US2322146A - Method and apparatus for removing coke from coking chambers - Google Patents

Method and apparatus for removing coke from coking chambers Download PDF

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US2322146A
US2322146A US407233A US40723341A US2322146A US 2322146 A US2322146 A US 2322146A US 407233 A US407233 A US 407233A US 40723341 A US40723341 A US 40723341A US 2322146 A US2322146 A US 2322146A
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coke
cutting
chamber
arm
cut
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US407233A
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Herman C Kuhn
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Sinclair Refining Co
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Sinclair Refining Co
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G9/00Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G9/14Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils in pipes or coils with or without auxiliary means, e.g. digesters, soaking drums, expansion means
    • C10G9/18Apparatus
    • C10G9/20Tube furnaces
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10BDESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B33/00Discharging devices; Coke guides
    • C10B33/006Decoking tools, e.g. hydraulic coke removing tools with boring or cutting nozzles

Definitions

  • the invention also includes novel apparatus adapted to this purpose.
  • the invention has utility with respect to other industrial operations, it is particularly applicable to the removal of coke deposits from the coking chambers of apparatus used in the processing of hydrocarbon oils.
  • My improved method of removing coke consists primarily in moving a cutting member radially and helically upwardly through the. coke deposit to progressively form a helical cut extending into the coke deposit a material distance, and a distance suificient that when the coke behind the forward edge of the cut is broken from the body of coke, the major portion will be in relatively large pieces, rather than in fines, and, as the cutting progresses through the coke bed, systematically breaking off the coke underlying the cut by the downward application of pressure thereon independently of the cutting action at a predetermined distanceto the rear of the forward edge of the cut.
  • the helical cut formed as Just described preferably extends from approximately the center .of the bed outwardly to a point just short of the-inner surface of the walls of the chamber.
  • the means forsystematically breaking ofi the coke underlying the cut may take various forms, and although independent of the cutter may be carried by, or form a part of the support for the.
  • the coke is broken off by mechanically forcing the upper and lower surfaces of the cut apart either continuously, as by means of a wedging action, or by periodic expansion at apoint along the helical cut a predetermined distance back of the cutting edge.
  • the cutting and breaking operations may with advantage be eflected by means of the novel apparatus presently to be described.
  • the chamber is first cut oil from the processing operation by means of valves or the like in the connecting lines and the chamber is freed of inflammable or combustible material such as oil or oil vapors in the customary manner.
  • the manway covers are then removed from the top and bottom of the chamber.
  • My invention includes a combination of operation especially designed to cooperate in overcoming the difficulties presented by such chamber arrangement. It includes also a novel combination of apparatus adapted to be inserted into the chamber through the restricted area of the manway and to cooperate in the carrying out of the several operations.
  • such guidance and support may be provided by first drilling a centering hole along the central axis of the coke bed and providing a pilot on the upper end of the cutting tool adapted to be contlnuously wedged into this centering hole as the cutting tool is forced upwardly.
  • This second operation may be readily accomplished in accordance with my invention by means of a novel device to be presently described designed to cooperate with the apparatus used in carrying out the other steps of the process and herein designated expanding reamer.
  • This reamer is adapted to be operated by the rotary driving shaft used in the drilling and cutting operations and is preferably likewise surmounted by a protrusion or pilot adapted to be wedged into the centering hole as the reamer is advanced so as to guide and support the upper end of the apparatus.
  • Figure l of the drawings represents a vertical cross-sectional view of a conventional coking chamber from which the manway covers have been removed and containing a bed of coke through which the preliminary boring of the centering hole has been only partially completed;
  • Figure 2 represents a similar view of the chamber and coke bed with the boring of the centering hole and the reaming operation completed and with the expanding reamer in position;
  • Figure 3 represents a similar view of the chamber and coke bed with the combination helical cutting and breaking tool in position and after the cutting of the spiral has been started;
  • Figures 4 and 5 represent, respectively, an elevation and a plan view of the expanding reamer tool
  • Figures 6 and 7 represent; respectively, in greater detail, an elevation and a plan view of one form of a combination helical cutting and breaking tool in position in the coking chamber;
  • Figure 8 represents a sectional view at AA of Figure 7;
  • Figure 9 is a cross-sectional elevational view showing details of the driving mechanism of an alternate form of helical cutting and breaking tool
  • Figure 10 represents a plan view of the outer end of the arm of the tool shown in Figure 9;
  • Figure 11 represents a cross-sectional view of Figure 10 along the lines BB.
  • Figure 12 represents a cross-sectional view of Figure 10 along lines CC.
  • the numeral l indicates a conventional vertically elongated, cylindrical coking chamber equipped with connecting flanges Ia and lb, lower manway 2 and upper manway 3.
  • the coking chamber When the coke-removal operation is started, the coking chamber is usually filled with coke from the bottom thereof up to a level approximating that indicated in the drawings at i.
  • the centering hole when completed, extends entirely through the coke bed as shown at 5 of Figures 2 and 3 of the drawings.
  • a conventional type rotary drill bit such as represented at 6 may be used.
  • the drill bit is advantageously adapted to be mounted on a vertically positioned rotary driving shaft 9 also used in the reaming and helical cutting and breaking operations and which is adapted to be centrally positioned beneath the manway 2.
  • the drive shaft 3 is adapted to be rotated and fed upwardly by conventional means such as diagrammatically represented at 'lon Figure l of the drawings and is preferably mounted on a track running beneath a plurality of coking chambers so as to be readily available for the alternate cleaning of a number of chambers.
  • the centering hole may advantageously be 8 to 10 inches in diameter.
  • This expanding reamer is adapted to be inserted through the manway 2 and to be attached to and rotated and fed upwardly by means of the driving shaft 9 used in the preceding operation.
  • the expanding reamer shown consists of a cutting head "I provided with a centrally positioned, upwardly projecting pilot or guide such as the. frustro-conical protrusion H, the upper base of which is of smaller and the lower base of larger diameter than the diameter of the centering hole bored by the preceding operation so that it is wedged into the centering hole as the tool is advanced, thus centering and guiding the reamer and supporting the upper end of the rotary shaft 8.
  • a cutting head "I provided with a centrally positioned, upwardly projecting pilot or guide such as the. frustro-conical protrusion H, the upper base of which is of smaller and the lower base of larger diameter than the diameter of the centering hole bored by the preceding operation so that it is wedged into the centering hole as the tool is advanced, thus centering and guiding the reamer and supporting the upper end of the rotary shaft 8.
