US2289917A - Process of continuous carbonization - Google Patents
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- US2289917A US2289917A US2289917DA US2289917A US 2289917 A US2289917 A US 2289917A US 2289917D A US2289917D A US 2289917DA US 2289917 A US2289917 A US 2289917A
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B53/00—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
- C10B53/02—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of cellulose-containing material
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B49/00—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated
- C10B49/02—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with hot gases or vapours, e.g. hot gases obtained by partial combustion of the charge
- C10B49/04—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with hot gases or vapours, e.g. hot gases obtained by partial combustion of the charge while moving the solid material to be treated
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/10—Biofuels, e.g. bio-diesel
Definitions
- the present invention relates to the destructive distillation of materials such as wood, peat, lignin and other cellulosic materials which, on being carbonized, give rise to an exothermic reaction.
- the invention more particularly relates to a method of continuously carrying out distillation by treating wood or other material, preferably dried, in a chamberv or retort with inert gases introduced into the retort through the cooling zone, i. e. the zone in which the carbonized material is cooled before it is discharged from the retort.
- a disadvantage of this method was the slow progress of carbonization, which could not be remedied by increasing the rate of flow of the inert gases, as said gases require to be heated in the cooling zone, and any increase in their rate of flow would result in lowering their temperature and gradually stopping the reaction
- Slow carbonization on the other hand lowers the efficiency of the process and causes the distillation products, e. g.
- the wood or other material to be carbonized is fed through a furnace or retort heated by a current of inert gases circulating through the retort in contracurrent to the wood, said gases being heated outside the retort and introduced into the retort at an ⁇ intermediate point thereof, in immediate vicinity of the carbonizing zone.
- cold i. e. ⁇ unheated gases are introduced ⁇ at or near the outlet for the carbonized materialf
- the rates of supply of the hot gases and of the cold gases are independently controllable so that it is possible both to obtain an efficient cooling of the charcoal and suitably to control the carbonizing Zone.
- the wood continuously charged into the retort thus can be brought by the hot gases exactly to the temperature which is necessary in order to induce the exothermic carbonization reaction, while the cold gases introduced separately absorb the heat developed by the exothermic reaction,
- carbonization can be carried out rapidly, as is necessary for successful continuous operation, Owing to the possibility of controlling the gas currents independently of each other, carbonization can be regulated in proportion to the input and vice versa, the extent of the carbonizing zone can be regulated as desired.
- a isthe carbonizing furnace or retort having at the top an inlet chamber b for the pieces of wood to be carbonized and at the bottom a discharge outlet c for the charcoal.
- hot inert gases are introduced into the retort at an intermediate point d thereof, whereas cold inert gases are introduced at e near the bottom, and the gaseous products of distillation are withdrawn from the top at f.
- the inert gases are circulated in a closed circuit. Issuing from the outlet f in admixture with the products of distillation they are led through a cooler g, a separator h and a scrubber i, whence the condensed products are co1- lected at 7'.
- a fan k sends the residual inert gases past a tapping pipe l for discharging excess gas, through a pipe m whence a portion of the gases passes through a heater n to the hot gas inlet d, while another portion flows through a pipe o to the cold gas inlet e.
- valve v1 then is fully open, valve v2 is partly open to regulate the outward ow of excess gas; valve v3 is closed while valves v4 and v5 are partly open to regulate the supply of gases at'd and at e respectively.
- the rate of progress of the wood through the retort and the rates of flow of the hot gases fed at d and of the cold gases fed at e are so regulateduthat, when reaching point d, the downwardly travelling wood has reached the temperature at which exothermic carbonization is initiated.
- the wood passes gradually and successively through a drying zone I and a torrefaction zone II while travelling in contracurrent to the upward flow of hot gases introduced at d and of the cooler gases introduced at e and heated in the lower portion of the retort.
- Carbonization being initiated at or near the level d continues throughout the zone indicated at III and is followed by cooling in zone IV in which the charcoal travels in contra-current to the upward flow of cold inert gases introduced at e.
