US2329731A - Drawing lubricant - Google Patents
Drawing lubricant Download PDFInfo
- Publication number
- US2329731A US2329731A US430585A US43058542A US2329731A US 2329731 A US2329731 A US 2329731A US 430585 A US430585 A US 430585A US 43058542 A US43058542 A US 43058542A US 2329731 A US2329731 A US 2329731A
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- US
- United States
- Prior art keywords
- soap
- metal
- hours
- immersing
- soap solution
- Prior art date
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- Expired - Lifetime
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M173/00—Lubricating compositions containing more than 10% water
- C10M173/02—Lubricating compositions containing more than 10% water not containing mineral or fatty oils
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/02—Water
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/24—Metal working without essential removal of material, e.g. forming, gorging, drawing, pressing, stamping, rolling or extruding; Punching metal
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/241—Manufacturing joint-less pipes
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/242—Hot working
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/243—Cold working
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/244—Metal working of specific metals
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/244—Metal working of specific metals
- C10N2040/245—Soft metals, e.g. aluminum
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/244—Metal working of specific metals
- C10N2040/246—Iron or steel
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/244—Metal working of specific metals
- C10N2040/247—Stainless steel
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2050/00—Form in which the lubricant is applied to the material being lubricated
- C10N2050/01—Emulsions, colloids, or micelles
Definitions
- This invention relates to a drawing lubricant which is particularly suitable for drawing relatively soft metals such as brass.
- the improved method herein described results in lower drawing pressures, lower tool and die wear and less pickup of metal by the drawing tools. In some applications it also enables one to eliminate an anneal between drawing operations or to perform a longer draw in a single operation.
- the lubricant consisting of an aqueous soap solution
- the metal to be drawn is immersed, sprayed or otherwise placed in contact for some time with the solution, much better results are obtained.
- the strength of the soap solution should vary from about 0.025% to 0.5% by weight of soap and preferably from 0.1% to 0.2% of soap is used.
- the soap used is one having a very low alkalinity and a fairly low titer, i. e., one which contains a high proportion of alkali metal oleate.
- the most important factor in drawing operations according to the present invention is the soaking or residence time of the metal to be drawn. It has been found that the soaking time should be from about 1 to or more hours and preferably from 3 to 8 hours.
- a further effect of usin a dilute soap solution is to increase hydrolysis and thus increase the concentration of acid soap which is formed.
- Figure 1 illustrates how the time of immersion affects the lubrication index. It can be seen that the index falls oil. rapidly when the time of immersion increases from a few seconds to several hours.
- the lubrication index is an expression used to show the approximate force required throughout the drawing operation. It is obtained by measuring the force continuously while drawing and adding the first maximum, the first minimum and the second maximum forces. Some lubricants require high initial force and much lower subsequent forces, while others require equal or higher subsequent forces in the drawing operation. Therefore, the lubrication index as herein used is representative of the over-all results which a lubricant gives. Obviously, the lower the index, the better is the lubricant.
- Figures 2 to 5 show the effect of immersion time and also show the eil'ect of concentration of soap on drawing forces.
- the ord nate represents force while the abscissa represents the length of draw.
- the scale is the same in each case.
- Figures are copies of the actual traces of an automatic recorder. Work is represented by the shaded area of each figure.
- Figure 2 illustrates the conventional practice-using a 2% solution of soap and immersing the piece to be drawn for 30 seconds.
- Figure 3 illustrates the use ofthe same concentration of soap with a 12 hour immersion period. It is apparent that considerably less power is consumed when the immersion time'is increased.
- Figure 4 illustrates the effect of using an aqueous solution containing 0.1% soap and immersing the pieces to be drawn for 30 seconds.
- Figure 5 illustrates the effect of using the be drawn for 12 hours. Both the initial force and the over-all power consumption are lower under these conditions. All of the above figures were obtained on an experimental machine making the fourth draw of -a calibre .30 cartridge case.
- another advantage of the present invention is the freedom from metal pick-up by the tools and dies.
- draw pieces were drawn which had been immersed in 2% soap solution for 30 seconds.
- the punch was found to be heavily coated with brass.
