US2301366A - Method for increasing the tempera - Google Patents
Method for increasing the tempera Download PDFInfo
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- US2301366A US2301366A US2301366DA US2301366A US 2301366 A US2301366 A US 2301366A US 2301366D A US2301366D A US 2301366DA US 2301366 A US2301366 A US 2301366A
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- temperature
- recrystallization
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- 229910045601 alloy Inorganic materials 0.000 description 62
- 239000000956 alloy Substances 0.000 description 62
- 238000001953 recrystallisation Methods 0.000 description 58
- REDXJYDRNCIFBQ-UHFFFAOYSA-N aluminium(3+) Chemical class [Al+3] REDXJYDRNCIFBQ-UHFFFAOYSA-N 0.000 description 40
- 239000002184 metal Substances 0.000 description 24
- 229910052751 metal Inorganic materials 0.000 description 24
- 239000010949 copper Substances 0.000 description 22
- 239000000203 mixture Substances 0.000 description 18
- 229910052802 copper Inorganic materials 0.000 description 16
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 16
- 239000000126 substance Substances 0.000 description 16
- RYGMFSIKBFXOCR-UHFFFAOYSA-N copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 12
- 150000002739 metals Chemical class 0.000 description 12
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 12
- 229910001030 Iron–nickel alloy Inorganic materials 0.000 description 8
- 229910052742 iron Inorganic materials 0.000 description 8
- 230000005291 magnetic Effects 0.000 description 8
- 229910052759 nickel Inorganic materials 0.000 description 8
- 229910002056 binary alloy Inorganic materials 0.000 description 6
- 238000002425 crystallisation Methods 0.000 description 6
- 230000005712 crystallization Effects 0.000 description 6
- 238000010586 diagram Methods 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 229910018054 Ni-Cu Inorganic materials 0.000 description 4
- 229910018481 Ni—Cu Inorganic materials 0.000 description 4
- 230000000875 corresponding Effects 0.000 description 4
- 230000008929 regeneration Effects 0.000 description 4
- 238000011069 regeneration method Methods 0.000 description 4
- 229910002482 Cu–Ni Inorganic materials 0.000 description 2
- 229910000640 Fe alloy Inorganic materials 0.000 description 2
- 229910000990 Ni alloy Inorganic materials 0.000 description 2
- 238000005275 alloying Methods 0.000 description 2
- 239000010953 base metal Substances 0.000 description 2
- 230000001419 dependent Effects 0.000 description 2
- 230000001809 detectable Effects 0.000 description 2
- 230000005294 ferromagnetic Effects 0.000 description 2
- 239000003302 ferromagnetic material Substances 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 230000005389 magnetism Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 229910001092 metal group alloy Inorganic materials 0.000 description 2
- 230000002441 reversible Effects 0.000 description 2
- 238000005096 rolling process Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 229910002058 ternary alloy Inorganic materials 0.000 description 2
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/16—Ferrous alloys, e.g. steel alloys containing copper
Definitions
- This invention relates to alloys of increased heat resistance, in particular as regards mechanical and magnetical hardness, and to'methods for producing and treating such alloys.
- an increased resistance against the softening influence of elevated operating temperatures is obtained by methods and means which raise the temperature of beginning recrystallization of the metal or alloy.
- recrystallization is understood a crystallization in the solid state of a metal and alloy which takes place at elevated temperatures and causes a regeneration of deformed grains.
- the recrystallization phenomenon is of considerable practical importance because it is the cause of or accompanied with changes in the mechanical and magnetical properties of the material.
- a mechanical softening commences as well as a magnetic softening in the case of ferromagnetic materials. 7 It is in many cases desirable to retard the beginning of the mechanical or magnetic softening until the highest possible temperature is attained, since in many apparatus,
- the temperatures of the beginning recrystallization are approximately one third to one fourth lower than the fusing temperature.
- the temperatures are shown as being dependent upon the degree of deformation.
- the available knowledge of the phenomena of recrystallization has not been sufficient to convey an exact idea of the influence of admixtures upon the recrystallization of metals or alloys.
- the invention is based on the discovery experimentally obtained that the phenomena of recrystallization of metals and alloys are defined by the period required to form the grains as well as by the velocity with which the size of the grains increases.
- the mean period necessary to regenerate the grains by recrystallization at a given temperature while the velocity is determined by the mean distance traversed in the unity of time by the boundaries of the grains during the crystallization.
