US2368945A - Process for the manufacture of preserved food products - Google Patents

Process for the manufacture of preserved food products Download PDF

Info

Publication number
US2368945A
US2368945A US348979A US34897940A US2368945A US 2368945 A US2368945 A US 2368945A US 348979 A US348979 A US 348979A US 34897940 A US34897940 A US 34897940A US 2368945 A US2368945 A US 2368945A
Authority
US
United States
Prior art keywords
paste
tubes
zone
evaporating
temperature
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US348979A
Inventor
David D Peebles
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Golden State Co Ltd
Original Assignee
Golden State Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Golden State Co Ltd filed Critical Golden State Co Ltd
Priority to US348979A priority Critical patent/US2368945A/en
Application granted granted Critical
Publication of US2368945A publication Critical patent/US2368945A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Images

Classifications

    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L19/00Products from fruits or vegetables; Preparation or treatment thereof
    • A23L19/09Mashed or comminuted products, e.g. pulp, purée, sauce, or products made therefrom, e.g. snacks

Definitions

  • This invention relates generally to processes for the manufacture of food products, particularly products of paste-like form. More specifically, the process is applicable to the processing and canning of tomato paste.
  • I first form a suitable pulp of the material which is to be preserved, as for example tomatoes.
  • the tomatoes can be crushed or passed through a suitable pulping machine, and the skins and seeds removed by suitable separating equipment.
  • the tomato pulp is then subjected to an evaporating operation which may be carried out in a number of stages, but which proceeds substantially continuously at a rapid rate without sub-
  • the type of evaporating equipment which is best suited for this purpose is one in which the material passes at high velocities through relatively long evaporating tubes.
  • a conduit or shroud H which surrounds the two groups of evaporating tubes.
  • Steam introduced through pipe l3 flows upwardly between the conduit I l and the outer walls of the jacket I2, before contacting the evaporating tubes, after which the steam flows downwardly about the evaporating tubes to a point near the lower end of these tubes, where condensate is drained away through pipe i6.
  • a separating chamber H which serves to receive material discharged from the lower ends of the evaporating tubes B, and which serves the purpose of separating liquid from vapor.
  • Pipe i8 is a vapor outlet from chamber I1, and a pipe l9 at the lower end of chamber i1 is for the purpose of draining away concentrate.
  • is secured to the lower side of tube sheet i l, and communicates with the inner group of evaporating pipes A.
  • the liquid to be concentrated is introduced into chamber 2
  • Pipe 20 serves to carry away non-condensable gases from the upper part of the heating J acket.
  • a distributing chamber 28 Above the tube sheet i0 and communicating with the upper ends of all of the'evaporating tubes, there is a distributing chamber 28.
  • the purpose of this chamber is to transfer and distribute material discharged from the upflow evaporating tubes A to the downiiow tubes B.
  • this chamber 23 is of. substantial height whereby the top wall 24 is considerably elevated above the upper ends of the evaporating tubes.
  • the purpose of this arrangement is to prevent plastering of the top wall 24, with the material discharged from tubes A, since it has been found that such plastering (which results from the use of a relatively short chamber 23) prevents proper operation of the evaporator, particularly in that it makes for uneven distribution of the liquid material into the downflow tubes B.
  • diffusion screens 26 In conjunction with chamber 23, I have shown spaced diffusion screens 26. These diffusion screens extend across the lower portion of the chamber 23, and are in the path of material discharged from the upper ends of the tubes A. They can be made of relatively coarse mesh wire, such as a woven wire screen of one-quarter inch mesh. These screens act in eflect as a brake against upwardvelocity of material, and in addition they aid in securing uniform distribution of small droplets of liquid to the tubes B.
  • the evaporating cycle of the equipment described involves an upfiow through the tubes A, followed immediately by downflow through the tubes B.
  • the concentrate separates from vapor and is immediately withdrawn through pipe l9.
  • the downflow tubes B There are in this instance about twice as many downflow tubes B as upfiow tubes, because of the larger volume of vapor passing through tubes B.
  • the mixed vapor-liquid phase material attains relatively high velocities in the evaporating tubes.
  • the mixed phase material discharges from the upper ends of the tubes A, it is impacted upon the screens 26, and immediately thereafter is discharged downwardly through the tubes B.
  • concentration As the material passes through the evaporator, and concentrate is not intermingled with more dilute material.
  • the evaporating tubes are relatively long in order to secure high velocities and in order to make possible a relatively high degree of conc'entration-by one pass of the material through the equipment.