  • the upper surface of the reamer head is also provided as shown with a plurality of cutting teeth I! spaced around the periphery of the so as to afford lateral support to the arms.
  • Cutting arms l3 are pivotally attached at one end to opposite sides of the reamer head It) at H so as to permit the swinging of the arms in an upward-over-and-downward direction.
  • the immediately downward swing of the arms 13 is arrested by means of lugs l5 which are shown in the drawing as slotted
  • the cutting arms may be collapsed while being inserted through the restricted area of the manway 2 and extended to substantially the diameter of the chamber as the reaming operation progresses.
  • the length of the arms will, of course, be governed by the diameter of the coking chambers with which the reamer is to be employed.
  • the coke is removed from the lower part of the manway flange. This may be accomplished either by hand or by the reamer head with the arms hanging in a vertical position.
  • the arms l3 of the reamer are then raised to a position as indicated by the dotted lines on Figure 4 of the drawings such that the distance between the upward tips ofthe respective arms permits their insertion into that portion of the manway from which the coke has been removed.
  • the reamer is then advanced upwardly to the lower surface of the coke andthe rotation and upward advance begun.
  • the reamer is centered and supported at its upper end by the pilot ll extending into the centering hole 5, as shown in the drawing.
  • the cutting mechanism of the spiral cutter is advantageously of the chain type, diagrammatically represented at IS in Figure 3 of the drawings, similar to that of thelchain cutters used in coal mining.
  • This helical cutter as shown, is adapted to be threaded or otherwise securely, fastened to the rotary driving shaft 9 used in the preceding boring and reaming operations.
  • Each type of the helical cutter is provided with a cutting arm frame structure l8 so connected to the main body or shank IQ of the tool as to ailowthe arm to swing upwardly from the horicut may be started.
  • the main body or shank IQ of the helical cutter is surmounted by a pilot or guide 20 adapted to project into the centering hole 5, as previously described with reference to the reamer, to guide and support the cutter.
  • a cutting chain 22 is carried by the driving sprocket 23 and the driven sprocket 24 which are rotatably mounted at opposite ends of the.
  • the driving sprocket is shownin Figures 6 and 7 as being driven by means of the air motor I! to which it is connected by a shaft 25, gearing 2B and shaft il.
  • the cutter arm is caused to rotate, for instance, in a counterclockwise direction, as indicated on Figure'l of the drawings, by means of the rotary drive shaft 9, while the cutting chain is operated in a clockwise direction. Simultaneously, thecutter is forced upwardly and by synchronizing the'rotary and upward movement of the cutting unit a helical cut is effected.
  • the planewithin which the cutting chain lies is preferably slightly inclined upwardly.from the horizontal in the direction in which the cutting arm rotates.
  • the angle of this inclination may be varied somewhat, depending upon the hardness of the coke or the like and the desired angle of inclination of the helix cut.
  • inclination of the plane of the cutting chain may advantageously be approximately 5 degrees rrs the horizontal.
  • the layer of coke intermediate the convolutions of the helix is systematically broken off, for instance by forcing apart the upper and lower surfaces of This breaking may be accomplished either by the continuous application of pressure, as by wedging action or by the intermittent application of. pressure by a periodic expanding actionat a predetermined distance back of the forward edge of the cutting arm.
  • Figures 6, 7 and 8 of the drawings Figure 8 being a cross-sectional elevation view of the cutting arm shown in Figures 7 and 8 at section AA.
  • the upper surface of the cutting arm may with advantage be provided with bearing guides 28 to form a bearing surface between the top surface .of the arm and the newly cut coke, as more clearly shown in Figure 8 of the drawings.
  • These bearing guides serve to maintain the cutting edge at the desired angle of inclination from the hori; mental and their shape will be governed by the particular angle of inclination chosen.
  • the bearing guides may be of uniform thickness extending from the outer to the inner end of the cutting arm.
  • the flaring lower surface 29 of the cutting arm which exerts pressure on the underlying layer of coke may likewise be of uniform thickness, extending from end to end over the cutting arm, lG-ShOWD in Figure 6 of the drawings.
  • the driving sprocket 23 of the cutting arm is actuated by shaft 21a extending upwardly through the rotary drive shaft 9, which shaft 21a may be driven by any convenient source of power, not shown.
  • are provided in the shaft 21a as well as for the cutter arm mounting to permit the tilting of the cutter arm, as previously described.
  • the shaft 21a is supported by the bushing Ila mounted in the inner end of the frame of the cutter arm.
  • the sprocket 23 is mounted on the shaft 21a at a point above the bushing 28::
  • adapted to cooperate with .the cam surface 32 of the coke-breaking plate 33.
  • the coke-breaking plate is pivotally connected to the frame of the cutter arm at 34 and is forced upwardly against the cam 3
  • the breaking plate 33 is provided with an opening through which the shaft 21a. extends with sumcient clearance to permit the breaking plate to swing downwardly, as will be presently described.
  • thrust bearings 36 are provided between the lower surface of the bushing 28a and the upper plane surface of the cam 3
  • the breaker plate 33 is periodically forced downwardly as the shaft 21a rotates.
  • the cam arrangement may be varied to some extent, depending upon the particular breaking requirement. Such cams are well known and need not be here described in detail. However, a particular cam design which may be used with advantage is one which forces Figure 11 of the drawings.
  • the breaker plate downwardly once for each revolution of the shaft 21d. For instance, while passing through an angle of 45 degrees, the. breaker plate may be forced uniformly downwardly and during the following 45 degrees may be permitted to uniformly rise. For the remaining 270 degrees the breaker plate may remain at rest in the upper position.
  • the breaker plate advantageously extends substantially the entire length of the cutter arm and may be ribbed, as previously described with reference to the friction guides, or may be of uniform thickness throughout.
  • the breaker plate is shownas having a plane lower surface.
  • a cam arrangement similar to that just described is also provided at the outer end of the cutting arm and is actuated by the rotation of the driven sprocket 24, as shown more particularly in
  • the rotating cam surface is at the lower end of the stud 31, projecting downwardly through the center of the hollow bearing 38 about which sprocket 24 rotates, the stud being an integral part of the plate 39 which is rigidly fastened to the sprocket 24 and rotates therewith.
