US2305217A - Process of cubing surface covering - Google Patents
Process of cubing surface covering Download PDFInfo
- Publication number
- US2305217A US2305217A US2305217DA US2305217A US 2305217 A US2305217 A US 2305217A US 2305217D A US2305217D A US 2305217DA US 2305217 A US2305217 A US 2305217A
- Authority
- US
- United States
- Prior art keywords
- oil
- siccative
- surface covering
- composition
- binders
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title description 12
- 239000003921 oil Substances 0.000 description 24
- 235000019198 oils Nutrition 0.000 description 23
- 239000000203 mixture Substances 0.000 description 21
- 239000011230 binding agent Substances 0.000 description 14
- 238000001035 drying Methods 0.000 description 10
- 229920005989 resin Polymers 0.000 description 7
- 239000011347 resin Substances 0.000 description 7
- 239000003513 alkali Substances 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 239000002253 acid Substances 0.000 description 4
- 235000011194 food seasoning agent Nutrition 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 229920000180 alkyd Polymers 0.000 description 3
- 239000000945 filler Substances 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- 241000276489 Merlangius merlangus Species 0.000 description 2
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- QDOXWKRWXJOMAK-UHFFFAOYSA-N dichromium trioxide Chemical compound O=[Cr]O[Cr]=O QDOXWKRWXJOMAK-UHFFFAOYSA-N 0.000 description 2
- 235000013312 flour Nutrition 0.000 description 2
- 238000001879 gelation Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 2
- 235000015112 vegetable and seed oil Nutrition 0.000 description 2
- 239000002023 wood Substances 0.000 description 2
- -1 'cycloaliphatic Chemical group 0.000 description 1
- MHVJRKBZMUDEEV-APQLOABGSA-N (+)-Pimaric acid Chemical compound [C@H]1([C@](CCC2)(C)C(O)=O)[C@@]2(C)[C@H]2CC[C@](C=C)(C)C=C2CC1 MHVJRKBZMUDEEV-APQLOABGSA-N 0.000 description 1
- MHVJRKBZMUDEEV-UHFFFAOYSA-N (-)-ent-pimara-8(14),15-dien-19-oic acid Natural products C1CCC(C(O)=O)(C)C2C1(C)C1CCC(C=C)(C)C=C1CC2 MHVJRKBZMUDEEV-UHFFFAOYSA-N 0.000 description 1
- VZXTWGWHSMCWGA-UHFFFAOYSA-N 1,3,5-triazine-2,4-diamine Chemical compound NC1=NC=NC(N)=N1 VZXTWGWHSMCWGA-UHFFFAOYSA-N 0.000 description 1
- 241000273930 Brevoortia tyrannus Species 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 241000016649 Copaifera officinalis Species 0.000 description 1
- XZMCDFZZKTWFGF-UHFFFAOYSA-N Cyanamide Chemical compound NC#N XZMCDFZZKTWFGF-UHFFFAOYSA-N 0.000 description 1
- 244000020551 Helianthus annuus Species 0.000 description 1
- 235000003222 Helianthus annuus Nutrition 0.000 description 1
- 240000007049 Juglans regia Species 0.000 description 1
- 235000009496 Juglans regia Nutrition 0.000 description 1
- 239000004868 Kauri gum Substances 0.000 description 1
- 241000219482 Lithops Species 0.000 description 1
- 235000004347 Perilla Nutrition 0.000 description 1
- 244000124853 Perilla frutescens Species 0.000 description 1
- 244000204900 Talipariti tiliaceum Species 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 229910000004 White lead Inorganic materials 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 230000001133 acceleration Effects 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 125000003710 aryl alkyl group Chemical group 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 239000010425 asbestos Substances 0.000 description 1
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 1
- 238000003490 calendering Methods 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical class [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 239000007799 cork Substances 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000010685 fatty oil Substances 0.000 description 1
- 235000021323 fish oil Nutrition 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 235000010985 glycerol esters of wood rosin Nutrition 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- DCYOBGZUOMKFPA-UHFFFAOYSA-N iron(2+);iron(3+);octadecacyanide Chemical compound [Fe+2].[Fe+2].[Fe+2].[Fe+3].[Fe+3].[Fe+3].[Fe+3].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-] DCYOBGZUOMKFPA-UHFFFAOYSA-N 0.000 description 1
- 239000011133 lead Substances 0.000 description 1
- MOUPNEIJQCETIW-UHFFFAOYSA-N lead chromate Chemical compound [Pb+2].[O-][Cr]([O-])(=O)=O MOUPNEIJQCETIW-UHFFFAOYSA-N 0.000 description 1