  • the chamber 23 can vary in height from say 12 to 36 inches. Greater height can be used if desired.
  • the evaporator When using the evaporator for the concentration of tomato paste, it is operated at atmospheric pressure, that is, with the pressure in separator ll at substantially atmospheric. Steam at suitable pressure is supplied to jacket I 2, as for example about 30 pounds per square inch.
  • the paste is preheated to a suitable temperature such as about 180 F.
  • the tomato paste can be passed twice through evaporating equipment of the type. described, whereby assuming that the paste originally contains around 6.5% solids, it is concentrated to, from say about 15 to solids in the first pass. In the second pass it can be concentrated to from to 65% solids. It is particularly desirable that equipment of the type illustrated, involving high velocity flow through long evaporating tubes, be used for the final stage of concentration. The first stage up to say about 15% solids can be carried out in conventional vacuum evaporating equipment. Between evaporating stages care is taken to avoid storage at high temperature for a sufficient length of time to deteriorate color. The entire evaporating procedure is preferably maintained substantially continuous until the desired concentrate is obtained.
  • the paste-like concentrate as it is removed from the separator I1, is at a temperature depending upon pressures maintained within the evaporator. With operation at atmospheric pressures, the temperature will vary from 190' F. to 220 F., depending upon the barometric pressure existing at the plant location. In a typical instance the temperature has been 215 F., and in most instances it will range from 210 F.
  • the paste is immediately passed through a suitable cooling appliance.
  • the cooler is directly connected with the separator I! so that the paste is not contacted by air and its sterility is preserved. It serves to rapidly reduce the temperature of the paste to a value which is still capable of sterilizing, but at which color is not impaired at a rapid rate, as for example 190 F. to 195 F. While at this temperature, it is introduced into cans by means of suitable canning machinery, and immediately after the cans are sealed they are tipped over to insure proper sterilization of the' head spaces in the cans. By using sterilized cans and by preventing introduction of micro-organisms while the cans are being filled and sealed, the paste can be cooled to lower temperatures than those specified, such as F., thus avoiding an extended cooling period after the cans are filled and sealed.
  • the paste may be at a temperature of 190 F. when it is introduced into the cans.
  • the lid of the can is immediately contacted with the hot paste, and complete sterilization of the interior of the can takes place without resorting to additional heat treatment.
  • Tomato paste canned according to my process retains its fresh color and flavor, due to the fact that the treatment prior to introducing the material into the cans occurs at a rapid continuous rate with proper regard to time and temperature factors, such as cause color and flavor impairment.
  • the desirable body is attributed to a conditioning of certain gel forming ingredients oi.- the paste, such as pectin.
  • the material is simultaneously concentrated and subjected to over .a short intervalsterilizing temperatures of time.
  • the paste has a good body in that it will stand up when poured upon a fiat surface, and in that the surface has a paste to be produced in said zone during formation of water vapor, supplying suflicient heat through the walls of said zone to maintain said temperature and cause formation oi. water vapor in said zone to produce said concentrated paste, maintaining a high velocity of flow of said streams in said zone to produce a mixed vaporliquid phase material in said zone, discharging the resulting mixture of concentrated paste and vapor from said zone and separating the sterilized concentrated paste from said vapor.
  • the process of preparing a concentrated and sterilized tomato paste from tomato pulp containing solids and water without substantially impairing the color and body of the resulting paste which comprises, passing the tomato pulp in a plurality of elongated flowing streams through a heating zone, maintaining a. temperature between 190 and 220 F. in said zone during formation of water vapor, supplying suflicient heat through the walls of said zone to maintain saidtemperature and cause formation of water vapor in said zone to produce said concentrated paste, maintaining a high velocity of flow of said streams in said zone to produce a mixed vaporliquid phase material in said zone, discharging the resulting mixture concentrated paste and vapor from said zone, separating the sterilized concentrated paste from said vapor.
  • the process of preparing a concentrated and sterilized tomato paste from tomato pulp containing solids and water without substantially impairing the color and body of the resulting paste which comprises, preheating the tomato pulp to a temperature of approximately 180 F., passing the preheated tomato pulp in a plurality of elongated flowing streams through a heating zone, maintaining a temperature between 190 and 220 F.

