US2430499A - Composition containing polyvinyl alcohol and lauryl pyridinium chloride - Google Patents
Composition containing polyvinyl alcohol and lauryl pyridinium chloride Download PDFInfo
- Publication number
- US2430499A US2430499A US520556A US52055644A US2430499A US 2430499 A US2430499 A US 2430499A US 520556 A US520556 A US 520556A US 52055644 A US52055644 A US 52055644A US 2430499 A US2430499 A US 2430499A
- Authority
- US
- United States
- Prior art keywords
- polyvinyl alcohol
- pyridinium chloride
- composition containing
- lauryl pyridinium
- containing polyvinyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000004372 Polyvinyl alcohol Substances 0.000 title description 13
- 229920002451 polyvinyl alcohol Polymers 0.000 title description 13
- GKQHIYSTBXDYNQ-UHFFFAOYSA-M 1-dodecylpyridin-1-ium;chloride Chemical compound [Cl-].CCCCCCCCCCCC[N+]1=CC=CC=C1 GKQHIYSTBXDYNQ-UHFFFAOYSA-M 0.000 title description 5
- 239000000203 mixture Substances 0.000 title description 2
- 229940068984 polyvinyl alcohol Drugs 0.000 description 12
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 12
- 239000000243 solution Substances 0.000 description 6
- 125000002091 cationic group Chemical group 0.000 description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 239000004744 fabric Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 230000000069 prophylactic effect Effects 0.000 description 1
- JUJWROOIHBZHMG-UHFFFAOYSA-O pyridinium Chemical compound C1=CC=[NH+]C=C1 JUJWROOIHBZHMG-UHFFFAOYSA-O 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/02—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D01F6/14—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds from polymers of unsaturated alcohols, e.g. polyvinyl alcohol, or of their acetals or ketals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3412—Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
- C08K5/3432—Six-membered rings
Definitions
- Our invention relates to the manufacture of filaments and particularly yarns from water solutions of polyvinyl alcohol.
- manufacture of such yarns it has been found that they do not have the requisite feel. but tend to be harsh and stiff and that fabrics made from them do not drape satisfactorily.
- glycerin and ethylene glycol have been added in an attempt to improve these qualities of the yarn, but these materials are unsatisfactory because they reduce the tensile strength substantially.
- lauryl pyridinium chloride is effective to improve the feed of polyvinyl alcohol yarn and the drape of cloth made from it, even when employed in quantities as small as 0.25% on the amount of polyvinyl alcohol in the.
- the modifying material as purchased in the open market may contain some free amine which tends to injure any copper fittings in the equipment. Therefore, it is advisable to neutralize such free amine by the addition of small quantities of sulfuric acid, hydrochloric or other suitable acids or acid salts.
- a filament forming solution comprising an aqueous solution of polyvinyl alcohol and a small quantity of lauryl pyridinium chloride, the amount of the chloride being from 0.25 to 2.50 per cent by weight of the polyvinyl alcohol.
- a filament comprising polyvinyl alcohol and a small quantity of lauryl pyridinlum chloride, the amount of chloride being from 0.25 to 2.50 per cent by weight of the polyvinylalcohol.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Description
atented Nov. 11, 1947 COMPOSITION CONTAINING LAURYL ALCOHOL AND CHLORIDE POLYVINYL PYRIDINIUM Gustavus J. Esselen, Swampscott, and Martin H. Gurley, Jr., Newton Center, Mass, assignors, by mesne assignments, to Pro-phy-lac-tic Brush Company,'Northampton, Mass, a corporation of Delaware No Drawing Application January 31', 1944, Serial No. 520,556
2 Claims.
Our invention relates to the manufacture of filaments and particularly yarns from water solutions of polyvinyl alcohol. Heretofore in the manufacture of such yarns, it has been found that they do not have the requisite feel. but tend to be harsh and stiff and that fabrics made from them do not drape satisfactorily. Heretofore, glycerin and ethylene glycol have been added in an attempt to improve these qualities of the yarn, but these materials are unsatisfactory because they reduce the tensile strength substantially. We have discovered that lauryl pyridinium chloride is effective to improve the feed of polyvinyl alcohol yarn and the drape of cloth made from it, even when employed in quantities as small as 0.25% on the amount of polyvinyl alcohol in the.
