US2400875A - Absorption and recovery of fluorides in amines of low basicity - Google Patents

Description

P atent ed May 28, 1946 ABSORPTION AND RECOVERY OF FLUO- RIDES AMINES LOW BASICITY Everett 0. Hughes, Cleveland Heights, and John D. Bartleson, Cleveland, Ohio, assignors to The Standard Oil Company, Cleveland, Ohio, a corporation oI'Ohio No Drawing. Application January .6, 1943,

Serial No. 471,456 1 17 Claims.

v This invention'relates to the recovery of fluorides,- and more particularly to the recovery of catalysts comprising either hydrogen fluoride or 'boron trifluoride by means of an absorbent, comprising an amine of low basicity.

Hydrogen fluoride and boron trifluoride may be used to exert catalytic effects in certain chemical reactions, particularly reactions involving hydrocarbons. The particular reactions in which such catalysts are employed are not a part of this invention and therefore need not be referred to in any great detail. However, some of the products resulting from these reactions, or some of the starting components therein, may have the catalysts in admixture therewith in a physical or physio-chemical admixture or loose chemical combination, and it may be desirable to separate the catalyst from these products or components. This is of significance not only when the product or component is wanted free from the catalyst but also when it is desired to separate the catalyst to prevent the loss thereof and for re-use, such as in a cyclic process. The latter aspect of the invention assumes particular importance when the catalyst is mixed with a product or component that is not to be re-cycled or is a waste product, and yet contains a, significant amount of the catalyst so that its disposal would obtain a substantial loss of the catalytic material.

It has been discovered that hydrogen fluoride and boron trifluoride each forms a particularly desirable type of complex with or is absorbed by amines of low basicity under appropriate conditions and that, this complex absorption product can be readily disassociated subsequently to alarge extent to desorb the fluoride without further chemical treatment. This discovery is utilized in accordance with the invention to separate hydrogen fluoride and boron trifluoride by absorption from hydrocarbons'or other chemical compounds with whichthe fluorides are mixed for the purcatalyst or for any other purposes. The desorptlon may be accomplished by lowering the pressure, heating or other methods of releasing the absorbed fluoride.

It has been discovered that when amines of low basicity are used as an absorbent, the fluorides can be desorbed, liberated or recovered almost completely from the amine-fluoride comv ciency than the amines used in accordance with our invention. The use of amines of low basicity also permits the use of lower desorption temperatures when the desorption, liberation or recovery is accomplished by heat. This reduces cor- .rosion, deterioration of the amine, operating costs, etc.

Hydrogen fluoride boils at 67 F., and therefore when utilized in reactions at temperatures above room temperature it is gaseous unless maintained under suitable pressures. Bbron trifluoride (B. P. l50 F.) is a gas unless liquefied by appropriate temperatures and pressures. Either I of the fluorides alone, or with other chemical components may be used as a catalyst either in the liquid or gaseous phase depending on the reaction involved, and the conditions of temperature and pressure. under which it is carried out. The products of the reaction; or the unreacted components, when released at any predetermined temperature and pressure maybe liquid or gaseous or both, or the products or components in either form under such conditions may contain the fluoride catalysts in simple admixture or more complex forms of combination. The invention may be used for separating the fluoride catalyst in any of these forms. However, be-

- cause of the relatively low boiling points of the fluorides, the invention assumes particular si niflcance when one of the products of the reaction is gaseous and is mixed with a. substantial amount of the catalyst in'gaseous form. Because of this significance the invention will be described hereinafter in connection with illustrative ex:

amples in which the catalyst is in gaseous form.-

The amines of low basicity which may be used --as the absorbent in accordance with the inven- Dose of recovering fluorides'ror further use as a tion may be any having a dissociation constant of not over a value of the order of 1, x 10 .These include halogenated, nitrated or other substituted amines which have a low basicity, and secondary and tertiary aromatic amines. Numerous examples can be given as illustrative of the invention, and the following may be mentioned: diphenylamine, ditolylamine, tritolylamine, phenyltolylamine and similar. compounds. Other substituted amines of low basicity which may be used are 0-, m-, or p-chloroaniline; o-, m-, or p-nitroaniline, monochlorodiphenylamine, dichlorodiphenylamine (with ms in any positions on the ring),mo'no-, or di-nitrodiphenylamin'es, monoor di-chlorophenyltolylamine, and monoor di-nitrotolylphenylamine, etc. Mixtures of two or more amines of low basicity may be used and this is particularly desirable when the comperature. pressure and other of the process.