  • Figure 10 of the drawings which is a. plan view of the outer end of the cutting arm, the breaker plate is shown as extending substantially the entire lengthof the arm and pivotally supported substantially throughout its length. A plurality of springs 35 are provided for pulling the plate upwardly against the cam surface.
  • This modified form of cutting arm may also be provided with friction ribs 28, as described with reference to Figures 6, 7 and 8.
  • the specific apparatus herein described is particularly adapted to the removal 'of coke from chambers provided with manways of considerably smaller diameter than the diameter of the chamber itself. It will be understood that my invention is also applicable to the removal of coke from chambers of different sizes and designs. Where the diameter of the lower end manway approximates that of the chamber, the second step of the process, 1, e. the reaming operation, becomes unnecessary. Likewise, where rigid support and guidance of the spiral cutter is otherwise provided, for instanceby the use of a larger, more rigid drive shaft 9, the boring of the centering hole may be omitted.
  • An alternate method of guiding and supporting the upper end of the reamer or of the spiral cutter is the extension of the rotary drive shaft-up throu h the upper manway 3 and the provision of a bearing in the upper manway for securing and supporting the upper end of the shaft.
  • This extension may be inserted from the top of the chamber through the centering hole and fastened on to the upper part of the reamer or helical cutter by conventional means.
  • the size of the rotary drill, reamer and helical cutter will, of course, depend somewhat upon the diameter of the chamber to be cleaned and the depth of the coke bed. It is necessary that the drive shaft used in the boring be sufficiently rigid to bore a true centering hole through the coke bed or otherwise the arms of the reamer or helical cutter might strike the metal walls of the chamber.
  • the coke bed is usually approximately 35 to 45 feet deep.
  • the arms of the reamer and the arm of the helical cutter be of such length as to provide, a clearance of about, an inch between the outer ends thereof and the walls of the chamber. This will leave a layer of coke about 1 inch thick around the walls of the chamber. This layer of colre and also that along the lower walls of the chamber which is not removed by the reamer may subsequently be removed by hand tools.
  • the coke-breaking mechanism may be carried by a second arm extending outwardly from the rotary driving shaft instead of being combined directly with the cutting arm, as previously described. Where a second arm is provided for carrying the breaking mechanism, it may advantageously be positioned at an angle of 180 degrees from the cutting arm. By this arrangement, the center of gravity of the revolving mechanism can be I made to coincide with or atleast approximate the axis of rotation thereof, thereby reducing shaft stresses. l
  • the wedging type of'breaking mechanism over the periodically expanding type, or vice versa, depends to a considerable extent upon the character of the coke deposit.
  • the periodically expanding arm is used, additional power must be supplied for its operation but relatively less force is required to rotate the am.
  • the coke deposit is of such character that it is easily broken ofi
  • the wedging type of arm may be satisfactorily used but, where the coke deposit is of such nature as to be broken off only with difficulty, the periodically expanding type of arm is preferred'because of the possibility of excessively straining the rotary drivin shaft in forcing the wedge into the cut.
  • An improved method of removing coke deposits in relatively large pieces from verticallyelongated cylindrical chambers which comprises moving a cutting member radially and helically upwardly through the coke deposit toprogressively sively form a helical cut extending into the coke deposit a material distance and a distance sufficient that when the coke behind the forward edge of the cut is broken from the body of coke, the major portion thereof will'be in relatively large pieces rather than in finesyand systematically breaking off the coke underlying the cut by the downward application of pressure thereon independently of the cutting action at a predetermined distance to'the rear of the forward edge of the cut.
  • An improved method of removing coke deposits in relatively large pieces from verticallyelongated cylindrical chambers which comprises moving a cutting member radially and helically upwardly through the coke deposit to progressively form a helica1 cut extending into the coke deposit a material distance and a distance sumcient that when the coke behind the forward edge of the cut is broken from the body of coke the major portion thereof will be in relatively large pieces rather than fines, and systematically and simultaneously breaking off the coke underlying the cut as the cutting progresses by the downward application of pressure thereon independentlyof the cutting action at a predetermined distance to the rear of the forward edge of the cut.
  • An improved method of removing coke deposits in relatively large pieces from verticallyelongated cylindrical chambers which comprises moving a cutting member radially and helically upwardly through the coke deposit to progressively form a helical cut extending into the coke deposit a material distance and a distance sufficient that when the coke behind the forward edge of the cut is broken from the body of coke themajor portion thereof will be in relatively large pieces rather than in fines, and systematically breaking off the coke underlying the cut independently of the cutting action by automatically forcing the walls of the cut apart at a predetermined distance to the rear of the forward edge of the cut. 7,
  • An improved method of removing coke deposits in relatively large pieces'from verticallyelongated cylindrical chambers which comprises moving a cutting member radially and helicallyupwardly. through the coke deposit to progressively form a helical cut extending into the coke deposit a material distance and a distance suflicient that when the coke behind the forward edge of the cut is broken from the body of coke the major portion thereof will be in relatively large, pieces rather than in fines, and systematically I breaking offthe coke underlying the cut independently of the cutting action by automatically forcing a wedge-shaped device into the spiral cut at a predetermined distance to the rear of the forward edge of the cut.
  • An improved method of removing coke deposits in relatively large pieces from a verticallyelongated cylindrical chamber through a manway located in the bottom end of the chamber and of smaller diameter than the diameter of the chamber which comprises boring a hole through the coke deposit along its central vertical axis, reaming out the coke from the lower end of the chamber to a diameter slightly less than the inner diameter of the chamber to permit the insertion of a radially movinghelical cutting tool, moving a cuttingmember radially and helically upwardly through the coke deposit to progressively form a helical cut extending into the coke deposit a material distance and a distance sufllcient that when the coke behind the relatively large pieces rather than inflnes, and
  • Apparatus for removing coke deposits from a vertically elongated, cylindrical chamber comprising a vertical shaft adapted to be rotated and simultaneously advanced upwardly and to be centrally positioned beneath a central lower opening in the chamber, a combined helical cutting and coke-breaking tool adapted to be securely fastened to the upper end of said shaft and comprising an outwardly extending arm pivotally connected to the shank of said tool and adapted to be swung upwardly to a position approaching the vertical but having its downward swing arrested at approximately the horizontal connected to the shank of said tool and adapted to be swung upwardly to a position approaching the vertical but having its downward swing arrested at approximately the horizontal position, a cutting chain supported by said arm having its cutting teeth projecting from the forward edge thereof and extending substantially throughout the length of the arm, said cutting chain being supported in a plane inclining upwardly from the horizontal toward its forward end and a driving mechanism for motivating said cutting chain, the rear edge of said arm being of greater thickness than the forward cutting edge.
