US2249888A - Moldable plastic composition - Google Patents

Moldable plastic composition Download PDF

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Publication number
US2249888A
US2249888A US181029A US18102937A US2249888A US 2249888 A US2249888 A US 2249888A US 181029 A US181029 A US 181029A US 18102937 A US18102937 A US 18102937A US 2249888 A US2249888 A US 2249888A
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United States
Prior art keywords
web
fibers
filler
plastic composition
binder
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Expired - Lifetime
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US181029A
Inventor
Milo C Dodge
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Columbian Rope Co
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Columbian Rope Co
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Publication date
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Priority to US181029A priority Critical patent/US2249888A/en
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Publication of US2249888A publication Critical patent/US2249888A/en
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/24Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
    • C08J5/245Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using natural fibres
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2361/00Characterised by the use of condensation polymers of aldehydes or ketones; Derivatives of such polymers
    • C08J2361/04Condensation polymers of aldehydes or ketones with phenols only
    • C08J2361/06Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S220/00Receptacles
    • Y10S220/09Receptacles insulating materials
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/249921Web or sheet containing structurally defined element or component
    • Y10T428/249924Noninterengaged fiber-containing paper-free web or sheet which is not of specified porosity
    • Y10T428/24994Fiber embedded in or on the surface of a polymeric matrix
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/60Nonwoven fabric [i.e., nonwoven strand or fiber material]
    • Y10T442/682Needled nonwoven fabric

Definitions

  • one object of the present invention is to provide a much less expensive filler material which can be used with the same facility as said woven materials and which will not appreciably affect the characteristics or properties required of a high quality molded plastic body.
  • a still further object is to provide a filler material in the form of a more or less compacted body which will facilitate handling thereof both in the impregnating thereof with the binder and in the loading thereof in the mold.
  • the compactness of the present filler also .permits the die-clicking therefrom of portion shaped to con-
  • Another object is to provide a filler which, while rather compact, is at the same time readily impregnated with the binder.
  • the filler material is composed of a mass of stapled fibers, preferably vegetable fibers, which have been reduced to web-like form in a carding machine and then subjected'to a needling or gigging action wherein a plurality of barbed needles are projected and retracted through the web to pull small groups or tufts of fibers through the web.
  • These tufts or groups of fibers extending through the web serve, primarily, to interlock the fibrous mass and render the mass more compact but the needles leave minute voids in the web which, of course, aid in permitting the binder solution gaining access to the interior of the mass.
  • Fig. 2 is a sectional view through the web of filler material
  • Fig. 3 is a perspective view, partly in section.
  • the fibers which are preferably of vegetable origin are all cut into desired lengths, if necessary, after which they are passed through a carding machine of usual construction, indicated at A in Fig. l by which they are formed into a continuous web B.
  • This web is then passed through a needle felting machine 0 which, as is well understood, comprises a plurality of reciprocatory needles having barbs formed thereon whereby tufts or groups of fibers D will be pushed or pulled through the web B when said needles are projected and retracted through the web.
  • the needles pass entirely through the web.
  • the fibers are treated or impregnated with a binder, preferably a phenol resin binder of the thermo-setting type.
  • a solution of the phenol-formaldehyde resin binder of the heat hardenable type is used.
  • the needling of the fiber web B causes the fibers to be interlaced or interlocked to an extent that the web retains its form under normal handling conditions and for this reason blanks may be cut from the web with clicker dies if desired, said blanks corresponding in shape to the cross-section of the mold in which the molding operation is performed.
  • the order in which the steps of treating the web with binder solution and of cutting blanks from the web, when this step is used, is immaterial.
  • the blanks are formed with the clicker dies E before treating the web with binder, one of said blanks F being shown immersed in the bath G of the binder.
  • One or more of the blanks F, or unshaped sections of the web when blanks are not formed can be placed in a mold and the molding operation carried out in the conventional manner as to temperatures and pressures, all as is well known in the plastic molding art.
  • the needling or gigging rather securely interlocks the fibers so as to aid in retaining the form of the web B.
  • the needled web of fibers possesses other important advantages as a filler material.
  • the openings formed in the web by the needles never close completely, thus forming minute voids extending through the web whereby permeation. or impregnation of the web with the possesses considerable strength, especially in resisting sudden shocks and impacts.
  • the promiscuous distribution of the fibers in the web has been found to impart more strength to projections on molded articles, for instance, the teeth on gear wheels.
  • this distribution or disposition of the fibers in the web results in a filler which will flow" more readily than is true or other fabricated fillers.
  • a moldable plastic composition composed essentially of a phenol formaldehyde resin binder of the heat hardenable type and a vegetable fiber filler of web-like form with small groups or tufts of the fibers extending through the web and interlocking the surrounding fibers in the web.
  • a moldable plastic composition composed essentially of a phenol formaldehyde resin binder Y binder solution is greatly facilitated. Also, the
  • a moldable plastic composition composed essentially of a phenol formaldehyde resin binder of the heat hardenable type and a vegetable fiber filler compacted into a web-like body with a ma- Jority of the fibers promiscuously disposed throughout the web and with groups or tufts of fibers extending through the web to maintain the compactness of the web, there being minute voids formed in said groups or tufts of fibers transversely of said web.
  • a moldable plastic composition composed essentially of a 'thermo-setting binder and a filler of web-like form composed of comparatively long vegetable fibers with small groups or tufts of the fibers extending through the web and interlocking the surrounding fibers in the web.
  • a moldable plastic composition composed essentially of a thermo-setting binder and a filler composed of vegetable fibers partially compacted into web-like form whereby penetration of the web by the binder is facilitated, said web having small groups or tufts of fibers extending therethrough and interlocking the surrounding fibers in the web.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Nonwoven Fabrics (AREA)

