US2302552A - Method and apparatus for treating lubricating oils - Google Patents
Method and apparatus for treating lubricating oils Download PDFInfo
- Publication number
- US2302552A US2302552A US200745A US20074538A US2302552A US 2302552 A US2302552 A US 2302552A US 200745 A US200745 A US 200745A US 20074538 A US20074538 A US 20074538A US 2302552 A US2302552 A US 2302552A
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- oil
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- addition agent
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M175/00—Working-up used lubricants to recover useful products ; Cleaning
- C10M175/0091—Treatment of oils in a continuous lubricating circuit (e.g. motor oil system)
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01M—LUBRICATING OF MACHINES OR ENGINES IN GENERAL; LUBRICATING INTERNAL COMBUSTION ENGINES; CRANKCASE VENTILATING
- F01M1/00—Pressure lubrication
- F01M1/10—Lubricating systems characterised by the provision therein of lubricant venting or purifying means, e.g. of filters
- F01M2001/105—Lubricating systems characterised by the provision therein of lubricant venting or purifying means, e.g. of filters characterised by the layout of the purification arrangements
- F01M2001/1057—Lubricating systems characterised by the provision therein of lubricant venting or purifying means, e.g. of filters characterised by the layout of the purification arrangements comprising a plurality of filters, parallel or serial
Definitions
- Thepresent invention relates to a method and device for treating lubricating oil during its use in the lubrication systems such as may be associated with internal combustion engines, steam turbines, compressors and the like, and relates more particularly to the maintenance of efiective concentrations of organic addition agents in said oil during use in such lubricating systems.v
- a principal object of this injection is the maintenance of effective concentrations of various organic addition agents, such as oxidation inhibltors, sludge inhibitors, film strength agents,
- a further object of this invention is the removal from engine lubricating oil of impurities such as carbon, metal particles, abrasive solids and sludge, prior to its treatment for the maintenance of effective concentrations of organic addition agents.
- the oil from the crankcase is first passed through a porous filtering medium, in order to remove carbon, abrasive solids, sludge or the like which would otherwise tend to accumulate on the impregnated absorbent medium and prevent solution of the addition agent in the oil.
- the filtering medium may be dispensed with in lubricating systems in which the oil does not become contaminated with foreign solids, sludge, and the like.
- the organic addition agents which I prefer lubricating oil at ordinary temperatures, the increase of solubility, with increase in temperature being very slight. Either a single addition agent, or a mixture of two or more of such agents, may be employed in accordance with my invention.
- a chamber i is provided with an oil inlet 2 and an outlet 3, and may be further provided with a permeable partition 4, such as a metal screen, which divides the chamber into two sections and 8.
- Section I is provided with a loosely packed, porous filtering medium such as clay, hair felt or other fibrous material, and serves to filter foreign solids such as carbon, abrasive particles and sludge from the engine oil.
- Section 8 is provided with a porous absorbent material, such as cotton waste, impregnated with an organic addition agent which is soluble in lubricating oil in relatively low concentrations.
- the porous absorbent material may be impregnated with the organic addition agent, if solid, by dissolving the agent in a suitable solvent, saturating the absorbent material with the solution so formed, and removing the solvent by vaporization.
- the oil in passing from the filtering section 5 through the impregnated absorbent medium in section 6, dissolves therefrom asmall quantity of the organic addition agent, thus compensating for the'loss of agent in the oil during use.
- screens 1 may be provided adjacent the ends of the chamber.
- Fig. 2 represents a modified construction of the device illustrated in Fig. l, the individual sections 5 and 6 being joined by a coupling or union 8. This modification permits renewal of either section 5 or 6 as necessity demands.
- FIG. 3 shows a further modification of the device, wherein sections 5 and 6 are connected in parallel, as distinguished from the preferred construction of Figures 1 and 2 in which the sections are disposed in series.
- each of the devices illustrated may be further provided with a conventional oil by-psss line (not shown) which insures a continuous fiow of oil to the engine parts to be lubricated. in the event that the treating device becomes clogged or otherwise disabled.
- my invention primarily with respect to the treatment of oils during use in the lubrication of internal combustion engines, my invention is also applicable to the treatment of lubricating oils employed in oil circulating systems of steam turbines, air or gas compressors, and the like.
- a device for purifying lubricating oil and for maintaining therein an effective concentration of an organic addition agent which comprises, in series, a porous filtering medium and a porous absorbent medium impregnated with an organic addition agent soluble in lubricating oil in relatively low concentrations, means for introducing used oil to the porous filtering medium and means'ior withdrawing treated oil from the porous absorbent medium impregnated with said organic addition agent.