Description

Feb. 6, 1945. PEEBLES 2,368,945
I PRocEss FOR THE MANUFACTURE OF PRESERVED FOOD PRODUCTS Filed July 31, 1940 IINVENTOR fla /d fl. Peek/65 ATTOR N E Y stantial rest or storage of the hot material.
Patented Feb. 6, 1945 PROCESS FOR THE MANUFACTURE OF PRESERVED FOOD PRODUCTS David D. Peebles, Berkeley, Calif; minor to Golden State Company, Ltd., San Francisc Calii'., a corporation of Delaware Application July 31, 1940, Serial No. 348,979
4 Claims.
This invention relates generally to processes for the manufacture of food products, particularly products of paste-like form. More specifically, the process is applicable to the processing and canning of tomato paste.
In the preparation of tomato paste, it has been common practice'to either concentrate the pulp by open kettle evaporation, or by vacuum evaporation. Evaporation in open kettles gives the paste a desirable body, but impairs color and like heat sensitive properties. By desirable body, I have reference to the ability of a final product containing at least 25% solids to stand up when poured out on a flat surface, and to have a grainy surface texture. Vacuum evaporation is capable of producing a paste without serious color impairment, but will not produce a product having the desired body. Because of serious color impairment with open kettle evaporation, it has been common practice to introduce artificial coloring materials in order to simulate a natural fresh color. a o
I have found that the natural fresh color of tomato paste or like material, and other desirable heat sensitive properties, can be retained by proper treatment of the material prior to introducing the paste into cans, and at the same time the desired body can also be imparted to the product. It is consequently an object of the present invention to provide such an improved process, applicable particularly to tomato paste, but which can also be used on related products involving somewhat the same problems.
In carrying out the present process, I first form a suitable pulp of the material which is to be preserved, as for example tomatoes. Thus the tomatoes can be crushed or passed through a suitable pulping machine, and the skins and seeds removed by suitable separating equipment. The tomato pulp is then subjected to an evaporating operation which may be carried out in a number of stages, but which proceeds substantially continuously at a rapid rate without sub- The type of evaporating equipment which is best suited for this purpose is one in which the material passes at high velocities through relatively long evaporating tubes.
I have found it particularly desirable to carry out the last stage of evaporation by use of equipment such as illustrated in the accompanying drawing. To briefly describe this equipment, it consists of two groups of evaporating tubes A and B. The upper ends of these tubes are attached to a tube sheet l0, and the lower ends to the tube sheet ll. Surrounding the evaporator tubes A and B there is a heater Jacket l2 into which steam can be introduced through the pipe connection l3.
Extending upwardly within the steam Jacket l2, there is a conduit or shroud H, which surrounds the two groups of evaporating tubes. Steam introduced through pipe l3 flows upwardly between the conduit I l and the outer walls of the jacket I2, before contacting the evaporating tubes, after which the steam flows downwardly about the evaporating tubes to a point near the lower end of these tubes, where condensate is drained away through pipe i6. Below the tube sheet I I there is a separating chamber H, which serves to receive material discharged from the lower ends of the evaporating tubes B, and which serves the purpose of separating liquid from vapor. Pipe i8 is a vapor outlet from chamber I1, and a pipe l9 at the lower end of chamber i1 is for the purpose of draining away concentrate. Chamber 2| is secured to the lower side of tube sheet i l, and communicates with the inner group of evaporating pipes A. The liquid to be concentrated is introduced into chamber 2| through pipe 22. Pipe 20 serves to carry away non-condensable gases from the upper part of the heating J acket.
Above the tube sheet i0 and communicating with the upper ends of all of the'evaporating tubes, there is a distributing chamber 28. The purpose of this chamber is to transfer and distribute material discharged from the upflow evaporating tubes A to the downiiow tubes B. Note that this chamber 23 is of. substantial height whereby the top wall 24 is considerably elevated above the upper ends of the evaporating tubes. The purpose of this arrangement is to prevent plastering of the top wall 24, with the material discharged from tubes A, since it has been found that such plastering (which results from the use of a relatively short chamber 23) prevents proper operation of the evaporator, particularly in that it makes for uneven distribution of the liquid material into the downflow tubes B.