solution. The nature of lauryl pyridinium chloride and similar salts is disclosed in United States Patent No. 2, 04,728, January 11, 1938, to Bertsch 8: Stober. I
In the experimental search to find some means of improving the feel 01' polyvinyl alcohol filaments, various anionic and cationic surface active substances were tried and it was found that none of the anionic substances had an appreciable effect, but that the substance mentioned materially improves the quality of the yarn or cloth. Since it is cationic in nature it was thought that cationic surface active agents in general would be effective. However, we were unable to find any other cationic substances than the one mentioned which was effective and conclude that the favorable results obtained were due to peculiar qualities of the material, rather than to its cationic nature.
In practicing our invention we make a solution 86 of polyvinyl alcohol in water, usually about 25% polyvinyl alcohol and 75% water and add to the solution from 0.25 to 2.50% of lauryl pyridinium chloride based on the weight of polyvinyl alcohol and then form the solution into filaments in .the manner customary in the manufacture of poly vinyl alcohol yarn.
We have further found that the modifying material as purchased in the open market may contain some free amine which tends to injure any copper fittings in the equipment. Therefore, it is advisable to neutralize such free amine by the addition of small quantities of sulfuric acid, hydrochloric or other suitable acids or acid salts.
We claim:
1. A filament forming solution comprising an aqueous solution of polyvinyl alcohol and a small quantity of lauryl pyridinium chloride, the amount of the chloride being from 0.25 to 2.50 per cent by weight of the polyvinyl alcohol.
2. A filament comprising polyvinyl alcohol and a small quantity of lauryl pyridinlum chloride, the amount of chloride being from 0.25 to 2.50 per cent by weight of the polyvinylalcohol.
. GUSTAVUS J. ESSELEN.
MARTIN H. GURLEY, Js.
REFERENCES CITED The following references are of record in the file of this patent:
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US520556A US2430499A (en) | 1944-01-31 | 1944-01-31 | Composition containing polyvinyl alcohol and lauryl pyridinium chloride |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US520556A US2430499A (en) | 1944-01-31 | 1944-01-31 | Composition containing polyvinyl alcohol and lauryl pyridinium chloride |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US2430499A true US2430499A (en) | 1947-11-11 |
Family
ID=24073116
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US520556A Expired - Lifetime US2430499A (en) | 1944-01-31 | 1944-01-31 | Composition containing polyvinyl alcohol and lauryl pyridinium chloride |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US2430499A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3240738A (en) * | 1960-09-28 | 1966-03-15 | Kurashiki Rayon Co | Polyvinyl alcohol spinning composition and method |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2072302A (en) * | 1931-03-10 | 1937-03-02 | Chemische Forschungs Gmbh | Polymerized vinyl alcohol articles and processes of making same |
| US2104728A (en) * | 1933-03-09 | 1938-01-11 | Bohme Fettchemie Gmbh | Wetting and dispersing agents and process of making the same |
-
1944
- 1944-01-31 US US520556A patent/US2430499A/en not_active Expired - Lifetime
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2072302A (en) * | 1931-03-10 | 1937-03-02 | Chemische Forschungs Gmbh | Polymerized vinyl alcohol articles and processes of making same |
| US2104728A (en) * | 1933-03-09 | 1938-01-11 | Bohme Fettchemie Gmbh | Wetting and dispersing agents and process of making the same |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3240738A (en) * | 1960-09-28 | 1966-03-15 | Kurashiki Rayon Co | Polyvinyl alcohol spinning composition and method |
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