US2348220A - Adhesive paper - Google Patents

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US2348220A
US2348220A US373900A US37390041A US2348220A US 2348220 A US2348220 A US 2348220A US 373900 A US373900 A US 373900A US 37390041 A US37390041 A US 37390041A US 2348220 A US2348220 A US 2348220A
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Prior art keywords
tape
adhesive
paper
telegraph
polyvinyl alcohol
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US373900A
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Bernard L Kline
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Western Union Telegraph Co
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Western Union Telegraph Co
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00Adhesives in the form of films or foils
    • C09J7/30Adhesives in the form of films or foils characterised by the adhesive composition
    • C09J7/32Water-activated adhesive, e.g. for gummed paper
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00Adhesives in the form of films or foils
    • C09J7/20Adhesives in the form of films or foils characterised by their carriers
    • C09J7/21Paper; Textile fabrics
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S446/00Amusement devices: toys
    • Y10S446/901Detachably adhesive
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/28Web or sheet containing structurally defined element or component and having an adhesive outermost layer
    • Y10T428/2852Adhesive compositions
    • Y10T428/2878Adhesive compositions including addition polymer from unsaturated monomer
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/2738Coating or impregnation intended to function as an adhesive to solid surfaces subsequently associated therewith

Definitions

  • This invention relates generally to adhesive paper, and more particularly to an adhesive coated web or tape adapted for use with telegraph printers.
  • the printed tape which issues from the ticker passes to an accumulator or receptacle from which it is pulled by an operator who passes the tape through a manually held device that moistens the gummed side thereof, the operator then shearing oil and applying lengths of the moistened tape to a telegraph delivery blank, the various lengths of printed tape thus applied each comprising a line of the message on the blank and disposed one below the other on the blank so that the message may readily be read by the addressee.
  • An object of the present invention is to obviate various disadvantages of the gummed tape heretofore employed, and to produce a tape or web with an improved adhesive film or coating thereon, which coating is extremely thin and is substantially non-hygroscopic, does not appreciably curl or warp the web or tape, and in which spoking of the tape rolls does not occur, and in which there is no substantial shrinkage of the adhesive film.
  • Another object is a tape or web having on one side thereof an adhesive film which is thinner than that heretofore obtainable consistent with the characteristic of having strong adhesive properties, the film being so thin and of such character as normally to be substantially transparent, and in which means are provided for enabling the gummed side of the tape or web readily to be visually distinguishable from the ungummed side thereof.
  • Fig. 1 shows a telegraph printer and associated apparatus employing a telegraph tape having an adhesive coating thereon in accordance with the invention
  • Fig. 2 is a fragmentary view of the printed or ungummed side of the telegraph tape'illustrated in Fig. 1;
  • Fig. 3 is a fragmentary view of the gummed side of the tape of Fig. 2.
  • Fig. 1 shows .a table or cabinet 9 having on one end thereof a well known form of high speed telegraph printer P which receives the incoming telegraph signals in permutation code and prints, by means of selectable type bars it, the message characters on the upper ungummed side Ila (Fig. 2) of a narrow tape ii.
  • the printer is enclosed in a housing II, a portion of which housing has been broken away in Fig. 1 in order to disclose certain of the elements employed in printing the messages and advancing the tape through the printer.
  • the underside of the tape has thereon an extremely thin film of a water-soluble adhesive hereinafter described in detail, and indicated at I lb in Fig. 3.
  • the tape with the adhesive film thereon is fed from a supply roll of tape rotatably mounted in a housing fl which is secured adjacent to the printer P by means of a support It extending. from the printer strucpending ture.
  • the tape II is pulled through an opening in the housing I, and then is passed around a tape guide roller l1 and thence into the printer housing, the roller ll serving also to twist or change the plane of the tape so that it approaches the printer in a horizontal plane.
  • the tape passes into the printer and over a platen roller II where the printing operations take place, and then passes downwardly between a pressure roller I8 and the platen roller, the pressure roller and platen roller serving as feed rollers for advancing the tape thrbugh the printeras the printing operations proceed. After leaving the rollers l8 and I3, the
  • a typewriter ribbon 20 is positioned adjacent to the tape I] so that as the selected type bars ID are successively caused to strike on the ribbon 20 the proper characters will beprinted on the tape II.