  • Apparatus for removing coke deposits from a vertically elongated, cylindrical chamber comprising a vertical shaft adapted to be rotated and simultaneously advanced upwardly and to be "centrally positioned beneath a central lower position, a cutting chain supported by said arm having its cutting teeth projecting from the forward edge thereof'and extending substantially throughout the length of the arm, said cutting chain being supported in a plane inclining upwardly from the horizontal toward its forward end, a driving mechanism for motivating said cutting chain and an expanding device to the rear of the forward edge of the arm adapted to force apart the surfaces of the cut made by the cutting teeth at a predetermined distance to the rear of the forward edge of the arm.
  • Apparatus for removing coke deposits from a vertically elongated, cylindrical chamber comprising a vertical shaft adapted to be rotated and simultaneously advanced upwardly and to be centrally positioned beneath a central lower opening opening in the chamber, a combined helical-cutting and coke-breaking tool adapted to be securely fastened to the upper end of said shaft and comprising an outwardly extending arm pivotally connected to the shank of said tool and adapted to be swung upwardly to a position approaching the vertical but having its downward swing arrested at approximately the horizontal position, a cutting chain supported by said arm having its cutting teeth projecting from the forward edge thereof and extending substantially throughout the length of the arm, said cutting chain being supported in a plane inclining upwardly from the horizontal toward its forward end, the lower surface of said am comprisinga rigid plate extending substantially the entire length of the arm and pivotally supported by the arm at its forward edge, a cam mechanism adapted periodically to force the rearward edge of the plate downwardly and a driving mechanism for motivating said cutting chain and the HERMAN

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Description

June 15, 1 43. Q H. c. KUHNI ,1
METHOD AND APPARATUS,FOR REMOVING COKE FROM COKING CHAMBERS Filed Aug. 16, 1941 v 4 Sheets-Sheet l L l A INVENTOR Herman (71 0/32 A J I I Pwwlw' If m. 7 u.
ATTORNEYS June 15, 1943. H. c. KUHN x 2,322,146
METHOD AND APPARATU FOR REMOVING COKE FROM CQKING CHAMBERS Filed Aug. 16, 1941 4'Sheets- Sheet 2 I I I, I /4" f /3 A; I I
INVENTOR Herman (Y /7 0 Z7z ATTORNEYS June 15,1943. HQ KUHN 2,322,146
METHOD AND APPARATUS FOR REMOVING COKE FROM coxme CHAMBER h Filed Aug. 16, 1941 4 Sheets-Sheet a5 XX a ATTORNEYS June 15, 1943. H. c. KUHN 2,322,145
METHOD AND APPARATUS FOR REMOVING COKE- 5410M COKING CHAMBERS Filed Aug. 16, 1941 4 Sheets-Sheet 4 v w M Z Z I .20
X5; 2762 j) 3 J5 Zfa.
I l J3 3. J4 J5 J3. J
v INVENTOR BY Pun iLflhmTmmbubnWrmm de.
ATTO R N EY5 Patented June 15, 1943 uturao STATES ATENT @FFHCE METHOD AND APPARATUS FOR. REMOVING COKE FROM CURING CHALEERS Herman 0. Kuhn, Hammond, 1nd,, assignor to Sinclair Refining Company, New York, N. Y., a corporation of Maine Application August 16, 1941, Serial No. 407,233
Y 8 Claims.
' material with a relatively large percentage of the coke in lump form and a minimum of fines or dust. The invention also includes novel apparatus adapted to this purpose.
Though the invention has utility with respect to other industrial operations, it is particularly applicable to the removal of coke deposits from the coking chambers of apparatus used in the processing of hydrocarbon oils.
In the vapor phase cracking of hydrocarbon oils, for example, very large quantities of coke are produced. This coke is a valuable by-product of the cracking operation. Its potential commercial value as-a fuel has, however, not been fully realized because of the difliculty of recovering the coke from the coking chambers in a condition best suited to compete with other types of solid fuel.
Previous attempts to recover the coke in lump form have met with only partial success for the reason that the proportion of fines to lumps has been excessively high.
The difficulty of recovering form as opposed to fines has been aggravated by the type of chamber in which the bed of coke is usually deposited. These chambers are customarily vertically elongated, cylindrical chambers of relatively small horizontal cross-section with respect to their height. At the period in the op-' eration when the removal of the coke becomes.
. to fines.
Not only is the commercial value of the fines materially less than the coke in lump form but a considerable amount of the coke has been lost during the coke-cleaning operation. Further, the fines being very light weight, readily become suspended in the atmosphere and cause disc mthe coke in lump- Such methods have been expensive fort to the workmen and others in the vicinity. Also,,the handling of the finely divided coke is more difficult. and expensive than the handling of the coke in lump form. I
Thesecoke deposits may readily be removed, in accordance with my invention, in predominantly lump form and with a minimum of cleaning time, labor and physical discomfort to the workmen. Further, the resulting lumps of coke are of more uniform size than have previously I been directly obtainable.
My improved method of removing coke consists primarily in moving a cutting member radially and helically upwardly through the. coke deposit to progressively form a helical cut extending into the coke deposit a material distance, and a distance suificient that when the coke behind the forward edge of the cut is broken from the body of coke, the major portion will be in relatively large pieces, rather than in fines, and, as the cutting progresses through the coke bed, systematically breaking off the coke underlying the cut by the downward application of pressure thereon independently of the cutting action at a predetermined distanceto the rear of the forward edge of the cut. The helical cut formed as Just described, preferably extends from approximately the center .of the bed outwardly to a point just short of the-inner surface of the walls of the chamber.
The means forsystematically breaking ofi the coke underlying the cut may take various forms, and although independent of the cutter may be carried by, or form a part of the support for the.
cutter. Preferably the coke is broken off by mechanically forcing the upper and lower surfaces of the cut apart either continuously, as by means of a wedging action, or by periodic expansion at apoint along the helical cut a predetermined distance back of the cutting edge. The cutting and breaking operations may with advantage be eflected by means of the novel apparatus presently to be described.