- FDZZZRQASAIRJF-UHFFFAOYSA-M malachite green Chemical compound [Cl-].C1=CC(N(C)C)=CC=C1C(C=1C=CC=CC=1)=C1C=CC(=[N+](C)C)C=C1 FDZZZRQASAIRJF-UHFFFAOYSA-M 0.000 description 1
- 229940107698 malachite green Drugs 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 235000012054 meals Nutrition 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 125000005609 naphthenate group Chemical group 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 229960003351 prussian blue Drugs 0.000 description 1
- 239000013225 prussian blue Substances 0.000 description 1
- 229910052895 riebeckite Inorganic materials 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 150000003505 terpenes Chemical class 0.000 description 1
- 235000007586 terpenes Nutrition 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 239000002383 tung oil Substances 0.000 description 1
- 235000020234 walnut Nutrition 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09F—NATURAL RESINS; FRENCH POLISH; DRYING-OILS; OIL DRYING AGENTS, i.e. SICCATIVES; TURPENTINE
- C09F9/00—Compounds to be used as driers, i.e. siccatives
Definitions
- This invention relates to the acceleration of the rate of curing or seasoning" of surface covering compositions such as floor covering compositions containing siccative binders, as well as to the improvement'in the alkali resistance of such compositions.
- An object of this invention is to provide accelerators for surface covering compositions containing siccative binders which will cause such compositions to cure more rapidly. Another object of this invention is to improve the alkali resistance of surface covering compositions containing siccative binders.
- R, R1, ,Rz, R3, and R4 may be aliphatic, 'cycloaliphatic, aralkyl or aryl, or R1, R2, R3, and R4 may be hy-- drogen.
- the material may be calendere zi on to burlap or other fibrous backing if desired.
- the sheeted material is placed in a stoving oven through which a current of heated air from about 70 C. to about 90 C. is circulated until the material is completely seasoned, i. e. untilthe sheet acquires the necessary degree of hardness.
- the hardness may be measured by any of the methods generally employed in the manufacture of linoleum. See the Federal Stock Catalogue (U. S. Government Printing Oflice), section 4, part 5, pages LLL-L-351 et seq. and pages LLL-L361 et seq., for the method employed herein,
- the time required for seasoning a 2 mm. of sheet of the above composition is about seven to eight days.
- the resulting seasoned floor covering shows improved alkali resistance.
- One method of determining alkali resistance is to measure the depth in millimeters to which a l 5% solution of sodium hydroxide in water penetrates in one hour at a temperature of F. By this method the alkali resistance of the seasoned sheets is about 0.24 mm. penetration.
- the binders may be derived from the drying oils and may be made in any convenient well-V known manner, such as the method described in British Patent 305,656 or the binders may comprise any of the various alkyd resins having siccative properties.
- seed oil is preferable for economic reasons but other siccative oils may be used such as, for example, menhaden or fish oil, tung oil, soy bean oil, perilla oil, oiticica oil, Scheiber oil, sunflower I seed oil, etc.
- siccative oil as used herei is intended to include not only the socalled drying oils but also the so-calied semidrying oils. Furthermore it is possible to use mixtures of siccative oils with other fatty oils of the non-drying type.
- so-called scrim-oil or shed oil either alone or fiuxed with rosin or other gums or resin and/or mixed with a proportion of the so-called mechanical oil. Either of these types of oils may be used singly if desired.
- rosin in admixture'with the oil although other substances of the same type may be used, e. g., kauri gum, Congo gum, ester gum, abietic. acid and its esters, pimaric acid, etc.
- linther siccative binders which may be used are the alkyd resins which have siccative properties.
- the drying oil modified reaction products of maleic or iumaric acid with terpenes and polyhydric alcohols are particularly desirable.
- Other alkyd resins which are modified with drying oils may be used such as the phthalicglyceride resins, the glycol-maleic resins, and
- mixed resins such as the phthalic-iumaric-glycolglyceride resins.