  • the printer shown in the figure is adapted to both send andreceive, and for this purpose the printer has a keyboard with a group 01 ,keys 24 thereon, although it will beappreciated that the printer may be of the receivingonly type.
  • the printed tape is pulled from the tape accumulator chamber 23 by an operator who causes the tape'to pass through a manually held. device D for moistening the adhesive side of the tape in order to facilitate the application thereof to the backing sheet or telegraph delivery blank b, one of which blanks is shown lying.
  • the tape moistening device may be any of various known types suit able for the purpose. Generally, and as'shown,
  • the device comprises a hollow cylindrical body 25 which forms a water reservoir and is of a suitable size I to be grasped in. the hand of the operator. .When 1 not in use, and as shown in Fig. l, the device; may rest in a support 26 having an uppercon cave surface forlr eceiving the cylindrical body 25. .A removable-screw cap 21 is provided onthe erator, -after which the operation is repeated forward end of the reservoir 25 and serves as a means for replenishing the water supply in" the 4 'I'l1e"cap has a forwardly. extending wedge-shaped. wick support or nose piece :'2 lhaving at thei'ront end thereof a flat bottomreservoir.
  • a detachable tape guiding channel 31 is mount! 1 t ed on the reservoir by spring clips-32 and is held in proper position relative to thewick holder 28 by lugs in” the manner shown ,in the figure or in any other suitable manner.
  • the rearward end of the tape snubl5 ber 33 has a projecting thumb piece 40 which may readily be engaged by the thumb of the operator for raising the snubbing member 33 out of contact with the tape or for lessening the snubbing action on the tape as may be desired.
  • the moistener-device When it is necessary to load the moistener with tape to be applied to the blank b, the moistener-device is held in the hand of the operator, and the tape snubbing member 33 is held upwardly by means of pressure exerted downward- The tape is then passed through the tape channel 3
  • the I adhesive on the underside of the tape comprises a an extremely thin fllm of a water-soluble powthe surface of the telegraph blank as 'theftape 1 is applied thereto.
  • the nose piece 28 has awell or recessed portion therein for receiving a wick as desirable properties of causing the adhesive film formed thereby to be substantially non-hygroscopic, non-curling, non-spoking and havingno" appreciable shrinkage when applied to the telegraph tape, which tape ordinarily is' anar'roww manila paper tape.
  • the polyvinyl alcohol is applied in anaqueous solution to a web which islater cut into narrow strips 'to form tapes.
  • the extremely thin adhesive coating obtained not only enables much less adhesive per ream of paper to be used but also enables the tape to lie flatter and closer to the telegraph blank b, and thus the possibility of having the strips of tape pasted on the telegraph blank caught and torn or mutilated during transfer and delivery of the blank is substantially minimized.
  • the adhesive coating is substantially transparent and is not readily distinguishable from the ungummed side of the tape, so that when the tape II is pulled from the accumulator chamber 23 by the operator and passed through the tape moistening device D it has been extremely difficult for the operator to know which side of the tape is the coated or underside, particularly since the initial portion of' the tape may not have any printed characters thereon.
  • a suitable coloring pigment or dyr preferably a water soluble dye such as watersoluble aniline dyes and water-soluble phenol dyes, the dyes or other coloring agent being dis solved or dispersed in the polyvinyl alcohol solution in an amount sufficient to cause the adhesive film on the tape to have a contrasting color from that of the ungummed side of the tape, and thus the adhesive side of the tape may readily be distinguished from the ungummed side.
  • a suitable coloring pigment or dyr preferably a water soluble dye such as watersoluble aniline dyes and water-soluble phenol dyes, the dyes or other coloring agent being dis solved or dispersed in the polyvinyl alcohol solution in an amount sufficient to cause the adhesive film on the tape to have a contrasting color from that of the ungummed side of the tape, and thus the adhesive side of the tape may readily be distinguished from the ungummed side.
  • Dyes suit able for the purpose may comprise the so-called acid dyes, certain of which are water-soluble, such as Acid Fushsin Red, Acid Aniline Blue, and Acid Aniline Green, although preferably the so-called basic dyes or equivalents thereof are employed since they are substantially all soluble in water and usually are the strongest tinctorially, and of these dyes Rhodamine B, Magenta, Erythrosin, Naphthol Green, Malachite Green, Methylene Blue, and Methyl Violet are particularly suitable for the purpose.
