US2297664A - Concentrating langbeinite - Google Patents
Concentrating langbeinite Download PDFInfo
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- US2297664A US2297664A US420818A US42081841A US2297664A US 2297664 A US2297664 A US 2297664A US 420818 A US420818 A US 420818A US 42081841 A US42081841 A US 42081841A US 2297664 A US2297664 A US 2297664A
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- langbeinite
- sylvite
- pulp
- carbon atoms
- ore
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/02—Froth-flotation processes
Definitions
- the invention further relates to the concentration of potash minerals by means of certain sulphonates, particularly alkali sulphonates, of derivatives of fatty acids of high molecular weight such as oleic, for example, or other saturated or unsaturated acids having eleven or more carbon atoms.
- potash minerals may be quickly and easily separated from the other minerals by such well-known processes as froth flotation or agglomeration and tabling. As a general rule we prefer to use the froth-flotation process.
- RCOXR'SOaM in which R is a straight chain hydrocarbon group having at least 11 carbon atoms such as C17H33, for example, X is oxygen or a NH group, R. is a divalent short chain hydrocarbon group of the general formula CnHZn such as C2H4, and M is a metal, usually an alkali metal.
- These compounds may be employed in conjunction with any other flotation reagents known to the art, as for example pine oil or other frothing agent, or fatty acids which have the effect of reducing the amount of sulphonate required although not capable of effecting the separation by themselves, or soluble salts of amines of high molecular weight which are effective in bringing about the separation of sylvite from the other constituents of the ores.
- any other flotation reagents known to the art, as for example pine oil or other frothing agent, or fatty acids which have the effect of reducing the amount of sulphonate required although not capable of effecting the separation by themselves, or soluble salts of amines of high molecular weight which are effective in bringing about the separation of sylvite from the other constituents of the ores.
- flotation reagents such as frothing agents, dispersing agents, agents controlling the pH value of the pulp, etc., may be used in addition to the sulphonates herein described.
- Example I the langbeinite is floated first, using Igepon AP-Extra as the collector. The tailings of this float are returned to the flotation machine and the sylvite is then concentrated. More specifically a synthetic mixture of equal weights of minus lO-mesh sylvinite ore and minus IO-mesh langbeinite ore was prepared, contain ing 6.5% K20 as sylvite and 6.5% K20 as langbeinite. This is equivalent to 10.3% sylvite and 28.7% langbeinite. A charge of this mixture was ground through a -mesh standard Tyler sieve in a laboratory rod mill.
- the ground material was added to a Fagergren laboratory flotation machine and Igepon AP-Extra was added to the pulp which was diluted to about 20% solids.
- the diluent was a saturated aqueous solution of ore constituents.
- the Igepon AP-Extra was added in stages of 2.50, 4.00, and 2.00 pounds per ton respectively, a froth being collected after each addition. There was no conditioning of reagent with the pulp.
- the froth products were joined and refloated twice.
- the tailing of the langbeinite float was returned to the flotation machine, diluted, the aliphatic amine was added, and a sylvite float was made. This froth was also cleaned twice. Results were as follows:
- EXAMPLE III In this example the fatty acid-Igepon combination is used to float langbeinite and amine to float sylvite.
- the synthetic ore mixture was the same as in Example I. It was deslimed at IO-mesh, then ground until all the grain were fine enough to pass through a 35-mesh Tyler standard sieve. Pulp was then added to Fagergren laboratory flotation machine and diluted to solids. The amine was added to this pulp and a sylvite float was made. The froth obtained was retreated twice. Tailing of the sylvite float was returned Reagents g g AP E t Lira/10150 I. n be ite float Igepon x m sglv ite i l oat Octadecylamine acctate. 1.00
- the middlings may be recirculated, thus enabling much of the values contained therein to be recovered.
- EXAMPLE V This example shows the efiectiveness of the fatty acid-Igepon combination on a langbeinite ore containing a slight quantity oi sylvite.
- the pulp was then placed in a. Fagergren laboratory flotation machine, diluted to 20% solids with saturated solution of ore constituents, the reagents were added and a float was made. The froth was retreated twice. The results were:
- EXAMPLE VII The same procedure was followed as in Example VI, except that the reagents for the langbeinite were added first and the langbeinite was floated, and then the reagents for the sylvite were added and the s'ylvite was then floated.
