US2394540A - Stretching of artificial yarn - Google Patents
Stretching of artificial yarn Download PDFInfo
- Publication number
- US2394540A US2394540A US499327A US49932743A US2394540A US 2394540 A US2394540 A US 2394540A US 499327 A US499327 A US 499327A US 49932743 A US49932743 A US 49932743A US 2394540 A US2394540 A US 2394540A
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- US
- United States
- Prior art keywords
- yarn
- roll
- filaments
- stretching
- cellulose
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02J—FINISHING OR DRESSING OF FILAMENTS, YARNS, THREADS, CORDS, ROPES OR THE LIKE
- D02J1/00—Modifying the structure or properties resulting from a particular structure; Modifying, retaining, or restoring the physical form or cross-sectional shape, e.g. by use of dies or squeeze rollers
- D02J1/22—Stretching or tensioning, shrinking or relaxing, e.g. by use of overfeed and underfeed apparatus, or preventing stretch
- D02J1/221—Preliminary treatments
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/02—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D01F6/18—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds from polymers of unsaturated nitriles, e.g. polyacrylonitrile, polyvinylidene cyanide
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
- Artificial Filaments (AREA)
Description
Feb. 12, 1946. T. G. FiNZEL 2,394,540
STRETCHING OF ARTIFICIAL YARN Filed Aug. 20, 1943 it f T he to n. G. Finz E1 INVENTOR.
BY 4WA ATTORNEY Patented Feb. 12, 1946 UNITED STATES PATENT OFFICE STRETCHING or ARTIFICIAL YARN Theron G. Finzel, Kenmore, N. Y., assignor to E. I. du Pont de Nemours & Company, Wilmington, Del., a corporation of Delaware Application August 20, 1943, Serial No. 499,327
3 Claims. (Cl. 8-132) This invention relates to a method for increas- More particularly, the invention relates to a method for heat-treating and stretching untwisted yarn of. synthetic, thermoplastic, filamentforming material whereby to increase the tenacity of the, yarn.
This application is a continuation-in-part of my copending application Serial No. 366,769 filed November 22, 1940. K
It is known to stretch artificial thermoplastic yarn and particularly cellulose derivative yarn which has been softened by heat. All of the known processes, however, suffer from the defect that filaments making up the yarn invariably adhere to one another, thereby imparting harshness to the yarn and rendering the same inferior in quality.
This invention has as an object a method for plasticizing yarn of synthetic, thermoplastic, filament-forming material and stretching the same without causing the filaments to adhere to each other. A further object is the provision of a method for heat treating thermoplastic cellulose derivative yarn, such as cellulose acetate yarn, to plasticize the same and stretching the yarn while in the plastic state to produce a yarn free of stuck or adhering filaments. These and other objects will more clearly appear hereinafter.
I have found that if an untwisted yarn or synihetic, thermoplastic, filament-forming material. such as cellulose acetate or acrylonitrile polymer, is first spread to a ribbon whereby to separate and to align all of the filaments in substantially the same plane. and the ribbon is softened through contact with a heated roll and then stretched in the softened condition. a yarn of greatly enhanced tenacity is produced which yarn is at the same time soft to the touch and is of all around superior quality. By first spreading the yarn to a ribbon. substantially all filaments thereof are brought into direct contact with the surface of the heated roll. The yarn may be stretched to any des red degree, say two, five. ten or even more times its original length. Cellulose acetate spun in the conventional manner possesses a tenacity of about 1.4 to about 1.7 grams per denier. Improvement in tenacity to 2.5 or more grams per denier is achieved by the herein described method.
Untwisted yarn of any synthetic, thermoplastic, filament-forming material may be treated in accordance with the principles of this invention. As representative of these thermoplastic filawent-forming materials may be mentioned cellulose esters such as cellulose acetate, cellulose propionate, cellulose butyrate, and cellulose nitrate; cellulose mixed esterssuch as cellulose acetate propionate, and cellulose acetate butyrate; cellulose ethers such as. ethyl cellulose and benzyl cellulose; mixed cellulose ethers, e. g. ethyl lauryl cellulose; mixed cellulose ether-esters such as ethyl cellulose acetate and methyl cellulose propionate; and noncellulosic thermoplastic materials such as acrylonitrile polymers, nylon, vinyl esters. vinyl ethers, methacrylates, polystyrene, and Vinyon.