Usually the only means of access to these cok-; ing chambers for the purpose of removing the coke deposits is through the manways in the upper and lower ends of the chamber. These manways are ordinarily of considerably smaller diameter than that of the chamber itself. Therefore, in order to make a helical cutupwardly through the coke deposit of substantially the inner diameter of the chamber, certain preliminary operations are usually necessary before the helical cutter can be brought into operating posi- U011.
For example, in the removal of coke deposits, in accordance with my invention, from a coking chamber such as previously described, the chamber is first cut oil from the processing operation by means of valves or the like in the connecting lines and the chamber is freed of inflammable or combustible material such as oil or oil vapors in the customary manner. The manway covers are then removed from the top and bottom of the chamber.
A bed of relatively firm coke is ordinarily found,
to extend downwardly from the bottom of the chamber into the space surrounded by the flange of the bottom manway. As previously noted, the manway is customarily of considerably smaller diameter than the chamber itself and, for this reason, a unique problem is presented with respect to ways and means of making sucha helical cut upwardly through the bed of coke.
My invention includes a combination of operation especially designed to cooperate in overcoming the difficulties presented by such chamber arrangement. It includes also a novel combination of apparatus adapted to be inserted into the chamber through the restricted area of the manway and to cooperate in the carrying out of the several operations.
To avoid the necessity of using excessively heavy and rigid driving shafts for the operation of the helical cutting tool, to be presently described, it is necessary 'to provide means for centering and supporting the upper end of the cutting tool. In accordance with my invention, such guidance and support may be provided by first drilling a centering hole along the central axis of the coke bed and providing a pilot on the upper end of the cutting tool adapted to be contlnuously wedged into this centering hole as the cutting tool is forced upwardly.
Also, before the helical cutting tool can be brought into position in the chamber, it is necessary to remove'the coke from the manway and from the bottom of the chamber to substantially the full diameter of the chamber and for a sufficient distance upwardly to permit the insertion of the helical cutter. This second operation may be readily accomplished in accordance with my invention by means of a novel device to be presently described designed to cooperate with the apparatus used in carrying out the other steps of the process and herein designated expanding reamer. This reamer is adapted to be operated by the rotary driving shaft used in the drilling and cutting operations and is preferably likewise surmounted by a protrusion or pilot adapted to be wedged into the centering hole as the reamer is advanced so as to guide and support the upper end of the apparatus.
My invention will be further described with reference to the accompanying drawings, in
which Figure l of the drawings represents a vertical cross-sectional view of a conventional coking chamber from which the manway covers have been removed and containing a bed of coke through which the preliminary boring of the centering hole has been only partially completed;
Figure 2 represents a similar view of the chamber and coke bed with the boring of the centering hole and the reaming operation completed and with the expanding reamer in position;
Figure 3 represents a similar view of the chamber and coke bed with the combination helical cutting and breaking tool in position and after the cutting of the spiral has been started;
Figures 4 and 5 represent, respectively, an elevation and a plan view of the expanding reamer tool;
Figures 6 and 7 represent; respectively, in greater detail, an elevation and a plan view of one form of a combination helical cutting and breaking tool in position in the coking chamber;
Figure 8 represents a sectional view at AA of Figure 7;
Figure 9 is a cross-sectional elevational view showing details of the driving mechanism of an alternate form of helical cutting and breaking tool;
Figure 10 represents a plan view of the outer end of the arm of the tool shown in Figure 9;
Figure 11 represents a cross-sectional view of Figure 10 along the lines BB; and
Figure 12 represents a cross-sectional view of Figure 10 along lines CC.
Referring particularly to Figures 1, 2 and 3, the numeral l indicates a conventional vertically elongated, cylindrical coking chamber equipped with connecting flanges Ia and lb, lower manway 2 and upper manway 3.
When the coke-removal operation is started, the coking chamber is usually filled with coke from the bottom thereof up to a level approximating that indicated in the drawings at i. The centering hole, when completed, extends entirely through the coke bed as shown at 5 of Figures 2 and 3 of the drawings.
In the boring of this centering hole a conventional type rotary drill bit such as represented at 6 may be used. The drill bit is advantageously adapted to be mounted on a vertically positioned rotary driving shaft 9 also used in the reaming and helical cutting and breaking operations and which is adapted to be centrally positioned beneath the manway 2. The drive shaft 3 is adapted to be rotated and fed upwardly by conventional means such as diagrammatically represented at 'lon Figure l of the drawings and is preferably mounted on a track running beneath a plurality of coking chambers so as to be readily available for the alternate cleaning of a number of chambers.
In the cleaning of a coking chamber, such as that shown in the drawings, having a diameter of 8 to 9 feet and an overall height of approxi mately 4550 feet, the centering hole may advantageously be 8 to 10 inches in diameter.
After the centering hole 5 has been completed, the driving shaft is withdrawn and the-rotary drill bit is replaced by an expanding reamer such, for example, as shown in Figure 2 at 8 and in vgreater detail in Figures 4 and 5 of the drawings.
This expanding reamer is adapted to be inserted through the manway 2 and to be attached to and rotated and fed upwardly by means of the driving shaft 9 used in the preceding operation.
The expanding reamer shown consists of a cutting head "I provided with a centrally positioned, upwardly projecting pilot or guide such as the. frustro-conical protrusion H, the upper base of which is of smaller and the lower base of larger diameter than the diameter of the centering hole bored by the preceding operation so that it is wedged into the centering hole as the tool is advanced, thus centering and guiding the reamer and supporting the upper end of the rotary shaft 8.
The upper surface of the reamer head is also provided as shown with a plurality of cutting teeth I! spaced around the periphery of the so as to afford lateral support to the arms.
reamer head and projecting upwardly therefrom, but of insufficient height to interfere with the operation of the pilot ll.
Cutting arms l3, as shown in greater detail in Figures 4 and of the drawings, are pivotally attached at one end to opposite sides of the reamer head It) at H so as to permit the swinging of the arms in an upward-over-and-downward direction. The immediately downward swing of the arms 13 is arrested by means of lugs l5 which are shown in the drawing as slotted By this arrangement the cutting arms may be collapsed while being inserted through the restricted area of the manway 2 and extended to substantially the diameter of the chamber as the reaming operation progresses. The length of the arms will, of course, be governed by the diameter of the coking chambers with which the reamer is to be employed.
Before starting the reaming operation, the coke is removed from the lower part of the manway flange. This may be accomplished either by hand or by the reamer head with the arms hanging in a vertical position.