- fatty acids are mentioned it is to be understood that these fatty acids may be used in emulsified form and that part of the sulphonated reagents may be used in preparing the emulsions.
- EXAMPLE VIII A compound prepared from lauric acid chloride, ethylene chlorohydrin and sodium sulphite and having the formula C11H23COOCH2CH2SO3N8. was employed in this example in which the procedure was the same as in Example V. This compound was used in the amount of 3.0 lbs. together with 7.0 lbs. of Chathams fatty acid and 0.3 lb. of pine oil, all per ton of feed.
- the concentrate was retreated twice giving a final product containing 89.5% of langbeinite, 1.9 KCl and 4.3% NaCl. This represented a 74.7% recovery of K20 and a ratio of concentration of 2.91.
- EXAMPLE IX A compound prepared from oleic acid chloride and propylene chlorohydrin having the formula C17H33COOCH2CH2CH2SO3Na was used in this example, the procedure again being the same as in Example V. This compound was used in the amount of 6.0 lbs. together with fatty acid 7.0 lbs. and pine oil 0.3 lb., all per ton of feed.
- the concentrate was retreated twice giving a final product containing 86.3% langbeinite.
- the langbeinite recovery was 64.1% and ratio of concentration 2.75.
- EXAMPLE X In this example a compound prepared from lauric acid chloride and proplylene chlorohydrin having the formula CiiH2aCOOCH2CI-I2CHzSO3Na was used. The recovery was not as high as in previous examples but a fairly good langbeinite concentrate was produced.
- alkali metal is used in the claims, it is intended to include ammonia.
- R is a straight chain aliphatic hydrocarbon group containing at least eleven carbon atoms
- X is oxygen or a NH group
- R is a divalent straight short chain hydrocarbon group containing not more than five carbon atoms
- M is an alkali metal
- R is an unsaturated straight chain hydrocarbon of at least eleven carbon atoms.
- R is a straight chain aliphatic hydrocarbon group containing at least eleven carbon atoms
- X is oxygen or a NH group
- R is a divalent straight short chain hydrocarbon group containing not more than five carbon atoms
- M is an alkali metal
- the step comprising adding toa pulp of the ore prepared by mixing the ore with a saturated aqueous solution of its soluble constituents a sulphonate of the general formula RCOXR'SOsM, where:
- R is a straight chain aliphatic hydrocarbon group containing at least eleven carbon atoms
- X is oxygen or a NH group
- R is a divalent straight short chain hydrocarbon group containing not more than five carbon atoms; and v M is an alkali metal,
- a cationic flotation agent which is an aliphatic amine having a straight chain hydrocarbon group containing at least seven carbon atoms, and separating the langbeinite and sylvite in the form of a concentrate.
- the cationic flotation agent is a member of the group consisting of straight chain aliphatic amines containing at least eleven carbon atoms and water-soluble salts of these amines formed from water-soluble acids.
- R is a straight chain aliphatic hydrocarbon group containing at least eleven carbon atoms
- X is oxygen or a NH group
- R is a divalent straight short chain hydrocarbon group containing not more than five carbon atoms
- M is an alkali metal
- R is a straight chain aliphatic hydrocarbon group containi'ngat least eleven carbon atoms
- X is oxygen or a NH group
- R is a divalent straight short chain hydrocarbon group containing not more than five carbon atoms
- M is an alkali metal
- R is a straight chain aliphatic hydrocarbon group containing at least eleven carbon atoms
- X is oxygen or a NH group
- R is a divalent straight short chain hydrocarbon group containing not more than five carbon atoms
- M is an alkali metal
Description
Patented Sept. 29, 1942 UNITED STATES PATENT OFF 2,297,664 ICE 2,297,664 oonoan'rm'rmc monnmrra Francis X. 'lartaron, Allen '1. Cole, and James B. Duke, Mulberry, Fla., assignors to Phosphate Recovery Corporation, Chicago, 111., a corporation of Delaware No Drawing. Application November 28, 1941, Serial No. 420,818
21 Claims. (Cl. 209167) minerals, langbeinite and sylvite may be recovered separately or in the form of a mixed concentrate from ores which contain both minerals.