If it is desired, the amines of low basicity may be mixedwith any unreactive compound miscible with or soluble in said amines and having a sufficiently high boiling point not to be volatile at .-any.of the temperatures employed in the recovery process.

Such a mixture generally lowers the melting point in somewhat the same manner-as a eutectic mixture of two or more amines of low basicity, and permits the use of said amines at a lower temperature in a liquid form.

* Merely as illustrative, the invention will be described as applied to one of its most significant variations in which the catalysts leave the reac- The tion zone as a gas'in a gaseous mixture. absorbing operation may be carried out in any manner in which the gaseous catalyst-containing phase \is brought into intimate contact with the amine of. low basicity in the liquid phase. temperature suitable for this absorption may be any from room temperature or higher or lower temperatures, up to that at which the equilibrium between'the absorption and the desorption renders the operation too inefilcient to be of value. Preferably the temperature should be such that the amine of low basicity is liquid. In general the absorption temperature may extend to 300? F. In a commercial application of the invention temperatures up to about 212 F. would probably be used, since this and temperatures below it are readily obtained with steam at atmospheric pres- -sure.

The temperature at which the desorption is' carried out, i. e., the operation in which the fluoride is separated from the amine of low basicity in which .it is absorbed, may be any temperature above that used for-the absorption up to the boilingpoint of said amine, or any diluents therein or any other components of the absorbent. The practical range extends from about 200 to 300 F. up to the boiling point of said ann'ne or mixture containing the same.

The pressure used during .the absorption and desorption is not particularly critical and may vary from a high vacuum to 1000 pounds per square inch or more, depending upon the nature of the process to which the process is applied. It is immaterial that some or all of the components in the absorbing or desorbingzone are 0 I liquefied under the pressure used.

During the desorption it may be desirable to bubble air, nitrogen or other inactive gas through the absorbent to facilitate theliberation of the fluorides. If desired, the gas may be separated from the fluoride by fractional condensation upon cooling.

Merely as illustrative of an absorption or desorption operation, the process may be practiced of diphenylamine (1'70 g.) was melted and 16 g. (0.80 mol) of hydrogen fluoride was absorbed The coming off before a temperature of 400 F. was reached. The absorbent lost about 14 g. The efliciency of the absorption and desorption can also be determined by a fluorine analysis of the absorbent complex and the absorbent remaining after the desorption operation. Such analysis shows that the absorbent-complex contains 6.2%

. fluorine. After the desorption operation is carried out the denuded absorbent contains 0.48% fluorine. These data represent a 92% removal of hydrogen fluoride in a single pass. The denuded absorbent is available to absorb further hydrogen fluoride and it may be recycled in a continuous operation.

When the invention is applied to the separation of boron trifluoride substantially the same amines of low basicity and conditions of absorption and desorption may be used as are used in separating hydrogen fluoride.

As'illustrative of an applicationof our invention to the recovery of boron trifluoride, diphenylwith diphenylamine as the absorbent. One mol I amine was used as the absorbent and 0.76 mol of boron trifluoride was absorbed per mol of the melted amine. Upon heating the absorbent complex to 525 F., about 79% of the'borontrifluoride was desorbed from the absorbent and could be recovered for re-use. The denuded amine absorbent can be returned to the process to absorb an additional quantity of boron trifluoride.

The invention may be applied readily to a continuous process utilizing an apparatus having absorption or desorption zones. The absorbent is introduced into and passed through the absorbingzone. The gaseous product or component of the reaction with which the fluoride is admixed may be passed through the absorption zone under higher or lower pressures.

While the invention has been illustrated with reference to amines of low basicity found to be particularly suitable, and the preferred temperatures are given that are especially suitable for use therewith, it will be understood that any amines of low basicity may be used. The temperature of the operation should be selected with reference to'the melting or boiling points of the amine absorbent, the absorbent and desorbent equilibrium characteristics, the pressures used, and other factors a will be apparent to one skilled in the art in the light of the explanation and disclosures herein. 9

The invention is of particular value in connection with a recovery of hydrogen fluoride and boron trifluoride in gaseous form and for this reason the invention has been described particularly with reference to'the fluorides in this form. But it is to be understood that the invention is not limited to such an operation because under appropriate conditions a liquid phase operation may be used.-

The invention is applicable to the recovery of the fluorides from any compound or composition with which-they may be admixed, the only limitation-in this regard being that the compound or composition with which the fluoride is admixed with the amin of low basicity. This invention is particularly applicable to the separation of the fluorides from normally gaseous saturated or will be appreciated that the invention is not nec- "essarily limited'to the recovery of fluorides in connection with a process in which they have been used as catalysts. They may be recovered from any other process, such a a process of purification or processes in which the fluorides are a 1 reacting component or a final product.