  • the Rhodamine B or Magenta are preferred for use with telegraph tape.
  • the amount of such dyes used is exceew ingly small, being only a fractional part of one percent of the aqueous adhesive solution.
  • the concentration of the polyvinyl alcohol in the aqueous solution is maintained low, but for various purposes the concentration may vary as, for example, from two to twenty percent of the aqueous solution, depending upon the character of the tape or web coated and the method of applying the adhesive film thereto, the lower concentrations giving the thinner coatings for a given method of application. In practice it has been found convenient to use a concentra tion of four to eight percent of the polyvinyl alcohol.
  • the aqueous solution of the polyvinyl alcohol, together with the added dye or dyes may be applied to the web in any of various suitable manners known in the art, as by spraying, brushing, roller coating, or the like, after which the web is dried and then is ready for processing or converting and use.
  • a polyvinyl alcohol which is referred to in the trade as of medium viscosity (generally identified as having a viscosity of twenty centipoises in a 4% aqueous solution at 20 C.) preferably is employed, but if desired a high viscosity polyvinyl alcohol (generally identified as having a viscosity of fifty centipoises in a 4% aqueous solution at 20 C.) may also be employed, both of the foregoing types of polyvinyl alcohol being soluble in water at ordinary temperatures.
  • the polyvinyl alcohol which is obtainable commercially as a white or creamy-white powder, is stirred into the desired amount of water until all lumps are broken up and a smooth mixture is obtained, the mixture being heated slightly if desired to facilitate solution of the polyvinyl alcohol powder, the resulting solution being clear and substantially colorless.
  • the desired pigment or dye is then added to this solution in an amount sufiicient to give the desired color to the applied adhesive coating.
  • various well known animal or vege table glues may be employed with the polyvinyl alcohol, so that a greater amount of adhesive per ream of paper may be used, thereby to assure complete coverage of the paper with the adhesive, the amount of such animal or vegetable glue preferably being insufilcient to cause the adhesive coating to be hygroscopic to an undesirable extent.
  • the invention has been described with reference to an adhesive film or layer on a telegraph tape or web, but it will be understood that various advantages of the ad- 7 hesive film disclosed may be utilized in connection with tapes or webs which may be thus gummed over their entire areas or restricted areas thereof for various purposes, such as for wrapping and envelope flaps, labels, postage stamps, and others, and for certain of these purpo$s the addition of a pigment or dye for coloring the film may be unnecessary.
  • the expression tape or web is employed in a generic sense to define various of such tapes and webs and which may comprise paper, linen or other material suitable therefor.
  • An adhesive paper having on one side thereof a thin, dry, remoistenable, substantially nonhygroscopic adhesive film comprising a watersolu-ble polyvinyl alcohol of the type which is readily soluble in water of a temperature up to approximately 70 C.
  • An adhesive paper having on one side thereof a dry, remoistenable, adhesive film comprising a watersoluble polyvinyl alcohol of the type which is readily soluble in water of a temperature up to approximately 70 C., said adhesive film when dry being extremely thin and having the characteristic of being substantially nonhygroscopic, said polyvinyl alcohol being present in the adhesive film in an amount of the order of one to two pounds'per ream of paper.
  • An adhesive paper having on oneside thereof a dry, remoistenable, adhesive film comprising a water-soluble polyvinyl alcohol of the type which is readily soluble in water of a temperature up to approximately 70 C., said adhesive film being readily soluble in water at ordinary temperatures and so thin and of such character as nor mally to be substantially transparent and not readily distinguishable from the ungummed side of the paper, and means for causing the adhesive side of the paper readily to be visually'ldistinguishable from the ungummed side thereof, said means comprising a water-soluble dye dispersed throughout said adhesive film, said dye being of a diflerent color from that of the ungummed side of the paper to produce a distinct color contrast'between the adhesive side and the ungummed side of the paper.