The invention further relates to the concentration of potash minerals by means of certain sulphonates, particularly alkali sulphonates, of derivatives of fatty acids of high molecular weight such as oleic, for example, or other saturated or unsaturated acids having eleven or more carbon atoms.
We have found that when ores of the class described are made into a pulp with water saturated with the soluble constituents of these ores, to which has been added a relatively small amount of such sulphonate, the potash minerals may be quickly and easily separated from the other minerals by such well-known processes as froth flotation or agglomeration and tabling. As a general rule we prefer to use the froth-flotation process.
The sulphonates that we have discovered to be effective for this purpose have the general they are not emulsified, to obtain equal recovformula: RCOXR'SOaM, in which R is a straight chain hydrocarbon group having at least 11 carbon atoms such as C17H33, for example, X is oxygen or a NH group, R. is a divalent short chain hydrocarbon group of the general formula CnHZn such as C2H4, and M is a metal, usually an alkali metal.
Compounds of this general formula that we have found to be particularly effective in the process of this invention are: 4
C1'1H3aCOOC2I-I4SO3Na (Igepon AP-Extra) and C1'1H33CONHC2H-1SO3N8. (Igepon T) both of which are available under the trade name of Igepon.
Three other compounds of this general formula RCOXR'SO3M were prepared by the action of acid chlorides on chlorohydrins as follows:
ROCl+HO.R'Cl RC'OOR' Cl and subsequent reaction with sodium sulphite:
R.COOR.C1+Na2SO3 RCOORSO3Na and were found to operate successfully in the process as shown below.
These compounds may be employed in conjunction with any other flotation reagents known to the art, as for example pine oil or other frothing agent, or fatty acids which have the effect of reducing the amount of sulphonate required although not capable of effecting the separation by themselves, or soluble salts of amines of high molecular weight which are effective in bringing about the separation of sylvite from the other constituents of the ores. When fatty acids are used in conjunction with sulphonates as described above we have found that greatly improved recovery of langbeinite is obtained if a part of the sulphonate is used to emulsify the fatty acid before it is added to the pulp, as illustrated in Example VI, or smaller amounts of the sulphonated reagents may be employed when the fatty acids are emulsified than when enes.
It is known that these amines are effective in the separation of sylvite from halite by froth fiotation and we make no claim to this separation, but by this invention we use amines in conjunction with the sulphonates herein described to eifect the separation of langbeinite and sylvite from the other constituents of the ores in the form of a mixed concentrate, or, alternatively, we use the' sulphonates and amines successively and separately to produce separate and. successive concentrates of langbeinite and of sylvite from potash ores containing them.
In carrying out the process of the invention we have found it advisable to crush the potash minerals to such a size that they will pass through a 35-mesh screen. In certain cases better results are obtained when theore is deslimed before flotation, particularly when sylvite is to be floated first, but in other cases the desliming step is unnecessary.
It is to be understood that other known flotation reagents such as frothing agents, dispersing agents, agents controlling the pH value of the pulp, etc., may be used in addition to the sulphonates herein described.
Further advantages of the process of the present invention will be apparent from the following examples, which are merely illustrative and are not to be construed as limiting the scope or spirit of the invention.
Example I In this example, the langbeinite is floated first, using Igepon AP-Extra as the collector. The tailings of this float are returned to the flotation machine and the sylvite is then concentrated. More specifically a synthetic mixture of equal weights of minus lO-mesh sylvinite ore and minus IO-mesh langbeinite ore was prepared, contain ing 6.5% K20 as sylvite and 6.5% K20 as langbeinite. This is equivalent to 10.3% sylvite and 28.7% langbeinite. A charge of this mixture was ground through a -mesh standard Tyler sieve in a laboratory rod mill. The ground material was added to a Fagergren laboratory flotation machine and Igepon AP-Extra was added to the pulp which was diluted to about 20% solids. The diluent was a saturated aqueous solution of ore constituents. The Igepon AP-Extra was added in stages of 2.50, 4.00, and 2.00 pounds per ton respectively, a froth being collected after each addition. There was no conditioning of reagent with the pulp. The froth products were joined and refloated twice. The tailing of the langbeinite float was returned to the flotation machine, diluted, the aliphatic amine was added, and a sylvite float was made. This froth was also cleaned twice. Results were as follows:
EXAMPLE III In this example the fatty acid-Igepon combination is used to float langbeinite and amine to float sylvite.