Reference is made to the co-assigned applicatidn of Burk, Serial Number 471,453, which claims the absorption and recovery of fluorides in amines generally.

Itwill be understood that'the invention is capable of manyapplications and modifications and it is not to be limited by any illustrative examples or other preferred form described herein except as required in the following claims.

We claim:

l. The method of recovering a volatile fluoride,

which comprises absorbing the fluoride in an amine having a dissociation constant of not over a value of about 1 10 and subsequently recovering the fluoride from said amine by heatingsaid amine and fluoride absorbed therein to liberate the fluoride therefrom without chemical modification of the compound other than any that may occur in said heating.

2. The method of recovering a volatile fluoride, which comprises absorbing the fluoride in an amine in liquid form, said amine having a dissociation constant of not over a value of about l and subsequently heating said amine in which the volatile fluoride is absorbed to liberate the fluoride from the amine.-

should not'form a complex or otherwise react amine in said recovery zone, and returning the denuded amine to the absorbing zone.

6.- The method of recovering hydrogen fluoride which comprises contacting a material containing the hydrogen fluoride with an amine to absorb at least a part of the hydrogen fluoride, said amine having a dissociation constant of not over a value of about 1X 10*", and heating said amine containing the absorbed hydrogen fluoride to lib-' erate atleast a part of the hydrogen fluoride therefrom. a

7. The methodof recovering boron trifluoride which comprises contacting a material containing the boron trifluoride with an amine to absorb at least a part of the boron trifluoride, said amine having a dissociation constant of not over a value of about 1 X 10' and heating said amine contain- 3. The method of recovering hydrogen fluoride,

which comprises absorbing thehydrogen fluoride in an amine in liquid form, said amine having a dissociationconstant of not ove'ra value of about 1 x 10- and subsequently heating said amine in which the hydrogen fluoride is absorbed to' liberate the hydrogen fluoride from the amine.

4. The method of recovering boron trifluoride,

which comprises absorbing the boron trifluoride in an amine in liquid form, said amine having a dissociation constant of not over a'value of about l 10-. and subsequently heating said amine in which the boron trifluoride is absorbed to liberate the boron trifluoride from the amine.

5; A method of recovering a volatile fluoride which comprises contactingv saidfluoride with an amine in an absorbing zone, said amine having a dissociationconstant of not over a value of about 1 10- withdrawingsaid amine and absorbed fluoride rrom'the absorbing zone and introducing it into a fluoride recovery zone, heating the sameto remove thefluoride from the ing ,the absorbed boron trifluoride to liberate at least a part of the boron trifluoride therefrom.

8. The method of recovering a fluoride selected from the group consisting of hydrogen fluoride and boron trifluoride, which comprises contacting a material containing the fluoride with an amine selected from the group consisting of secondary and tertiary aromatic amines, to absorb at least .a part of the fluoride, and heating said amine containing the absorbed fluoride to liberate at least a part of the fluoride therefrom.

9. Themethod of recovering fluoride selected from the group consisting of hydrogen fluoride and boron trifluoride, which comprises contacting a material containing the fluoride with diphenylamine to absorb at least a part of the fluoride, and heating said diphenylamine containing the absorbed fluoride to liberate at, least apart of the fluoride therefrom.

10. A method'of recovering hydrogen fluoride, which comprises contacting said hydrogen fluoride with an amine in an absorbing zone and at a temperature such that the amine is liquid, said amine having a dissociation constant of not over a value of about l 10- removing said amine and the absorbed hydrogen fluoride from the absorbing zone and introducing it into a, fluoride recovery zone, heating the amine and absorbed hydrogen fluoride in said recovery zone to a temperature above that maintained in the absorbing zone to liberate the hydrogen fluoride-from the amine.

11. A method of recovering boron trifluoride, which comprises contacting said boron trifluoride with an amine in an absorbing zone and at a temperature such that the amine is liquid, said amine having a. dissociation constant of not over a value of about 1 l0 removing said amine and the absorbed boron trifluoride from the absorbingfrom the group consisting of hydrogen fluoride and boron trifluoride, which comprises contact ing said fluoride with an amine in an absorbing zone and ate. temperature such that theamine "is liquid, said amine having a dissociation constant of not over a value of about 1x10- removing said amine and the absorbed fluoride from the absorbing zone and introducing it into a fluoride recovery zone, heating the amine and absorbed fluoride in said recovery zone to a temperature abovethat maintained in the absorbing zone to liberate the fluoride from the amine, and

returning the denuded amine to the absorbing zone.