  • An adhesive paper having on one side thereof a dry, remoistenable, adhesive film comprising a water-soluble polyvinyl alcohol of the type which is readily soluble in water of a temperature up to approximately 70 C., said adhesive film being readily soluble in water at ordinary temperatures and so thin and of such character as normally to be substantially transparent and not readily distinguishable from the ungummed side of the paper, and means for causing the adhesive side of the paper readily to be visually distinguishable from the ungummed side thereof, said means comprising a water-soluble basic dye dispersed throughout said adhesive film, said dye being of a different color from that of the ungummed side of the paper to produce a distinct color contrast between the adhesive side and the ungummed side of the paper.

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  • Organic Chemistry (AREA)
  • Adhesive Tapes (AREA)

Description

y 1944- B. L. KLINE 2,348,220
ADHESIVE PAPER Filed Jan. 10, 1941 FIG.2
HAPPY BIRTHDAY FIG. 3
INVENTOR 'B. L. KL! NE ATTORNEY Patented May 9, 1944 ADHESIVE PAPER Company York, N. Y., a corporation of New York ,New
Application January 10, 1941, Serial No. 373,900
Claims. (CL 117-122) This invention relates generally to adhesive paper, and more particularly to an adhesive coated web or tape adapted for use with telegraph printers.
It is a general practice in the reception of telegraph messages to cause the messages to be printed, as by a high speed telegraph printer, on a narrow gummed paper tape which is supplied from a roll of such tape moimted adjacent to or within the printer housing, the tape being fed through the printer as the characters are impressed on the ungummed side thereof in response to the received telegraph signals. The printed tape which issues from the ticker passes to an accumulator or receptacle from which it is pulled by an operator who passes the tape through a manually held device that moistens the gummed side thereof, the operator then shearing oil and applying lengths of the moistened tape to a telegraph delivery blank, the various lengths of printed tape thus applied each comprising a line of the message on the blank and disposed one below the other on the blank so that the message may readily be read by the addressee.
Prior to the present invention, various wellknown animal and vegetable glues were employed as the adhesive on the gummed side of the tape, but such gummed tape has exhibited numerous disadvantages. For example, many'of the adhesive coatings heretofore employed have been hygroscopic, and since the paper telegraph tape normally is hygroscopic to some extent, both the tape and adhesive coating absorb moisture from the surrounding air when the humidity is high, thus causing the adhesive coating to become sticky due to the absorbed moisture and tending to cause the gummed tape comprising adjoining convolutions of a tape roll to stick together, and the tape to stick to the platen and other parts of the printer and interfering with the operation of the printer and the proper advancement of the tape. If coatings were applied which were made substantially non-hygroscopic by the introduction of hardening compounds, then the adhesive was not readily moistened, particularly in dry weather, and the tape did not securely stick to the telegraph blank on which it was posted. Moreover, with the coatings formerly employed to produce gummed tape, it was generally necessary that the gummed sheet or web, after drying and prior to slitting, be passed through a fbreaking operation to break up the adhesive coating, which breaking operation was necessary to reduce curling and warping of the tape, spoking of the tape rolls, and other undesirable eflects resulting from shrinkage of the glue coating on the tape.
An object of the present invention is to obviate various disadvantages of the gummed tape heretofore employed, and to produce a tape or web with an improved adhesive film or coating thereon, which coating is extremely thin and is substantially non-hygroscopic, does not appreciably curl or warp the web or tape, and in which spoking of the tape rolls does not occur, and in which there is no substantial shrinkage of the adhesive film.
Another object is a tape or web having on one side thereof an adhesive film which is thinner than that heretofore obtainable consistent with the characteristic of having strong adhesive properties, the film being so thin and of such character as normally to be substantially transparent, and in which means are provided for enabling the gummed side of the tape or web readily to be visually distinguishable from the ungummed side thereof.
Other objects and advantages will be apparent from the following description, taken in connection with the accompanying drawing, in which:
Fig. 1 shows a telegraph printer and associated apparatus employing a telegraph tape having an adhesive coating thereon in accordance with the invention;
Fig. 2 is a fragmentary view of the printed or ungummed side of the telegraph tape'illustrated in Fig. 1; and
Fig. 3 is a fragmentary view of the gummed side of the tape of Fig. 2.