- the carbonization reaction extends beyond the inlet of the hot gases, in the direction of travel of the wood. Owing to the fact that cold gases are continuously introduced at the bottom of the retort, the volatile distillation products which are evolved in the carbonizing zone III, i. e. beyond the point ,d of introduction of the hot inert gases, remain ⁇ only for a short time in contact with charcoal at high temperature, and I have ascertained the surprising fact that said volatile products are not decomposed to an appreciable extent, even though they pass through material in the course of carbonizing at high temperature.
- the gaseous distillation products are withdrawn with the inert gases at f.
- valuable products such as methanol, acetic acid etc.
- a certain percentage of said products remain in the circulating gases. It is an advantage of my process that the greater part of the products remaining in the circulating gases are not decomposed since, when they are again passed through the retort, only the gases introduced at e pass through carbonized material liable to favor their decomposition.
- the temperature and the quantity of inert gases to be introduced depend on the amount of wood charged, the size of the pieces of wood and the degree of moisture of the wood. As stated, the rate of input of the wood at b and the rate of flow of both the hot gases introduced 'at d and the cool gases introduced at e are such that a well defined carbonization zone is created in the vicinity of point d, between two zones of gradually decreasing temperatures.
- the temperature of the hot inert gases at d is about 300 to 600 C., while the temperature of the cold gases at e is under 40 C.
- the gases and vapors escaping from the retort at f should preferably be at a temperature high enough to ensure that no condensation of the distilled products will take place in the cool upper portion of the retort, Such is normally the case when the exit gases have a temperature of at least 100 C.
- the exit gases have a temperature of at least 100 C.
- I may use retorts or furnaces of any suitable construction.
- a vertical retort as shown in the accompanying drawing in which the wood travels downwardly by gravity, the hot inert gases being introduced near or beneath the middle portion of the retort and the cool gases being introduced at the bottom near the discharge 600 C. at a point about one fifth of the heightl of the retort, and 150 cubic meters of inert gases at atmospheric temperature at the bottom of the retort, near the charcoal outlet.
- the carbonizing zone in the retort forms adjacent the level where the hot gases i are introduced, At the upper end of the retort the gases laden with distillation products are drawn of! at C. whereas, at the bottom, 230 kilogs. per hour of charcoal with very high carbon content are discharged into a sealed receptacle p.
- the yields in acetic acid and methanol are approximately 15 to 30% higher than those attainable with discontinuous carbonization processes.
- inert gases I may use any gases which are not adapted to react with the distillation products, i. e. gases which are free from oxygen.
- gases which are free from oxygen.
- Advantageously use can be made of the distillation gases formed in the course of the carbonization process, in which case the gases may be circulated in a closed circuit as above described.
- I may use, as inert gases, natural gas where available, or producer gas or the like, and the gases may flow in an open circuit.
- Fresh gas being supplied through pipe q and valve v3, a regulated portion of said gas is sent to the retort through the heater n and another regulated portion through the pipe o, the operation being the same as above described.
- All the gases may be drawn off atl, the valve v1 being closed, or the valve v1 may be partly open, so that a portion of the inert gases is circulated through m and mixed with fresh gases from q.
- the heating of the inert gases introduced at d may be effected in any suitable way, as by preheating or by combustion, i. e. the heater n may be a heat exchanger, or a furnace, or a gas producer, the heating in any case being such that when entering the carbonization retort, the gases are at a temperature of from 300 to 600 C. or even more, according to the amount of volatile products it is desired to allow to remain in the charcoal.
- the separation of the distillation products from the circulating gases may be performed in the usual manner. Since, as stated before, the hot circulating gases do not, or do only partly, come into contact with the charcoal, it is possible to recirculate the hot distillation gases without having completely separated therefrom the distillation products. Thus said products will concentrate in the gases, and if 4desired they may be separated only in the branch circuit 0 leading the unheated gases to the bottom of the retort, or in the branch pipe l through which excess gas is tapped from the circuit.