- a device for purifying lubricating oil and for maintaining therein an effective concentration of an organic addition agent which comprises a chamber, a permeable partition disposed within said chamber and dividing said chamber into two sections, a porous filtering medium disposed in one section of said chamber, a porousabsorbent medium impregnated with an organic addition agent soluble in lubricating oil in relatively low concentrations disposed in the second section of said chamber, means for introducing used oil into the first mentioned section and means for withdrawing treated oil from the second section of said chamber.
- a device for purifying lubricating oil and for maintaining therein an eilective concentration of an organic addition agent which comprises a chamber, a porous filtering medium disposed in one section of said chamber, a porous absorbent medium impregnated with an organic addition agent soluble in lubricating oil in relatively low concentrations disposed in a second section of said chamber, means for introducing used oil into the first mentioned section, and means iorwithdrawing treated oil from the second section of said chamber.
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubrication Details And Ventilation Of Internal Combustion Engines (AREA)
- Lubricants (AREA)
Description
7 J. w. JOHNSON ,30
METHOD AND APPARATUS FOR TREATING LUBRICATING OILS Filed April 7, 1938 Hgl' IIIIIIIIIIIIIIIIIIllIIIlIIIlIIlII/IIIIIIIIIIIIIIIIIIIII 3 2 'IIIIIIIIIIIIIIIII IIIIIA 7 7 Inventor James W Jflmson By/MQ Patented Nov. 17, 1942 METHOD AND APPARATUS FOR TREATING LUBRICATING OILS James W. Johnson, Philadelphia, Pa., assignor to The Atlantic Refining Company, Philadelphia, Pa., a corporation of Pennsylvania Application April 7, 1938, Serial No. 200,745
3 Clailns.
Thepresent invention relates to a method and device for treating lubricating oil during its use in the lubrication systems such as may be associated with internal combustion engines, steam turbines, compressors and the like, and relates more particularly to the maintenance of efiective concentrations of organic addition agents in said oil during use in such lubricating systems.v
A principal object of this injection is the maintenance of effective concentrations of various organic addition agents, such as oxidation inhibltors, sludge inhibitors, film strength agents,
to employ are those which are soluble in the oil to the extent of, for example, from about 0.02% to about 0.5% at temperatures normally encountered in engine operation, and may be illustrated by the following examples. The percentages given indicate the maximum solubility in engine and oiliness" agents in lubricating oil during its use in internal combustion engines.
A further object of this invention is the removal from engine lubricating oil of impurities such as carbon, metal particles, abrasive solids and sludge, prior to its treatment for the maintenance of effective concentrations of organic addition agents. I
Heretofore it has been customary to add to lubricating oils, prior to their use, a suitable proportion of one or more agents for inhibiting oxi- I dation, sludging, bearing corrosion and the like, or for the purpose of increasing film strength and oiliness. Since many of these agents are relatively slightly soluble in lubricating oil, only small quantities thereof could be incorporated in the oil and still retain a satisfactory and marketable appearance. Moreover, upon extended use of these compounded oils, particularly in crankcase service of internal combustion engines, the effectiveness of the added agents progressively decreased, and in many cases such agents failed completely, due to consumption and/or chemical reaction associated with their inhibitingeifect.
I. have found that such difliculties may be overcome by replenishing the addition agent in the lubricating oil as it is consumed during use. This may be accomplished, in accordance with my invention, by passing oil, for example, from the engine crankcase through a chamber provided with a porous absorbent medium impregnated with an organic addition agent which is soluble in the oil in relatively low concentrations. The oil, in passing through the impregnated absorbent medium, dissolves therefrom suflicient of the addition agent to continuously maintain an effective concentration of the agent in solution therein. Preferably, the oil from the crankcase is first passed through a porous filtering medium, in order to remove carbon, abrasive solids, sludge or the like which would otherwise tend to accumulate on the impregnated absorbent medium and prevent solution of the addition agent in the oil. It is to be understood, however, that the filtering medium may be dispensed with in lubricating systems in which the oil does not become contaminated with foreign solids, sludge, and the like. The organic addition agents which I prefer lubricating oil at ordinary temperatures, the increase of solubility, with increase in temperature being very slight. Either a single addition agent, or a mixture of two or more of such agents, may be employed in accordance with my invention.