Referring to the drawing, Fig. 1 shows .a table or cabinet 9 having on one end thereof a well known form of high speed telegraph printer P which receives the incoming telegraph signals in permutation code and prints, by means of selectable type bars it, the message characters on the upper ungummed side Ila (Fig. 2) of a narrow tape ii. The printer is enclosed in a housing II, a portion of which housing has been broken away in Fig. 1 in order to disclose certain of the elements employed in printing the messages and advancing the tape through the printer. The underside of the tape has thereon an extremely thin film of a water-soluble adhesive hereinafter described in detail, and indicated at I lb in Fig. 3. Referring again to Fig. l, the tape with the adhesive film thereon is fed from a supply roll of tape rotatably mounted in a housing fl which is secured adjacent to the printer P by means of a support It extending. from the printer strucpending ture. As shown in the -flgure, the tape II is pulled through an opening in the housing I, and then is passed around a tape guide roller l1 and thence into the printer housing, the roller ll serving also to twist or change the plane of the tape so that it approaches the printer in a horizontal plane. The tape passes into the printer and over a platen roller II where the printing operations take place, and then passes downwardly between a pressure roller I8 and the platen roller, the pressure roller and platen roller serving as feed rollers for advancing the tape thrbugh the printeras the printing operations proceed. After leaving the rollers l8 and I3, the
tape passes out of the printer through a tape guide 2| and down a tape chute 22 into an accumulator or temporary storage chamber 33. A typewriter ribbon 20 is positioned adjacent to the tape I] so that as the selected type bars ID are successively caused to strike on the ribbon 20 the proper characters will beprinted on the tape II. The printer shown in the figure is adapted to both send andreceive, and for this purpose the printer has a keyboard with a group 01 ,keys 24 thereon, although it will beappreciated that the printer may be of the receivingonly type. v
The printed tape is pulled from the tape accumulator chamber 23 by an operator who causes the tape'to pass through a manually held. device D for moistening the adhesive side of the tape in order to facilitate the application thereof to the backing sheet or telegraph delivery blank b, one of which blanks is shown lying.
on the top of the table 9. The tape moistening device may be any of various known types suit able for the purpose. Generally, and as'shown,
it comprises a hollow cylindrical body 25 which forms a water reservoir and is of a suitable size I to be grasped in. the hand of the operator. .When 1 not in use, and as shown in Fig. l, the device; may rest in a support 26 having an uppercon cave surface forlr eceiving the cylindrical body 25. .A removable-screw cap 21 is provided onthe erator, -after which the operation is repeated forward end of the reservoir 25 and serves as a means for replenishing the water supply in" the 4 'I'l1e"cap has a forwardly. extending wedge-shaped. wick support or nose piece :'2 lhaving at thei'ront end thereof a flat bottomreservoir.
which is adaptedto engage with and slide along 28 or other form 'of moisture carrying medium, the wick well being in communication with, the
interior of there'ceiver 25 by means of apa's age,
not shown.
A detachable tape guiding channel 31 is mount! 1 t ed on the reservoir by spring clips-32 and is held in proper position relative to thewick holder 28 by lugs in" the manner shown ,in the figure or in any other suitable manner. A tape snubbing lever 33 is pivotally mounted on the tape'guiding channel, as by means of a'pin 3l' mounted in lugs secured to the channel 'fstructure.= The forward: end of the tape snubbing-,member' f3 has rounded portions 35 adapted to bejarfagainstj a sloping shoulder or abutment:.'36' jalso,secured; I
' ture, and depm; or-i p hat the to that peguiding channel fstru roii'r the member 33 is,
the tane belu fi 25 1y on the thumb piece 40.
10 is pulled from the tape moistening device, therebyto produce sufllcient resistance to the movement of the tape toinsure that the tape is pressed firmly against the moistening wick at all times. The rearward end of the tape snubl5 ber 33 has a projecting thumb piece 40 which may readily be engaged by the thumb of the operator for raising the snubbing member 33 out of contact with the tape or for lessening the snubbing action on the tape as may be desired.
