US2270400A - Fuel - Google Patents

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Publication number
US2270400A
US2270400A US306813A US30681339A US2270400A US 2270400 A US2270400 A US 2270400A US 306813 A US306813 A US 306813A US 30681339 A US30681339 A US 30681339A US 2270400 A US2270400 A US 2270400A
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US
United States
Prior art keywords
fuel
ignition
tetranitromethane
engine
combustion
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
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US306813A
Inventor
Joseph A Wyler
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Trojan Powder Co
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Trojan Powder Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Trojan Powder Co filed Critical Trojan Powder Co
Priority to US306813A priority Critical patent/US2270400A/en
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Publication of US2270400A publication Critical patent/US2270400A/en
Anticipated expiration legal-status Critical
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Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/22Organic compounds containing nitrogen
    • C10L1/23Organic compounds containing nitrogen containing at least one nitrogen-to-oxygen bond, e.g. nitro-compounds, nitrates, nitrites
    • C10L1/231Organic compounds containing nitrogen containing at least one nitrogen-to-oxygen bond, e.g. nitro-compounds, nitrates, nitrites nitro compounds; nitrates; nitrites

Definitions

  • Tetranitromethane dissolves in all proportions in these materials, has a boiling point of about 127 C. and a very favorable vapor tension. It is insoluble in water and, when dry, is non-corrosive to metals.
  • butyl nitrate for use in improv-.
  • I claim: 1. The method of accelerating the ignition of liquid fuels in an internal combustion engine of the typewherein ignition of the fuel is spontaneously effected by injection into the compressed air in the engine cylinder which comprises admixing with the fuel prior to ignition a minor proportion of tetranitromethane.

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Output Control And Ontrol Of Special Type Engine (AREA)
  • Combustion Methods Of Internal-Combustion Engines (AREA)

Description

Patented Jan. 20, 1942 'UNITED STATES PATENT OFFICE".
FUEL
Joseph A. Wyler, Allentown, Pa., assignor to Trojan Powder Company, Allentown, Pa.
No Drawing.
2 Claims.
ject is to improve the combustion characteris-"t tics of fuels generally used in' automobile and aeroplane engines.
Other and further objects will become apparent upon a perusal of this specification.
I have discovered that the addition or small proportions of tetranitromethane (C(NOzh) to oils used in Diesel engines produces a fuel of improved characteristics. In general I may use as much as by weight, of tetranitromethane in the final mixture, although I prefer about 0.5- 1.5%. In a test, using an oil which was already of an especially high quality (octane number of 68), in an engine which was also of exceptionally high quality (in which the combustion-accelerating reagent would have less chance of showing improvement than it would have in the average compression-ignition engine) compared to the usual compression-ignition engines, it was found that the addition of 4% of tetra'nitromethane produced a fuel which gave a higher maximum cylinder pressure (without knock) for the same advance angle, an improved exhaust appearance, a general improvement inthe combustion of the fuel, a decrease in the ignition la by 1 crankshaft degree in at 2,000 R. P. M. and permitted four degrees further retardation of injection before misfiring occurred. With an inferior fuel-oil to start with these improvements would be more marked, or a lesser amount of tetranitromethane could be used for obtaining the same relative improvement.
Application November 30, 1939, Serial No. 306,813
(Cl. 44-9) I The solubility and volatility of tetranitro- 'methane are exceptionally favorable for its usev not only in .the heavier paraflinic oils, but also in the lighter petroleum distillates as kerosene 5 and gasoline. Tetranitromethane dissolves in all proportions in these materials, has a boiling point of about 127 C. and a very favorable vapor tension. It is insoluble in water and, when dry, is non-corrosive to metals.
10 Applicant is aware of the disclosure of such agents as methyl nitrate, (CHaNOs) ethyl nitrate,
butyl nitrate, and the like, for use in improv-.
ing the ignition characteristics of oils and wishes to emphasize that his agent, tetranitromethane,
is a material of an entirely different chemical and molecular constitution and is not in itself an explosive, as are methyl and ethyl nitrates.
Although my improved fuel is intended mainly i for Diesel engine use. I may use a mixture of gasoline and tetranitromethanes, say about 95 parts (by weight) of gasoline to as much as 5 parts (by weight) of tetranitromethane in autoi motive engines in order to obtain improved combustion characteristics. B I do not limit myself to the above description except as indicated in the appended claims.
I claim: 1. The method of accelerating the ignition of liquid fuels in an internal combustion engine of the typewherein ignition of the fuel is spontaneously effected by injection into the compressed air in the engine cylinder which comprises admixing with the fuel prior to ignition a minor proportion of tetranitromethane.
2. The method of accelerating the ignition or liquid fuels in an internal combustion engine of the type wherein ignition of the fuel is spontaneously effected by injection into the compressed air in the engine cylinder which comprises admixmg with the fuel prior to ignition about 0.5% of tetran'itromethane.
w JOSEPH A. WYLER,
US306813A 1939-11-30 1939-11-30 Fuel Expired - Lifetime US2270400A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US306813A US2270400A (en) 1939-11-30 1939-11-30 Fuel

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US306813A US2270400A (en) 1939-11-30 1939-11-30 Fuel

Publications (1)

Publication Number Publication Date
US2270400A true US2270400A (en) 1942-01-20

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Family Applications (1)

Application Number Title Priority Date Filing Date
US306813A Expired - Lifetime US2270400A (en) 1939-11-30 1939-11-30 Fuel

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