- I may also introduce the heated gases at different points and at different temperatures into the retort, for instance through separate circuits.
- less highly heated gases may be introduced into zones of lower temperature, such as the drying zone, and such gases may contain relatively high amounts of volatile products.
- the height of the temperature maximum within the retort depends essentially on the rate of iiow and on the temperature of the hot gases.
- Zone 0f highest temperature may be enlarged and its temperature lowered by suitably increasing the rate of flow of the hot gases.
Description
, Patented July 14, 1942 PROCESS F CONTINUOUS CARBONIZATION 0F CELLULOSIC MATERIALS Auguste Lambotte, Brussels, Belgium Application December 5, 1939, Serial No. 307,707 In Germany July 9, 1938 2 Claims.
The present invention relates to the destructive distillation of materials such as wood, peat, lignin and other cellulosic materials which, on being carbonized, give rise to an exothermic reaction.
The invention more particularly relates to a method of continuously carrying out distillation by treating wood or other material, preferably dried, in a chamberv or retort with inert gases introduced into the retort through the cooling zone, i. e. the zone in which the carbonized material is cooled before it is discharged from the retort. Hitherto a disadvantage of this method was the slow progress of carbonization, which could not be remedied by increasing the rate of flow of the inert gases, as said gases require to be heated in the cooling zone, and any increase in their rate of flow would result in lowering their temperature and gradually stopping the reaction Slow carbonization on the other hand lowers the efficiency of the process and causes the distillation products, e. g. methanol and acetic acid, to remain too long in the carbonizing zone at a high temperature which favors their decomposition, thereby decreasing the yield in valuable distillation products. Furthermore the gases issuing at a slow rate from the cooling zone are not evenly distributed through the material, and the discharged charcoal is incompletely carbonized.
It is an object of my invention to avoid these disadvantages and to provide a process in which carbonization is accelerated, while a high yield in distillation products is obtained.
In accordance with my invention the wood or other material to be carbonized is fed through a furnace or retort heated by a current of inert gases circulating through the retort in contracurrent to the wood, said gases being heated outside the retort and introduced into the retort at an` intermediate point thereof, in immediate vicinity of the carbonizing zone. In addition, cold i. e. `unheated gases are introduced `at or near the outlet for the carbonized materialf The rates of supply of the hot gases and of the cold gases are independently controllable so that it is possible both to obtain an efficient cooling of the charcoal and suitably to control the carbonizing Zone.
The wood continuously charged into the retort thus can be brought by the hot gases exactly to the temperature which is necessary in order to induce the exothermic carbonization reaction, while the cold gases introduced separately absorb the heat developed by the exothermic reaction,
thereby avoiding overheating of the distillation products in contact with the material being carbonized. In this way carbonization can be carried out rapidly, as is necessary for successful continuous operation, Owing to the possibility of controlling the gas currents independently of each other, carbonization can be regulated in proportion to the input and vice versa, the extent of the carbonizing zone can be regulated as desired.
In the accompanying drawing illustrating diagrammatically, by way of example, a plant for carrying out the present invention, a isthe carbonizing furnace or retort having at the top an inlet chamber b for the pieces of wood to be carbonized and at the bottom a discharge outlet c for the charcoal. In operation hot inert gases are introduced into the retort at an intermediate point d thereof, whereas cold inert gases are introduced at e near the bottom, and the gaseous products of distillation are withdrawn from the top at f.
In one method of carrying out my improved process, the inert gases are circulated in a closed circuit. Issuing from the outlet f in admixture with the products of distillation they are led through a cooler g, a separator h and a scrubber i, whence the condensed products are co1- lected at 7'. A fan k sends the residual inert gases past a tapping pipe l for discharging excess gas, through a pipe m whence a portion of the gases passes through a heater n to the hot gas inlet d, while another portion flows through a pipe o to the cold gas inlet e. It will be understood that valve v1 then is fully open, valve v2 is partly open to regulate the outward ow of excess gas; valve v3 is closed while valves v4 and v5 are partly open to regulate the supply of gases at'd and at e respectively.