- the temperature of the beginning recrystallization is therefore the temperature at which, for instance, a radiographically detectable regeneration of grain has taken place after a given duration of test in a material deformed in a certain manner.
- a base consisting substantially of a single metal or of an alloy of completely miscible metals forming homogeneous mixed crystals in any mutual proportion, is added a substance which is incompletely soluble in the base metal or alloy and thus forms with the starting substance 9. miscibility gap.
- the auxiliary substance may consist of a metal or an alloy.
- Figs. 1 and 2 are diagrams showing schematically the fusing temperatures (Ts) and the temperatures of beginning crystallization (Ta) independence upon the composition of an alloyof two components A, B, and C, D respectivelm'the percentages of the components being indicated along the base line of the diagram.
- Ts representsthe melting temperature
- Ta the temperature of beginning recrystallization of a metal consisting to 100% of component A
- Ts and Tnf in-- dicate the corresponding temperatures of component B.
- FIG. 1 exemplifies an alloy composed of 60% A and 40% B, t: indicating the fusing interval and T1: the temperature of beginning recrystallization of this alloy.
- the two components A and B whose fusing points Ts and Ts do not appreciably differ from each other, are completely miscible, i. e. capable of being mixed in any proportion with each other.
- the temperature of the begin- In order to raise this temperature required for ning recrystallization indicated by line b is in this case almost independent of the composition of the alloy.
- the reversible Fe-Ni alloys, Cu-Ni and other mixed crystal alloys are representatives of such alloy systems.
- Fig. 2 shows a binary alloy system whose two components C and D are of limited solubility relative to each other so that they form a miscibility gap.
- This gap is indicated in Fig. 2 by the shaded area enclosed by curve c and the base line.
- the solubility limit represented by curve 0 depends upon the ratio of the two components C and D as well as on the temperature of the .composition.
- the temperature of beginning recrystallization indicated by curve b, depends considerably on the percentile composition, and it is an essen tial point in connection with the present invention that this dependency is similar to the dependence of the solubility limit (curve c) on the percentile composition.
- curve b representing the relationship between the temperature of the beginning recrystallization limit is exceeded so that the composition lies;
- the alloy represented by line 1/ begins to recrystallize at a temperature Ty considerably above the corresponding temperaturevalues TR and Ta 01 the alloying components.
- the method according to the invention is not limited to binary systems but may generally be applied to any alloy consisting of a plurality of substances.
- the ternary system Fe-Ni-Cu is hereinafter dealt with more specifically.
- the ternary 'Fe-Ni-Cu system may be regarded as a composition of a base alloy of the completely miscible components Fe and Ni with an addition of Cu forming a miscibility gap'with the Fe-Ni base.
- the following table indicates various Cu percentages oi alloys in which the remainder consistssubstantially of Fe and N1 in a proportion of 60 to 40. In other words, the copper has been added to a base alloy containing about 60% Fe and about 40% Ni.
- the specimens tested were manufactured by rolling thecastalloy with a total reduction in thickness of 99%.
- the finished specimens were heated to the temperatures and tor the periods indicated in the tables, and the beginning recrystallization and the recrystallization periods were determined by examining the grains of the material. i
- a ferromagnetic article which in normal use is subjected to an elevated temperature of at least about 500 centigrade and adapted to remain magnetic at said elevated temperature, consisting substantially of a base" alloy of iron and nickel containing more iron than nickel and having a temperature of beginning recrystallization below 500 centigrade, and an addition of copper in a percentage within the miscibility gap of copper and said base alloy, said percentage being at least about 6% and 'sufilcient to' raise the temperature oi beginning recrystallization substantially above 500 centigrade.
- An article of manufacture which in normal use is subjected to an operating temperature of at least about 500 centigrade and adapted to maintain hardness or magnetism at said operating temperature, consisting substantially of a base alloy of completely miscible components of the iron group, said alloy containing iron as the predominant ingredient and nickel and having a temperature of beginning recrystallization below said operating temperature, and an addition consisting of copper incompletely miscible with said base alloy so as to form a miscibility gap therewith, said addition having a percentage lying within said miscibility gap, whereby the temperature of beginning recrystallization is raised substantially above said operating temperature.
- a heat-resistant article which in normal operation is subjected to operating temperatures above 500 centigrade, consisting substantially of a base substance selected from the group consisting of the individual metals and metal alloys of completely miscible components, said' base substance having a temperature of beginning recrystallization below said operating temperature, and an addition of metal incompletely miscible with said base substance so as to form a miscibility gap, said addition having a percentage lying in said miscibility gap, and characterized by having the temperature of beginning recrystallization increased above said operating temperature due to said addition.
