US2382699A - Slushing oil compositions - Google Patents
Slushing oil compositions Download PDFInfo
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- US2382699A US2382699A US372831A US37283141A US2382699A US 2382699 A US2382699 A US 2382699A US 372831 A US372831 A US 372831A US 37283141 A US37283141 A US 37283141A US 2382699 A US2382699 A US 2382699A
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- slushing
- amines
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M163/00—Lubricating compositions characterised by the additive being a mixture of a compound of unknown or incompletely defined constitution and a non-macromolecular compound, each of these compounds being essential
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M101/00—Lubricating compositions characterised by the base-material being a mineral or fatty oil
- C10M101/02—Petroleum fractions
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M133/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen
- C10M133/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen having a carbon chain of less than 30 atoms
- C10M133/04—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M133/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M133/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen
- C10M133/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen having a carbon chain of less than 30 atoms
- C10M133/04—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M133/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
- C10M133/08—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M133/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen
- C10M133/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen having a carbon chain of less than 30 atoms
- C10M133/38—Heterocyclic nitrogen compounds
- C10M133/48—Heterocyclic nitrogen compounds the ring containing both nitrogen and oxygen
- C10M133/50—Morpholines
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M135/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing sulfur, selenium or tellurium
- C10M135/08—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing sulfur, selenium or tellurium containing a sulfur-to-oxygen bond
- C10M135/10—Sulfonic acids or derivatives thereof
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- C10M159/00—Lubricating compositions characterised by the additive being of unknown or incompletely defined constitution
- C10M159/02—Natural products
- C10M159/08—Fatty oils
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- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
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- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
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- C10M2203/1006—Petroleum or coal fractions, e.g. tars, solvents, bitumen used as base material
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- C10M2203/104—Aromatic fractions
- C10M2203/1045—Aromatic fractions used as base material
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- C10M2203/106—Naphthenic fractions
- C10M2203/1065—Naphthenic fractions used as base material
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- C10M2203/108—Residual fractions, e.g. bright stocks
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- C10M2203/1085—Residual fractions, e.g. bright stocks used as base material
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/18—Natural waxes, e.g. ceresin, ozocerite, bees wax, carnauba; Degras
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- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/40—Fatty vegetable or animal oils
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/40—Fatty vegetable or animal oils
- C10M2207/402—Castor oils
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- C10M2207/40—Fatty vegetable or animal oils
- C10M2207/404—Fatty vegetable or animal oils obtained from genetically modified species
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- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
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- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
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- C10M2215/042—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
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- C10M2215/044—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms having cycloaliphatic groups
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- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
- C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
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- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
Definitions
- This invention relates to slushing compositions, that is, to non-drying compositions of matter for arrestin preventing and inhibiting the corrosion of metals.
- slushing composition involves the formation of a relatively thick, viscous liquid or semisolid layer which is easily removable from the surfaces over which it is spread by wiping with a cloth or flushing with a readily available solvent. More durable coatings may be obtained by employing a more viscous oil base and heating the mixture prior to application to allow better treatment of the surface. In no case, however. is the protective layer of the nature of a difllcultly-removable varnish-like layer.
- the use of slushing compositions is particularly advantageous when metallic surfaces have to be temporarily protected such as engine parts during storage or tubing during shipment.
- compositions of the invention are therefore improved slushing oil compositions which contain in addition to the usual constituents of the nature of a protective base material which may be a fatty compound, a mineral oil of about lubricating consistency or a more resistant non-drying coating material, small amounts of salts of nitrogen base compounds such as the organic amines and heterocyclic nitrogen bases, and organic acids.
- a protective base material which may be a fatty compound, a mineral oil of about lubricating consistency or a more resistant non-drying coating material
- small amounts of salts of nitrogen base compounds such as the organic amines and heterocyclic nitrogen bases, and organic acids.
- a type of anti-rust composition which is appreciably improved by the addition thereto of the compounds of this invention is that disclosed in Patent 2,182,992.