Referring to the accompanying drawing wherein the method and apparatus suitable for carry-' ing out the method of this invention are illustrated diagrammatically, Fig. 1 is a diagrammatic representation of an arrangement of means suitable for carrying out the invention; Figs. 2 and 3 show one method for varying the time contact of the yarn with the hot roll; Fig. 4 is a crosssection on the line A--A of Fig. 3; Fig. 5 shows auxiliary means for heating the yarn on the heated roll; Fig. 6 is a plan view of a preferred means for spreading the yarn; and Fig. '7 is a section on the line BB of Fig. 6.
In Fig. 1, a thermoplastic yarn such a cellulose acetate yarn possessing no twist and of any reasonable denier and comprised of a plurality of filaments is unwound from a supply package (not shown) and passed around a feed or snubbing roller I and thread advancing roller 2 used to feed the untwisted cellulose acetate yarn over a guide and then through a yarn spreading device 3 onto a heated cylinder roll 4. Rolls l and 4 rotate at the same peripheral speed. The yarn is softened on the hot surface of roll 4 and is withdrawn from roll 4 over a guide roller 5 at a speed greater than the peripheral speed of roll 4. The ratio of yarn draw-off speed to the peripheral speed of roll 4 may be two, five. ten or more. Rolls l and 4 are driven in a counterclockwise direction, as indicated. After the yarn is cooled below the softening temperature, it may be twisted in any well-known manner. After st etching, the tenacity of the yarn is materiallv increased and the yarn denier is reduced in pro-. portion to the stretch ratio.
The yarn must remain in-contact with roll 4 for such a length of time to effect sufiicient softening so as to allow stretching of the cellulose acetate yarn at a tension of from 0.01 to 0.5 gram per denier of the stretched yarn. The time of contact may be controlled by the diameter of the heating roll, the speed of the roll. or the angle of contact alpha (or) (Figs. 2 and 3) of the yarn on the roll. Obviously, the higher the peripheral speed of the roll, the greater must be the angle or contact alpha. I
The cylinder 4 is heated in any suitable manner, as for instance, by electrical means, high pressure steam, or vapor or liquids, to sumciently high temperature to efl'ect a suitable softening of the yarn in contact therewith.
Fig. 4 shows a section through A-A of Fig. 3.
This illustrates one method of heating roll 4.
' Shaft G of roll 4 is supported by a bearing I around which bearing an insulating layer 8, such as mica, etc., is wound. On top of the insulating layer 8 and close to the inner surface of roll 4, there is wound-a 'helical coil 9 of alloy wire having a high electrical resistance to act as an electrical heating ducing the necessary time of heating and improving the uniformity of heatingas compared with the heating characteristics of the simple hot roll.
In Figs. 6 and '7, details of a preferred form of spreading device are shown. The device consists of two resilient thin sheets such as spring steel or spring brass leaves or other sheets which are suitably supported and allowed to exert a mild pressure against each other. As yarn passes between these flat surfaces, suilicient pressure is brought to bear on the untwisted yarn to flatten the yarn into a form of a ribbon wherein the filaments lie in substantially a single plane. If yarn of a heavy denier is used, a number of the above described spreading devices may be used in series to an advantage. Another method for spreading and separating the filaments of a yarn into ribbon-like form may consist of a series of rods over the sur faces of which the untwisted yarn is passed. Other methods for spreading the filaments of a yarn may consist of a device which directs air jets against the yarn and then allows the separated filaments to pass over a flat surface. The use of an electrical charge applied to the yarn which causes the filament to balloon out and then passing the separated filaments over a flat surface may be applied to advantage.
Application of the method of this invention is further illustrated by the following examples.
Example I A 3000 denier cellulose acetate yarn (about 54% combined acetic acid) containing 150 filaments and possessing no twist was fed onto a heated roll set-up, the diagrammatic sketch of which is shown in Fig. 2. The yarn was fed onto the heated roll at the rate of 242" per minute and drawn from the roll at the rate of 1280" per minute. The diameter of the heated roll was 2" and its temperature was approximately 240 C. The filament spreading device consisted of two spring steel leaves 0.0045" thick, pressing mildly against each other. The average tension of the yarn as it was drawn from the heated roll was approximately 65 grams. After cooling, the stretched yarn was twisted to the extent of two turns per inch. Upon testing at 70 F. and 60% relative humidity, it showed a tenacity of 2.5 grams per denier.
Example II A 3000 denier, 150 filament cellulose acetate aseasso' yarn (about 54% combined acetic acid) possessing no twist was fed through a filament spreading device onto a heated roll, as illustrated in Fig, 2, at
the rate 0! 128" per minute and was withdrawn .1
from the heated roll at the rate of 1280" per minute with an average yarn tension of 60 grams. The roll was heated to a temperature of 256 C. and the angle of contact of the yarn with the roll was approximately 150. The stretched yam showed a tenacity of 2.2 grams per denier.