Description
TEMPERATURE 10, 1942- BUMM ETAL ,301,366
METHOD FOR INCREASING THE TEMPERATURE OF THE BEGINNING RECRYSTALLIZATIGN OF METALS AND ALLOYS Filed April 12, 1939 '2b 0 o'e'o' PERCENTAGE OF compo/van 0 4 z'o n o's'o 'ab.' WW Co Paws/{mas 0;
COMPONENT 6 Patented Nov. 10, 1942 METHOD FOR INCREASING THE TEMPERA- TURE OF THE BEGINNING RECRYSTAL- LIZATION F METALS AND ALLOYS Hellmut Rum and Horst Guido Miiller, Berlin-. Charlottenburg, Germany; vested in the Allen Property Custodian Application'April 12, 1939, Serial No.'267,382
' In Germany April 14, 1938 r 3Claims.
This invention relates to alloys of increased heat resistance, in particular as regards mechanical and magnetical hardness, and to'methods for producing and treating such alloys. According to the invention, an increased resistance against the softening influence of elevated operating temperatures is obtained by methods and means which raise the temperature of beginning recrystallization of the metal or alloy.
By recrystallization is understood a crystallization in the solid state of a metal and alloy which takes place at elevated temperatures and causes a regeneration of deformed grains. The recrystallization phenomenon is of considerable practical importance because it is the cause of or accompanied with changes in the mechanical and magnetical properties of the material. In particular, with the beginning of the recrystallizae tion, a mechanical softening commences as well as a magnetic softening in the case of ferromagnetic materials. 7 It is in many cases desirable to retard the beginning of the mechanical or magnetic softening until the highest possible temperature is attained, since in many apparatus,
- machines or devices great mechanical or magnetic hardness is required at relatively high operating temperatures.
The temperatures of the beginning recrystallization are approximately one third to one fourth lower than the fusing temperature. In the socalled recrystallization diagrams, the temperatures are shown as being dependent upon the degree of deformation. However, the available knowledge of the phenomena of recrystallization has not been sufficient to convey an exact idea of the influence of admixtures upon the recrystallization of metals or alloys.
The invention is based on the discovery experimentally obtained that the phenomena of recrystallization of metals and alloys are defined by the period required to form the grains as well as by the velocity with which the size of the grains increases. By this period is understood the mean period necessary to regenerate the grains by recrystallization at a given temperature, while the velocity is determined by the mean distance traversed in the unity of time by the boundaries of the grains during the crystallization. The temperature of the beginning recrystallization" is therefore the temperature at which, for instance, a radiographically detectable regeneration of grain has taken place after a given duration of test in a material deformed in a certain manner.
the beginning recrystallization the invention proceedsas follows. To a base consisting substantially of a single metal or of an alloy of completely miscible metals forming homogeneous mixed crystals in any mutual proportion, is added a substance which is incompletely soluble in the base metal or alloy and thus forms with the starting substance 9. miscibility gap. The auxiliary substance may consist of a metal or an alloy.
For explaining the invention, two binary systems are hereinafter discussed with reference to the drawing-in which Figs. 1 and 2 are diagrams showing schematically the fusing temperatures (Ts) and the temperatures of beginning crystallization (Ta) independence upon the composition of an alloyof two components A, B, and C, D respectivelm'the percentages of the components being indicated along the base line of the diagram. In Fig. 1, for instance point Ts representsthe melting temperature and Ta the temperature of beginning recrystallization of a metal consisting to 100% of component A, while Ts and Tnf in-- dicate the corresponding temperatures of component B. Line X in Fig. 1 exemplifies an alloy composed of 60% A and 40% B, t: indicating the fusing interval and T1: the temperature of beginning recrystallization of this alloy. In Fig. 1 the two components A and B, whose fusing points Ts and Ts do not appreciably differ from each other, are completely miscible, i. e. capable of being mixed in any proportion with each other. The temperature of the begin- In order to raise this temperature required for ning recrystallization indicated by line b is in this case almost independent of the composition of the alloy. The reversible Fe-Ni alloys, Cu-Ni and other mixed crystal alloys are representatives of such alloy systems.