- These compositions are composed of a petroleum oil of lubricating oil consistency blended with a fatty compound, such as degras, and mahogany soap such as an alkaline metal soap of the oil-soluble sulfonates derived from petroleum by treating oils with concentrated sulfuric acid.
- a fatty compound such as degras
- mahogany soap such as an alkaline metal soap of the oil-soluble sulfonates derived from petroleum by treating oils with concentrated sulfuric acid.
- the following formula is a specific example:
- Amines which uponreaction with an organic acid are hydrophilic are the alkylol amines such as phenyl ethanolamine, diethyl ethanolamine or ethyl diethanolamine, the lower molecular weight aliphatic primary amines such as the amyl and hexyl amines and the lower molecular weight 30 heterocyclic nitrogen bases such as pyridine, quinoline and morpholine.
- the acids which are suitable for reaction with these amines to prepare hydrophilic soaps are the unsaturated fatty acids of between and carbon atoms which react with the particular amine to form a stable compound.
- the naphthenic acids derived from petroleum especially those from the naphtha, gas oil and lubricating oil ranges, are advantageous in this regard.
- any amine which reacts with an organic acid to form a stable compound may be employed.
- the saturated fatty acids above carbon atoms are the least desirable 'acid constituents of the soaps suitable for compositions according to the. present invention.
- the amine salts employed in this invention as additives in the various compositions may be pre pared by the reaction of the amine or mixture of amines with an organic acid or mixture of such acids.
- Natural fats may be used as a source of the fatty acids and when so employed the fats may be saponifled by heating with the amine at a high temperature and thus the amine salt is prepared directly.
- the naphthenate salts may be formed-from the naphthenic acids derived from any of the naphthenic acid containing mineral oil crudes or fractions thereof.
- the acids may be extracted from the petroleum distillates by any of the known processes such as by distilling over caustic soda, extracting the sodium naphthenates invention, particularly the amine soaps in amounts between 0.25% and 5.0%.
- the efilcacy of coating compositions is evaluated by certain standard tests of which the humidifier test and displacement of various aqueous solutions are the more important.
- HUMDDIFIER TEST Tssr Psoczmms Sand blasted panels of hot rolled steel (automobile body sheet steel) are dipped into slushing compound samples, then maintained vertically in a box for 16 hours under ordinary room conditions. Compounds containing petrolatum are applied at temperatures above their melting point and fluid products are applied at room temperatures. The coated panels are thenplaced and spaced apart in an upright position in a humidifier chamber having a. volume of 16 cu. ft. and air of a given humidity and temperature is injected at a rate 01-12 cu. ft./hr. In the test the temperature is maintained at 100 F., the humidity at The time, in hours. for a panel subjected under these conditions to develop a rusting appearance is observed and recorded as the resistance life of the coating composition.
- Humidifier test [100' ilk-100% humidity] Hours to Compound initial rusts 1 Coastal SAE 40 lubricating oil 2 0 Coastal 2% diethylethsnolsmine oleste. c) Coastal 2% dicyclohexylamine naphthenste.
- the addition agents of this invention are effective as corrosion inhibitors and agents ior displacing moisture from metallic surfaces when incorporated in protective base compositions.
- the resultant compositions are eii'ective for protecting finely-polished surfaces and for heavy machinery parts exposed to weathering. Individual compontions have characteristics adapted for the particular uses for which theyare to be employed.
- the consistency of thevarious tions is determinedbytheservicereqmrementsandthemannor in which the compositions are to be an tothesuriacestobeprotected.
- the compomtions may contain in addition to the protective base a volatile material such as. gasoline which some time stter'applicstion ottbej composition to the surfaces ev porates and leaves behindalayerofprotectivemsterisloftheboss' and addition agent of this invention.
- compositions materials which are semi-solid or evensolidinordertowithstsndths ponelssrethensuspendedverticsllyior2hours ll eli'ectsotexposm e'toheavyrainssndothersting compositions of suitable consistency and protective quality no deterioration'of the aniline surfaces and therefore of engine eiilciency occurs as the result of storage or delays in shipment through varied atmospheric and climatic condi-' tions.