In operation, the rate of progress of the wood through the retort and the rates of flow of the hot gases fed at d and of the cold gases fed at e are so regulateduthat, when reaching point d, the downwardly travelling wood has reached the temperature at which exothermic carbonization is initiated. Thus, the wood passes gradually and successively through a drying zone I and a torrefaction zone II while travelling in contracurrent to the upward flow of hot gases introduced at d and of the cooler gases introduced at e and heated in the lower portion of the retort. Carbonization being initiated at or near the level d continues throughout the zone indicated at III and is followed by cooling in zone IV in which the charcoal travels in contra-current to the upward flow of cold inert gases introduced at e.
It has been found that, as shown, the carbonization reaction extends beyond the inlet of the hot gases, in the direction of travel of the wood. Owing to the fact that cold gases are continuously introduced at the bottom of the retort, the volatile distillation products which are evolved in the carbonizing zone III, i. e. beyond the point ,d of introduction of the hot inert gases, remain \only for a short time in contact with charcoal at high temperature, and I have ascertained the surprising fact that said volatile products are not decomposed to an appreciable extent, even though they pass through material in the course of carbonizing at high temperature.
The gaseous distillation products are withdrawn with the inert gases at f. When the valuable products, such as methanol, acetic acid etc. are condensed, a certain percentage of said products remain in the circulating gases. It is an advantage of my process that the greater part of the products remaining in the circulating gases are not decomposed since, when they are again passed through the retort, only the gases introduced at e pass through carbonized material liable to favor their decomposition.
The temperature and the quantity of inert gases to be introduced depend on the amount of wood charged, the size of the pieces of wood and the degree of moisture of the wood. As stated, the rate of input of the wood at b and the rate of flow of both the hot gases introduced 'at d and the cool gases introduced at e are such that a well defined carbonization zone is created in the vicinity of point d, between two zones of gradually decreasing temperatures.
In practice, the temperature of the hot inert gases at d is about 300 to 600 C., while the temperature of the cold gases at e is under 40 C. The gases and vapors escaping from the retort at f should preferably be at a temperature high enough to ensure that no condensation of the distilled products will take place in the cool upper portion of the retort, Such is normally the case when the exit gases have a temperature of at least 100 C. For carbonizing 1 cubic meter of wood, there is usually required a total amount of about 800 to 2000 cubic meters of inert gasesy of which 150 to 200 cubic meters are used as cold gases.
I have found that I have full control of the carbonization when the rate of travel of the wood and the rate of flow of the hot gases are so adjusted that the zone of carbonization forms beyond the inlet of the hot gasespthe said zone then being swept only by the cooling gases. Under these conditions, by merely varying the rate of flow of the cooling gases I am enabled to control the evolution of heat. The location of the exotherrnic reaction zone can easily be ascertained by temperature tests; thus if the exothermic zone were situated above the hot gas inlet, the temperature in the retort would rise above the temperature of the inert gases introduced at d.
For carrying out my improved process I may use retorts or furnaces of any suitable construction. Preferably I use a vertical retort as shown in the accompanying drawing in which the wood travels downwardly by gravity, the hot inert gases being introduced near or beneath the middle portion of the retort and the cool gases being introduced at the bottom near the discharge 600 C. at a point about one fifth of the heightl of the retort, and 150 cubic meters of inert gases at atmospheric temperature at the bottom of the retort, near the charcoal outlet. Under these conditions the carbonizing zone in the retort forms adjacent the level where the hot gases i are introduced, At the upper end of the retort the gases laden with distillation products are drawn of! at C. whereas, at the bottom, 230 kilogs. per hour of charcoal with very high carbon content are discharged into a sealed receptacle p.
The yields in acetic acid and methanol are approximately 15 to 30% higher than those attainable with discontinuous carbonization processes.
As inert gases I may use any gases which are not adapted to react with the distillation products, i. e. gases which are free from oxygen. Advantageously use can be made of the distillation gases formed in the course of the carbonization process, in which case the gases may be circulated in a closed circuit as above described.