Sludge inhibitors and bearing corrosion inhibitors:
Weight, per cent Thiourea 0.02 o-Tolyl thiourea 0.03 Phenyl thiourea 0.02 Diphenyl thiourea 0.03 S-di-p-tolyl thiourea 0. 20 Di-o-tolyl thiourea s 0. 06 Di-fl-naphthylamine 0. 05 Catechol 0.50 Tetr'amethylthiuram disulflde 0.'15 Dipentamethylene thiuram monosulfide 0. 15 Thiodiphenylamine 0. 30 Furfuramide 0. 30 p-Hydroxyphenylmorpholine 0. 05 Z-amino, 4-nitrophenol 0. 02 m-Dinitrobenzene 0.30 Sym-trinitrobenzene 0. 30 Hexamethylene tetramine 0.20 PYIOE'BQIIOL; 0.05 Resorcinol 0. 03 2, 4 diamino 'diphenylamine 0130 p-Hydroxy diphenyl -0. 15 Di-a-naphthol 0. 30 p-hydroxy anthraquinone -s 0.30 p-Aminophenol 0.30 p-dithio diglycol 0.10 30 m-Diamino benzene 0.
Film strength agents.
Tri-phenyl methyl phosphonium iodide- 0. l0
My invention may be further illustrated with reference to the accompanying drawing in which Figures 1, 2, and 3 are sectional views of three modifications of my device for treating engine lubricating oil. In these figures, corresponding elements are similarly numbered.
Referring to Fig. a chamber i is provided with an oil inlet 2 and an outlet 3, and may be further provided with a permeable partition 4, such as a metal screen, which divides the chamber into two sections and 8. Section I is provided with a loosely packed, porous filtering medium such as clay, hair felt or other fibrous material, and serves to filter foreign solids such as carbon, abrasive particles and sludge from the engine oil. Section 8 is provided with a porous absorbent material, such as cotton waste, impregnated with an organic addition agent which is soluble in lubricating oil in relatively low concentrations. The porous absorbent material may be impregnated with the organic addition agent, if solid, by dissolving the agent in a suitable solvent, saturating the absorbent material with the solution so formed, and removing the solvent by vaporization. The oil, in passing from the filtering section 5 through the impregnated absorbent medium in section 6, dissolves therefrom asmall quantity of the organic addition agent, thus compensating for the'loss of agent in the oil during use. In order to maintain the filtering medium and the impregnated absorbent medium in position within chamber l, screens 1 may be provided adjacent the ends of the chamber.
Fig. 2 represents a modified construction of the device illustrated in Fig. l, the individual sections 5 and 6 being joined by a coupling or union 8. This modification permits renewal of either section 5 or 6 as necessity demands.
Fig. 3 shows a further modification of the device, wherein sections 5 and 6 are connected in parallel, as distinguished from the preferred construction of Figures 1 and 2 in which the sections are disposed in series.
The devices illustrated in Figures l, 2 and 3 may be installed in the conventional oil circulation system associated with the crankcase of,
an internal combustion engine, the used oil from the crankcase being introduced into the device by means of oil inlet line 2 and the treated oil withdrawn therefrom through outlet line 3. Each of the devices illustrated may be further provided with a conventional oil by-psss line (not shown) which insures a continuous fiow of oil to the engine parts to be lubricated. in the event that the treating device becomes clogged or otherwise disabled.
While I have described my invention primarily with respect to the treatment of oils during use in the lubrication of internal combustion engines, my invention is also applicable to the treatment of lubricating oils employed in oil circulating systems of steam turbines, air or gas compressors, and the like.
What I claim is:
1. A device for purifying lubricating oil and for maintaining therein an effective concentration of an organic addition agent, which comprises, in series, a porous filtering medium and a porous absorbent medium impregnated with an organic addition agent soluble in lubricating oil in relatively low concentrations, means for introducing used oil to the porous filtering medium and means'ior withdrawing treated oil from the porous absorbent medium impregnated with said organic addition agent.
2. A device for purifying lubricating oil and for maintaining therein an effective concentration of an organic addition agent, which comprises a chamber, a permeable partition disposed within said chamber and dividing said chamber into two sections, a porous filtering medium disposed in one section of said chamber, a porousabsorbent medium impregnated with an organic addition agent soluble in lubricating oil in relatively low concentrations disposed in the second section of said chamber, means for introducing used oil into the first mentioned section and means for withdrawing treated oil from the second section of said chamber.