- compositiom of this invention that are suitable for use in the protection of engine assemblies have suitable solubilities in light lubricating oils which are generally employed as solvents to flush the system before placing the.
- the mechanism and operation of the tions m cnaine assemblies is particularly m aminesoaps inthevarlous-compositionsarenot undeifstoodandiliisnotdeairedtobelifitedto any particular theory as to the operation thereof, itisbelievedthattheaminesoapspresentinthe compositions have some etfect in neutralizing nascent .acids formed nearthe surface of the metals.
- scope have an actiondiifer-' ent from thatwhen dissolved in water and have capacity to inhibit the development of electrochemical relations in the surface of the metal.
- a slushing composition comprising a viscous petroleum fraction to which is added 5% degras,
Description
I Patented Aug. 14, i945 SLUSHING OIL COMPOSITIONS Gordon W. Duncan, Scotch Plains, N. 1., asslgnor to Standard Oil Development Company, acor- 4 poration of Delaware No Drawing. Application January 2, 1941, Serial No. 372,831
1 Claim. (01. 106-14) This invention relates to slushing compositions, that is, to non-drying compositions of matter for arrestin preventing and inhibiting the corrosion of metals.
The corrosion of a metal is considered the result of chemical reactions between the environ ment and the metallic surface due to differences in electromotive forces in and about the surface of the metal. By coating metallic surfaces with an inert, impervious film, the development of these electrochemical relations can be impeded and ar-- rested and thus active corrosion prevented. The use of a slushing composition involves the formation of a relatively thick, viscous liquid or semisolid layer which is easily removable from the surfaces over which it is spread by wiping with a cloth or flushing with a readily available solvent. More durable coatings may be obtained by employing a more viscous oil base and heating the mixture prior to application to allow better treatment of the surface. In no case, however. is the protective layer of the nature of a difllcultly-removable varnish-like layer. The use of slushing compositions is particularly advantageous when metallic surfaces have to be temporarily protected such as engine parts during storage or tubing during shipment.
It has now been found that when small amounts of salts of certain nitrogen base compounds and organic acids are incorporated in slushing compositions the composite is characterized by marked anti-corrosive properties and the capacity in many cases of the composites to displace moisture from the metallic surfaces. The compositions of the invention are therefore improved slushing oil compositions which contain in addition to the usual constituents of the nature of a protective base material which may be a fatty compound, a mineral oil of about lubricating consistency or a more resistant non-drying coating material, small amounts of salts of nitrogen base compounds such as the organic amines and heterocyclic nitrogen bases, and organic acids. These new type addition agents are either dissolved or finely dispersed in anti-rust compositions. A type of anti-rust composition which is appreciably improved by the addition thereto of the compounds of this invention is that disclosed in Patent 2,182,992. These compositions are composed of a petroleum oil of lubricating oil consistency blended with a fatty compound, such as degras, and mahogany soap such as an alkaline metal soap of the oil-soluble sulfonates derived from petroleum by treating oils with concentrated sulfuric acid. The following formula is a specific example:
. 'Per cent Petroleum oil (750 secs. Saybolt at 100 F.) 85 50% oil solution of sodium salts of oil-soluble sulfonic acids formed on treating petroleum stocks with concentrated sulfuric acid l Degras All of the common amines, that is, the readily available primary, secondary and tertiary amines, in combination with fatty or naphthenic acids have been found to be very eflective anti-corrosive agents when incorporated in hydrocarbon and fatty base protective compositions. A preferred class of compounds are the salts of those amines boiling above about 150 F. but which are sufliciently basic to form relatively stable soaps with the respective acids. Where water displacement properties are of importance, it has been found desirable to employ those soaps which have atflnity for water or appreciable solubility in water.
