US2402814A - Alloy steel - Google Patents

Alloy steel Download PDF

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Publication number
US2402814A
US2402814A US437912A US43791242A US2402814A US 2402814 A US2402814 A US 2402814A US 437912 A US437912 A US 437912A US 43791242 A US43791242 A US 43791242A US 2402814 A US2402814 A US 2402814A
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United States
Prior art keywords
alloy steel
temperatures
titanium
remainder
molybdenum
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Expired - Lifetime
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US437912A
Inventor
Hatfield William Herbert
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Firth Vickers Stainless Steels Ltd
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Firth Vickers Stainless Steels Ltd
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/50Ferrous alloys, e.g. steel alloys containing chromium with nickel with titanium or zirconium

Definitions

  • This invention relates to alloy steel and an important object is to provide an alloy steel adapted for the manufacture of mechanical parts which are to operate under stress at temperatures up to 800 C. and require to have high creep resistance under such working conditions.
  • the term mechanical parts is to be regarded as comprehensive and includes such objects as power plant, components or units thereof, and apparatus generally intended for operation in a range of temperature extending up to 800 C., and subjected during such operation to considerable stress.
  • the invention is based on the discovery that alloy steels containing carbon, nickel, chromium, molybdenum, copper and titanium in certain critical percentages possess creep resistance values, at temperatures up to 800 C., which have hitherto been regarded as unattainable.
  • composition is as follows:
  • the alloy may also contain silicon up to 2%, manganese up to 2% and vanadium up to 1%.
  • the steel of this example possesses abnormally high creep resistance at elevated temperatures and is therefore essentially suitable for use in the manufacture according to the invention.
  • the iabrication oi apparatus required to operate under stress at high temperatures that is up to 800 C., from an alloy steel comprising carbon up to 1.5%, nickel 15-25%, chromium 12- 4 20%, molybdenum 24%, copper 24%, titanium 0.25-2% and the remainder iron.
  • a mechanical part required to operate under stress at high temperatures that is, up to 800 C., and having high creep resistance under such conditions, said part consisting oi alloy steel comprising carbon up to 1.5%, nickel 15-25%, chromium 12-20%, molybdenum 2-6%, copper 2-6%, titanium 0.25-2% and the remainder iron.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Heat Treatment Of Steel (AREA)

