US2281273A - Photographic subtractive multicolor picture - Google Patents
Photographic subtractive multicolor picture Download PDFInfo
- Publication number
- US2281273A US2281273A US250162A US25016239A US2281273A US 2281273 A US2281273 A US 2281273A US 250162 A US250162 A US 250162A US 25016239 A US25016239 A US 25016239A US 2281273 A US2281273 A US 2281273A
- Authority
- US
- United States
- Prior art keywords
- blue
- layer
- image
- bath
- color
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000010410 layer Substances 0.000 description 37
- 229910052709 silver Inorganic materials 0.000 description 25
- 239000004332 silver Substances 0.000 description 25
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 18
- 238000000034 method Methods 0.000 description 18
- 238000004061 bleaching Methods 0.000 description 17
- 239000000975 dye Substances 0.000 description 17
- 239000000463 material Substances 0.000 description 17
- 230000035807 sensation Effects 0.000 description 14
- 239000000839 emulsion Substances 0.000 description 8
- -1 silver halide Chemical class 0.000 description 7
- 238000001035 drying Methods 0.000 description 4
- DCYOBGZUOMKFPA-UHFFFAOYSA-N iron(2+);iron(3+);octadecacyanide Chemical compound [Fe+2].[Fe+2].[Fe+2].[Fe+3].[Fe+3].[Fe+3].[Fe+3].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-] DCYOBGZUOMKFPA-UHFFFAOYSA-N 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 229960003351 prussian blue Drugs 0.000 description 4
- 239000013225 prussian blue Substances 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- 239000002253 acid Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000007800 oxidant agent Substances 0.000 description 3
- 230000001590 oxidative effect Effects 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- SOCTUWSJJQCPFX-UHFFFAOYSA-N dichromate(2-) Chemical compound [O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O SOCTUWSJJQCPFX-UHFFFAOYSA-N 0.000 description 2
- UETZVSHORCDDTH-UHFFFAOYSA-N iron(2+);hexacyanide Chemical compound [Fe+2].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-] UETZVSHORCDDTH-UHFFFAOYSA-N 0.000 description 2
- 238000012737 microarray-based gene expression Methods 0.000 description 2
- 238000012243 multiplex automated genomic engineering Methods 0.000 description 2
- 206010010071 Coma Diseases 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 description 1
- 238000005562 fading Methods 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- KMUONIBRACKNSN-UHFFFAOYSA-N potassium dichromate Chemical compound [K+].[K+].[O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O KMUONIBRACKNSN-UHFFFAOYSA-N 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
- 230000004304 visual acuity Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C7/00—Multicolour photographic processes or agents therefor; Regeneration of such processing agents; Photosensitive materials for multicolour processes
- G03C7/28—Silver dye bleach processes; Materials therefor; Preparing or processing such materials
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C8/00—Diffusion transfer processes or agents therefor; Photosensitive materials for such processes
- G03C8/02—Photosensitive materials characterised by the image-forming section
- G03C8/04—Photosensitive materials characterised by the image-forming section the substances transferred by diffusion consisting of inorganic or organo-metallic compounds derived from photosensitive noble metals
Definitions
- a material which on one side comprises two layers having purple and yellow dyestuffs which are bleached proportionally.
- This arrangement of layers has especial advantage when a lenticular screen bipack is used as exposure material for a three-color exposure.
- the front film in this case is a lenticular screen film and comprises the blue and green sensations, whereas the back fllm becomes the red sensation.
- the front film in order to obtain a better resolving power, is developed to a positive by the reversal process.
- the back film on the other hand is preferably developed to a negative, for in the reversal development it is more difficult to avoid variations of density and these, particularly if they occur in the blue-green component image, produce unpleasant variations of color in the copy.
- the above mentioned multi-layer copying material is particularly well suited for such an exposure material, for it is necessary to have positives for the silver bleaching out dyestufi' layers and a negative for the layer which is to be toned with Prussian blue as the master images.
- Yet another object of the invention is the provision of a treatment with a bichromate-sulfuric acid bath.
- a bichromate-sulfuric acid bath By means of this bath the original color densityof the ferrocyanideblue image is restored.
- the gradually increasing darkening of the blue image referred to above does not occur and copies capable of reproduction are obtained.
- the invention involvesa considerable simplification of the whole working in that simultaneously with this use of the bichromate-sulfuric acid bath the silver remaining from the silver bleaching out dyestuffotherwise would be effected by a milder oxidizing agent, for instance with a Farmer's reducer or copper chloride followed by fixing.
- a milder oxidizing agent for instance with a Farmer's reducer or copper chloride followed by fixing.
- bichromate-sulfurlc acid for'removal of the silver, since the most commonlyused blue-green dyestuifs are wholly or partially destroyed.
- ithas been found most unexpectedly that the usual purple and yellow dyestuffs are stable to the bichromate-sulfuric acid bath.
- the film is then developed and fixed, toned in blue on the side carrying the red sensation byfloating in one of the known blue toning baths, fixed and subsequently bleached by a usual silver bleaching out dye bath.
- the film is then run through a bath having the following composition:
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Silver Salt Photography Or Processing Solution Therefor (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEI0060210 | 1938-01-11 |
Publications (1)
Publication Number | Publication Date |
---|---|
US2281273A true US2281273A (en) | 1942-04-28 |
Family
ID=7195189
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US250162A Expired - Lifetime US2281273A (en) | 1938-01-11 | 1939-01-10 | Photographic subtractive multicolor picture |
Country Status (4)
Country | Link |
---|---|
US (1) | US2281273A (enrdf_load_stackoverflow) |
BE (1) | BE432075A (enrdf_load_stackoverflow) |
FR (1) | FR848675A (enrdf_load_stackoverflow) |
GB (1) | GB510523A (enrdf_load_stackoverflow) |
-
0
- BE BE432075D patent/BE432075A/xx unknown
-
1938
- 1938-01-31 GB GB2984/38A patent/GB510523A/en not_active Expired
-
1939
- 1939-01-10 US US250162A patent/US2281273A/en not_active Expired - Lifetime
- 1939-01-10 FR FR848675D patent/FR848675A/fr not_active Expired
Also Published As
Publication number | Publication date |
---|---|
GB510523A (en) | 1939-07-31 |
FR848675A (fr) | 1939-11-03 |
BE432075A (enrdf_load_stackoverflow) |
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