US2278321A - Method of making cast metal ingots - Google Patents
Method of making cast metal ingots Download PDFInfo
- Publication number
- US2278321A US2278321A US154311A US15431137A US2278321A US 2278321 A US2278321 A US 2278321A US 154311 A US154311 A US 154311A US 15431137 A US15431137 A US 15431137A US 2278321 A US2278321 A US 2278321A
- Authority
- US
- United States
- Prior art keywords
- flux
- metal
- cast metal
- electrode
- metal ingots
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229910052751 metal Inorganic materials 0.000 title description 22
- 239000002184 metal Substances 0.000 title description 22
- 238000004519 manufacturing process Methods 0.000 title 1
- 230000004907 flux Effects 0.000 description 19
- 238000000034 method Methods 0.000 description 7
- 230000008021 deposition Effects 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 150000004760 silicates Chemical class 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 238000005266 casting Methods 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 238000004581 coalescence Methods 0.000 description 1
- 229910052681 coesite Inorganic materials 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229910052906 cristobalite Inorganic materials 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 239000010436 fluorite Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 239000000615 nonconductor Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 229910052682 stishovite Inorganic materials 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B9/00—General processes of refining or remelting of metals; Apparatus for electroslag or arc remelting of metals
- C22B9/16—Remelting metals
- C22B9/18—Electroslag remelting
Definitions
- the invention relates to cast metals and has for its principal object the provision of sound cast metal bodies substantially free from shrinkage cavities and pipes.
- Molten metal is ordinarily poured or castinto a mold where it cools and solidifies as a cast ingot.
- the metal shrinks, forming cavities and pipes in the upper part,of the ingot, and certain of the ingredients of the metal tend to segregate and become concentrated in the neighborhood of the cavities. segregated materials constitutes a defect, and the defective portion-which in some instances amounts to as much as one-third of the lengthof the ingot-must be cut off and discarded if the best grade of metal is desired.
- the method of the invention comprises essentially the electrical heating and deposition of metal within a cavity having a conductive bottom, the deposition being efiected under a relatively deep layer of flux.
- a mold cavity is formed from an electrically conductive bottom member B and side walls W, the latter being conductive or nonconductive, as desired.
- a layer of unbonded comminuted flux F is placed on the bottom B of the cavity, and the electrode E is inserted in the flux, the electrode being supported in any convenient manner, as by a holder H. Electric current is passed between the electrode and the conductive bottom. as shown, metal is deposited from the electrode ontotlie bottom, and a casting of deposited metal is thereby built up progressively, a pool or blanket of fused flux being maintained'on the molten deposited metal.
- a wide variety of voltages and current densities may be used, and the best conditions of voltage, current, and electrode diameter will depend largely on the required composition, amount, and temperature of the metal to be added. In general, much heavier currents should be used than are customary in, for instance, ordinary open arc welding operations. For example, in a typical instance suitable conditions are attained by the use of thirty to fifty volts and a current of IOOO-amperes through an elec- The presence of pipes, cavities, and' trode having a diameter of one-quarter inch, or a current of 2000 amperes through a threeeighths inch diameter electrode. nating or direct current may be used.
- the composition of the flux F is important, because, although a large number of materials can be used for the purpose; all suitable fluxes must be substantially free from substances which would evolve gases during the operation. Thus, decomposable carbonates, oxides which will react with constituents of the electrode, ingot, or flux to evolve gases, water, and similar substances, should be absent. is an excellent way to drive off or stably fix undesirable constituents.
- the prefused flux may be comminuted for convenience in use.
- the melting point of the flux is preferably slightlylower than that of the metal ingot.
- flux should also be a nonconductor when cold I and a high resistance conductor when molten.
- silicates of the alkaline earth metals are entirely suitable for use as the flux.
- Other materials may be added, for instance silicates of the alkaline metals and of iron and'manganese, as well as alumina and fluorspar.
- An example of a suitable flux is one containing, by proximate analysis, about 30% 0:10, 9% MgO, 56% SiO2, and 5% A1203.
- a blanket or layer of unfused flux F is maintained above the molten flux on the molten metal, of a depth suiiicient to smother, 'submerge, or suppress the open are which would otherwise be observed between the electrode E and the ingot.
- coalescence of metal proceed with little or no external evidence of heating, despite the heavy currents used. Because the heating region is hidden under the flux blanket, it is impossible to observe whether or not a special type of arc is formed, but it is probable that there is no are, as the term arc is usually interpreted.
- Method of producing a shaped, homogeneous, sound, and clean metal body which comprises placing a layer of unbonded, comminuted, substantially nongassing fiux consisting chiefly of silicates on the bottom of a mold having a conductive bottom; inserting an end of a fusible bare metal electrode deep into said flux layer but out of contact with said conductive bottom; passing between said electrode and said bottom sufllcient electric current to meltprogressively suc- Either alter- Prefusion of the flux peres per one-quarter inch of electrode diam eter, that an open arc would be formed in the absence of the said blanket of unfused comminuted flux, and the last-mentioned blanket 5 being effective to completely smother such open BIO.
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Manufacture And Refinement Of Metals (AREA)
Description
March 31, 1942. J KEIR 2,278,321
METHOD MAKING CAST METAL INGOTS Filed July 1'7,v 19:57
INVENTOR 2%.. Maw
Patented Mar. 31, 1942 METHOD or MAKING CAST METAL moors James M. Keir, New York, N. Y., assignor'to The Linde Air Products Company, a corporation of Ohio Application July 17, 1937, Serial No. 154,311 1 Claim. (01124409) The invention relates to cast metals and has for its principal object the provision of sound cast metal bodies substantially free from shrinkage cavities and pipes.