The arms l3 of the reamer are then raised to a position as indicated by the dotted lines on Figure 4 of the drawings such that the distance between the upward tips ofthe respective arms permits their insertion into that portion of the manway from which the coke has been removed. The reamer is then advanced upwardly to the lower surface of the coke andthe rotation and upward advance begun.
As the reamer is advanced upwardly against the coke there is a tendency for the arms 'to be forced outwardly. However, until the arms have progressed past the'manway flange their outward movement is restrained by the metal walls thereof. After passing the manway flange the arms I3 are forced outwardly as shown in Figure 2 of the drawings and the coke in the lower part of the chamber is cut away by the reamer as there indicated to provide space for the insertion of the helical cutter.
During this reaming operation the reamer is centered and supported at its upper end by the pilot ll extending into the centering hole 5, as shown in the drawing.
When the reaming operation has progressed to approximately the extent indicated on Figure 2 'of the drawings, the reamer is withdrawn from the chamber, this being possible by reason of the collapsible arrangement of the arms l3, disconnected from the shaft 9 and replaced by the combination helical cutting and breaking tool, generally referred to herein as helical cutter."
The cutting mechanism of the spiral cutter is advantageously of the chain type, diagrammatically represented at IS in Figure 3 of the drawings, similar to that of thelchain cutters used in coal mining. This helical cutter, as shown, is adapted to be threaded or otherwise securely, fastened to the rotary driving shaft 9 used in the preceding boring and reaming operations.
' the like formingan integral part of the helical cutter suchas shown diagrammatically on Figure 3 at l'l.
Details of two specific types of spiral cutters found to be particularly suitable for the purposes the cut.
of the present invention are shown by Figures 6 to 12, inclusive, of the drawings.
Each type of the helical cutter is provided with a cutting arm frame structure l8 so connected to the main body or shank IQ of the tool as to ailowthe arm to swing upwardly from the horicut may be started. 7 The main body or shank IQ of the helical cutter is surmounted by a pilot or guide 20 adapted to project into the centering hole 5, as previously described with reference to the reamer, to guide and support the cutter.
A cutting chain 22 is carried by the driving sprocket 23 and the driven sprocket 24 which are rotatably mounted at opposite ends of the.
cutting arm. The driving sprocket is shownin Figures 6 and 7 as being driven by means of the air motor I! to which it is connected by a shaft 25, gearing 2B and shaft il.
- In operation the cutter arm is caused to rotate, for instance, in a counterclockwise direction, as indicated on Figure'l of the drawings, by means of the rotary drive shaft 9, while the cutting chain is operated in a clockwise direction. Simultaneously, thecutter is forced upwardly and by synchronizing the'rotary and upward movement of the cutting unit a helical cut is effected.
To facilitate the upward progress of the cut, the planewithin which the cutting chain lies is preferably slightly inclined upwardly.from the horizontal in the direction in which the cutting arm rotates. The angle of this inclination may be varied somewhat, depending upon the hardness of the coke or the like and the desired angle of inclination of the helix cut. For cutting a spiral such as indicated above with an advance o =approximately 8 inches per revolution of the armhan inclination of the plane of the cutting chain may advantageously be approximately 5 degrees rrs the horizontal.
As previously stated, simultaneously with the helicalcutting operation of my invention the layer of coke intermediate the convolutions of the helix is systematically broken off, for instance by forcing apart the upper and lower surfaces of This breaking may be accomplished either by the continuous application of pressure, as by wedging action or by the intermittent application of. pressure by a periodic expanding actionat a predetermined distance back of the forward edge of the cutting arm.
One method of breaking off the coke by wedging action and effective means for accomplishing the same is illustrated by Figures 6, 7 and 8 of the drawings, Figure 8 being a cross-sectional elevation view of the cutting arm shown in Figures 7 and 8 at section AA.
In Figure 8 the cutting arm is shown as increasing in thickness from the front toward the rear so that as the cuttingarm advances the wedging action thereof exerts an increasing pressure on the underlying layer of coke, causing'it to fracture and drop to the lower portion of the chamber I from whence it is removedthrough the manway 2,
The upper surface of the cutting arm may with advantage be provided with bearing guides 28 to form a bearing surface between the top surface .of the arm and the newly cut coke, as more clearly shown in Figure 8 of the drawings. These bearing guides serve to maintain the cutting edge at the desired angle of inclination from the hori; mental and their shape will be governed by the particular angle of inclination chosen. The bearing guides may be of uniform thickness extending from the outer to the inner end of the cutting arm. However, to reduce the friction between the cutting arm and the newly cut coke, I prefer to provide guides composed of ribs projecting upwardly from the frame of the arm, as shown" at 23 on Figure 7 of the drawings, conforming in shape to the arc of a circle, the center of which coincides with the center of rotation of the cutting arm.
- The flaring lower surface 29 of the cutting arm which exerts pressure on the underlying layer of coke may likewise be of uniform thickness, extending from end to end over the cutting arm, lG-ShOWD in Figure 6 of the drawings. However, I prefer for this purpose the ribbed arrangement just described with reference to the bearing guides.
A variation in the cutting arm design embodying an alternate means of breaking off the coke. i. e. by the intermittent application of pressure, is shown by Figures 9 to 12, inclusive, of the drawings.
In this modified arrangement, as appears in Figure 9, the driving sprocket 23 of the cutting arm is actuated by shaft 21a extending upwardly through the rotary drive shaft 9, which shaft 21a may be driven by any convenient source of power, not shown. Pivotal connections 2| are provided in the shaft 21a as well as for the cutter arm mounting to permit the tilting of the cutter arm, as previously described. Above the pivotal conneetion 2| the shaft 21a is supported by the bushing Ila mounted in the inner end of the frame of the cutter arm. The sprocket 23 is mounted on the shaft 21a at a point above the bushing 28::
and is secured to the shaft by means of the pin bushing 23a is a cam 3| adapted to cooperate with .the cam surface 32 of the coke-breaking plate 33. The coke-breaking plate is pivotally connected to the frame of the cutter arm at 34 and is forced upwardly against the cam 3| by flexible means such as the springs 35.' As shown in the drawings, the breaking plate 33 is provided with an opening through which the shaft 21a. extends with sumcient clearance to permit the breaking plate to swing downwardly, as will be presently described. Between the lower surface of the bushing 28a and the upper plane surface of the cam 3|, and also between the upper surface of said bushing and the lower surface of the hub of sprocket 23, thrust bearings 36 are provided.