20 When it is necessary to load the moistener with tape to be applied to the blank b, the moistener-device is held in the hand of the operator, and the tape snubbing member 33 is held upwardly by means of pressure exerted downward- The tape is then passed through the tape channel 3| and over the sloping shelf 36, under the guiding pin 31, over, the face-of the wick 23, and under the tape guiding ,rollers 38, after which the tape snub-, ao'bing member 33 is released so that its portion,
35 the gumined side of which has been moistened when the tape is pulled from the deviceD, is 1 placed in 'the proper position on the left hand portion of the blank-b and the end held by the .flngers'of one hand of the operator as the tape 9 moistening device is caused to press the tapefirmly on the' blank b, and as the right hand portion of the blank is approached the tape is shea'red oif, by means of a thimble having a .fshearingedge and worn on the hand of the opuntil the entire message has been pasted on the blank! .Inaccordance with the present invention the I adhesive on the underside of the tape comprises a an extremely thin fllm of a water-soluble powthe surface of the telegraph blank as 'theftape 1 is applied thereto. The nose piece 28 has awell or recessed portion therein for receiving a wick as desirable properties of causing the adhesive film formed thereby to be substantially non-hygroscopic, non-curling, non-spoking and havingno" appreciable shrinkage when applied to the telegraph tape, which tape ordinarily is' anar'roww manila paper tape.
The polyvinyl alcohol is applied in anaqueous solution to a web which islater cut into narrow strips 'to form tapes.
g5 Several of the suitable polyvinyl alcohols may be obtained as a commercial product and have thecharacteristio-inthat they dissolve readily in water of a temperature up. to approximately .'l0 C., ,and the' concentration of the aqueous 7o solutionof the} polyvinyl alcohol may be such that the resultant adhesive film on the tape when dry is extremely while at the same time retaining the characteristic of being a powerful 'adhesive. Byjreason of the fact that an exse' 38 tremely thin'fllm. may thus be empl y the amount of polyvinyl alcohol, as compared to animal and vegetable glues of the types heretofore employed, may be very substantially reduced. For instance, on standard tapes of the type heretofore employed it was necessary to use approximately six pounds of glue per ream of paper (17 x 22 inches), but by using the solution of polyvinyl alcohol, particularly in the lower range of concentrations, suitable coatings in which the polyvinyl-alcohol is used in amounts as low as three-quarters of a pound to a pound per ream of paper have been obtained. In general it will be found that from one to two pounds of polyvinyl alcohol per ream will give satisfactory results for most purposes.
The extremely thin adhesive coating obtained not only enables much less adhesive per ream of paper to be used but also enables the tape to lie flatter and closer to the telegraph blank b, and thus the possibility of having the strips of tape pasted on the telegraph blank caught and torn or mutilated during transfer and delivery of the blank is substantially minimized. For instance, it is common in large telegraph exchanges to feed the various receiving blanks into belt conveyors or chutes for transporting the same to various points of delivery or for routing the messages for further transmission thereof, and if any of the tape strips pasted on the telegraph blanks have projecting edges or ends, there is a possibility of such edges or ends being caught on the belt conveyors or chutes through whichthe telegraph blanks pass, with consequent mutilation or tearing of the messages thereon. The very thin adhesive coating obtainable with the present invention not only eliminates this possibility but also, due to the fact that the tape lies closer to the blank than was heretofore possible, the appearance of the blank and message thereon is greatly improved.
When very thin adhesive coatings of the polyvinyl alcohol are employed, due to the extreme thinness of the adhesivefilm and also because of the colorless character of the polyvinyl alcohol, the adhesive coating is substantially transparent and is not readily distinguishable from the ungummed side of the tape, so that when the tape II is pulled from the accumulator chamber 23 by the operator and passed through the tape moistening device D it has been extremely difficult for the operator to know which side of the tape is the coated or underside, particularly since the initial portion of' the tape may not have any printed characters thereon. Thus, it has hap pened that the tape has been pulled through the tape moistening device with the adhesive side of the tape upwardly and when the printed characters on the ungummed side of the tape were reached they were underneath, so that the printed side of the tape would inadvertently come in contact with the moistening wick 29 and thus cause the printed characters to be defaced or mutilated for some interval of time before the operator noticed that the tape was being pulled through with the printed side underneath, thereby resulting in the mutilation and possible loss of one or more messages.