The synthetic ore mixture was the same as in Example I. It was deslimed at IO-mesh, then ground until all the grain were fine enough to pass through a 35-mesh Tyler standard sieve. Pulp was then added to Fagergren laboratory flotation machine and diluted to solids. The amine was added to this pulp and a sylvite float was made. The froth obtained was retreated twice. Tailing of the sylvite float was returned Reagents g g AP E t Lira/10150 I. n be ite float Igepon x m sglv ite i l oat Octadecylamine acctate. 1.00
K10 Product Weight K 0 80 C1 KC! Lang. NaCl Rec Per cent 'Iotnl 100. 0 13.17 20. 99 39. 17 100.0 24. 9 25. 58 58. 07 5. 34 48. 3 6. 6 17. 66 36. 78 25.40 8.9 21.1 12. 89 16. 81 42. 40 20.7 3. 7 57. 09 0.69 46. 00 16. 0 0. 8 21.95 1.96 49.00 1. 4 4. 2 2.95 1.94 55. 0.9 38. 7 1. 1. 08 57. 20 3. 8
The middlings may be recirculated, thus enabling much of the values contained therein to be recovered.
EXAMPLE 11 Same as Example I, except Igepon T was used was used for both the sylvite float and the V langbeinite float. The results were:
Lbs. per ton of original feed Reagent Sylvite float gggz Octadecylamine acetate 1.00 Pine il 0. 12 Chatham fatty acid 4 29 Pine 0. 24 Igepon AP--Extm 3- 00 Product Weight K10 so. 01 KCl Lang NaCl Per cent EXAMPLE IV as the collector. The feed was deslimed prior to grinding. No sylvite float was made. "Igepon T" was added in stages of 3.00, 2.00, and 2.00 pounds per ton respectively, the Iroths being joined and This example deals with a bulk float in which both langbeinite and sylvite are floated together.
retreated together. The results were: 65 The feed was prepared as in Example III. To
Product Weight K10 so. 01 x01 Lang. Nabi $3 11. 31 20. 01 30. as 7.58 28.81 58. 04 100. 0 22 25 33.50 7.20 10.70 77.01 3. 41 33.0 14.07 30.00 2100 3.0 12. 01 a2. 02 a0. 00 24. a 6. 19 l. 51 56. 00 28. 4 14. 30.31 22.00 0.3
the pulp at 20% solids in Fagergren flotation machine, all the reagents were added and a float was then made. The froth obtained was retreated twice. The results were:
Reagents, lbs./tn of original feed Octadecylamine acetate 1.00 Chatham fatty acid 4.29 Pine n11 0.24. Igepon AP-Extra 3.00
Product Weight mo so. 01 KCl Lang. NaCl 5;?
' Percent Total 100.0 12.30 11.58 47.37 Cone 23.3 30.00 44.04 15.37 Mimi-2--- 3.5 44.91 1.50 49.60 Midd-1 7.3 18.58 1.70 55.50 Tail 60.8 2.79 0.88 59.10 Slime"--. -5.1 11.71 7.89 40.70
EXAMPLE V This example shows the efiectiveness of the fatty acid-Igepon combination on a langbeinite ore containing a slight quantity oi sylvite.
The charge of ore was ground so that all grains passed through 35-mesh Tyler standard screen.
Product Weight Kg0 50; Cl NaCl Percent EXAMPLE VI A charge of minus 10-mesh natural mixed are 7 of langbeinite, sylvite and halite from 850-Ioot level of the mine 01 the Union Potash & Chemical Co. of Carlsbad, N. M, was deslimed, then the oversize on a -mesh screen was ground through. The screened ore was added to a Fagergren fiotation machine and diluted to 20% solids.
