US2296723A - Method of deep-drawing ethyl cellulose films - Google Patents
Method of deep-drawing ethyl cellulose films Download PDFInfo
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- US2296723A US2296723A US339492A US33949240A US2296723A US 2296723 A US2296723 A US 2296723A US 339492 A US339492 A US 339492A US 33949240 A US33949240 A US 33949240A US 2296723 A US2296723 A US 2296723A
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- film
- ethyl cellulose
- deep
- films
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C51/00—Shaping by thermoforming, i.e. shaping sheets or sheet like preforms after heating, e.g. shaping sheets in matched moulds or by deep-drawing; Apparatus therefor
- B29C51/002—Shaping by thermoforming, i.e. shaping sheets or sheet like preforms after heating, e.g. shaping sheets in matched moulds or by deep-drawing; Apparatus therefor characterised by the choice of material
Definitions
- This invention relates to the making of hollow shapes from thermoplastic films by a process of drawing,
- a hollow article may be made from a thermoplastic film'by clamping the film over the opening of a heated die and pressingthe film into the die by means of a suitably shaped ram. By this means the film isdrawn so that it conforms to the shape of the die.
- a further object is to prevent whitening of ethyl cellulose film on drawing.
- Another object is to prevent the sticking of ethyl cellulose film tothe die during drawing operations;
- the invention may be illustrated by reference to the accompanying drawing in whichds shown in diagrammatic form a conventional deep-drawing apparatus, and in greatly exaggerated form a the instant invention include the household detergent known as Dreft, the commercial wetting agent sold under the name Duponal W. A, and the emulsifying agent known as Duponal M. E. All-of these products are composed largely of sodium lauryl sulfate.
- the ethyl cel ulose film prior to drawing, is treated with a solution comprising an alkali metal salt of a sulfuric acid ester of a higher saturated fatty alcohol containing 10 or more carbon atoms.
- the film is then dried or allowed to dry, and is drawn to a hollow shape.
- these salts are termed high molal salts. Suitable high molal salts are: sodium lauryl sulfate, sodium stearyl sulfate, potassium cetyl sulfate, and sodium palmityl sulfate.
- the solution comprising the high molal salts may also contain minor proportions (up to 50 per cent of the weight of the high molal salt) of colorless inorganic salts such as sodium sulfate.
- the treatment of the ethyl cellulose films with the solution of "high molal. salts should be carried out so that on drying a thin, substantially continuous, yet invisible coating of the salt results.
- the coating should be as thin as possible on grounds of economy and in order to produce perfectly clear films.
- the treatment of the film may be carried out in any customary manner using a dilute solution of high molal salt.
- the film may be clipped in and out of the solution and excess liquid removed by means of a rubber squeegee blade or roller, or the solution may be spread on the filmv by means of brushes, a roller, a doctor blade, or by spraying.
- plasticizers are not necessary to incorporate plasticizers with ethyl cellulose when'making films suitable for drawing, though up to 20 per cent of the film composition may consist of plasticizer.
- plasticizers For most applied to the-clamp ring around the periphery of the die opening.
- unplasticized ethyl ethyl cellulose film is particularly useful for making hollow shapes which are to be used for packaging foodstufis.
- Example Cylindrical cup shapes were prepared by deepdrawing operations performed on ethyl cellulose films which had been treated with the high molal salts previously mentioned.
- the drawing machine consisted essentially of a heated female die member having a cross section of 3.25 inches internal diameter. There was a cylindrical ram of about 3.23 inches diameter so adjusted and Y positioned that it could be driven to any predetermined depth into the heated die cavity. When I the die and the ram were disengaged, there was an annular ledge about 7 inches in diameter surrounding the opening of the female die member and a clamp ring of like over-all diameter, ad-
- the method which comprises coating a film, containing organo-soluble ethyl cellulose as the principal film-forming ingredient, with a thin surface layer composed substantially of an alkali metal salt of the acid sulfate of a saturated higher fatty alcohol containing at least 10 car- .bon atoms, drying the said coating, and drawing the film to make a hollow article.
- the method which comprises coating a film consisting essentially of organo-soluble ethyl cellulose with a thin surface layer composed substantially of an alkali metal salt of the acid sulfate of a saturated higher fatty alcohol containing at least 10 carbon atoms, drying the said coating, and drawing the film to make a hollow article.