- fillers or pigments may be used.
- fillers are: cork, cellulose pulp, asbestos, cottonwood tree pulp, walnut shell meal, glass fibers, foliated glass, etc.
- pigments which may be used the following are included: lithopone, barytes, zinc oxide, titanium oxide, chromates, red lead, white lead, malachite green, chrome green, chrome yellow, Prussian blue, iron oxide, etc.
- dyes and lakes may be used if desirable.
- driers in the preparation 01 the binders.
- the drier is usually added to the binder during the oxidation process and if desirable additional drier may be added when the binder, fillers, etc., are mixed together.
- Suitable driers include the oil soluble salts such as the naphthenates, resinates and linoleates of cobalt, lead, manganese, zinc, and chromium. Only a small proportion of these driers based on the siccative oil content, is generally sufilcient, e. g. about 0.005-1%, although larger proportions may be used as expedient. Obviously various mixtures 01 driers may be used.
- seasoning as applied to linoleum compositions indicates the process of curing by heating or equivalent treatment to polymerize and/or oxidize the composition to a stage wherein the floor covering is sufficiently hard and reasoaair though they may be added before or during the oxidation of the binder. If my accelerators are added before or during the oxidation they appear to inhibit somewhat the gelation of the Sierra-- tive binder. It is to be noted, however, that after gelation my accelerators speed up the curing of the siccative composition.
- a siccative material selected from the group consisting oi drying oils and drying oil modified poiyhydric alcohol-polycarboxylic acid resins, the step which comprises adding to such a composition a auananiine.
- a surface covering composition including a siccative material se lected from the group consisting of drying oils and drying oil modified polyhydric alcohol-polycarboxylic acid resins, the step which comprises adding to such a composition acetcguanamine.
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Description
Fatented Dec. 15, 1942 PROCESS OF CURING SURFACE COVERING MATERIALS Walter W. Durant, Old Greenwich, Conn., assignor to American Cyanamid Company, New York, N. Y., a corporation of Maine No Drawing. Application November 30, 1939, Serial No. 306,900
2 Claims.
This invention relates to the acceleration of the rate of curing or seasoning" of surface covering compositions such as floor covering compositions containing siccative binders, as well as to the improvement'in the alkali resistance of such compositions.
An object of this invention is to provide accelerators for surface covering compositions containing siccative binders which will cause such compositions to cure more rapidly. Another object of this invention is to improve the alkali resistance of surface covering compositions containing siccative binders.
These and other objects are attained by incorporating in a siccative composition which is to be used in a floor covering composition or other surface covering composition a guanamine, i. e. of the probable formula:
or the tautomeric forms thereof, wherein R, R1, ,Rz, R3, and R4 may be aliphatic, 'cycloaliphatic, aralkyl or aryl, or R1, R2, R3, and R4 may be hy-- drogen.
The following example is given by way of illus- -tration and not in limitation.
Example Parts by weight Binder Wood flour 30 Whiting 20 Lithop 20 A togimnamine .3
mixed and disintegrated and then calendered.
The material may be calendere zi on to burlap or other fibrous backing if desired. The sheeted material is placed in a stoving oven through which a current of heated air from about 70 C. to about 90 C. is circulated until the material is completely seasoned, i. e. untilthe sheet acquires the necessary degree of hardness.
The hardness may be measured by any of the methods generally employed in the manufacture of linoleum. See the Federal Stock Catalogue (U. S. Government Printing Oflice), section 4, part 5, pages LLL-L-351 et seq. and pages LLL-L361 et seq., for the method employed herein, The time required for seasoning a 2 mm. of sheet of the above composition is about seven to eight days. The resulting seasoned floor covering shows improved alkali resistance. One method of determining alkali resistance is to measure the depth in millimeters to which a l 5% solution of sodium hydroxide in water penetrates in one hour at a temperature of F. By this method the alkali resistance of the seasoned sheets is about 0.24 mm. penetration.
The seasoning speed of a 2 mm. sheet of the 0.28 mm. The marked improvement obtained with my composition is outstanding inasmuch as I have found it to be very difficult to improve the alkali resistance by even as little as 0.01 mm.