Molten metal is ordinarily poured or castinto a mold where it cools and solidifies as a cast ingot. In the course of cooling and solidifying, the metal shrinks, forming cavities and pipes in the upper part,of the ingot, and certain of the ingredients of the metal tend to segregate and become concentrated in the neighborhood of the cavities. segregated materials constitutes a defect, and the defective portion-which in some instances amounts to as much as one-third of the lengthof the ingot-must be cut off and discarded if the best grade of metal is desired.
According to the present invention, the abovedescribed defects of cast metal ingots are substantially eliminated. -In general, the method of the invention comprises essentially the electrical heating and deposition of metal within a cavity having a conductive bottom, the deposition being efiected under a relatively deep layer of flux.
The accompanying drawing illustrates the method of the invention.
The procedure to be described with reference to the single'figure of the drawing is particularly adapted for making relatively small castings, although it is not limited thereto. In this procedure. a mold cavity is formed from an electrically conductive bottom member B and side walls W, the latter being conductive or nonconductive, as desired. A layer of unbonded comminuted flux F is placed on the bottom B of the cavity, and the electrode E is inserted in the flux, the electrode being supported in any convenient manner, as by a holder H. Electric current is passed between the electrode and the conductive bottom. as shown, metal is deposited from the electrode ontotlie bottom, and a casting of deposited metal is thereby built up progressively, a pool or blanket of fused flux being maintained'on the molten deposited metal.
A wide variety of voltages and current densities may be used, and the best conditions of voltage, current, and electrode diameter will depend largely on the required composition, amount, and temperature of the metal to be added. In general, much heavier currents should be used than are customary in, for instance, ordinary open arc welding operations. For example, in a typical instance suitable conditions are attained by the use of thirty to fifty volts and a current of IOOO-amperes through an elec- The presence of pipes, cavities, and' trode having a diameter of one-quarter inch, or a current of 2000 amperes through a threeeighths inch diameter electrode. nating or direct current may be used.
The composition of the flux F is important, because, although a large number of materials can be used for the purpose; all suitable fluxes must be substantially free from substances which would evolve gases during the operation. Thus, decomposable carbonates, oxides which will react with constituents of the electrode, ingot, or flux to evolve gases, water, and similar substances, should be absent. is an excellent way to drive off or stably fix undesirable constituents. The prefused flux may be comminuted for convenience in use.
The melting point of the flux is preferably slightlylower than that of the metal ingot. The
flux should also be a nonconductor when cold I and a high resistance conductor when molten.
silicates of the alkaline earth metals are entirely suitable for use as the flux. Other materials may be added, for instance silicates of the alkaline metals and of iron and'manganese, as well as alumina and fluorspar. An example of a suitable flux is one containing, by proximate analysis, about 30% 0:10, 9% MgO, 56% SiO2, and 5% A1203.
A blanket or layer of unfused flux F is maintained above the molten flux on the molten metal, of a depth suiiicient to smother, 'submerge, or suppress the open are which would otherwise be observed between the electrode E and the ingot. The'melting, deposition, and
" coalescence of metal proceed with little or no external evidence of heating, despite the heavy currents used. Because the heating region is hidden under the flux blanket, it is impossible to observe whether or not a special type of arc is formed, but it is probable that there is no are, as the term arc is usually interpreted.
I have observed that metal deposited under a layer of flux in the manner described above is remarkably homogeneous, clean, and sound.
I claim:
Method of producing a shaped, homogeneous, sound, and clean metal body which comprises placing a layer of unbonded, comminuted, substantially nongassing fiux consisting chiefly of silicates on the bottom of a mold having a conductive bottom; inserting an end of a fusible bare metal electrode deep into said flux layer but out of contact with said conductive bottom; passing between said electrode and said bottom sufllcient electric current to meltprogressively suc- Either alter- Prefusion of the flux peres per one-quarter inch of electrode diam eter, that an open arc would be formed in the absence of the said blanket of unfused comminuted flux, and the last-mentioned blanket 5 being effective to completely smother such open BIO.
JAIVIES M. KEIR.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US154311A US2278321A (en) | 1937-07-17 | 1937-07-17 | Method of making cast metal ingots |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US154311A US2278321A (en) | 1937-07-17 | 1937-07-17 | Method of making cast metal ingots |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US2278321A true US2278321A (en) | 1942-03-31 |
Family
ID=22550839
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US154311A Expired - Lifetime US2278321A (en) | 1937-07-17 | 1937-07-17 | Method of making cast metal ingots |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US2278321A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2897555A (en) * | 1956-12-22 | 1959-08-04 | Nishikiori Seiji | Steel ingot making composition, method and apparatus |
| US3835914A (en) * | 1972-03-01 | 1974-09-17 | Mitsubishi Heavy Ind Ltd | Process for producing metallic articles by electroslag remelting |
| US4015069A (en) * | 1974-08-16 | 1977-03-29 | Owen Robert G | Apparatus for extracting metals from ore |
-
1937
- 1937-07-17 US US154311A patent/US2278321A/en not_active Expired - Lifetime
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2897555A (en) * | 1956-12-22 | 1959-08-04 | Nishikiori Seiji | Steel ingot making composition, method and apparatus |
| US3835914A (en) * | 1972-03-01 | 1974-09-17 | Mitsubishi Heavy Ind Ltd | Process for producing metallic articles by electroslag remelting |
| US4015069A (en) * | 1974-08-16 | 1977-03-29 | Owen Robert G | Apparatus for extracting metals from ore |
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