- the method which comprises coating a film consisting essentially of organo-soluble ethyl cellulose and a plasticizer therefor in amount less than about 20 per cent of the weight of said film with a thin surface layer composed substantially of an alkali metal salt of the acid sulfate of a saturated higher fatty alcohol containing at least 10 carbon atoms, drying the said coating, and drawing the film to make a hollow article.
- the method which comprises coating 9. film, containing as the principal film-forming ingredient, organo-soluble ethyl cellulose of from about 44 to about 46.5 per cent ethoxy content,. with a thin surface layer composed substantially of an alkali metal salt of the acid sulfate 01' a saturated higher fatty alcohol containing at least 10 carbon atoms, drying the said coating, 5
- the method which comprises coating a film, containing organo-soluble ethyl cellulose as the principal film-forming ingredient, with a thin surface layer composed substantially of sodium 10' lauryl sulfate, drying the said coating, and subjecting the film to a drawing operation to make a hollow article.
- organo-soluble ethyl cellulose as the 15 principal film-forming ingredient, with a thin surface layer consisting essentially of sodium lauryl sulfate and a minor proportion relative thereto of a colorless, water-soluble inorganic salt, drying the said coating, .and subjecting the 20 -soluble ethyl cellulose as the principal filmforming ingredient, said film bearing a thin surface coating composed substantially of an alkali metal salt of a saturated higher fatty alcohol containing at least 10 carbon atoms.
Description
- depth.
Patented Sept. 22, 1942 ma'rnon or DEEP-DRAWING ETHYL CELLULOSE FILMS Richard s. McClurg and Frederick c. Dulmage,
Jr., Midland, Mich., asslgnors to The Dow Chemical Company, Midland, Mlch., a corporation of Michigan Application June 8, 1940, Serial No. 339,492
8 Claims. (01.18-56) This invention relates to the making of hollow shapes from thermoplastic films by a process of drawing,
It is known that a hollow article may be made from a thermoplastic film'by clamping the film over the opening of a heated die and pressingthe film into the die by means of a suitably shaped ram. By this means the film isdrawn so that it conforms to the shape of the die.
When using ethyl cellulose films it has heretofore been possible to make only comparatively shallow drawn articles such as, for example, caps for milk bottles. Attempts to make deep-drawn articles have resulted in the appearance of whitened areas extending from the edge of the clampdown the walls of the drawn article. This whitening appears to result from local overstrain of the film; it is unsightly and renders the drawn article useless. Whitening almost invariably occurs when articles having walls one inch ormore high, for example, cylindrical cup-shaped articles, are drawn from untreated film blanks, and frequently occurs when drawing articles of lesser It isaccordingly a m object of this invention make useful deep-drawn articlesfrom ethyl cellulose.
A further object is to prevent whitening of ethyl cellulose film on drawing. t Another object is to prevent the sticking of ethyl cellulose film tothe die during drawing operations;
The invention may be illustrated by reference to the accompanying drawing in whichds shown in diagrammatic form a conventional deep-drawing apparatus, and in greatly exaggerated form a the instant invention include the household detergent known as Dreft, the commercial wetting agent sold under the name Duponal W. A, and the emulsifying agent known as Duponal M. E. All-of these products are composed largely of sodium lauryl sulfate.
Among the efforts to find an alternative and equally effective method of drawing ethyl cellulose film to that described. in the present application there has been tried:
' (1) The use of common lubricants such as 'mineral oil and soap on the ram, die and clamp ring of the drawing machine, or on the film surface.
sheet of ethyl cellulose having on its surface a thin coating of a high-molal salt."
According to our invention, the ethyl cel ulose film, prior to drawing, is treated with a solution comprising an alkali metal salt of a sulfuric acid ester of a higher saturated fatty alcohol containing 10 or more carbon atoms. The film is then dried or allowed to dry, and is drawn to a hollow shape. For the purpose of the present invention, these salts are termed high molal salts. Suitable high molal salts are: sodium lauryl sulfate, sodium stearyl sulfate, potassium cetyl sulfate, and sodium palmityl sulfate.
The solution comprising the high molal salts may also contain minor proportions (up to 50 per cent of the weight of the high molal salt) of colorless inorganic salts such as sodium sulfate.
Commercial products which may be dissolved in water to form solutions useful in carrying out (2) The treatment of the ethyl cellulose film prior to drawing'with thin continuous coatings of each of the substances tabulated below:
Commercial name elieved to be- A high molecular weight quaternary ammo- Sapamine nium salt used as a wetting and emulsifying agent. Aresklene 375... Dibutyl phenylphenol sodium disulionate.
nx Sodium stearate.