3. A device for purifying lubricating oil and for maintaining therein an eilective concentration of an organic addition agent, which comprises a chamber, a porous filtering medium disposed in one section of said chamber, a porous absorbent medium impregnated with an organic addition agent soluble in lubricating oil in relatively low concentrations disposed in a second section of said chamber, means for introducing used oil into the first mentioned section, and means iorwithdrawing treated oil from the second section of said chamber.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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US200745A US2302552A (en) | 1938-04-07 | 1938-04-07 | Method and apparatus for treating lubricating oils |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US200745A US2302552A (en) | 1938-04-07 | 1938-04-07 | Method and apparatus for treating lubricating oils |
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US2302552A true US2302552A (en) | 1942-11-17 |
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US200745A Expired - Lifetime US2302552A (en) | 1938-04-07 | 1938-04-07 | Method and apparatus for treating lubricating oils |
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Cited By (25)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2435734A (en) * | 1941-05-31 | 1948-02-10 | Ulric B Bray | Method of and apparatus for filtering oil |
US2435707A (en) * | 1941-05-31 | 1948-02-10 | Ulric B Bray | Method of and apparatus for treating oil |
US2683081A (en) * | 1950-12-09 | 1954-07-06 | Ethyl Corp | Stabilized organic compositions |
US2955028A (en) * | 1955-10-17 | 1960-10-04 | Ethyl Corp | Fuel systems for compression ignition engines |
US2979160A (en) * | 1956-11-05 | 1961-04-11 | Continental Motors Corp | Lubrication system |
US3156647A (en) * | 1962-02-26 | 1964-11-10 | Gen Motors Corp | Filter for a dry cleaning apparatus |
US3156648A (en) * | 1962-03-16 | 1964-11-10 | Gen Motors Corp | Filter cartridge for a dry cleaning system |
US3198334A (en) * | 1962-02-26 | 1965-08-03 | Gen Motors Corp | Filter for a dry cleaning apparatus |
US3296136A (en) * | 1963-11-13 | 1967-01-03 | Sinclair Research Inc | Lubricant compositions of improved oxidation resistance |
US3336223A (en) * | 1965-06-08 | 1967-08-15 | Atlantic Refining Co | Method and means for maintaining an effective concentration of additives in oil |
US3485324A (en) * | 1967-11-07 | 1969-12-23 | Allis Chalmers Mfg Co | Piston cooling system |
US3521753A (en) * | 1968-04-30 | 1970-07-28 | Werner P Schoening | Filtering and heating of liquids by use of a flexible cellular blanket |
US3945208A (en) * | 1974-01-02 | 1976-03-23 | Allis-Chalmers Corporation | Filtration for integrated tractor hydraulic system |
JPS51116462A (en) * | 1975-04-04 | 1976-10-13 | Showa Shell Sekiyu Kk | Oil filter immersed with pitting preventive agent of cam and tappet |
US4179019A (en) * | 1978-01-09 | 1979-12-18 | Danziger Harry Lee | Apparatus for reclaiming used lubricating oils |
US4246107A (en) * | 1978-03-06 | 1981-01-20 | Asahi Kasei Kogyo Kabushiki Kaisha | Separation of lymphocytes from lymphocyte-containing suspension by filtration |
DE3019141A1 (en) * | 1980-01-11 | 1981-07-16 | Tecnocar S.p.A., 10095 Grugliasco, Torino | OIL FILTERS FOR COMBUSTION ENGINES |
US4362630A (en) * | 1977-07-22 | 1982-12-07 | Exxon Research And Engineering Co. | Side stream monitoring |
US4512299A (en) * | 1983-12-12 | 1985-04-23 | International Harvester Company | Automotive engine with improved multifilter lubrication system |
US4592843A (en) * | 1984-10-03 | 1986-06-03 | Morton Thiokol, Inc. | Method for removal of organometallics from wastewater |
US4601831A (en) * | 1984-10-03 | 1986-07-22 | Morton Thiokol, Inc. | Antimicrobial adjustment technique |
WO1988005072A2 (en) * | 1987-01-07 | 1988-07-14 | Exxon Chemical Patents, Inc. | Removal of carcinogenic hydrocarbons from used lubricating oil |
US4897187A (en) * | 1988-12-05 | 1990-01-30 | Rice William J | Portable water filtration apparatus |
US5067455A (en) * | 1989-11-04 | 1991-11-26 | Nippondenso Co., Ltd. | Method and apparatus for adding additives to lubricating oil |