Alternately I may use, as inert gases, natural gas where available, or producer gas or the like, and the gases may flow in an open circuit. Fresh gas being supplied through pipe q and valve v3, a regulated portion of said gas is sent to the retort through the heater n and another regulated portion through the pipe o, the operation being the same as above described. All the gases may be drawn off atl, the valve v1 being closed, or the valve v1 may be partly open, so that a portion of the inert gases is circulated through m and mixed with fresh gases from q.
Whatever be the manner of circulating the gases; the heating of the inert gases introduced at d may be effected in any suitable way, as by preheating or by combustion, i. e. the heater n may be a heat exchanger, or a furnace, or a gas producer, the heating in any case being such that when entering the carbonization retort, the gases are at a temperature of from 300 to 600 C. or even more, according to the amount of volatile products it is desired to allow to remain in the charcoal.
The separation of the distillation products from the circulating gases may be performed in the usual manner. Since, as stated before, the hot circulating gases do not, or do only partly, come into contact with the charcoal, it is possible to recirculate the hot distillation gases without having completely separated therefrom the distillation products. Thus said products will concentrate in the gases, and if 4desired they may be separated only in the branch circuit 0 leading the unheated gases to the bottom of the retort, or in the branch pipe l through which excess gas is tapped from the circuit.
I may also introduce the heated gases at different points and at different temperatures into the retort, for instance through separate circuits. In this case less highly heated gases may be introduced into zones of lower temperature, such as the drying zone, and such gases may contain relatively high amounts of volatile products.
The height of the temperature maximum within the retort depends essentially on the rate of iiow and on the temperature of the hot gases.
outlet for the charcoal. With the retort 5 meters 75 The Zone 0f highest temperature may be enlarged and its temperature lowered by suitably increasing the rate of flow of the hot gases.
I claim:
1. In a process of continuous carbonization of cellulosic materials in which heat is carefully regulated for the production of acetic acid and methanol, passing the material to be carbonized through a chamber, introducing inert gases heated to between about 300 C. and 600 C. from the outside directly into said chamber at an intermediate point thereof to cause a carbonizing zone to form in said chamber in the vicinity of said point, introducing inert gases at a temperature under about 40 C. into said chambernear the discharge end thereof, causing said hot and said cold inert gases to travel through said charnberv in contra-current to said material, controlling. the rate of travel of said material and the rates of flow of said hot inert gases and said cold inert gases to produce a carbonizing zone in said retort located beyond and having its beginning immediately beyond the point of introduction of said hot inert gases in the direction of travel of said material, withdrawing said inert gases from said chamber together with the acetic acid and methanol at a temperature of at least 100 C., and separating said acetic acid and methanol from said inert gases.
2. In a process of conlinuous carbonization of cellulosic materials in which heat is carefully regulated for the production of acetic acid and methanol, passing the material to be carbonized through a chamber. introducing inert gases heated to between about 300 C. and 600 C. from the outside directly into said chamber at an intermediate point thereof to cause a carbonizing zone to form in said chamber in the vicinity of said point, introducing inert gases at a temperature under about C. into said chamber near the discharge end thereof, causing said hot and said cold inert gases to travel through said chamber in contra-current to said material, controlling the rate of travel of said material and the rates of flow of said hot inert gases and said cold inert gases to produce a carbonizing zone in said retort located beyond and having its beginning immediately beyond the point of introduction of said hot inert gases in lthe direction of travel of said material, withdrawing said inert gases from said chamber together with the acetic acid and methanol at a temperature of at least C., separating said acetic acid and methanol from said inert gases, heating to between about 300 C.,and 600 C. a portion of the separated inert gases and leading them to said chamber as inert hot'gases, and leading another portion oi the separated inert gases at a temperature under about 40 C. to said chamber as inert cold gases.
AUGUSTE LAMBIOTTE.