Description

Patented June 25, 1946 ALLOY STEEL William Herbert Hatfield, Shemeld, England, assignor to Firth-Vickers Stainless Steels Limited, Shemeld, England, a British company No Drawing. Application April 6, 1942, Serial No. 437,912. In Great Britain April 7, 1941 This invention relates to alloy steel and an important object is to provide an alloy steel adapted for the manufacture of mechanical parts which are to operate under stress at temperatures up to 800 C. and require to have high creep resistance under such working conditions. The term mechanical parts" is to be regarded as comprehensive and includes such objects as power plant, components or units thereof, and apparatus generally intended for operation in a range of temperature extending up to 800 C., and subjected during such operation to considerable stress.
The invention is based on the discovery that alloy steels containing carbon, nickel, chromium, molybdenum, copper and titanium in certain critical percentages possess creep resistance values, at temperatures up to 800 C., which have hitherto been regarded as unattainable.
Alloy steels containing the constituents above recited, but with much wider ranges prescribed for the permissible percentages of such constituents have been claimed to possess resistance to acids and other chemical agents and also to oxidation, scaling and corrosion at high temperatures, but it will be appreciated that the property of resistance to corrosion and scaling is by no means allied to, or to be confused with, resistance to creep.
According to this invention mechanical parts required for operation at temperatures up to 800 C., whilst subjected to considerable stress, are manufactured from steels lying within the following range of composition:
this characteristic which is essential to the invention it is to be emphasized that the above limits of proportion of the several constituents of the alloy are critical. Furthermore, importance is to be attached to the inclusion of titanium as an essential constituent.
The preferred range of composition is as follows:
Per cent C Up to 0.3 Ni 16.0 to 18.0 Cr 12.0 to 16.0 Mo 3.0 to 4.5 Cu 3.0 to 4.5 TL 0.25 to 1.0
' Fe Remainder 8 Claims. (Cl. 75-125) The alloy may also contain silicon up to 2%, manganese up to 2% and vanadium up to 1%.
Example Time yield 400 0. 500 0. 600 0. 700 0. 8G? C.
Tons/sq. in 18. 5 l5 0. 5 2
From the above figures it will be seen that the steel of this example possesses abnormally high creep resistance at elevated temperatures and is therefore essentially suitable for use in the manufacture according to the invention.
I claim:
1. Alloy steel possessing high creep resistance when applied for the manufacture of mechanical parts to be operated under stress at temperatures up to 800 0., comprising the following constituents and critical percentages: Carbon up to 1.5%, nickel 15.0 to 25.0%, chromium 12.0 to 20.0%, molybdenum 2.0 to 6.0%, copper 2.0 to 6.0%, titanium 0.25 to 2.0% and iron the remainder.
2. Alloy steel possessing high creep resistance when applied for the manufacture of mechanical parts to be operated under stress at temperatures up to 800 0., comprising the following constituents and critical percentages: carbon up to 0.3%, nickel 16.0 to 18.0%, chromium 12.0 to 16.0%, molybdenum 3.0 to 4.5%, copper 3.0 to 4.5%, titanium 0.25 to 1.0%, and iron the remainder.
3. Alloy steel possessing high creep resistance when applied for the manufacture of mechanical parts to be operated under stress at temperatures up to 800 0., comprising the following constituents and critical percentages: carbon up to 1.5%, silicon up to 2.0%, manganese up to 2.0%, nickel 15.0 to 25.0%, chromium 12.0 to 20.0%, molybdenum 2.0 to 6.0%, copper 2.0 to 6.0%, titanium 0.25 to 2.0%, and iron the remainder.
4. Alloy steel possessing high creep resistance when applied for the manufacture of mechanical parts to be operated under stress at temperatures up to 800 0., comprising the following constituents and critical percentages: carbon up to 0.3%, silicon up to 2.0%, manganese up to 2.0%, nickel 16.0 to 18.0%, chromium 12.0 to 16.0%, molybdenum 3.0 to 4.5%, copper 3.0 to 4.5%, titanium 0.25 to 1.0%, and iron the remainder.
5. Alloy steel possessing high creep resistance when applied for the manufacture of mechanical parts to be operated under stress at temperatures up to 800 0., comprising the following constituents and critical percentages: carbon 0.08%, silicon 0.28%. manganese 0.24%, nickel 16.93%, chromium 13.87%, molybdenum 4.31%, copper 4.47%, titanium 0.51% and iron the remainder.
6. Alloy steel according to claim 1 and containing vanadium up to 1.0% displacing an equivalent percentage of iron remainder.
7. The iabrication oi apparatus required to operate under stress at high temperatures, that is up to 800 C., from an alloy steel comprising carbon up to 1.5%, nickel 15-25%, chromium 12- 4 20%, molybdenum 24%, copper 24%, titanium 0.25-2% and the remainder iron.
8. A mechanical part required to operate under stress at high temperatures, that is, up to 800 C., and having high creep resistance under such conditions, said part consisting oi alloy steel comprising carbon up to 1.5%, nickel 15-25%, chromium 12-20%, molybdenum 2-6%, copper 2-6%, titanium 0.25-2% and the remainder iron.
WILLIAM HERBERT HATFIELD.
US437912A 1941-04-07 1942-04-06 Alloy steel Expired - Lifetime US2402814A (en)

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2447897A (en) * 1946-05-23 1948-08-24 Armco Steel Corp High-temperature stainless steel
US2528497A (en) * 1946-10-23 1950-11-07 Armco Steel Corp Alloy steel
US2540509A (en) * 1947-10-14 1951-02-06 Armco Steel Corp High-temperature stainless steel
US2556373A (en) * 1949-08-23 1951-06-12 Thos Firth & John Brown Ltd Alloy steels for use at elevated temperatures
US2633420A (en) * 1949-10-21 1953-03-31 Spitz Karl Alloy irons and steels
US2891858A (en) * 1955-09-28 1959-06-23 Carpenter Steel Co Single phase austenitic alloy steel
US3357868A (en) * 1964-11-17 1967-12-12 Armco Steel Corp Stainless steel and method
FR2467888A1 (en) * 1979-10-22 1981-04-30 Japan Atomic Energy Res Inst AUSTENITIC ALLOY BASED ON IRON REINFORCED SOLID SOLUTION

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2447897A (en) * 1946-05-23 1948-08-24 Armco Steel Corp High-temperature stainless steel
US2528497A (en) * 1946-10-23 1950-11-07 Armco Steel Corp Alloy steel
US2540509A (en) * 1947-10-14 1951-02-06 Armco Steel Corp High-temperature stainless steel
US2556373A (en) * 1949-08-23 1951-06-12 Thos Firth & John Brown Ltd Alloy steels for use at elevated temperatures
US2633420A (en) * 1949-10-21 1953-03-31 Spitz Karl Alloy irons and steels
US2891858A (en) * 1955-09-28 1959-06-23 Carpenter Steel Co Single phase austenitic alloy steel
US3357868A (en) * 1964-11-17 1967-12-12 Armco Steel Corp Stainless steel and method
FR2467888A1 (en) * 1979-10-22 1981-04-30 Japan Atomic Energy Res Inst AUSTENITIC ALLOY BASED ON IRON REINFORCED SOLID SOLUTION

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