Example III A 580 denier, 58 filament cellulose acetate yarn (about 54% combined acetic acid) possessing no twist was passed through a spreading device and 256" per minute and was drawn from the heated roll at the rate of 1280" per minute under an average tension of approximately 10 grams. The angle of contact of the-yam with the roll was approximately 203 and the temperature of the heated roll was approximately 240 C. The temperature of the air between the heated roll and the auxiliary heating element 1 I as shown in Fig. 5 was approximately 215 C. After twisting the cold yarn to the extent of approximately two turns .per inch, the yarn showed a tenacity of 2.3 grams Der denier.
Example IV A 440 denier, 40 filament, no twist yarn pre-' pared by dry spinning a solution-of acrylonitrile polymer of 103,000 average molecular weight (as determined by viscosity data using the Staudinger equation) dissolved in dimethyl formamide, was passed through a spring leaf filament spreading device and around a hot roll as shown in Fig. 2. The yarn was fed onto a heated roll at the rate of inches per minute and drawn from this roll at the rate of 1450 inches per minute, thereby stretching the yarn .ten times. The diameter of the hot roll was 1%" and the angle of contact ofthe yarn with the hot roll was approximately 330 while the temperature to which the roll-was heated was -180 C.
The unstretched yam of 440 denier showed a tenacity of 0.6 gram per denier. The yarn was stretched down to 42-45 denier and showed a tenacity of 4.3 grams per denier.
The copending application of George Henry Latham, Serial No. 562,012, filed November 4, 1944 (a continuation-in-part of his copending application ,Serial No. 447,466, filed June 17, 1942) describes the dissolving of acrylonitrile polymers in dimethyl formamide and in other solvents and the formation of shaped articles from such solutions. The copending application of Daniel C. Meloon, Serial No. 496,397, filed July 28., 1943, describes the heat-stretching of acrylonitrile polymer articles. No claim is made in the present application to the inventions of said Latham and Meloon copending applications and the invention of this application is limited as set forth in the claims.
It is understood that my invention is not limitedto the precise details described, but is susceptible rather to-wide variation and comprehends all modifications and equivalents falling within the spirit of the invention as defined by the claims.
I claim:
1. The process which comprises spreading an untwisted yam comprised of a plurality of filaments of synthetic, thermoplastic, filamentforming material to the point where all of the 15 filaments are separated and lie in substantially 3. The process which comprises flattening an untwisted yarn comprised of filaments of acrylonitrile polymer to the point where all of the filaments are separated and lie in substantially the same lane, passing the flattened yarn over a heated rotating roll whereby to render the yarn plastic, and stretching the plastic yarn while it is in the separated state.
. THERON G. FINZEL.
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US499327A US2394540A (en) | 1943-08-20 | 1943-08-20 | Stretching of artificial yarn |
GB15917/44A GB581526A (en) | 1943-08-20 | 1944-08-21 | Process for heat-treating and stretching untwisted yarn consisting of a polymer of acrylonitrile |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US499327A US2394540A (en) | 1943-08-20 | 1943-08-20 | Stretching of artificial yarn |
Publications (1)
Publication Number | Publication Date |
---|---|
US2394540A true US2394540A (en) | 1946-02-12 |
Family
ID=23984838
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US499327A Expired - Lifetime US2394540A (en) | 1943-08-20 | 1943-08-20 | Stretching of artificial yarn |
Country Status (2)
Country | Link |
---|---|
US (1) | US2394540A (en) |
GB (1) | GB581526A (en) |
Cited By (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2494649A (en) * | 1944-07-24 | 1950-01-17 | Celanese Corp | Method of tire building and material used therein |
US2611923A (en) * | 1949-08-31 | 1952-09-30 | Du Pont | Method and apparatus for the drawing of synthetic funicular structures |
US2677590A (en) * | 1950-07-07 | 1954-05-04 | Du Pont | Removal of porosity in wet-spun acrylonitrile filaments by treatment with heated fluids |