- Anal;- ysis of the coating disclosed that 2 mg. of copper had been deposited on the punch.
- the test was then repeated, using draw pieces which had been immersed for 6 hours in 0.1% soap. After drawing about 100 draw pieces, there was no visible deposit of brass on the punch.
- a further advantage of the present invention is that the apparent ductility of the metal is increased as determined by the Olsen cupping test.
- This test is one in which a sheet of the metal to be tested is supported by a die ring 1 inch in diameter and a 7 inch steel ball is pressed into the test metal to form a cup. The height of the cup which is formed before fracture and the distance from the die ring to the point of fracture give an indication of the apparent ductility of the metal.
- A7F helght oi main in. at time of fracture.
- metal forming is used to include drawing, cupping, extrusion, reverse extrusion, upsetting and the like.
- metal forming comprising immersing the metal to be formed in an aqueous soap solution for a period of at least one hour prior to forming. 2.
- metal forming the improve ment comprising immersing the metal to be formed in an aqueous soap solution containing from about 0.025% to 0.5% soap for a period of at least one hour prior to forming.
- the irm provement comprising immersing the metal to be formed in an aqueous soap solution containing from about 0.025% to 0.5% soap for a period of from 3 to 8 hours prior to forming.
- the im provement comprising immersing the metal to be formed in an aqueous soap solution for a period of from 3 to 8 hours prior to forming.
- the improvement comprising immersing the metal to be formed in an aqueous soap solution containing from about 0.1% to 0.2% of soap for a period 40 of at least one hour prior to forming.
- the improvement comprising immersing the metal to be formed in an aqueous soap solution containing from about 0.1% to 0.2% soap for'a period of from 3 to 8 hours prior to forming.
- the improvement comprising immersing the brass in an aqueous soap solution containing from about 0.1% to 0.2% soap for a period of from 3 to 8 hours prior to drawing.
Description
Sept. 21, 1943. s. SPRING 2,329,731
DRAWING LUBRICANT Filed Feb. 12, 1942 2 Sheets-Sheet 1 Email iFL fi yw ww TEM- 5. SPRING Sept. 21, 1943.
ANT ab. 12, 1942 HH E k a T WORK I! 67 af pfil Samuel. iprin M Q J W Patented Sept. 21, 1943 UNITED STATES PATENT OFFICE (Granted under the act of March 3, 1883, as
amended April 30, 1928; 370 0. G. 757) The invention described herein may be manufactured and used by or for the Government for governmental purposes, without the payment to me of any royalty thereon.
This invention relates to a drawing lubricant which is particularly suitable for drawing relatively soft metals such as brass.
In drawing brass it is customary to use an aqueous soap solution as a lubricant. Ordinarily about 2% by weight of soap is used, and the solution is applied to the work before drawing by dipping or spraying.
It is the object of' the present invention to provide an improved method of using known drawing lubricants. The improved method herein described results in lower drawing pressures, lower tool and die wear and less pickup of metal by the drawing tools. In some applications it also enables one to eliminate an anneal between drawing operations or to perform a longer draw in a single operation.
' In conventional drawing operations the lubricant, consisting of an aqueous soap solution, is applied to the piece to be drawn immediately before drawing. It has now been found that if a more dilute soap solution is used and the metal to be drawn is immersed, sprayed or otherwise placed in contact for some time with the solution, much better results are obtained. The strength of the soap solution should vary from about 0.025% to 0.5% by weight of soap and preferably from 0.1% to 0.2% of soap is used.
If extremely hard water is used in the preparation of the soap solution, slightly more soap may be used to compensate for the hardness. Although most ordinary soaps are satisfactory, preferably the soap used is one having a very low alkalinity and a fairly low titer, i. e., one which contains a high proportion of alkali metal oleate.
The most important factor in drawing operations according to the present invention is the soaking or residence time of the metal to be drawn. It has been found that the soaking time should be from about 1 to or more hours and preferably from 3 to 8 hours.