Description

July 22, 1941. a M. c. DODGE 2,249,888
MOLDABLE PLASTIC COMPOSITION Filed Dec. 21, 1957 form to the mold.
Patented July 22, 1941 MOLDABLE PLASTIC COMPOSITION Milo 0. Dodge, Auburn, N. Y., assignor to Columbian Rope Company, Auburn, N. Y., a corporation of New York Application December 21, 1937, Serial No. 181,029 Claims. (Cl. 18-475) This invention relates to improvements in molded plastic bodies and, particularly, to the filler material used in producing such bodies.
Various woven materials have heretofore been used as a filler for molded plastics and one object of the present invention is to provide a much less expensive filler material which can be used with the same facility as said woven materials and which will not appreciably affect the characteristics or properties required of a high quality molded plastic body.
It has also heretofore been proposed to use a filler of loose fibers which are promiscuously deposited in the mold in forming the molded body and, to increase the resistance of the molded body to breaking strains, it has been further proposed to use substantially parallel fibers in sliverformation as a filler. These forms of filler, however, are rather bulky in the mold and a further object of the invention is to provide a filler material which will be less bulky.
A still further object is to provide a filler material in the form of a more or less compacted body which will facilitate handling thereof both in the impregnating thereof with the binder and in the loading thereof in the mold. The compactness of the present filler also .permits the die-clicking therefrom of portion shaped to con- Another object is to provide a filler which, while rather compact, is at the same time readily impregnated with the binder. More specifically, the filler material is composed of a mass of stapled fibers, preferably vegetable fibers, which have been reduced to web-like form in a carding machine and then subjected'to a needling or gigging action wherein a plurality of barbed needles are projected and retracted through the web to pull small groups or tufts of fibers through the web. These tufts or groups of fibers extending through the web serve, primarily, to interlock the fibrous mass and render the mass more compact but the needles leave minute voids in the web which, of course, aid in permitting the binder solution gaining access to the interior of the mass.
With these and other objects in view, the invention consists in certain details of construction and combinations and arrangements of parts, all as will hereinafter be more fully described and the novel features thereof particularly pointed out in the appended claims.
In the accompanying drawing- Figure 11s a side elevation illustrating more or less diagrammatically the apparatus for producing the filler material;
Fig. 2 is a sectional view through the web of filler material; and
Fig. 3 is a perspective view, partly in section.
of a disc cut by choker dies from said web.
The fibers which are preferably of vegetable origin are all cut into desired lengths, if necessary, after which they are passed through a carding machine of usual construction, indicated at A in Fig. l by which they are formed into a continuous web B. This web is then passed through a needle felting machine 0 which, as is well understood, comprises a plurality of reciprocatory needles having barbs formed thereon whereby tufts or groups of fibers D will be pushed or pulled through the web B when said needles are projected and retracted through the web. In usual practice the needles pass entirely through the web. Subsequent to this so-called "needling or gigging operation, the fibers are treated or impregnated with a binder, preferably a phenol resin binder of the thermo-setting type. Preferably, a solution of the phenol-formaldehyde resin binder of the heat hardenable type is used.