In contrast thereto, Fig. 2 shows a binary alloy system whose two components C and D are of limited solubility relative to each other so that they form a miscibility gap. This gap is indicated in Fig. 2 by the shaded area enclosed by curve c and the base line. The solubility limit represented by curve 0 depends upon the ratio of the two components C and D as well as on the temperature of the .composition. In such an alloy, the temperature of beginning recrystallization, indicated by curve b, depends considerably on the percentile composition, and it is an essen tial point in connection with the present invention that this dependency is similar to the dependence of the solubility limit (curve c) on the percentile composition. In other words, the curve b representing the relationship between the temperature of the beginning recrystallization limit is exceeded so that the composition lies;
and the composition of the alloy coincides practically with the solubility limit c within a considerable range of composition. Representatives of the beginning recrystallization. If, however,-
so much substance is added that the solubility within the shaded area the temperature of the beginning recrystallization increases considerably. The alloy represented by line 1/, for instance, begins to recrystallize at a temperature Ty considerably above the corresponding temperaturevalues TR and Ta 01 the alloying components.
It is understood that the method according to the invention is not limited to binary systems but may generally be applied to any alloy consisting of a plurality of substances. such an alloy the ternary system Fe-Ni-Cu is hereinafter dealt with more specifically. The ternary 'Fe-Ni-Cu system may be regarded as a composition of a base alloy of the completely miscible components Fe and Ni with an addition of Cu forming a miscibility gap'with the Fe-Ni base. The following table indicates various Cu percentages oi alloys in which the remainder consistssubstantially of Fe and N1 in a proportion of 60 to 40. In other words, the copper has been added to a base alloy containing about 60% Fe and about 40% Ni. The specimens tested were manufactured by rolling thecastalloy with a total reduction in thickness of 99%. The finished specimens were heated to the temperatures and tor the periods indicated in the tables, and the beginning recrystallization and the recrystallization periods were determined by examining the grains of the material. i
Column IV of the table indicates a considerable increase in the time required for a recrystallization of the grains, this increase being particularly eflective between 2.7% Cu and 6% Cu. The temperature of 500C. is exceeded in many electrical and other apparatus during their normal operation. Articles of Fe-Ni alloys forming part of As an example of' such apparatus therefore are magnetically and mechanically resistant to operating temperatures of such or similar magnitude if they contain an addition of for instance 6% copper. Column V indicates 'more exactly the minimum temperature at which the recrystallization begins with different Cu percentages. The increase of this temperature is also especially noticeable between 2.! and 6% copper. The invention thus renders it possible to advantageously employ Fe-Ni alloys, or other metals and alloys of the type above explained, in cases for which they were believed unsuitable because of an insufilcient stability of their properties at elevated temperatures.
What is claimed is:
1. A ferromagnetic article which in normal use is subjected to an elevated temperature of at least about 500 centigrade and adapted to remain magnetic at said elevated temperature, consisting substantially of a base" alloy of iron and nickel containing more iron than nickel and having a temperature of beginning recrystallization below 500 centigrade, and an addition of copper in a percentage within the miscibility gap of copper and said base alloy, said percentage being at least about 6% and 'sufilcient to' raise the temperature oi beginning recrystallization substantially above 500 centigrade.
2. An article of manufacture which in normal use is subjected to an operating temperature of at least about 500 centigrade and adapted to maintain hardness or magnetism at said operating temperature, consisting substantially of a base alloy of completely miscible components of the iron group, said alloy containing iron as the predominant ingredient and nickel and having a temperature of beginning recrystallization below said operating temperature, and an addition consisting of copper incompletely miscible with said base alloy so as to form a miscibility gap therewith, said addition having a percentage lying within said miscibility gap, whereby the temperature of beginning recrystallization is raised substantially above said operating temperature.
3. A heat-resistant article which in normal operation is subjected to operating temperatures above 500 centigrade, consisting substantially of a base substance selected from the group consisting of the individual metals and metal alloys of completely miscible components, said' base substance having a temperature of beginning recrystallization below said operating temperature, and an addition of metal incompletely miscible with said base substance so as to form a miscibility gap, said addition having a percentage lying in said miscibility gap, and characterized by having the temperature of beginning recrystallization increased above said operating temperature due to said addition.
HELLMU'I BUmli. HORST GUIDO MULLER.
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2968548A (en) * | 1958-01-13 | 1961-01-17 | Int Nickel Co | Temperature compensating iron-nickelcopper alloys |
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0
- US US2301366D patent/US2301366A/en not_active Expired - Lifetime
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2968548A (en) * | 1958-01-13 | 1961-01-17 | Int Nickel Co | Temperature compensating iron-nickelcopper alloys |
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