By the cam arrangement shown, the breaker plate 33 is periodically forced downwardly as the shaft 21a rotates. The cam arrangement may be varied to some extent, depending upon the particular breaking requirement. Such cams are well known and need not be here described in detail. However, a particular cam design which may be used with advantage is one which forces Figure 11 of the drawings.
the breaker plate downwardly once for each revolution of the shaft 21d. For instance, while passing through an angle of 45 degrees, the. breaker plate may be forced uniformly downwardly and during the following 45 degrees may be permitted to uniformly rise. For the remaining 270 degrees the breaker plate may remain at rest in the upper position.
The breaker plate advantageously extends substantially the entire length of the cutter arm and may be ribbed, as previously described with reference to the friction guides, or may be of uniform thickness throughout. In Figures 10, 11 and 12, the breaker plate is shownas having a plane lower surface.
A cam arrangement similar to that just described is also provided at the outer end of the cutting arm and is actuated by the rotation of the driven sprocket 24, as shown more particularly in In the arrangement there shown, the rotating cam surface is at the lower end of the stud 31, projecting downwardly through the center of the hollow bearing 38 about which sprocket 24 rotates, the stud being an integral part of the plate 39 which is rigidly fastened to the sprocket 24 and rotates therewith.
In Figure 10 of the drawings, which is a. plan view of the outer end of the cutting arm, the breaker plate is shown as extending substantially the entire lengthof the arm and pivotally supported substantially throughout its length. A plurality of springs 35 are provided for pulling the plate upwardly against the cam surface. This modified form of cutting arm may also be provided with friction ribs 28, as described with reference to Figures 6, 7 and 8.
The specific apparatus herein described is particularly adapted to the removal 'of coke from chambers provided with manways of considerably smaller diameter than the diameter of the chamber itself. It will be understood that my invention is also applicable to the removal of coke from chambers of different sizes and designs. Where the diameter of the lower end manway approximates that of the chamber, the second step of the process, 1, e. the reaming operation, becomes unnecessary. Likewise, where rigid support and guidance of the spiral cutter is otherwise provided, for instanceby the use of a larger, more rigid drive shaft 9, the boring of the centering hole may be omitted.
An alternate method of guiding and supporting the upper end of the reamer or of the spiral cutter, not specifically shown in the drawings but which may be employed with advantage, is the extension of the rotary drive shaft-up throu h the upper manway 3 and the provision of a bearing in the upper manway for securing and supporting the upper end of the shaft. This extension may be inserted from the top of the chamber through the centering hole and fastened on to the upper part of the reamer or helical cutter by conventional means.
The size of the rotary drill, reamer and helical cutter will, of course, depend somewhat upon the diameter of the chamber to be cleaned and the depth of the coke bed. It is necessary that the drive shaft used in the boring be sufficiently rigid to bore a true centering hole through the coke bed or otherwise the arms of the reamer or helical cutter might strike the metal walls of the chamber.
In removing coke from coking chambers of the size normally used commercially in the vapor phase cracking of petroleum oil, it is desirable to provide suflicient clearance to allow for slight deviations of the centering hole from the true center of the chamber. For example, with a coking chamber approximately 8 to 9 feet in diameter and approximately 45 to 50 feet overall height, the coke bed is usually approximately 35 to 45 feet deep. .In the reaming and cutting operations in chambers of this size, it is advisable that the arms of the reamer and the arm of the helical cutter be of such length as to provide, a clearance of about, an inch between the outer ends thereof and the walls of the chamber. This will leave a layer of coke about 1 inch thick around the walls of the chamber. This layer of colre and also that along the lower walls of the chamber which is not removed by the reamer may subsequently be removed by hand tools.
Fines Lumps Drilling operation pounds. 750 Beaming operation do 13, 400 .(uttmg operation do.. i 22, 500 67, 500
' Total coke do 36, 650 67. 500 Per cent total .per cent 35 65 Where the size of the manway will permit, the coke-breaking mechanism may be carried by a second arm extending outwardly from the rotary driving shaft instead of being combined directly with the cutting arm, as previously described. Where a second arm is provided for carrying the breaking mechanism, it may advantageously be positioned at an angle of 180 degrees from the cutting arm. By this arrangement, the center of gravity of the revolving mechanism can be I made to coincide with or atleast approximate the axis of rotation thereof, thereby reducing shaft stresses. l
Preference for the wedging type of'breaking mechanism over the periodically expanding type, or vice versa, depends to a considerable extent upon the character of the coke deposit. Where the periodically expanding arm is used, additional power must be supplied for its operation but relatively less force is required to rotate the am. Where the coke deposit is of such character that it is easily broken ofi, the wedging type of arm may be satisfactorily used but, where the coke deposit is of such nature as to be broken off only with difficulty, the periodically expanding type of arm is preferred'because of the possibility of excessively straining the rotary drivin shaft in forcing the wedge into the cut.
I claim:
1. An improved method of removing coke deposits in relatively large pieces from verticallyelongated cylindrical chambers which comprises moving a cutting member radially and helically upwardly through the coke deposit to progres sively form a helical cut extending into the coke deposit a material distance and a distance sufficient that when the coke behind the forward edge of the cut is broken from the body of coke, the major portion thereof will'be in relatively large pieces rather than in finesyand systematically breaking off the coke underlying the cut by the downward application of pressure thereon independently of the cutting action at a predetermined distance to'the rear of the forward edge of the cut.
2. An improved method of removing coke deposits in relatively large pieces from verticallyelongated cylindrical chambers which comprises moving a cutting member radially and helically upwardly through the coke deposit to progressively form a helica1 cut extending into the coke deposit a material distance and a distance sumcient that when the coke behind the forward edge of the cut is broken from the body of coke the major portion thereof will be in relatively large pieces rather than fines, and systematically and simultaneously breaking off the coke underlying the cut as the cutting progresses by the downward application of pressure thereon independentlyof the cutting action at a predetermined distance to the rear of the forward edge of the cut.