The needling of the fiber web B causes the fibers to be interlaced or interlocked to an extent that the web retains its form under normal handling conditions and for this reason blanks may be cut from the web with clicker dies if desired, said blanks corresponding in shape to the cross-section of the mold in which the molding operation is performed. The order in which the steps of treating the web with binder solution and of cutting blanks from the web, when this step is used, is immaterial. However, in the present illustration the blanks are formed with the clicker dies E before treating the web with binder, one of said blanks F being shown immersed in the bath G of the binder. One or more of the blanks F, or unshaped sections of the web when blanks are not formed, can be placed in a mold and the molding operation carried out in the conventional manner as to temperatures and pressures, all as is well known in the plastic molding art.
As previously mentioned, the needling or gigging rather securely interlocks the fibers so as to aid in retaining the form of the web B. However, the needled web of fibers possesses other important advantages as a filler material. For
instance, the openings formed in the web by the needles never close completely, thus forming minute voids extending through the web whereby permeation. or impregnation of the web with the possesses considerable strength, especially in resisting sudden shocks and impacts. The promiscuous distribution of the fibers in the web has been found to impart more strength to projections on molded articles, for instance, the teeth on gear wheels. In addition, this distribution or disposition of the fibers in the web results in a filler which will flow" more readily than is true or other fabricated fillers.
' What I claim is:
1. A moldable plastic composition composed essentially of a phenol formaldehyde resin binder of the heat hardenable type and a vegetable fiber filler of web-like form with small groups or tufts of the fibers extending through the web and interlocking the surrounding fibers in the web.
2. A moldable plastic composition composed essentially of a phenol formaldehyde resin binder Y binder solution is greatly facilitated. Also, the
of the heat hardenable type and a vegetable fiber filler of web-like formation with small groups or tufts of the fiber extending through the web and interlocking the surrounding fibers in the web, there being minute voids formed in said groups or tufts of fibers transversely of said web.
3. A moldable plastic composition composed essentially of a phenol formaldehyde resin binder of the heat hardenable type and a vegetable fiber filler compacted into a web-like body with a ma- Jority of the fibers promiscuously disposed throughout the web and with groups or tufts of fibers extending through the web to maintain the compactness of the web, there being minute voids formed in said groups or tufts of fibers transversely of said web.
4. A moldable plastic composition composed essentially of a 'thermo-setting binder and a filler of web-like form composed of comparatively long vegetable fibers with small groups or tufts of the fibers extending through the web and interlocking the surrounding fibers in the web.
5. A moldable plastic composition composed essentially of a thermo-setting binder and a filler composed of vegetable fibers partially compacted into web-like form whereby penetration of the web by the binder is facilitated, said web having small groups or tufts of fibers extending therethrough and interlocking the surrounding fibers in the web. MILO C. DODGE.
US181029A 1937-12-21 1937-12-21 Moldable plastic composition Expired - Lifetime US2249888A (en)