The binders may be derived from the drying oils and may be made in any convenient well-V known manner, such as the method described in British Patent 305,656 or the binders may comprise any of the various alkyd resins having siccative properties. seed oil is preferable for economic reasons but other siccative oils may be used such as, for example, menhaden or fish oil, tung oil, soy bean oil, perilla oil, oiticica oil, Scheiber oil, sunflower I seed oil, etc. The term siccative oil as used herei is intended to include not only the socalled drying oils but also the so-calied semidrying oils. Furthermore it is possible to use mixtures of siccative oils with other fatty oils of the non-drying type.
It may be preferable in the manufacture of linoleum to make use of so-called scrim-oil or shed oil either alone or fiuxed with rosin or other gums or resin and/or mixed with a proportion of the so-called mechanical oil. Either of these types of oils may be used singly if desired.
In the preparation of the siccative oil binders it is customary to use rosin in admixture'with the oil although other substances of the same type may be used, e. g., kauri gum, Congo gum, ester gum, abietic. acid and its esters, pimaric acid, etc.
For drying oil binders, linther siccative binders which may be used are the alkyd resins which have siccative properties. Among these, the drying oil modified reaction products of maleic or iumaric acid with terpenes and polyhydric alcohols are particularly desirable. Other alkyd resins which are modified with drying oils may be used such as the phthalicglyceride resins, the glycol-maleic resins, and
mixed resins such as the phthalic-iumaric-glycolglyceride resins.
Instead of wood flour and/or the whiting and lithopone used in the example, other fillers or pigments may be used. Examples of such fillers are: cork, cellulose pulp, asbestos, cottonwood tree pulp, walnut shell meal, glass fibers, foliated glass, etc. Among the pigments which may be used the following are included: lithopone, barytes, zinc oxide, titanium oxide, chromates, red lead, white lead, malachite green, chrome green, chrome yellow, Prussian blue, iron oxide, etc. Similarly dyes and lakes may be used if desirable.
It is generally preferable to use driers in the preparation 01 the binders. The drier is usually added to the binder during the oxidation process and if desirable additional drier may be added when the binder, fillers, etc., are mixed together. Suitable driers include the oil soluble salts such as the naphthenates, resinates and linoleates of cobalt, lead, manganese, zinc, and chromium. Only a small proportion of these driers based on the siccative oil content, is generally sufilcient, e. g. about 0.005-1%, although larger proportions may be used as expedient. Obviously various mixtures 01 driers may be used.
The term seasoning as applied to linoleum compositions indicates the process of curing by heating or equivalent treatment to polymerize and/or oxidize the composition to a stage wherein the floor covering is sufficiently hard and reasoaair though they may be added before or during the oxidation of the binder. If my accelerators are added before or during the oxidation they appear to inhibit somewhat the gelation of the Sierra-- tive binder. It is to be noted, however, that after gelation my accelerators speed up the curing of the siccative composition.
Obviously many modifications in the processes and compositions described above may be Without departing from th SI, rit scope oi the invention as defined in the appended claims.
I claim:
1. In a process of curing surface covering composition, including a siccative material selected from the group consisting oi drying oils and drying oil modified poiyhydric alcohol-polycarboxylic acid resins, the step which comprises adding to such a composition a auananiine.
2. In a process of curing a surface covering composition including a siccative material se lected from the group consisting of drying oils and drying oil modified polyhydric alcohol-polycarboxylic acid resins, the step which comprises adding to such a composition acetcguanamine.
WALTER
Publications (1)
Publication Number | Publication Date |
---|---|
US2305217A true US2305217A (en) | 1942-12-15 |
Family
ID=3433021
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US2305217D Expired - Lifetime US2305217A (en) | Process of cubing surface covering |
Country Status (1)
Country | Link |
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US (1) | US2305217A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3478026A (en) * | 1967-08-16 | 1969-11-11 | Armour Pharma | 6 - cycloalkylguanamines,preparations and methods for treating inflammatory conditions therewith |
-
0
- US US2305217D patent/US2305217A/en not_active Expired - Lifetime
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3478026A (en) * | 1967-08-16 | 1969-11-11 | Armour Pharma | 6 - cycloalkylguanamines,preparations and methods for treating inflammatory conditions therewith |
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