3. An improved method of removing coke deposits in relatively large pieces from verticallyelongated cylindrical chambers which comprises moving a cutting member radially and helically upwardly through the coke deposit to progressively form a helical cut extending into the coke deposit a material distance and a distance sufficient that when the coke behind the forward edge of the cut is broken from the body of coke themajor portion thereof will be in relatively large pieces rather than in fines, and systematically breaking off the coke underlying the cut independently of the cutting action by automatically forcing the walls of the cut apart at a predetermined distance to the rear of the forward edge of the cut. 7,
4. An improved method of removing coke deposits in relatively large pieces'from verticallyelongated cylindrical chambers which comprises moving a cutting member radially and helicallyupwardly. through the coke deposit to progressively form a helical cut extending into the coke deposit a material distance and a distance suflicient that when the coke behind the forward edge of the cut is broken from the body of coke the major portion thereof will be in relatively large, pieces rather than in fines, and systematically I breaking offthe coke underlying the cut independently of the cutting action by automatically forcing a wedge-shaped device into the spiral cut at a predetermined distance to the rear of the forward edge of the cut.
5. An improved method of removing coke deposits in relatively large pieces from a verticallyelongated cylindrical chamber through a manway located in the bottom end of the chamber and of smaller diameter than the diameter of the chamber which comprises boring a hole through the coke deposit along its central vertical axis, reaming out the coke from the lower end of the chamber to a diameter slightly less than the inner diameter of the chamber to permit the insertion of a radially movinghelical cutting tool, moving a cuttingmember radially and helically upwardly through the coke deposit to progressively form a helical cut extending into the coke deposit a material distance and a distance sufllcient that when the coke behind the relatively large pieces rather than inflnes, and
systematically breaking of! the cokeunderlying the cut by the downward application of pressure thereon independently of the cutting action at a predetermined distance to the rear of the forward edge of the cut. 7 s
6. Apparatus for removing coke deposits from a vertically elongated, cylindrical chamber comprising a vertical shaft adapted to be rotated and simultaneously advanced upwardly and to be centrally positioned beneath a central lower opening in the chamber, a combined helical cutting and coke-breaking tool adapted to be securely fastened to the upper end of said shaft and comprising an outwardly extending arm pivotally connected to the shank of said tool and adapted to be swung upwardly to a position approaching the vertical but having its downward swing arrested at approximately the horizontal connected to the shank of said tool and adapted to be swung upwardly to a position approaching the vertical but having its downward swing arrested at approximately the horizontal position, a cutting chain supported by said arm having its cutting teeth projecting from the forward edge thereof and extending substantially throughout the length of the arm, said cutting chain being supported in a plane inclining upwardly from the horizontal toward its forward end and a driving mechanism for motivating said cutting chain, the rear edge of said arm being of greater thickness than the forward cutting edge.
8. Apparatus for removing coke deposits from a vertically elongated, cylindrical chamber comprising a vertical shaft adapted to be rotated and simultaneously advanced upwardly and to be "centrally positioned beneath a central lower position, a cutting chain supported by said arm having its cutting teeth projecting from the forward edge thereof'and extending substantially throughout the length of the arm, said cutting chain being supported in a plane inclining upwardly from the horizontal toward its forward end, a driving mechanism for motivating said cutting chain and an expanding device to the rear of the forward edge of the arm adapted to force apart the surfaces of the cut made by the cutting teeth at a predetermined distance to the rear of the forward edge of the arm.
7. Apparatus for removing coke deposits from a vertically elongated, cylindrical chamber comprising a vertical shaft adapted to be rotated and simultaneously advanced upwardly and to be centrally positioned beneath a central lower opening opening in the chamber, a combined helical-cutting and coke-breaking tool adapted to be securely fastened to the upper end of said shaft and comprising an outwardly extending arm pivotally connected to the shank of said tool and adapted to be swung upwardly to a position approaching the vertical but having its downward swing arrested at approximately the horizontal position, a cutting chain supported by said arm having its cutting teeth projecting from the forward edge thereof and extending substantially throughout the length of the arm, said cutting chain being supported in a plane inclining upwardly from the horizontal toward its forward end, the lower surface of said am comprisinga rigid plate extending substantially the entire length of the arm and pivotally supported by the arm at its forward edge, a cam mechanism adapted periodically to force the rearward edge of the plate downwardly and a driving mechanism for motivating said cutting chain and the HERMAN C. KUHN.
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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2761160A (en) * 1952-08-16 1956-09-04 Standard Oil Co Coke removal drilling rig
US2890858A (en) * 1957-06-18 1959-06-16 Smith Ramsey Deep well chain saw
US2998333A (en) * 1955-05-04 1961-08-29 Kearney & Trecker Corp Machine tool for removing material from a container
US3104989A (en) * 1956-06-28 1963-09-24 Kearney & Trecker Corp Machine tool for removing a mass of material from a container and method
US3275168A (en) * 1963-09-24 1966-09-27 Schleich Josef Devices for removing stored material from silos
US3280416A (en) * 1964-04-20 1966-10-25 James M Forsyth Two-stage drill for mechanical decoking or the like
US3380260A (en) * 1964-07-31 1968-04-30 Redl Narciss Albert Tunnel-boring machine
US3475801A (en) * 1967-06-23 1969-11-04 Fuji Photo Film Co Ltd Cutting apparatus
JP2018051417A (en) * 2015-06-26 2018-04-05 ユーレキャット ソシエテ アノニム Method for completely emptying catalyst reactor

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2761160A (en) * 1952-08-16 1956-09-04 Standard Oil Co Coke removal drilling rig
US2998333A (en) * 1955-05-04 1961-08-29 Kearney & Trecker Corp Machine tool for removing material from a container
US3104989A (en) * 1956-06-28 1963-09-24 Kearney & Trecker Corp Machine tool for removing a mass of material from a container and method
US2890858A (en) * 1957-06-18 1959-06-16 Smith Ramsey Deep well chain saw
US3275168A (en) * 1963-09-24 1966-09-27 Schleich Josef Devices for removing stored material from silos
US3280416A (en) * 1964-04-20 1966-10-25 James M Forsyth Two-stage drill for mechanical decoking or the like
US3380260A (en) * 1964-07-31 1968-04-30 Redl Narciss Albert Tunnel-boring machine
US3475801A (en) * 1967-06-23 1969-11-04 Fuji Photo Film Co Ltd Cutting apparatus
JP2018051417A (en) * 2015-06-26 2018-04-05 ユーレキャット ソシエテ アノニム Method for completely emptying catalyst reactor
US10065165B2 (en) * 2015-06-26 2018-09-04 Eurecat S.A. Method for completely emptying a catalytic reactor

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