Although this invention is not predicated on any theory of its operation, it is believed that the long soaking time gives the molecules of the soap solution more opportunity to orient themselves at the water-metal interfacg and result in a more complete adsorption of' 'tfi'Y y acid and/ or acid soap. Similarly the use of the more dilute soap solution aids in orientation by lessennormal gel structure which permitsa greater rate of diffusion of the fatty acid and/or' acid soap molecules.
A further effect of usin a dilute soap solution is to increase hydrolysis and thus increase the concentration of acid soap which is formed.
Figure 1 illustrates how the time of immersion affects the lubrication index. It can be seen that the index falls oil. rapidly when the time of immersion increases from a few seconds to several hours. The lubrication index is an expression used to show the approximate force required throughout the drawing operation. It is obtained by measuring the force continuously while drawing and adding the first maximum, the first minimum and the second maximum forces. Some lubricants require high initial force and much lower subsequent forces, while others require equal or higher subsequent forces in the drawing operation. Therefore, the lubrication index as herein used is representative of the over-all results which a lubricant gives. Obviously, the lower the index, the better is the lubricant.
According to Figure 1, increasing the immersion time from a few seconds to 1 hour causes a considerable decrease in the lubrication index. Increasing the time to 3 hours auses an even greater decrease, and the decrease continues until a time of about 8 or 10 hours is reached- Thus, increasing the immersion time to only 1 hour gives very advantageous results according to the present invention, while increasing the time to about 8 hours gives the maximum benefit obtainable.
Figures 2 to 5 show the effect of immersion time and also show the eil'ect of concentration of soap on drawing forces. In each figure the ord nate represents force while the abscissa represents the length of draw. The scale is the same in each case. These curves are copies of the actual traces of an automatic recorder. Work is represented by the shaded area of each figure. Figure 2 illustrates the conventional practice-using a 2% solution of soap and immersing the piece to be drawn for 30 seconds. Figure 3 illustrates the use ofthe same concentration of soap with a 12 hour immersion period. It is apparent that considerably less power is consumed when the immersion time'is increased. Figure 4, illustrates the effect of using an aqueous solution containing 0.1% soap and immersing the pieces to be drawn for 30 seconds. The results are equal to or only slightly better than when the more concentrated soap solution is used. Figure 5 illustrates the effect of using the be drawn for 12 hours. Both the initial force and the over-all power consumption are lower under these conditions. All of the above figures were obtained on an experimental machine making the fourth draw of -a calibre .30 cartridge case.
Power consumption measurements were also made using a high speed commercial drawing machine. It was found that the machine running empty consumed 205 watt hours in a cycle equivalent to a drawing operation. When the machine was used for drawing cups the power consumption increased to 533 watt hours per draw for cups which had been immersed in 2% soap for 1 to 5 minutes. When cups were used which had been immersed in 0.1% soap solution for 7 hours the power decreased to 496 watt hours per draw.
In addition to decreasing the power consumption, another advantage of the present invention is the freedom from metal pick-up by the tools and dies. In one test 47 draw pieces were drawn which had been immersed in 2% soap solution for 30 seconds. At the end of this time the punch; was found to be heavily coated with brass. Anal;- ysis of the coating disclosed that 2 mg. of copper had been deposited on the punch. The test was then repeated, using draw pieces which had been immersed for 6 hours in 0.1% soap. After drawing about 100 draw pieces, there was no visible deposit of brass on the punch.
A further advantage of the present invention is that the apparent ductility of the metal is increased as determined by the Olsen cupping test. This test is one in which a sheet of the metal to be tested is supported by a die ring 1 inch in diameter and a 7 inch steel ball is pressed into the test metal to form a cup. The height of the cup which is formed before fracture and the distance from the die ring to the point of fracture give an indication of the apparent ductility of the metal.
In the data given below a cup was preformed to a height of .28 inch before a lubricant was applied. When a sheet of 7040 brass, 0.042 inch thick was used, the following data were obtained:
Where: A7F=helght oi main in. at time of fracture.
d=distnncsin .irombaseoicuptopointoflhcture This improved ductility allows longer individ- Y 0.1% soap solution and immersing the pieces to ual draws or, in some instances, the elimination of an anneal between drawing operations.