In conjunction with chamber 23, I have shown spaced diffusion screens 26. These diffusion screens extend across the lower portion of the chamber 23, and are in the path of material discharged from the upper ends of the tubes A. They can be made of relatively coarse mesh wire, such as a woven wire screen of one-quarter inch mesh. These screens act in eflect as a brake against upwardvelocity of material, and in addition they aid in securing uniform distribution of small droplets of liquid to the tubes B.
As will be evident from the foregoing description, the evaporating cycle of the equipment described involves an upfiow through the tubes A, followed immediately by downflow through the tubes B. In the separator I 'I the concentrate separates from vapor and is immediately withdrawn through pipe l9. There are in this instance about twice as many downflow tubes B as upfiow tubes, because of the larger volume of vapor passing through tubes B.
In operating the above evaporator the mixed vapor-liquid phase material attains relatively high velocities in the evaporating tubes. As the mixed phase material discharges from the upper ends of the tubes A, it is impacted upon the screens 26, and immediately thereafter is discharged downwardly through the tubes B. There is no plastering of the walls of chamber 23 with concentrate, and there is a relatively even distribution in the downflow tubes B, with the liquid phase material being introduced into these tubes in the form of droplets or atomized particles. There is a continuous increase in concentration as the material passes through the evaporator, and concentrate is not intermingled with more dilute material.
The evaporating tubes are relatively long in order to secure high velocities and in order to make possible a relatively high degree of conc'entration-by one pass of the material through the equipment. For example, in one installation where the evaporating tubes are 1% inches inside diameter, they are 20 feet in length. The chamber 23 can vary in height from say 12 to 36 inches. Greater height can be used if desired. When using the evaporator for the concentration of tomato paste, it is operated at atmospheric pressure, that is, with the pressure in separator ll at substantially atmospheric. Steam at suitable pressure is supplied to jacket I 2, as for example about 30 pounds per square inch. Immediately before being introduced through pipe 22 the paste is preheated to a suitable temperature such as about 180 F.
To continue with the description of my process, the tomato paste can be passed twice through evaporating equipment of the type. described, whereby assuming that the paste originally contains around 6.5% solids, it is concentrated to, from say about 15 to solids in the first pass. In the second pass it can be concentrated to from to 65% solids. It is particularly desirable that equipment of the type illustrated, involving high velocity flow through long evaporating tubes, be used for the final stage of concentration. The first stage up to say about 15% solids can be carried out in conventional vacuum evaporating equipment. Between evaporating stages care is taken to avoid storage at high temperature for a sufficient length of time to deteriorate color. The entire evaporating procedure is preferably maintained substantially continuous until the desired concentrate is obtained.
The paste-like concentrate, as it is removed from the separator I1, is at a temperature depending upon pressures maintained within the evaporator. With operation at atmospheric pressures, the temperature will vary from 190' F. to 220 F., depending upon the barometric pressure existing at the plant location. In a typical instance the temperature has been 215 F., and in most instances it will range from 210 F.
to 220 F. Assuming that the temperature is in excess of about 195 F., the paste is immediately passed through a suitable cooling appliance. The cooler is directly connected with the separator I! so that the paste is not contacted by air and its sterility is preserved. It serves to rapidly reduce the temperature of the paste to a value which is still capable of sterilizing, but at which color is not impaired at a rapid rate, as for example 190 F. to 195 F. While at this temperature, it is introduced into cans by means of suitable canning machinery, and immediately after the cans are sealed they are tipped over to insure proper sterilization of the' head spaces in the cans. By using sterilized cans and by preventing introduction of micro-organisms while the cans are being filled and sealed, the paste can be cooled to lower temperatures than those specified, such as F., thus avoiding an extended cooling period after the cans are filled and sealed.
In the foregoing reference has been made-to withdrawal of the paste from separator ll at temperatures ranging from 190 F. to 220 F. Such temperatures are definitely sterilizing to material like tomato paste. In fact, it is generally considered that temperatures above F. are sterilizing temperatures for tomato paste, although F. or higher is considered to be safer. Thus it may be said that my process carries out the final evaporating step whereby the paste is withdrawn at a sterilizing temperature.