Moreover, when the tape supply for the printer becomes exhausted, it is necessary to insert a fresh roll of gummed tape in the tape housing II, and if an operator in pulling the tape H from the tape roll and passing it around the tape guide roller 11 cannot readily tell which is the gummed side of the tape, she may. twist the tape in the wrong direction where it passes around the roller l1, thus causing the adhesive side of the tape to be uppermost, so that the printing will take place on the gummed side of the tape, and thus prevent the tape from being applied to the blank b. A considerable length of printed tape may run off before such a condition would be noticed, and it would be necessary to then locally reproduce the messages on the ungummed side of another piece of tape, thus resulting in delay and also additional handling and expense in connection with the forwarding or delivery of the messages.
In order to obviate the possibility of mistaking the gummed and ungummed sides of the tape, there is added a suitable coloring pigment or dyr. preferably a water soluble dye such as watersoluble aniline dyes and water-soluble phenol dyes, the dyes or other coloring agent being dis solved or dispersed in the polyvinyl alcohol solution in an amount sufficient to cause the adhesive film on the tape to have a contrasting color from that of the ungummed side of the tape, and thus the adhesive side of the tape may readily be distinguished from the ungummed side. Dyes suit able for the purpose may comprise the so-called acid dyes, certain of which are water-soluble, such as Acid Fushsin Red, Acid Aniline Blue, and Acid Aniline Green, although preferably the so-called basic dyes or equivalents thereof are employed since they are substantially all soluble in water and usually are the strongest tinctorially, and of these dyes Rhodamine B, Magenta, Erythrosin, Naphthol Green, Malachite Green, Methylene Blue, and Methyl Violet are particularly suitable for the purpose. In practice, the Rhodamine B or Magenta are preferred for use with telegraph tape. The amount of such dyes used is exceew ingly small, being only a fractional part of one percent of the aqueous adhesive solution.
While all the foregoing dyes are suitable for the purposes of coloring the adhesive film on telegraph tape, if an adhesive web or film in accordance with the invention is employed for other purposes, it may be desirable to use those dyes which have been certified as suitable for food use, such as Acid Aniline Blue and Erythrosin. The addition of the foregoing dyes does not in any manner aifect the desired adhesive properties of the film, and selection of the particular color of the dye or combination of dyes employed will depend upon the color of the uncoated side of the web or paper.
Preferably, the concentration of the polyvinyl alcohol in the aqueous solution is maintained low, but for various purposes the concentration may vary as, for example, from two to twenty percent of the aqueous solution, depending upon the character of the tape or web coated and the method of applying the adhesive film thereto, the lower concentrations giving the thinner coatings for a given method of application. In practice it has been found convenient to use a concentra tion of four to eight percent of the polyvinyl alcohol. The aqueous solution of the polyvinyl alcohol, together with the added dye or dyes, may be applied to the web in any of various suitable manners known in the art, as by spraying, brushing, roller coating, or the like, after which the web is dried and then is ready for processing or converting and use. A polyvinyl alcohol which is referred to in the trade as of medium viscosity (generally identified as having a viscosity of twenty centipoises in a 4% aqueous solution at 20 C.) preferably is employed, but if desired a high viscosity polyvinyl alcohol (generally identified as having a viscosity of fifty centipoises in a 4% aqueous solution at 20 C.) may also be employed, both of the foregoing types of polyvinyl alcohol being soluble in water at ordinary temperatures.
In preparing the adhesive solution, the polyvinyl alcohol, which is obtainable commercially as a white or creamy-white powder, is stirred into the desired amount of water until all lumps are broken up and a smooth mixture is obtained, the mixture being heated slightly if desired to facilitate solution of the polyvinyl alcohol powder, the resulting solution being clear and substantially colorless. The desired pigment or dye is then added to this solution in an amount sufiicient to give the desired color to the applied adhesive coating.
If desired, various well known animal or vege table glues may be employed with the polyvinyl alcohol, so that a greater amount of adhesive per ream of paper may be used, thereby to assure complete coverage of the paper with the adhesive, the amount of such animal or vegetable glue preferably being insufilcient to cause the adhesive coating to be hygroscopic to an undesirable extent.
For purposes of illustration, the invention has been described with reference to an adhesive film or layer on a telegraph tape or web, but it will be understood that various advantages of the ad- 7 hesive film disclosed may be utilized in connection with tapes or webs which may be thus gummed over their entire areas or restricted areas thereof for various purposes, such as for wrapping and envelope flaps, labels, postage stamps, and others, and for certain of these purpo$s the addition of a pigment or dye for coloring the film may be unnecessary. For brevity, the expression tape or web is employed in a generic sense to define various of such tapes and webs and which may comprise paper, linen or other material suitable therefor.