Throughout this specification frequent reference has been made to the drawing of brass. It
6 is obvious that this invention is equally applicable to the drawing of other ductile metals, such as, copper, zinc, or gliding metal, and is also applicable to other metal forming operations where metal is formed in a manner similar to drawing,
10 such as cupping, extrusion, reverse extrusion, up-
setting and the like.
In the claims the term metal forming is used to include drawing, cupping, extrusion, reverse extrusion, upsetting and the like.
I claim:
1. In the process of ,metal forming the improvement comprising immersing the metal to be formed in an aqueous soap solution for a period of at least one hour prior to forming. 2. In the process of metal forming the improve ment comprising immersing the metal to be formed in an aqueous soap solution containing from about 0.025% to 0.5% soap for a period of at least one hour prior to forming.
3. The process of claim 2 in which the soap has a low titer.
4. In the process of metal forming the irm provement comprising immersing the metal to be formed in an aqueous soap solution containing from about 0.025% to 0.5% soap for a period of from 3 to 8 hours prior to forming.
5. In the process of metal forming the im provement comprising immersing the metal to be formed in an aqueous soap solution for a period of from 3 to 8 hours prior to forming.
6. In the process of metal forming the improvement comprising immersing the metal to be formed in an aqueous soap solution containing from about 0.1% to 0.2% of soap for a period 40 of at least one hour prior to forming.
7. In the process of metal forming the improvement comprising immersing the metal to be formed in an aqueous soap solution containing from about 0.1% to 0.2% soap for'a period of from 3 to 8 hours prior to forming.
8. In the process of drawing metals the improvement comprising immersing the metal to be drawn for a period of at least one hour in an aqueous soap solution.
9. The process of claim 8 in which the soap has a low alkalinity and titer.
10. In the process of drawing brass the improvement comprising immersing the brass in an aqueous soap solution containing from about 0.1% to 0.2% soap for a period of from 3 to 8 hours prior to drawing.
SAMUEL SPRING.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US430585A US2329731A (en) | 1942-02-12 | 1942-02-12 | Drawing lubricant |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US430585A US2329731A (en) | 1942-02-12 | 1942-02-12 | Drawing lubricant |
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US2329731A true US2329731A (en) | 1943-09-21 |
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Application Number | Title | Priority Date | Filing Date |
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US430585A Expired - Lifetime US2329731A (en) | 1942-02-12 | 1942-02-12 | Drawing lubricant |
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Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2631978A (en) * | 1949-05-13 | 1953-03-17 | Frederick C Bersworth | Metalworking lubricant solution |
US2686488A (en) * | 1948-01-14 | 1954-08-17 | Harley A Montgomery | Method of treating and cold deep drawing sheet metal |
US2739128A (en) * | 1951-03-23 | 1956-03-20 | ||
US2902449A (en) * | 1952-12-01 | 1959-09-01 | Dehydag Gmbh | Aqueous lubricant composition |
US3098294A (en) * | 1960-11-30 | 1963-07-23 | Arthur M Shapiro | Lubricant for metal forming process |
US10316397B2 (en) * | 2016-03-11 | 2019-06-11 | Fuji Xerox Co., Ltd. | Method of preparing cylindrical metal member, metallic ingot for impact pressing, and method of preparing electrophotographic photoreceptor |
-
1942
- 1942-02-12 US US430585A patent/US2329731A/en not_active Expired - Lifetime
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2686488A (en) * | 1948-01-14 | 1954-08-17 | Harley A Montgomery | Method of treating and cold deep drawing sheet metal |
US2631978A (en) * | 1949-05-13 | 1953-03-17 | Frederick C Bersworth | Metalworking lubricant solution |
US2739128A (en) * | 1951-03-23 | 1956-03-20 | ||
US2902449A (en) * | 1952-12-01 | 1959-09-01 | Dehydag Gmbh | Aqueous lubricant composition |
US3098294A (en) * | 1960-11-30 | 1963-07-23 | Arthur M Shapiro | Lubricant for metal forming process |
US10316397B2 (en) * | 2016-03-11 | 2019-06-11 | Fuji Xerox Co., Ltd. | Method of preparing cylindrical metal member, metallic ingot for impact pressing, and method of preparing electrophotographic photoreceptor |
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