It has been found that if the cans after being sealed are not immediately tipped over, the.
small space'between the lid and the upper surface of the paste may not be properly sterilized,
and therefore spoilage may occur, even though the paste may be at a temperature of 190 F. when it is introduced into the cans. When the cans are immediately tipped over after being filled and sealed, the lid of the can is immediately contacted with the hot paste, and complete sterilization of the interior of the can takes place without resorting to additional heat treatment.
Tomato paste canned according to my process retains its fresh color and flavor, due to the fact that the treatment prior to introducing the material into the cans occurs at a rapid continuous rate with proper regard to time and temperature factors, such as cause color and flavor impairment.
grainy texture. The desirable body is attributed to a conditioning of certain gel forming ingredients oi.- the paste, such as pectin. During treatment in the evaporator as described, the material is simultaneously concentrated and subjected to over .a short intervalsterilizing temperatures of time. a
This application is a continuation in part of my copending application Serial No. 223,682,
In addition the paste has a good body in that it will stand up when poured upon a fiat surface, and in that the surface has a paste to be produced in said zone during formation of water vapor, supplying suflicient heat through the walls of said zone to maintain said temperature and cause formation oi. water vapor in said zone to produce said concentrated paste, maintaining a high velocity of flow of said streams in said zone to produce a mixed vaporliquid phase material in said zone, discharging the resulting mixture of concentrated paste and vapor from said zone and separating the sterilized concentrated paste from said vapor.
2. The process of preparing a concentrated and sterilized tomato paste from tomato pulp containing solids and water without substantially impairing the color and body of the resulting paste, which comprises, passing the tomato pulp in a plurality of elongated flowing streams through a heating zone, maintaining a. temperature between 190 and 220 F. in said zone during formation of water vapor, supplying suflicient heat through the walls of said zone to maintain saidtemperature and cause formation of water vapor in said zone to produce said concentrated paste, maintaining a high velocity of flow of said streams in said zone to produce a mixed vaporliquid phase material in said zone, discharging the resulting mixture concentrated paste and vapor from said zone, separating the sterilized concentrated paste from said vapor.
3. The process of preparing a concentrated and sterilized tomato paste from tomato pulp containing solids and water without substantially impairing the color and body of the resulting paste, which comprises, preheating the tomato pulp to a temperature of approximately 180 F., passing the preheated tomato pulp in a plurality of elongated flowing streams through a heating zone, maintaining a temperature between 190 and 220 F. in said zone during formation of water vapor, supplying sufllcient heat through the walls 01' said zone to maintain said temperature and cause formation of water vapor in said zone to produce said concentrated paste, maintainingv a high velocity of flow of said streams in said zone to produce a mixed vaporliquid phase material in said zone, discharging the resulting mixture of concentrated paste and vapor from said zone and separatingrthe sterilized concentrated paste from said vapor while at a sterilizing temperature.
v 4. The process of preparing a concentrated and sterilized tomato paste from tomato pulp containing solids and water without substantially impairing the color and body 01' the, resulting paste, which comprises, passing the tomato pulp in a plurality of elongated flowing streams through a heating zone, maintaining a temperature between 210 and 220 F. in said zone during formation of water vapor therein, supplying suflicient heat through the walls of said zone to maintain said temperature and cause formation of water vapor in said zone to produce a concentrated paste containing at least 25% solids, maintaining a relatively high velocity of flow of said streams in said zone to produce a mixed vapor-liquid phase material in said zone, discharging the resulting mixture of .conceno trated paste and vapor from said zone and sepcontainers.
arating the sterilized concentrated paste from said vapor while at a sterilizing temperature, and cooling said concentrated paste to a temperature between approximately and F. preparatory to placed said cooled concentrated paste in sealed DAVID D. PEEBLES.
US348979A 1940-07-31 1940-07-31 Process for the manufacture of preserved food products Expired - Lifetime US2368945A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US348979A US2368945A (en) 1940-07-31 1940-07-31 Process for the manufacture of preserved food products

