ortho phosphoric acid and the sodium salt of 2-ethyl-hexyl, 3-methylbutyl ortho-phosphoric acid, said composition having a pH of about 7.
A HERscHIm G. SMITH.
MARK L. HILL. 'Ill'ltOY L. CAN-TRELL.
REFERENCES CITED The following references are of record in the v file of this patent:
UNITED STATES PATENTS 212,439 Great Britain Mar. 13, 1924
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US2442024A true US2442024A (en) | 1948-05-25 |
Family
ID=3435890
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US2442024D Expired - Lifetime US2442024A (en) | Cleaning and polishing composition |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US2442024A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2602049A (en) * | 1948-12-24 | 1952-07-01 | Gulf Oil Corp | Antioxidants for mineral oil lubricants and compositions containing the same |
| US3418243A (en) * | 1965-01-04 | 1968-12-24 | Bissell Inc | Art of cleaning carpets |
| US9657256B2 (en) * | 2015-09-14 | 2017-05-23 | Mega Products, Llc | Environmentally safe porcelain cleaning formulation, method and kit |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB212439A (en) * | 1923-04-13 | 1924-03-13 | Thomas Edward Stanton | A cleaning fluid for glass, porcelain, and the like |
| US1675227A (en) * | 1922-12-26 | 1928-06-26 | Austin B Reeve | Cleaning and polishing composition |
| US2371655A (en) * | 1941-12-06 | 1945-03-20 | Gulf Oil Corp | Lubricant compositions |
| US2374113A (en) * | 1943-11-19 | 1945-04-17 | Pennsylvania Salt Mfg Co | Solvent emulsion cleaner |
-
0
- US US2442024D patent/US2442024A/en not_active Expired - Lifetime
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1675227A (en) * | 1922-12-26 | 1928-06-26 | Austin B Reeve | Cleaning and polishing composition |
| GB212439A (en) * | 1923-04-13 | 1924-03-13 | Thomas Edward Stanton | A cleaning fluid for glass, porcelain, and the like |
| US2371655A (en) * | 1941-12-06 | 1945-03-20 | Gulf Oil Corp | Lubricant compositions |
| US2374113A (en) * | 1943-11-19 | 1945-04-17 | Pennsylvania Salt Mfg Co | Solvent emulsion cleaner |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2602049A (en) * | 1948-12-24 | 1952-07-01 | Gulf Oil Corp | Antioxidants for mineral oil lubricants and compositions containing the same |
| US3418243A (en) * | 1965-01-04 | 1968-12-24 | Bissell Inc | Art of cleaning carpets |
| US9657256B2 (en) * | 2015-09-14 | 2017-05-23 | Mega Products, Llc | Environmentally safe porcelain cleaning formulation, method and kit |
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