US20100108018A1 (en) * | 2006-06-21 | 2010-05-06 | Castrol Limited | Apparatus and method for adding one or more additives to an engine lubricant |
-
1938
- 1938-04-07 US US200745A patent/US2302552A/en not_active Expired - Lifetime
Cited By (30)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2435707A (en) * | 1941-05-31 | 1948-02-10 | Ulric B Bray | Method of and apparatus for treating oil |
US2435734A (en) * | 1941-05-31 | 1948-02-10 | Ulric B Bray | Method of and apparatus for filtering oil |
US2683081A (en) * | 1950-12-09 | 1954-07-06 | Ethyl Corp | Stabilized organic compositions |
US2955028A (en) * | 1955-10-17 | 1960-10-04 | Ethyl Corp | Fuel systems for compression ignition engines |
US2979160A (en) * | 1956-11-05 | 1961-04-11 | Continental Motors Corp | Lubrication system |
US3198334A (en) * | 1962-02-26 | 1965-08-03 | Gen Motors Corp | Filter for a dry cleaning apparatus |
US3156647A (en) * | 1962-02-26 | 1964-11-10 | Gen Motors Corp | Filter for a dry cleaning apparatus |
US3156648A (en) * | 1962-03-16 | 1964-11-10 | Gen Motors Corp | Filter cartridge for a dry cleaning system |
US3296136A (en) * | 1963-11-13 | 1967-01-03 | Sinclair Research Inc | Lubricant compositions of improved oxidation resistance |
US3336223A (en) * | 1965-06-08 | 1967-08-15 | Atlantic Refining Co | Method and means for maintaining an effective concentration of additives in oil |
US3485324A (en) * | 1967-11-07 | 1969-12-23 | Allis Chalmers Mfg Co | Piston cooling system |
US3521753A (en) * | 1968-04-30 | 1970-07-28 | Werner P Schoening | Filtering and heating of liquids by use of a flexible cellular blanket |
US3945208A (en) * | 1974-01-02 | 1976-03-23 | Allis-Chalmers Corporation | Filtration for integrated tractor hydraulic system |
JPS51116462A (en) * | 1975-04-04 | 1976-10-13 | Showa Shell Sekiyu Kk | Oil filter immersed with pitting preventive agent of cam and tappet |
US4362630A (en) * | 1977-07-22 | 1982-12-07 | Exxon Research And Engineering Co. | Side stream monitoring |
US4179019A (en) * | 1978-01-09 | 1979-12-18 | Danziger Harry Lee | Apparatus for reclaiming used lubricating oils |
US4246107A (en) * | 1978-03-06 | 1981-01-20 | Asahi Kasei Kogyo Kabushiki Kaisha | Separation of lymphocytes from lymphocyte-containing suspension by filtration |
DE3019141A1 (en) * | 1980-01-11 | 1981-07-16 | Tecnocar S.p.A., 10095 Grugliasco, Torino | OIL FILTERS FOR COMBUSTION ENGINES |
US4512299A (en) * | 1983-12-12 | 1985-04-23 | International Harvester Company | Automotive engine with improved multifilter lubrication system |
US4592843A (en) * | 1984-10-03 | 1986-06-03 | Morton Thiokol, Inc. | Method for removal of organometallics from wastewater |
US4601831A (en) * | 1984-10-03 | 1986-07-22 | Morton Thiokol, Inc. | Antimicrobial adjustment technique |
EP0275148A2 (en) * | 1987-01-07 | 1988-07-20 | Exxon Chemical Patents Inc. | Removal of carcinogenic hydrocarbons from used lubricating oil |
WO1988005072A2 (en) * | 1987-01-07 | 1988-07-14 | Exxon Chemical Patents, Inc. | Removal of carcinogenic hydrocarbons from used lubricating oil |
WO1988005072A3 (en) * | 1987-01-07 | 1988-10-06 | Exxon Chemical Ltd | Removal of carcinogenic hydrocarbons from used lubricating oil |
EP0275148A3 (en) * | 1987-01-07 | 1988-12-07 | Exxon Chemical Patents Inc. | Removal of carcinogenic hydrocarbons from used lubricating oil |
US4977871A (en) * | 1987-01-07 | 1990-12-18 | Exxon Chemical Patents, Inc. | Removal of carcinogenic hydrocarbons from used lubricating oil using activated carbon |
US4897187A (en) * | 1988-12-05 | 1990-01-30 | Rice William J | Portable water filtration apparatus |
US5067455A (en) * | 1989-11-04 | 1991-11-26 | Nippondenso Co., Ltd. | Method and apparatus for adding additives to lubricating oil |
US20100108018A1 (en) * | 2006-06-21 | 2010-05-06 | Castrol Limited | Apparatus and method for adding one or more additives to an engine lubricant |
US8327818B2 (en) | 2006-06-21 | 2012-12-11 | Castrol Limited | Apparatus and method for adding one or more additives to an engine lubricant |
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