Octyl ester oi sodium succinate.
Sodium alkyl naphthalene sulionate. Triton 8 18... A high molecular weight {quaternary ammoniuin sal weight acids.
' Neither class of treatment led to successful deepdrawing of ethylcellulose films, as the film would seize and crack under the distorting influence of the drawing device.
It is necessary that the treatment of the ethyl cellulose films with the solution of "high molal. salts should be carried out so that on drying a thin, substantially continuous, yet invisible coating of the salt results. The coating should be as thin as possible on grounds of economy and in order to produce perfectly clear films. The treatment of the film may be carried out in any customary manner using a dilute solution of high molal salt. Thus the film may be clipped in and out of the solution and excess liquid removed by means of a rubber squeegee blade or roller, or the solution may be spread on the filmv by means of brushes, a roller, a doctor blade, or by spraying. In our preferred method, we use an approximately 0.75 per cent by weight aqueous solution of high molal salt and apply a thin continuous coating of it to-the film by means. of a roll coating machine. ,We find that in all cases it is unneccssary'to use a solution of concentration greater than about 3 per cent. After treatt. g Complex methyl esters o i high molecular lulose of ethoxy content as low as 44 per cent.
which is sufiiciently uniformly substituted to yield smooth, fiowable solutions suitable for film casting purposes. This material and ethyl celluloses of higher ethoxy contents are suitable for making filmsfor drawing. However, it is preferred for most purposes to use ethyl cellulose of ethoxy content in the range from 44 to 46.5 per cent approximately as this material yields harder films of higher softening temperatures than do materials of the higher ethoiiy range.
It is not necessary to incorporate plasticizers with ethyl cellulose when'making films suitable for drawing, though up to 20 per cent of the film composition may consist of plasticizer. For most applied to the-clamp ring around the periphery of the die opening. By way of contrast, at-
tempts to make similar articles from the untreated film discs when using a corresponding die temperature and a corresponding pressure on the clamp ring resulted in breaking the untreated films. When, however, the pressure on the clamp ring about the die opening was reduced to about 5 pounds per square inch, deep-drawn cylindrical cups could be produced from the untreated film, but their appearance was marred by the occurrence of whitened areas, which extended downwards from the top edges of the cups purposes it is preferred to use unplasticized ethyl ethyl cellulose film is particularly useful for making hollow shapes which are to be used for packaging foodstufis.
Films comprising plasticizerpear to be under considerable strain and the articles containing them are deemed unmarketable. When still lower pressures were employed to retain the untreated discs in a position over the die opening, the film slipped as the ram was driven home and the shaped article was badly wrinkled and worthless.
As an indication that the high molal salts exert solely a surface effect on the films, it might be pointed out that when film blanks which had once been treated with sodium higher alkyl sulfates were subsequently immersed in water prior to drawing and then dried, they exhibited the same mechanical difiiculties and presented the generally do not have this advantage; most I plasticizers impart at least a slight taste and/or odor to foodstuffs when stored in contact with them.
The following example illustrates the practice of theinvention, but it should not be construed as limiting its scope.
Example Cylindrical cup shapes were prepared by deepdrawing operations performed on ethyl cellulose films which had been treated with the high molal salts previously mentioned. The drawing machine consisted essentially of a heated female die member having a cross section of 3.25 inches internal diameter. There was a cylindrical ram of about 3.23 inches diameter so adjusted and Y positioned that it could be driven to any predetermined depth into the heated die cavity. When I the die and the ram were disengaged, there was an annular ledge about 7 inches in diameter surrounding the opening of the female die member and a clamp ring of like over-all diameter, ad-
justably tensioned, so as to seize and hold firmly the edges of the film blanks to be subjected to tests reported, the die was heated to a temperature of about 250 F. Cylindrical cups having smooth unblemished walls about 2.5 inches high could be made from the discs of treated ethyl cellulose when the film blank was retained under a pressure of about 10 pounds per square inch,
, same problem in the production of useful drawn shapes as did the films which had; been given no prior surface treatment.