Amines which uponreaction with an organic acid are hydrophilic are the alkylol amines such as phenyl ethanolamine, diethyl ethanolamine or ethyl diethanolamine, the lower molecular weight aliphatic primary amines such as the amyl and hexyl amines and the lower molecular weight 30 heterocyclic nitrogen bases such as pyridine, quinoline and morpholine. The acids which are suitable for reaction with these amines to prepare hydrophilic soaps are the unsaturated fatty acids of between and carbon atoms which react with the particular amine to form a stable compound. Besides this group of unsaturated fatty acids,the naphthenic acids derived from petroleum especially those from the naphtha, gas oil and lubricating oil ranges, are advantageous in this regard. For the preparation of soaps within the scope of this invention however, that is for incorporation in compositions upon which no particular emphasis is laid as to their water displacing ability, any amine which reacts with an organic acid to form a stable compound may be employed. The saturated fatty acids above carbon atoms are the least desirable 'acid constituents of the soaps suitable for compositions according to the. present invention. I
The amine salts employed in this invention as additives in the various compositions may be pre pared by the reaction of the amine or mixture of amines with an organic acid or mixture of such acids. Natural fats may be used as a source of the fatty acids and when so employed the fats may be saponifled by heating with the amine at a high temperature and thus the amine salt is prepared directly. The naphthenate salts may be formed-from the naphthenic acids derived from any of the naphthenic acid containing mineral oil crudes or fractions thereof. The acids may be extracted from the petroleum distillates by any of the known processes such as by distilling over caustic soda, extracting the sodium naphthenates invention, particularly the amine soaps in amounts between 0.25% and 5.0%. and preferably between 1 and 3% by weight to mineral or vegetable oil or wax bases. In the case of vegetable oils, such as castor oil, amine soaps in amounts between 1 and 5%, with or without a diluent such as alcohol, are effective rust preventative compositions. Furthermore, these compositions have substantially no eifect upon rubber.
The efilcacy of coating compositions is evaluated by certain standard tests of which the humidifier test and displacement of various aqueous solutions are the more important.
HUMDDIFIER TEST Tssr Psoczmms Sand blasted panels of hot rolled steel (automobile body sheet steel) are dipped into slushing compound samples, then maintained vertically in a box for 16 hours under ordinary room conditions. Compounds containing petrolatum are applied at temperatures above their melting point and fluid products are applied at room temperatures. The coated panels are thenplaced and spaced apart in an upright position in a humidifier chamber having a. volume of 16 cu. ft. and air of a given humidity and temperature is injected at a rate 01-12 cu. ft./hr. In the test the temperature is maintained at 100 F., the humidity at The time, in hours. for a panel subjected under these conditions to develop a rusting appearance is observed and recorded as the resistance life of the coating composition.
The following data illustrate the rust preventative effectiveness of various compositions:
Humidifier test [100' ilk-100% humidity] Hours to Compound initial rusts 1 Coastal SAE 40 lubricating oil 2 0 Coastal 2% diethylethsnolsmine oleste. c) Coastal 2% dicyclohexylamine naphthenste. 192 2 slammg coasts] BAE 40 lubricating oil 30% petro- 24 b) 70% Coastsl SAE 40 lubricating 011 dicyclohexylsmine nsphthenste 250+ (a) Petrolstum 24-48 (h) Petrolstum+ 1% dicyclohexylsmine nsphthensm 200+ so Peimlstum 1% morpholine nsphthenste...-. 230+ e Clstoro 3 (b Castor oil 5% morpholine oleste no WATER DIBPIACEIIEN'I' TEST Sand blasted panels ot'hot rolled steel s dipped in an aqueous solution and while still wet are immediately immersed in the slushing compounds for a period of one minute. The
in the laboratory atmosphere, then washed with naphtha, and examined for signs of corrosion. In a series of tests, the effects of many different amine soaps in a mixture of petroleum naphtha and 25% SAE 20 mineral lubricating oil were investigated with the following results:
Tap water displacement tests V corrosion 1. 7 naphtha+25% SAE20 lubricat-' ingoil (A) Severe 2. A+2% morpholine naphthenaie-- None 1 3. A+2% morpholine oleate None 4. A+2% morpholine soap of oxidized wax acids, (partially solublelL--- Light 5. A+2% diethylethanolamine naphthenate None 6. A+2% diethylethanolamine oleate- None 7. A+2% diethylethanolamine soap oi oxidized wax acids (partially soluble) Light 8. A+2'% dicyclohexylamine naphthenate Trace 9. A+2% dicyclohexylamine soap of oxidized wax acids Light 10. A+2% dicyclohexylamine oleate Medium -()xidized wax acids include both unsaturated and saturated iatty acids.