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US348979A US2368945A (en) 1940-07-31 1940-07-31 Process for the manufacture of preserved food products

Publications (1)

Publication Number Publication Date
US2368945A true US2368945A (en) 1945-02-06

Family

ID=23370383

Family Applications (1)

Application Number Title Priority Date Filing Date
US348979A Expired - Lifetime US2368945A (en) 1940-07-31 1940-07-31 Process for the manufacture of preserved food products

Country Status (1)

Country Link
US (1) US2368945A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2701771A (en) * 1949-06-24 1955-02-08 C & C Super Corp Preparation of sweetened fruit juice concentrate
US3052559A (en) * 1959-08-17 1962-09-04 Foremost Dairies Inc Sterilizing process
US3873753A (en) * 1970-05-26 1975-03-25 Purdue Research Foundation Method for processing and storing tomatoes
US20110080800A1 (en) * 2006-07-24 2011-04-07 Tarpaulin.Com, Inc. System and method for agitating pouched products

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2701771A (en) * 1949-06-24 1955-02-08 C & C Super Corp Preparation of sweetened fruit juice concentrate
US3052559A (en) * 1959-08-17 1962-09-04 Foremost Dairies Inc Sterilizing process
US3873753A (en) * 1970-05-26 1975-03-25 Purdue Research Foundation Method for processing and storing tomatoes
US20110080800A1 (en) * 2006-07-24 2011-04-07 Tarpaulin.Com, Inc. System and method for agitating pouched products
US8177415B1 (en) 2006-07-24 2012-05-15 Tarpaulin.Com, Inc. System for agitating pouched products
US8197117B2 (en) 2006-07-24 2012-06-12 Tarpaulin.Com, Inc. Method for agitating pouched products

Similar Documents

Publication Publication Date Title
US2999024A (en) Method of preparing cooked egg yolk and cooked egg yolk product
US2368945A (en) Process for the manufacture of preserved food products
CA1267066A (en) Processing and packaging system for flexible containers
US3391009A (en) Manufacture of concentrated fruit juice
US2395051A (en) Buttermaking means
US1949427A (en) Process for drying grain, seeds, and the like in vacua apparatus therefor
US3567470A (en) Milk sterilization process
US2423746A (en) Method for the evaporation and concentration of liquids
WO1996015677A1 (en) A plant for continuously sterilising fluids, such as milk and cream
US6706302B1 (en) Apparatus and method for treatment of fluent food products
US2076597A (en) Method of producing liquid evaporated blood
US3010832A (en) Method and apparatus for continuous heat-treatment of heat-sensitive liquids
US2257531A (en) Evaporating apparatus and method
US2644758A (en) Pasteurizing methods and apparatus
US2435424A (en) Regenerative heating device
US2343886A (en) Dairy product deodorizer
US2090985A (en) Evaporating apparatus and method
US3428463A (en) Method of producing high density,low viscosity fruit juice concentrate
US3512471A (en) Apparatus for removing water by evaporation from liquid mixtures
US2625488A (en) Processing of heat-sensitive fluids
US999707A (en) Process of desiccating milk.
US1295943A (en) Method of manufacturing food products from fruits and vegetables and the products.
US2732008A (en) Process of low temperature evaporation
US2115470A (en) Method of deodorizing and pasteurizing liquids
US1785530A (en) Method of crystallization