Reagents, lbs./ton of original feed Emulsion: 4.64
The pulp was then placed in a. Fagergren laboratory flotation machine, diluted to 20% solids with saturated solution of ore constituents, the reagents were added and a float was made. The froth was retreated twice. The results were:
Reagents, ZbsJton of original feed The flotation K20 recovery, excluding slime loss, was 90.1%.
EXAMPLE VII The same procedure was followed as in Example VI, except that the reagents for the langbeinite were added first and the langbeinite was floated, and then the reagents for the sylvite were added and the s'ylvite was then floated.
Lba/ton of original feed Reagents Chatham fiatty acid 4.29
Igepon riF Ezti-e 3.00
Pine nil 0.24
Emulsion:
Chatham fatty acid Igepon AI -Extra...
Igepon AP-Extra Octadecylamine acetate Product Weight K 0. so. 01 K01 Lang NBC] 5;?
Per cent 'I'he total overall K20 recovery was 80.45%. The total flotation recovery, excluding slimes, was 88.90%.
Where fatty acids are mentioned it is to be understood that these fatty acids may be used in emulsified form and that part of the sulphonated reagents may be used in preparing the emulsions.
EXAMPLE VIII A compound prepared from lauric acid chloride, ethylene chlorohydrin and sodium sulphite and having the formula C11H23COOCH2CH2SO3N8. was employed in this example in which the procedure was the same as in Example V. This compound was used in the amount of 3.0 lbs. together with 7.0 lbs. of Chathams fatty acid and 0.3 lb. of pine oil, all per ton of feed.
The concentrate was retreated twice giving a final product containing 89.5% of langbeinite, 1.9 KCl and 4.3% NaCl. This represented a 74.7% recovery of K20 and a ratio of concentration of 2.91.
EXAMPLE IX A compound prepared from oleic acid chloride and propylene chlorohydrin having the formula C17H33COOCH2CH2CH2SO3Na was used in this example, the procedure again being the same as in Example V. This compound was used in the amount of 6.0 lbs. together with fatty acid 7.0 lbs. and pine oil 0.3 lb., all per ton of feed.
The concentrate was retreated twice giving a final product containing 86.3% langbeinite.
The langbeinite recovery was 64.1% and ratio of concentration 2.75.
EXAMPLE X In this example a compound prepared from lauric acid chloride and proplylene chlorohydrin having the formula CiiH2aCOOCH2CI-I2CHzSO3Na was used. The recovery was not as high as in previous examples but a fairly good langbeinite concentrate was produced.
Where the term alkali metal is used in the claims, it is intended to include ammonia.
What is claimed is 1. In the wet concentration of potash ores containing langbeinite, the step of mixing with a pulp of the ore, prepared by adding the ore to a saturated aqueous solution of its soluble constituents, a metallic sulphonate of the general formula RCOXR'SOsM, where:
R is a straight chain aliphatic hydrocarbon group containing at least eleven carbon atoms;
X is oxygen or a NH group;
R is a divalent straight short chain hydrocarbon group containing not more than five carbon atoms; and
M is an alkali metal,
and separating the langbeinite from the pulp in the form of a concentrate.
2. The process according to claim 1, in which R is an unsaturated straight chain hydrocarbon of at least eleven carbon atoms.
3. The process according to claim 1, in which R is the ethylene group Cal-I4,
4. In the flotation concentration of potash ores containing langbeinite, the step of mixing with a pulp of the ore prepared by adding the ore to a saturated solution of its soluble constituents an alkali sulphonate of the general formula RCOIGt'SOsM, where:
R is a straight chain aliphatic hydrocarbon group containing at least eleven carbon atoms;
X is oxygen or a NH group;
R is a divalent straight short chain hydrocarbon group containing not more than five carbon atoms; and
M is an alkali metal,
- and separating the langbeinite in the form of a floating froth.
5. In the concentration by flotation of potash ores containing langbeinite, the step of agitat- I ing the ores in a saturated solution of their soluble constituents with an alkali sulphonate of the formula C17H33COOC2H4SO3M where C1'1H33 is the hydrocarbon radical of oleic acid and M is an alkali metal, and separating the langbeinite in the form of a floating froth.