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Cited By (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2439137A (en) * 1940-12-20 1948-04-06 Thompson S Ltd Laminated plastic article
US2553412A (en) * 1942-08-28 1951-05-15 Wood Conversion Co Molding fiber composition
US2569169A (en) * 1942-09-10 1951-09-25 Wood Conversion Co Production of hot-bonded fiber felts
US2574371A (en) * 1946-12-28 1951-11-06 Guenther C F Brandes Method of making baskets
US2761493A (en) * 1952-07-07 1956-09-04 Charles E Lenz Upholstery cushions
US2769741A (en) * 1953-01-19 1956-11-06 Malloran Corp Method of making a fibrous article
US2809145A (en) * 1955-01-18 1957-10-08 Mcdermott Francis Roland Vibration-absorbing pad and process of manufacture
US2938292A (en) * 1955-08-18 1960-05-31 Ultra Violet Products Inc Fingerprinting system
US2970365A (en) * 1958-08-04 1961-02-07 Morgenstern David Needled fabric and method
US2978785A (en) * 1956-03-05 1961-04-11 Celanese Corp Bonded batting, or non-woven fabric
US3051171A (en) * 1959-02-04 1962-08-28 Johnson & Johnson Surgical dressing
US3053253A (en) * 1959-02-04 1962-09-11 Johnson & Johnson Bandage
US3121656A (en) * 1961-07-28 1964-02-18 Contours Unltd Moldable composition
US3199167A (en) * 1961-02-09 1965-08-10 West Point Pepperell Inc Process of manufacturing nonwoven fabrics
US3240658A (en) * 1960-05-18 1966-03-15 Johns Manville Fiber reinforced plastic material and method of preparing
US3607609A (en) * 1965-11-13 1971-09-21 Svit Np Artificial leather made of collagen fibers mixed with synthetic fibers and method of making same
US4708900A (en) * 1984-04-30 1987-11-24 Henkel Kommanditgesellschaft Auf Aktien Fibrous perfume carrier for artificial flowers and a process for its manufacture
DE102014113279A1 (en) * 2014-09-15 2016-03-17 Airbus Operations Gmbh Fiber composite component with an electrically conductive fiber material for reinforcement and apparatus for producing the same

Cited By (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2439137A (en) * 1940-12-20 1948-04-06 Thompson S Ltd Laminated plastic article
US2553412A (en) * 1942-08-28 1951-05-15 Wood Conversion Co Molding fiber composition
US2569169A (en) * 1942-09-10 1951-09-25 Wood Conversion Co Production of hot-bonded fiber felts
US2574371A (en) * 1946-12-28 1951-11-06 Guenther C F Brandes Method of making baskets
US2761493A (en) * 1952-07-07 1956-09-04 Charles E Lenz Upholstery cushions
US2769741A (en) * 1953-01-19 1956-11-06 Malloran Corp Method of making a fibrous article
US2809145A (en) * 1955-01-18 1957-10-08 Mcdermott Francis Roland Vibration-absorbing pad and process of manufacture
US2938292A (en) * 1955-08-18 1960-05-31 Ultra Violet Products Inc Fingerprinting system
US2978785A (en) * 1956-03-05 1961-04-11 Celanese Corp Bonded batting, or non-woven fabric
US2970365A (en) * 1958-08-04 1961-02-07 Morgenstern David Needled fabric and method
US3051171A (en) * 1959-02-04 1962-08-28 Johnson & Johnson Surgical dressing
US3053253A (en) * 1959-02-04 1962-09-11 Johnson & Johnson Bandage
US3240658A (en) * 1960-05-18 1966-03-15 Johns Manville Fiber reinforced plastic material and method of preparing
US3199167A (en) * 1961-02-09 1965-08-10 West Point Pepperell Inc Process of manufacturing nonwoven fabrics
US3121656A (en) * 1961-07-28 1964-02-18 Contours Unltd Moldable composition
US3607609A (en) * 1965-11-13 1971-09-21 Svit Np Artificial leather made of collagen fibers mixed with synthetic fibers and method of making same
US4708900A (en) * 1984-04-30 1987-11-24 Henkel Kommanditgesellschaft Auf Aktien Fibrous perfume carrier for artificial flowers and a process for its manufacture
DE102014113279A1 (en) * 2014-09-15 2016-03-17 Airbus Operations Gmbh Fiber composite component with an electrically conductive fiber material for reinforcement and apparatus for producing the same

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