I claim:
1. An adhesive paper having on one side thereof a thin, dry, remoistenable, substantially nonhygroscopic adhesive film comprising a watersolu-ble polyvinyl alcohol of the type which is readily soluble in water of a temperature up to approximately 70 C.
2. .An adhesive paper tape having on one side thereof a thin, dry, remoistenable, substantially non-hygroscopic adhesive film comprising a water-soluble polyvinyl alcohol of the type which is readily soluble in water of a temperature up to approximately C.'
3. An adhesive paper having on one side thereof a dry, remoistenable, adhesive film comprising a watersoluble polyvinyl alcohol of the type which is readily soluble in water of a temperature up to approximately 70 C., said adhesive film when dry being extremely thin and having the characteristic of being substantially nonhygroscopic, said polyvinyl alcohol being present in the adhesive film in an amount of the order of one to two pounds'per ream of paper.
4. An adhesive paper having on oneside thereof a dry, remoistenable, adhesive film comprising a water-soluble polyvinyl alcohol of the type which is readily soluble in water of a temperature up to approximately 70 C., said adhesive film being readily soluble in water at ordinary temperatures and so thin and of such character as nor mally to be substantially transparent and not readily distinguishable from the ungummed side of the paper, and means for causing the adhesive side of the paper readily to be visually'ldistinguishable from the ungummed side thereof, said means comprising a water-soluble dye dispersed throughout said adhesive film, said dye being of a diflerent color from that of the ungummed side of the paper to produce a distinct color contrast'between the adhesive side and the ungummed side of the paper.
5. An adhesive paper having on one side thereof a dry, remoistenable, adhesive film comprising a water-soluble polyvinyl alcohol of the type which is readily soluble in water of a temperature up to approximately 70 C., said adhesive film being readily soluble in water at ordinary temperatures and so thin and of such character as normally to be substantially transparent and not readily distinguishable from the ungummed side of the paper, and means for causing the adhesive side of the paper readily to be visually distinguishable from the ungummed side thereof, said means comprising a water-soluble basic dye dispersed throughout said adhesive film, said dye being of a different color from that of the ungummed side of the paper to produce a distinct color contrast between the adhesive side and the ungummed side of the paper.
BERNARD L. KLINE.
US373900A 1941-01-10 1941-01-10 Adhesive paper Expired - Lifetime US2348220A (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2804395A (en) * 1953-09-04 1957-08-27 Setrak K Boyajian Envelopes and the like with remoistenable adhesive comprising polyvinyl alcohol
US3477166A (en) * 1965-08-05 1969-11-11 Frank E Wolf Amusement and educational toy
EP0049483A2 (en) * 1980-10-04 1982-04-14 Joachim Dudzik Water-soluble label, method of manufacturing same and its application
US20110033698A1 (en) * 2009-06-14 2011-02-10 Woods Michael C Liner-Free Label and Systems
US11345113B2 (en) * 2011-08-30 2022-05-31 Cerium Group Limited Composite protective sheet material

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2804395A (en) * 1953-09-04 1957-08-27 Setrak K Boyajian Envelopes and the like with remoistenable adhesive comprising polyvinyl alcohol
US3477166A (en) * 1965-08-05 1969-11-11 Frank E Wolf Amusement and educational toy
EP0049483A2 (en) * 1980-10-04 1982-04-14 Joachim Dudzik Water-soluble label, method of manufacturing same and its application
EP0049483A3 (en) * 1980-10-04 1982-06-02 Joachim Dudzik Water-soluble label, method of manufacturing same and its application
US4444839A (en) * 1980-10-04 1984-04-24 Hoechst Aktiengesellschaft Water-soluble label, a process for its preparation and its use
US20110033698A1 (en) * 2009-06-14 2011-02-10 Woods Michael C Liner-Free Label and Systems
US9085384B2 (en) 2009-06-14 2015-07-21 Nulabel Technologies, Inc. Liner-free label and systems
US11345113B2 (en) * 2011-08-30 2022-05-31 Cerium Group Limited Composite protective sheet material

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