6. In the concentration by flotation of potash ores containing langbeinite, the step of agitating the ores in a saturated solution of their soluble constituents with an alkali sulphonate of the formula Ci'zH33CONHC2I-I4SO3M where C17H33 is the hydrocarbon radical of oleic acid and M is an alkali metal, and separating the langbeinite in the form of a floating froth.
'7. The process according to claim 4, in which a fatty acid of high molecular weight is added to the pulp together with the alkali sulphonate.
8. The process according to claim 5 in which a fatty acid of high molecular weight is added to the pulp together with the alkali sulphonate.
9. The process according to claim 6, in which a fatty acid of high molecular weight is added to the pulp together with the alkali sulphonate.
10. In the concentration of potash ores containing langbeinite and sylvite, the step comprising adding toa pulp of the ore prepared by mixing the ore with a saturated aqueous solution of its soluble constituents a sulphonate of the general formula RCOXR'SOsM, where:
R is a straight chain aliphatic hydrocarbon group containing at least eleven carbon atoms;
X is oxygen or a NH group;
R is a divalent straight short chain hydrocarbon group containing not more than five carbon atoms; and v M is an alkali metal,
and a cationic flotation agent which is an aliphatic amine having a straight chain hydrocarbon group containing at least seven carbon atoms, and separating the langbeinite and sylvite in the form of a concentrate.
11. The process according to claim 10, in which the cationic flotation agent is a member of the group consisting of straight chain aliphatic amines containing at least eleven carbon atoms and water-soluble salts of these amines formed from water-soluble acids.
12. The process according to claim 10, in which a high molecular weight fatty acid is added to th; pulp in addition to the sulphonate and amine sa 13. In the flotation concentration of potash ores containing langbeinite and sylvite, the step of adding to a pulp of the ore prepared by mixing the ore with a saturated aqueous solution of its soluble constituents a compound of the general formula RCOXR'SOaM, where:
R is a straight chain aliphatic hydrocarbon group containing at least eleven carbon atoms;
X is oxygen or a NH group;
R is a divalent straight short chain hydrocarbon group containing not more than five carbon atoms; and
M is an alkali metal,
and a salt of a straight chain aliphatic amine containing at least seven carbon atoms. agitating the pulp, and separating the langbeinite and sylvite in the form of a floating froth.
14. The process according to claim 9, in which a high molecular weight fatty acid is added to the pulp in addition to the other reagents.
15. The process according to claim 5, in which a fatty acid of high molecular weight and a cationic flotation agent which is an aliphatic amine having a straight chain containing at least seven carbon atoms is employed in addition to the alkali sulphonate.
16. The process according to claim 6, in which a fatty acid of high molecular weight and a cationic flotation agent which is an aliphatic amine having a straight chain containing at least seven carbon atoms is employed in addition to the alkal1 sulphonate.
17. In the concentration of potash minerals from ores containing langbeinite and sylvite, the steps of mixing with a pulp of the ore a compound of the general formula RCOXR'SO3M as (mined in claim 1 and removing a concentrate consisting principally of langbeinite and then adding a cationic flotation agent which is an aliphatic amine having a straight chain containing at least seven carbon atoms and removing a second concentrate consisting chiefly of sylvite.
18. In the concentration of potash minerals from ores containing langbeinite and sylvite, the steps of mixing with a pulp of the ore a cationic flotation reagent which is an aliphatic amine having a straight chain containing at least seven carbon atoms and separating a concentrate consisting chiefly of sylvite and then adding a compound of the general formula RCOXR'SOaM, where:
R is a straight chain aliphatic hydrocarbon group containi'ngat least eleven carbon atoms;
X is oxygen or a NH group;
R is a divalent straight short chain hydrocarbon group containing not more than five carbon atoms; and
M is an alkali metal,
of adding to a pulp of the ore prepared by mixing the ore with a saturated aqueous solution of its soluble constituents a compound of the general formula RCOXRSOJM, where:
R is a straight chain aliphatic hydrocarbon group containing at least eleven carbon atoms;
X is oxygen or a NH group;
R is a divalent straight short chain hydrocarbon group containing not more than five carbon atoms; and
M is an alkali metal,
and octadecylamine acetate, agitating the pulp, and separating the langbeinite and sylvite in the form of a floating froth.