In another test similarly conducted the ability or these agents to displace corrosive solutions other than tap water is evaluated.
Corrosion by aqueous solution displacanent-test 0.7% sodium chloride, 0.4% 1mm scid, 0.1% urea in distilled water.
The addition agents of this invention are effective as corrosion inhibitors and agents ior displacing moisture from metallic surfaces when incorporated in protective base compositions. The resultant compositions are eii'ective for protecting finely-polished surfaces and for heavy machinery parts exposed to weathering. Individual compontions have characteristics adapted for the particular uses for which theyare to be employed. The
consistency of thevarious tions is determinedbytheservicereqmrementsandthemannor in which the compositions are to be an tothesuriacestobeprotected. Thus.inthe oi' the protection of highly finished mete-l suchsscutlemandthennelysmundenghie surfaces the compomtions may contain in addition to the protective base a volatile material such as. gasoline which some time stter'applicstion ottbej composition to the surfaces ev porates and leaves behindalayerofprotectivemsterisloftheboss' and addition agent of this invention. In other cases it is preferable to employ as anti-rust compositions materials or which are semi-solid or evensolidinordertowithstsndths ponelssrethensuspendedverticsllyior2hours ll eli'ectsotexposm e'toheavyrainssndothersting compositions of suitable consistency and protective quality no deterioration'of the aniline surfaces and therefore of engine eiilciency occurs as the result of storage or delays in shipment through varied atmospheric and climatic condi-' tions. Furthermore, compositiom of this invention that are suitable for use in the protection of engine assemblies have suitable solubilities in light lubricating oils which are generally employed as solvents to flush the system before placing the.
engine in service. An added p perty of such compositions is that the constituents which are incorporated have no harmful effect upon lubricating oils which are subsequently employed in the lubrication of the engine. The addition agents of this invention as a group do not exert any deleterious effect upon mineral lubricating oils and therefore their incorporation-in slushing composivantageous. I
Although the mechanism and operation of the tions m cnaine assemblies is particularly m aminesoaps inthevarlous-compositionsarenot undeifstoodandiliisnotdeairedtobelifitedto any particular theory as to the operation thereof, itisbelievedthattheaminesoapspresentinthe compositions have some etfect in neutralizing nascent .acids formed nearthe surface of the metals.
. It is believed that the scope have an actiondiifer-' ent from thatwhen dissolved in water and have capacity to inhibit the development of electrochemical relations in the surface of the metal.
. It is not intended that this invention be limited to any of the particular examples which have been Y given'for purpose of illustration nor by any of the theories as to the operation of the invention,
but only by the app nded claims in which it is desired to claim all th novelty inherent in the invention.
What is claimed is:
A slushing composition comprising a viscous petroleum fraction to which is added 5% degras,
10% of a 50% oil solution of sodium salts of oilsoluble sulfonic acids formed on treating petroleum stocks with concentrated sulfuric acid and 0.25% to 5% of dicyclohexylamine naphthenate.
I GORDON w. Duncan.