' a result of a catalytic process of treating hydrocarbons; which method comprises passing said hydrocarbon and catalyst containing mixture through an absorbing zone in contact with an amine at a temperature such that the amine is catalyst comprising a fluoride selected from the group consisting of hydrogen fluoride and boron trifiuoride, from a gaseous hydrocarbon containing phase with which said catalyst is admixed as a result of a catalytic process of treating hydrocarbons; which method comprises passing said liquid; said amine having a dissociation constant of not over a value of about 1x10- separately removing from the absorbing zone said amine in which the fluoride is absorbed and the fluoride ireed hydrocarbon phase; introducing the amine 1 ing said hydrocarbon and catalyst containing mixture through an absorbing zone in contact with an amine selected from the group consisting of secondary and tertiary aromatic amines,

which amine is maintained at a temperature such that it is liquid; separately ,removing from the absorbing zone, the amine in which the fluoride is absorbed, and the fluoride freed hydrocarbon phase; introducing the amine and the fluoride into a fluoride recovery zone at a higher temperature than in said absorbing zone to release the fluoride from said amine.

15. A method of recovering a catalyst comprising boron trifluoride, from a hydrocarbon containing phase with which said catalyst is admixed as a resultof a catalytic process of treating.hy'droc arbons; which method comprises passing said hydrocarbon and catalyst containing mixture through an absorbing zone in contact with diphenylamine at a temperature such that said diphenylamine is liquid; separately removing from the absorbing zone, the diphenylamine in which the fluoride is absorbed, and the fluoride freed hydrocarbon phase; introducing the diphenylamine and the fluoride into a fluoride recover-y zone at a higher temperature than in said absorbing zone to release the fluoride from the diphenylamine.

hydrocarbon and catalyst containing mixture through an absorbing zoneyin contact with an amine at a temperature such that the amine is liquid; said amino having a dissociation constant of not over a value of about 1 1o separately removing from the absorbing zone, said amine in which the fluoride is absorbed, and the fluoride freed hydrocarbon phase; introducing the amine and the fluoride into a fluoride recovery zone and applying heat to maintain said recovery zone at a temperature higher than in the'absorbing zone and to release the fluoride from ;the amine; returning the denuded amine to the absorbing zone to absorb the fluoride from an additional quantity of the hydrocarbon and catalyst containing phase; and returning the released fluorideto the catalytic hydrocarbon treating process.

17. A method of recovering fluorides from a catalyst comprising a fluoride selected from the group consisting of hydrogen fluoride and boron 'trifluoride, from a gaseoushydrocarbon containing phase with which said catalyst is admixed as a resultof a catalyst process of treating hydrocarbons; which method comprising passing said hydrocarbon and catalyst containing mixture through an absorbing zone in contact with an amine at a temperature at least such that the amine is liquid, and up to 360 F.; said amine having a dissociation constant of not'over a value of about 1X10- separately removing from the absorbing zone, said amine in which at least a part of the fluoride is absorbed, and the fluoride freed hydrocarbon phase; introducing the amine and the fluoride into a'fluoride recovery zone and applying heat to maintain said recovery zone at a temperature higher than in the absorbing zone and not more than the boiling point of the amine under the recovery conditions and to release at least a part of the fluoride from the amine; returning the denuded amine to the absorbing zone to absorb the fluoride from an additional quantity of the hydrocarbon and catalyst containing 16. A' method of recovering fluorides from a phase; and returning the released fluoride to the catalytic hydrocarbon treating process.

. EVERETT c. HUGHES. JOHN D. 'BARTLESON.

Certificate of .Corretion Patent No, 2,400,875. May 28,1946.

EVERETT o. HUGHES ET :AL.

It is hereby certified that errors appear in the printed specification of the above numbered patent requiring correction as follows: Page 1, second column, line 4, after the word desorption strike out liberation or recovery and insert the same in line 3, same page and column, after desorption; page 3, second column, line 29,

- claim 9, before fluoride insert a; page 4, second column, line 29, claim 17, for cata;

lyst read catalytic; line 30, same claim, for comprising read comprises; and that the said Letters Patent should be read with these corrections therein that the same may conform to the record of the case in the Patent Ofiice.

Signed and sealed this 13thday of August, A. D. 1946.

LESLIE FRAZER, 1

First Assistant Oomnz'su'one'rcf Patents.