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Cited By (34)
Publication number | Priority date | Publication date | Assignee | Title |
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US2687992A (en) * | 1949-06-28 | 1954-08-31 | Universal Oil Prod Co | Conversion of heavy petroleums in a fluidized coking operation |
US2738315A (en) * | 1951-10-31 | 1956-03-13 | Esso Res And Eugineering Compa | Shale distillation |
US2752292A (en) * | 1951-08-31 | 1956-06-26 | California Research Corp | Shale retorting process |
US2774726A (en) * | 1950-08-22 | 1956-12-18 | Foster Wheeler Corp | Apparatus for the recovery of oil and gaseous products from shale |
US3177128A (en) * | 1961-10-30 | 1965-04-06 | Bart V Vartanian | Apparatus for producing carbon by direct heating with recycled volatile by-products |
US3298928A (en) * | 1963-11-22 | 1967-01-17 | Weyerhaeuser Co | Pyrolysis of cellulosic material in concurrent gaseous flow |
US3523911A (en) * | 1969-02-26 | 1970-08-11 | Harald F Funk | Method of separating components of cellulosic material |
US3888742A (en) * | 1974-01-23 | 1975-06-10 | Waagner Biro American | Pollution-free coal-preheating with waste heat from dry coke-quenching |
US4329202A (en) * | 1977-03-23 | 1982-05-11 | Enerco, Inc. | Continuous heating process for producing char from cellulosic material |
US4401513A (en) * | 1980-09-26 | 1983-08-30 | Brewer John C | Apparatus for pyrolyzing shredded tires |
US4402791A (en) * | 1981-08-10 | 1983-09-06 | Brewer John C | Apparatus for pyrolyzing shredded tires |
US4419185A (en) * | 1981-07-16 | 1983-12-06 | American Carbons, Inc. | Pyrolysis system with hot gas recirculation |
US4465556A (en) * | 1981-07-16 | 1984-08-14 | American Carbons, Inc. | Pyrolysis system with hot gas recirculation |
US4553978A (en) * | 1981-08-28 | 1985-11-19 | Association Pour La Recherche Et Le Developpement Des Methodes Et Processus Industriels | Process for converting ligneous matter of vegetable origin by torrefaction, and product obtained thereby |
US4935099A (en) * | 1988-06-21 | 1990-06-19 | Metallgesellschaft Aktiengesellschaft | Process for making wood charcoal |
US5104490A (en) * | 1987-10-26 | 1992-04-14 | W.E.R.E. International Inc. Of Iowa | Apparatus for converting waste material to gaseous and char materials |
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US5584970A (en) * | 1994-03-12 | 1996-12-17 | Metallgesellschaft Aktiengesellschaft | Process of producing wood charcoal in a moving bed |
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Cited By (62)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2687992A (en) * | 1949-06-28 | 1954-08-31 | Universal Oil Prod Co | Conversion of heavy petroleums in a fluidized coking operation |
US2774726A (en) * | 1950-08-22 | 1956-12-18 | Foster Wheeler Corp | Apparatus for the recovery of oil and gaseous products from shale |
US2752292A (en) * | 1951-08-31 | 1956-06-26 | California Research Corp | Shale retorting process |
US2738315A (en) * | 1951-10-31 | 1956-03-13 | Esso Res And Eugineering Compa | Shale distillation |
US3177128A (en) * | 1961-10-30 | 1965-04-06 | Bart V Vartanian | Apparatus for producing carbon by direct heating with recycled volatile by-products |
US3298928A (en) * | 1963-11-22 | 1967-01-17 | Weyerhaeuser Co | Pyrolysis of cellulosic material in concurrent gaseous flow |
US3523911A (en) * | 1969-02-26 | 1970-08-11 | Harald F Funk | Method of separating components of cellulosic material |
US3888742A (en) * | 1974-01-23 | 1975-06-10 | Waagner Biro American | Pollution-free coal-preheating with waste heat from dry coke-quenching |
US4329202A (en) * | 1977-03-23 | 1982-05-11 | Enerco, Inc. | Continuous heating process for producing char from cellulosic material |
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