21. The process according to claim 13, where the potash ores contain langbeinite, sylvite and halite.
' FRANCIS K. TARTARON.
ALLEN T. COLE. JAMES B. DUKE.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US420818A US2297664A (en) | 1941-11-28 | 1941-11-28 | Concentrating langbeinite |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US420818A US2297664A (en) | 1941-11-28 | 1941-11-28 | Concentrating langbeinite |
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| Publication Number | Publication Date |
|---|---|
| US2297664A true US2297664A (en) | 1942-09-29 |
Family
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US420818A Expired - Lifetime US2297664A (en) | 1941-11-28 | 1941-11-28 | Concentrating langbeinite |
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| US (1) | US2297664A (en) |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2604988A (en) * | 1946-07-16 | 1952-07-29 | Mines Domaniales De Potasse | Froth flotation of potassium chloride from sodium chloride |
| US2644580A (en) * | 1949-07-06 | 1953-07-07 | Koppers Co Inc | Mineral flotation |
| US2652150A (en) * | 1948-04-03 | 1953-09-15 | Saskatchewan Potash | Froth flotation of sylvinite ore |
| US2721657A (en) * | 1952-04-24 | 1955-10-25 | American Metal Co Ltd | Froth flotation concentration of potash ores containing sylvite |
| US2727626A (en) * | 1952-11-15 | 1955-12-20 | Compania Salitrera Anglo Lauta | Froth flotation |
| US2783885A (en) * | 1952-11-15 | 1957-03-05 | Compania Salitrera Anglo Lauta | Froth flotation |
| US2861687A (en) * | 1955-09-09 | 1958-11-25 | Southwestern Eng Co | Flotation of heavy metal oxides |
| US3049233A (en) * | 1956-05-17 | 1962-08-14 | Montedison Spa | Process for separation of schoenite from sodium chloride by means of flotation |
| US3275141A (en) * | 1964-01-31 | 1966-09-27 | Internat Minerals & Chemicals | Beneficiation of langbeinite-containing materials |
| US3447681A (en) * | 1967-04-17 | 1969-06-03 | Jose L Ramirez | Separation of kainite from potassium chloride by flotation |
| US4514290A (en) * | 1982-03-05 | 1985-04-30 | Kenogard Ab | Flotation collector composition and its use |
-
1941
- 1941-11-28 US US420818A patent/US2297664A/en not_active Expired - Lifetime
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2604988A (en) * | 1946-07-16 | 1952-07-29 | Mines Domaniales De Potasse | Froth flotation of potassium chloride from sodium chloride |
| US2652150A (en) * | 1948-04-03 | 1953-09-15 | Saskatchewan Potash | Froth flotation of sylvinite ore |
| US2644580A (en) * | 1949-07-06 | 1953-07-07 | Koppers Co Inc | Mineral flotation |
| US2721657A (en) * | 1952-04-24 | 1955-10-25 | American Metal Co Ltd | Froth flotation concentration of potash ores containing sylvite |
| US2727626A (en) * | 1952-11-15 | 1955-12-20 | Compania Salitrera Anglo Lauta | Froth flotation |
| US2783885A (en) * | 1952-11-15 | 1957-03-05 | Compania Salitrera Anglo Lauta | Froth flotation |
| US2861687A (en) * | 1955-09-09 | 1958-11-25 | Southwestern Eng Co | Flotation of heavy metal oxides |
| US3049233A (en) * | 1956-05-17 | 1962-08-14 | Montedison Spa | Process for separation of schoenite from sodium chloride by means of flotation |
| US3275141A (en) * | 1964-01-31 | 1966-09-27 | Internat Minerals & Chemicals | Beneficiation of langbeinite-containing materials |
| US3447681A (en) * | 1967-04-17 | 1969-06-03 | Jose L Ramirez | Separation of kainite from potassium chloride by flotation |
| US4514290A (en) * | 1982-03-05 | 1985-04-30 | Kenogard Ab | Flotation collector composition and its use |
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