Although it may be believed, and it appears correctly so, that the eflicacy of the high molal salts in producing smooth-walled, unblemished deep-drawn articles when operating as described herein depends upon some lubricating quality of the salts, it is quite obvious that the mere provision of a lubricant is not enough to achieve the desired result. This becomes apparent from the surprisingly large number of substances normally employed as surface,lubricants other than the high molal salts, none of which were effective in producing satisfactory deep-drawn shapes from ethyl cellulose film. A partial list of such g, unsuccessful lubricants has been given hereinabove We claim:
1. The method which comprises coating a film, containing organo-soluble ethyl cellulose as the principal film-forming ingredient, with a thin surface layer composed substantially of an alkali metal salt of the acid sulfate of a saturated higher fatty alcohol containing at least 10 car- .bon atoms, drying the said coating, and drawing the film to make a hollow article.
2. The method which comprises coating a film consisting essentially of organo-soluble ethyl cellulose with a thin surface layer composed substantially of an alkali metal salt of the acid sulfate of a saturated higher fatty alcohol containing at least 10 carbon atoms, drying the said coating, and drawing the film to make a hollow article.
'3. The method which comprises coating a film consisting essentially of organo-soluble ethyl cellulose and a plasticizer therefor in amount less than about 20 per cent of the weight of said film with a thin surface layer composed substantially of an alkali metal salt of the acid sulfate of a saturated higher fatty alcohol containing at least 10 carbon atoms, drying the said coating, and drawing the film to make a hollow article.
4. The method which comprises coating 9. film, containing as the principal film-forming ingredient, organo-soluble ethyl cellulose of from about 44 to about 46.5 per cent ethoxy content,. with a thin surface layer composed substantially of an alkali metal salt of the acid sulfate 01' a saturated higher fatty alcohol containing at least 10 carbon atoms, drying the said coating, 5
and drawing the film to make a hollow article.
5. The method which comprises coating a film, containing organo-soluble ethyl cellulose as the principal film-forming ingredient, with a thin surface layer composed substantially of sodium 10' lauryl sulfate, drying the said coating, and subjecting the film to a drawing operation to make a hollow article.
6. The method which comprises coating a film,
containing organo-soluble ethyl cellulose as the 15 principal film-forming ingredient, with a thin surface layer consisting essentially of sodium lauryl sulfate and a minor proportion relative thereto of a colorless, water-soluble inorganic salt, drying the said coating, .and subjecting the 20 -soluble ethyl cellulose as the principal filmforming ingredient, said film bearing a thin surface coating composed substantially of an alkali metal salt of a saturated higher fatty alcohol containing at least 10 carbon atoms.
RICHARD S..MCCLURG. FREDERICK C. DULMAGE, JR.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US339492A US2296723A (en) | 1940-06-08 | 1940-06-08 | Method of deep-drawing ethyl cellulose films |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US339492A US2296723A (en) | 1940-06-08 | 1940-06-08 | Method of deep-drawing ethyl cellulose films |
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US2296723A true US2296723A (en) | 1942-09-22 |
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US339492A Expired - Lifetime US2296723A (en) | 1940-06-08 | 1940-06-08 | Method of deep-drawing ethyl cellulose films |
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2464060A (en) * | 1943-11-24 | 1949-03-08 | Dictaphone Corp | Method of forming endless belts useful as sound recording media |
US2693618A (en) * | 1949-09-01 | 1954-11-09 | Jesse R Crossan | Packaging apparatus |
US2701893A (en) * | 1951-08-06 | 1955-02-15 | Joseph Lincoln Mfg Company Inc | Apparatus for making hat covers |
US3374301A (en) * | 1965-06-01 | 1968-03-19 | Dow Chemical Co | Method of thermoforming alkenyl aromatic resinous sheet |
US3506751A (en) * | 1968-05-03 | 1970-04-14 | Continental Can Co | Method of drawing plastic containers |
-
1940
- 1940-06-08 US US339492A patent/US2296723A/en not_active Expired - Lifetime
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2464060A (en) * | 1943-11-24 | 1949-03-08 | Dictaphone Corp | Method of forming endless belts useful as sound recording media |
US2693618A (en) * | 1949-09-01 | 1954-11-09 | Jesse R Crossan | Packaging apparatus |
US2701893A (en) * | 1951-08-06 | 1955-02-15 | Joseph Lincoln Mfg Company Inc | Apparatus for making hat covers |
US3374301A (en) * | 1965-06-01 | 1968-03-19 | Dow Chemical Co | Method of thermoforming alkenyl aromatic resinous sheet |
US3506751A (en) * | 1968-05-03 | 1970-04-14 | Continental Can Co | Method of drawing plastic containers |
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