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US372831A US2382699A (en) | 1941-01-02 | 1941-01-02 | Slushing oil compositions |
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US372831A US2382699A (en) | 1941-01-02 | 1941-01-02 | Slushing oil compositions |
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Cited By (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2430951A (en) * | 1943-11-27 | 1947-11-18 | Standard Oil Co | Corrosion inhibiting compositions |
US2481585A (en) * | 1945-09-17 | 1949-09-13 | Michael W Freeman | Lubricating oil composition |
US2484010A (en) * | 1946-12-31 | 1949-10-11 | Hercules Powder Co Ltd | Corrosion inhibitor |
US2490264A (en) * | 1947-10-10 | 1949-12-06 | Standard Oil Dev Co | Rust preventing composition |
US2520356A (en) * | 1946-09-25 | 1950-08-29 | Tide Water Associated Oil Comp | Method for inhibiting corrosion of ferrous metal |
US2533300A (en) * | 1945-12-31 | 1950-12-12 | Sinclair Refining Co | Morpholine mahogany sulfonate as a rust inhibitor for petroleum oils |
US2556289A (en) * | 1949-12-27 | 1951-06-12 | Standard Oil Dev Co | Wire rope lubricant |
US2564423A (en) * | 1948-05-29 | 1951-08-14 | Shell Dev | Corrosion preventive composition |
US2564422A (en) * | 1947-04-28 | 1951-08-14 | Shell Dev | Corrosion preventive composition |
US2574955A (en) * | 1948-07-14 | 1951-11-13 | Tide Water Associated Oil Comp | Esterified alkylolamine salts of acid esters of phosphorus acids |
US2574954A (en) * | 1947-09-23 | 1951-11-13 | Tide Water Associated Oil Comp | Rust-inhibiting compositions |
US2587955A (en) * | 1947-04-28 | 1952-03-04 | Shell Dev | Corrosion preventive composition |
US2695848A (en) * | 1950-05-25 | 1954-11-30 | Tide Water Associated Oil Comp | Rust-preventive compositions |
US2796408A (en) * | 1954-07-16 | 1957-06-18 | Standard Oil Co | Corrosion-inhibiting and fingerprintremoving composition |
US2798045A (en) * | 1954-09-27 | 1957-07-02 | Shell Dev | Lubricating compositions |
-
1941
- 1941-01-02 US US372831A patent/US2382699A/en not_active Expired - Lifetime
Cited By (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2430951A (en) * | 1943-11-27 | 1947-11-18 | Standard Oil Co | Corrosion inhibiting compositions |
US2481585A (en) * | 1945-09-17 | 1949-09-13 | Michael W Freeman | Lubricating oil composition |
US2533300A (en) * | 1945-12-31 | 1950-12-12 | Sinclair Refining Co | Morpholine mahogany sulfonate as a rust inhibitor for petroleum oils |
US2520356A (en) * | 1946-09-25 | 1950-08-29 | Tide Water Associated Oil Comp | Method for inhibiting corrosion of ferrous metal |
US2484010A (en) * | 1946-12-31 | 1949-10-11 | Hercules Powder Co Ltd | Corrosion inhibitor |
US2587955A (en) * | 1947-04-28 | 1952-03-04 | Shell Dev | Corrosion preventive composition |
US2564422A (en) * | 1947-04-28 | 1951-08-14 | Shell Dev | Corrosion preventive composition |
US2574954A (en) * | 1947-09-23 | 1951-11-13 | Tide Water Associated Oil Comp | Rust-inhibiting compositions |
US2490264A (en) * | 1947-10-10 | 1949-12-06 | Standard Oil Dev Co | Rust preventing composition |
US2564423A (en) * | 1948-05-29 | 1951-08-14 | Shell Dev | Corrosion preventive composition |
US2574955A (en) * | 1948-07-14 | 1951-11-13 | Tide Water Associated Oil Comp | Esterified alkylolamine salts of acid esters of phosphorus acids |
US2556289A (en) * | 1949-12-27 | 1951-06-12 | Standard Oil Dev Co | Wire rope lubricant |
US2695848A (en) * | 1950-05-25 | 1954-11-30 | Tide Water Associated Oil Comp | Rust-preventive compositions |
US2796408A (en) * | 1954-07-16 | 1957-06-18 | Standard Oil Co | Corrosion-inhibiting and fingerprintremoving composition |
US2798045A (en) * | 1954-09-27 | 1957-07-02 | Shell Dev | Lubricating compositions |
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