US2677591A (en) * | 1950-07-07 | 1954-05-04 | Du Pont | Removal of porosity in wet-spun acrylonitrile filaments by pressing against a hot surface |
US2799915A (en) * | 1953-03-30 | 1957-07-23 | Johns Manville | Thermal modification of acrylonitrile polymers |
US2821458A (en) * | 1954-04-08 | 1958-01-28 | Du Pont | Process for producing uniform polyacrylonitrile fibers by heat relaxing solvent containing undrawn fibers, removing solvent and drawing the fibers |
US2869972A (en) * | 1952-12-31 | 1959-01-20 | Eastman Kodak Co | Method of treating yarns and filaments and products produced thereby |
US2913802A (en) * | 1953-07-16 | 1959-11-24 | Johns Manville | Thermal modification of acrylonitrile yarns |
US2920176A (en) * | 1957-10-28 | 1960-01-05 | Chemstrand Corp | Heating device |
US2934400A (en) * | 1955-03-19 | 1960-04-26 | Glanzstoff Ag | Process of manufacturing fibers of polyethylene terephthalate |
US3018157A (en) * | 1954-10-28 | 1962-01-23 | Du Pont | Process of producing uniformly dyeing polyacrylonitrile filaments by heat stretching the water wetted filaments |
US3077004A (en) * | 1956-03-23 | 1963-02-12 | Du Pont | Filament drawing |
US3280241A (en) * | 1960-12-06 | 1966-10-18 | Scragg & Sons | Drawn branched filament |
US3336900A (en) * | 1966-04-06 | 1967-08-22 | Du Pont | Filamentary yarn lubricating apparatus |
US3825724A (en) * | 1971-08-16 | 1974-07-23 | Xerox Corp | Wrap adjust device for controlling engagement between a web and roller |
US4004330A (en) * | 1972-01-03 | 1977-01-25 | Techniservice Division Textured Yarn Co., Inc. | Textile treatment apparatus |
US4229404A (en) * | 1978-04-28 | 1980-10-21 | Phillips Petroleum Company | Method for drawing yarn |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2736944A (en) * | 1953-09-02 | 1956-03-06 | John Bright & Brothers Ltd | Means for stretching cords, yarns and the like |
BE523460A (en) * | 1953-09-23 | |||
US2921358A (en) * | 1956-01-26 | 1960-01-19 | Deering Milliken Res Corp | Apparatus for producing elasticized thermoplastic yarns |
-
1943
- 1943-08-20 US US499327A patent/US2394540A/en not_active Expired - Lifetime
-
1944
- 1944-08-21 GB GB15917/44A patent/GB581526A/en not_active Expired
Cited By (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2494649A (en) * | 1944-07-24 | 1950-01-17 | Celanese Corp | Method of tire building and material used therein |
US2611923A (en) * | 1949-08-31 | 1952-09-30 | Du Pont | Method and apparatus for the drawing of synthetic funicular structures |
US2677590A (en) * | 1950-07-07 | 1954-05-04 | Du Pont | Removal of porosity in wet-spun acrylonitrile filaments by treatment with heated fluids |
US2677591A (en) * | 1950-07-07 | 1954-05-04 | Du Pont | Removal of porosity in wet-spun acrylonitrile filaments by pressing against a hot surface |
US2869972A (en) * | 1952-12-31 | 1959-01-20 | Eastman Kodak Co | Method of treating yarns and filaments and products produced thereby |
US2799915A (en) * | 1953-03-30 | 1957-07-23 | Johns Manville | Thermal modification of acrylonitrile polymers |
US2913802A (en) * | 1953-07-16 | 1959-11-24 | Johns Manville | Thermal modification of acrylonitrile yarns |
US2821458A (en) * | 1954-04-08 | 1958-01-28 | Du Pont | Process for producing uniform polyacrylonitrile fibers by heat relaxing solvent containing undrawn fibers, removing solvent and drawing the fibers |
US3018157A (en) * | 1954-10-28 | 1962-01-23 | Du Pont | Process of producing uniformly dyeing polyacrylonitrile filaments by heat stretching the water wetted filaments |
US2934400A (en) * | 1955-03-19 | 1960-04-26 | Glanzstoff Ag | Process of manufacturing fibers of polyethylene terephthalate |
US3077004A (en) * | 1956-03-23 | 1963-02-12 | Du Pont | Filament drawing |
US2920176A (en) * | 1957-10-28 | 1960-01-05 | Chemstrand Corp | Heating device |
US3280241A (en) * | 1960-12-06 | 1966-10-18 | Scragg & Sons | Drawn branched filament |
US3336900A (en) * | 1966-04-06 | 1967-08-22 | Du Pont | Filamentary yarn lubricating apparatus |
US3825724A (en) * | 1971-08-16 | 1974-07-23 | Xerox Corp | Wrap adjust device for controlling engagement between a web and roller |
US4004330A (en) * | 1972-01-03 | 1977-01-25 | Techniservice Division Textured Yarn Co., Inc. | Textile treatment apparatus |
US4229404A (en) * | 1978-04-28 | 1980-10-21 | Phillips Petroleum Company | Method for drawing yarn |
Also Published As
Publication number | Publication date |
---|---|
GB581526A (en) | 1946-10-16 |
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