US2424995A - Selenium element and method - Google Patents
Selenium element and method Download PDFInfo
- Publication number
- US2424995A US2424995A US464642A US46464242A US2424995A US 2424995 A US2424995 A US 2424995A US 464642 A US464642 A US 464642A US 46464242 A US46464242 A US 46464242A US 2424995 A US2424995 A US 2424995A
- Authority
- US
- United States
- Prior art keywords
- selenium
- aluminum
- coating
- anodizing
- disc
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 title description 26
- 239000011669 selenium Substances 0.000 title description 25
- 229910052711 selenium Inorganic materials 0.000 title description 25
- 238000000034 method Methods 0.000 title description 8
- 238000000576 coating method Methods 0.000 description 17
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 16
- 229910052782 aluminium Inorganic materials 0.000 description 16
- 239000011248 coating agent Substances 0.000 description 16
- 238000007743 anodising Methods 0.000 description 10
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 3
- 235000011149 sulphuric acid Nutrition 0.000 description 3
- 239000001117 sulphuric acid Substances 0.000 description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- MXRIRQGCELJRSN-UHFFFAOYSA-N O.O.O.[Al] Chemical compound O.O.O.[Al] MXRIRQGCELJRSN-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 208000027418 Wounds and injury Diseases 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 208000014674 injury Diseases 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000010445 mica Substances 0.000 description 2
- 229910052618 mica group Inorganic materials 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000000266 injurious effect Effects 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Images
Classifications
-
- H01L21/103—
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01F—MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
- H01F17/00—Fixed inductances of the signal type
Definitions
- This invention relates to selenium elements and particularly to a method of applying .pressure against a selenium coated plate.
- the object of the invention is to provide an arrangement whereby a selenium coating can be 3 Claims. (01. 175-386) placed under a pressure without damageto the selenium.
- mica is expensive and not always easily obtainable in a satisfactory form.
- an aluminum sheet can satisfactorily be pressed against the selenium if it is provided'with a hydrated oxide coating of a rather critical quality.
- a hydrated oxide coating of a rather critical quality By the use of such an oxidized aluminum sheet it is possible to bring the sheet into high pressure contact with the selenium for a considerable period of time, such as a number of hours without injuring the selenium.
- the oxide coating on the aluminum is too thin the selenium is injured or contaminated, apparently by reaction with the surface of the aluminum, and if on the other hand the coating is too thick the selenium tends to adhere to the aluminum more readily than to the base plate with consequent injury to the selenium surface.
- a coating of the proper thickness and qualityit is possible to apply a heavy pressure against the selenium and to heat treat it at the same time fo a considerable time, if desired, and thus improve the characteristics of the selenium.
- FIG. 1 is a top view of a pressure device for compressing the selenium coated plate
- the disc I is a flat sheet which may be circular, preferably of steel and preferably also nickel coated and roughened in .a wellknown manner to receive a coating of selenium 2.
- the selenium coating may be applied in any wellknown manner such as by placing selenium powder on the disc and then heating the disc to melt the powder and fuse it to the disc.
- the disc is shown with a centrally located hole 3 which is customarily used in order to build up a selenium element stack on a mandrel. Plates 4 and 5 represent the pressure plates of a press, the rest of the press mechanism not being illustrated.
- the plate or disc 6 is the aluminum disc which has on it a coating of hydrated aluminum oxide 1 facing the selenium layer 2.
- a current density of about 16.5 amperes per square root of aluminum surface area to be coated is satisfactory, although we have discovered that this can be varied within fairly wide limits, such as from about 4 to 32 amperes per'square foot; and we allow this current to flow for about seventeen minutes at this rate. While the current density to be used is not very critical so long as it is sufficient for the anodizing, the concentration of the solution in combination ,with the time of anodizing is of importance in determining the quality of the coating. If it is not desired to coat the back of the aluminum disc. the coating on the back may be prevented as by covering the back with a material which will not coat, such as styrene. Fig.
- thinner oxide coatingsthan those obtained by the above procedure may be round satisfactory enough.
- the thinner coatings may be obtained by the same anodizing process as described above except that the time of the anodizing in the solution may. be made shorter or the current density may be made less.
Landscapes
- Engineering & Computer Science (AREA)
- Power Engineering (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Electroplating Methods And Accessories (AREA)
- Non-Insulated Conductors (AREA)
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
BE468191D BE468191A (fi) | 1942-11-05 | ||
BE468181D BE468181A (fi) | 1942-11-05 | ||
US464642A US2424995A (en) | 1942-11-05 | 1942-11-05 | Selenium element and method |
GB17893/43A GB564981A (en) | 1942-11-05 | 1943-10-29 | Methods of making selenium elements such as for electric rectifiers |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US464642A US2424995A (en) | 1942-11-05 | 1942-11-05 | Selenium element and method |
Publications (1)
Publication Number | Publication Date |
---|---|
US2424995A true US2424995A (en) | 1947-08-05 |
Family
ID=23844717
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US464642A Expired - Lifetime US2424995A (en) | 1942-11-05 | 1942-11-05 | Selenium element and method |
Country Status (3)
Country | Link |
---|---|
US (1) | US2424995A (fi) |
BE (2) | BE468181A (fi) |
GB (1) | GB564981A (fi) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2551048A (en) * | 1947-07-19 | 1951-05-01 | Vickers Inc | Method of making selenium coated elements |
US2567877A (en) * | 1947-07-11 | 1951-09-11 | Ment Jack De | Electrochemical bonding of aluminum with other materials |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3220881A (en) * | 1960-11-30 | 1965-11-30 | Gen Telephone & Elect | Method of making a non-linear resistor |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2203328A (en) * | 1938-08-06 | 1940-06-04 | Suddeutsche App Fabrik G M B H | Manufacturing selenium valve disks for rectifiers and photoelectric cells |
US2221596A (en) * | 1938-01-22 | 1940-11-12 | Fides Gmbh | Method of manufacturing dry rectifiers |
-
0
- BE BE468191D patent/BE468191A/xx unknown
- BE BE468181D patent/BE468181A/xx unknown
-
1942
- 1942-11-05 US US464642A patent/US2424995A/en not_active Expired - Lifetime
-
1943
- 1943-10-29 GB GB17893/43A patent/GB564981A/en not_active Expired
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2221596A (en) * | 1938-01-22 | 1940-11-12 | Fides Gmbh | Method of manufacturing dry rectifiers |
US2203328A (en) * | 1938-08-06 | 1940-06-04 | Suddeutsche App Fabrik G M B H | Manufacturing selenium valve disks for rectifiers and photoelectric cells |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2567877A (en) * | 1947-07-11 | 1951-09-11 | Ment Jack De | Electrochemical bonding of aluminum with other materials |
US2551048A (en) * | 1947-07-19 | 1951-05-01 | Vickers Inc | Method of making selenium coated elements |
Also Published As
Publication number | Publication date |
---|---|
GB564981A (en) | 1944-10-20 |
BE468181A (fi) | |
BE468191A (fi) |
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